Multi-layer 2D material assemblies provide a great number of interfaces beneficial for electromagnetic wave absorption.However,avoiding agglomeration and achieving layer-by-layer ordered intercalation remain chal-leng...Multi-layer 2D material assemblies provide a great number of interfaces beneficial for electromagnetic wave absorption.However,avoiding agglomeration and achieving layer-by-layer ordered intercalation remain chal-lenging.Here,3D reduced graphene oxide(rGO)/MXene/TiO_(2)/Fe_(2)C lightweight porous microspheres with periodical intercalated structures and pronounced inter-facial effects were constructed by spray-freeze-drying and microwave irradiation based on the Maxwell–Wagner effect.Such approach reinforced interfacial effects via defects introduction,porous skeleton,multi-layer assembly and multi-compo-nent system,leading to synergistic loss mechanisms.The abundant 2D/2D/0D/0D intercalated heterojunctions in the microspheres provide a high density of polari-zation charges while generating abundant polarization sites,resulting in boosted interfacial polarization,which is verified by CST Microwave Studio simulations.By precisely tuning the 2D nanosheets intercalation in the heterostructures,both the polarization loss and impedance matching improve significantly.At a low filler loading of 5 wt%,the polarization loss rate exceeds 70%,and a minimum reflection loss(RLmin)of-67.4 dB can be achieved.Moreover,radar cross-section simulations further confirm the attenuation ability of the optimized porous microspheres.These results not only provide novel insights into understanding and enhancing interfacial effects,but also constitute an attractive platform for implementing heterointerface engineering based on customized 2D hierarchical architectures.展开更多
Integrating heterogeneous interface through nanostructure design and interfacial modification is essential to realize strengthened interfacial polarization relaxation in electromagnetic wave absorption.However,an in-d...Integrating heterogeneous interface through nanostructure design and interfacial modification is essential to realize strengthened interfacial polarization relaxation in electromagnetic wave absorption.However,an in-depth comprehension of the interfacial polarization behavior at hetero-junction/interface is highly desired but remains a great challenge.Herein,a Mott-Schottky heterojunction consisting of honeycomb-like porous N-doped carbon confined CoP nanoparticles(CoP@HNC)is designed to elevate the interfacial polarization strength.Simultaneously,corresponding electron migration and redistribution between the heterointerface of defective carbon and CoP nanoparticles are revealed.The significant difference in the work function on both sides of heterogeneous interface boosts the interfacial polarization in high frequency region.Furthermore,the relevant spectroscopic characterizations demonstrate that electron spontaneously migrates from CoP to N-doped carbon at the heterointerface,thereby contributing to the accumulation of electron on defective carbon side and the distribution of hole on CoP side.Impressively,benefitting from the synergistic effects of three-dimensional porous conductive carbon skeleton,foreign N heteroatoms,special CoP nanoparticles,and the resultant CoP/N-doped carbon Mott-Schottky heterojunction,the CoP@HNC exhibits remarkable electromagnetic wave absorption performances with minimum reflection loss up to−60.8 dB and the maximum effective absorption bandwidth of 4.96 GHz,which is superior to most of recently reported transition metal phosphides microwave absorbing composites.The present work opens a new avenue for designing heterogeneous interface to realize strengthened microwave absorption capability and also reveals the in-depth influence of interface structure on electromagnetic wave absorption.展开更多
Dispersion of ultrafine alumina suspension is examined by using particle size analyzer. The zeta potential and contact angle measurements were used to discuss the electrokinetic behavior and surface wettability of alu...Dispersion of ultrafine alumina suspension is examined by using particle size analyzer. The zeta potential and contact angle measurements were used to discuss the electrokinetic behavior and surface wettability of alumina in modifier solution, and to calculate the electrostatic interaction forces and interfacial interaction forces between alumina particles. The aggregation of ultrafine alumina occurs near its PZC. Addition of modifier increases the zeta potential of alumina and its surface hydrophilicity, resulting in increase of electrostatic and hydration repulsion. It makes the suspension of ultrafine alumina completely dispersed. The average particle size of the suspension is decreased from 1.73 μm in absence of modifier to 0.8 μm in the presence of tripolyphosphate. According to polar interfacial interaction approach, the hydration forces responsible for the stability of alumina suspension in the presence of modifier have also been obtained. The extended DLVO theory is successful to describe the dispersion behavior of ultrafine alumina in modifier solution.展开更多
Exposing waxy oils to an electric field may significantly improve their cold flowability.Our previous study has shown that interfacial polarization,i.e.,charged particle accumulation on the wax particle surface,is the...Exposing waxy oils to an electric field may significantly improve their cold flowability.Our previous study has shown that interfacial polarization,i.e.,charged particle accumulation on the wax particle surface,is the primary mechanism of the electrorheological behavior of waxy oils.However,the way that charged particles interact with wax particles under an electric field remains unknown.In this study,we found no viscosity and impedance change for two waxy crude oils after their exposure to a high-voltage electric field.However,the yield stresses were reduced obviously.We thus proposed that the collision of colloidal particles such as resins and asphaltenes with the wax particles could be an essential mechanism that the wax particle structure was weakened.To verify this hypothesis,a series of ad hoc experiments were carried out,i.e.,by performing electrorheological tests on model waxy oils containing additives removable under an electric field,including electrically-neutral colloidal particles(Fe3O4),charged colloidal particles(resins),and oil-soluble electrolyte(C22H14CoO4),respectively,and demonstrated that upon application of a high-voltage electric field,charged particles in a waxy oil may move and thus collide with wax particles,and consequently adhere to the wax particle surface.The particle collision results in damage to the wax particle network,and the electrostatic repulsion arising from the adhesion of the charged particle on the wax particle diminishes attraction between wax particles.This study clarifies the process of interfacial polarization.展开更多
With the gradually increasing protection awareness about electromagnetic pollution,the demand for absorbing materials with renewability and environmental friendliness has attracted widespread attention.In this work,co...With the gradually increasing protection awareness about electromagnetic pollution,the demand for absorbing materials with renewability and environmental friendliness has attracted widespread attention.In this work,composites consisting of straw-derived biochar combined with NiCo alloy were successfully fabricated through high-temperature carbonization and subsequent hydrothermal reaction.The electromagnetic parameters of the porous biocarbon/NiCo composites can be effectively modified by altering their NiCo content,and their improved absorbing performance can be attributed to the synergy effect of magnetic-dielectric characteristics.An exceptional reflection loss of-27.0 dB at 2.2 mm thickness and an effective absorption bandwidth of 4.4 GHz(11.7-16.1 GHz)were achieved.These results revealed that the porous biocarbon/NiCo composites could be used as a new generation absorbing material because of their low density,light weight,excellent conductivity,and strong absorption.展开更多
Lightweight and efficient carbon-based microwave absorbents are significant in addressing the increasing severity of electromagnetic pollution.In this study,hierarchical NiO/Ni nanosheets with a tuneable phase and mor...Lightweight and efficient carbon-based microwave absorbents are significant in addressing the increasing severity of electromagnetic pollution.In this study,hierarchical NiO/Ni nanosheets with a tuneable phase and morphology supported on a carbon fiber substrate(CF@NiO/Ni)were fabricated using a hydrothermal approach and post-annealing treatment.As the annealing temperature increases,more metallic Ni is formed,and an apparent porosity appears on the sheet surface.Benefiting from the advantages of a three-dimensional(3D)conducting network,hierarchical porous structure,reinforced dipole/interface polarization,multiple scattering,and good impedance matching,the CF@NiO/Ni-500 composite exhibits an excellent microwave absorption performance even at a filling rate of only 3wt%.Specifically,its minimal reflection loss is-43.92 dB,and the qualified bandwidth is up to 5.64 GHz.In addition,the low radar cross-section area of the CF@NiO/Ni composite coating confirms its strong ability to suppress electromagnetic wave scattering.We expect that this work could contribute to a deeper understanding of the phase and morphology evolution in enhancing microwave absorption.展开更多
In order to obtain the microwave absorption(MA)materials with light weight,high efficiency and tunable properties,the carbonized mesophase pitch(CMP)with the variation in carbonization temperatures and particle sizes ...In order to obtain the microwave absorption(MA)materials with light weight,high efficiency and tunable properties,the carbonized mesophase pitch(CMP)with the variation in carbonization temperatures and particle sizes were prepared and characterized.The carbonization temperature mainly controlled the graphitization degree of the CMP to affect their conductive loss.The carbon residues were generated on the CMP surface when the temperature was higher than 700℃,which contributed significantly to the polarization loss of the CMP.For scale regulation,the segregation between the particles in the paraffin ring caused by the reduction particles of CMP carbonization at 750℃(750 CMP)resulted in a significant reduction in conductive losses while improving their impedance matching.The 750 CMP over 300 mesh sieved had the strongest MA properties of-53 d B at 3.4 GHz within 5.5 mm.Moreover,the prepared CMPs were multi-layer compounded and optimized by CST microwave studio.The synergistic effect derived from the improved impedance matching and the enhanced interfacial polarization resulted in significant reflection loss in multi-layer CMP.Overall,these findings lead to the systematically regulation of carbon-based materials for MA,showing an attractive application prospect for the preparation of high-performance MA materials.展开更多
Crystalline Fe/MnO@C core–shell nanocapsules inlaid in porous amorphous carbon matrix(FMCA)was synthesized successfully with a novel confinement strategy.The heterogeneous Fe/MnO nanocrystals are with approximate sin...Crystalline Fe/MnO@C core–shell nanocapsules inlaid in porous amorphous carbon matrix(FMCA)was synthesized successfully with a novel confinement strategy.The heterogeneous Fe/MnO nanocrystals are with approximate single-domain size which gives rise to natural resonance in 2–18 GHz.The addition of MnO2 confines degree of graphitization catalyzed by iron and contributes to the formation of amorphous carbon.The heterogeneous materials composed of crystalline–amorphous structures disperse evenly and its density is significantly reduced on account of porous properties.Meanwhile,adjustable dielectric loss is achieved by interrupting Fe core aggregation and stacking graphene conductive network.The dielectric loss synergistically with magnetic loss endows the FMCA enhanced absorption.The optimal reflection loss(RL)is up to−45 dB,and the effective bandwidth(RL<−10 dB)is 5.0 GHz with 2.0 mm thickness.The proposed confinement strategy not only lays the foundation for designing high-performance microwave absorber,but also offers a general duty synthesis method for heterogeneous crystalline–amorphous composites with tunable composition in other fields.展开更多
Toward the increasingly serious problem of electromagnetic wave pollution,the development of absorbing material with the properties of the light,thin,wide,strong,and multiple applications scenarios is still a huge cha...Toward the increasingly serious problem of electromagnetic wave pollution,the development of absorbing material with the properties of the light,thin,wide,strong,and multiple applications scenarios is still a huge challenge.Herein,the core-shell nickel oxide/silicon carbide whiskers(NiO/SiCw)with variational NiO morphologies(tulle-,flower,and rod-like)were designed and fabricated via a facile prehydrothermal method and post-annealing process.For the NiO shell morphology,it can effectively be controlled by the proportion of Ni(NO_(3))_(2)·6H_(2)O,NH_(4)Cl,and CO(NH_(2))_(2).The structure of NiO/SiCw samples was investigated by XRD,SEM,XPS,TEM,and N2 absorption-desorption.Compared to other morphologies of NiO,the flower-like NiO/SiCw possess a porous structure and large surface area that can benefit from the multiple reflections and attenuation of the microwave.As an absorber,the composite with the flower-like NiO/SiCw filler loading of 50%manifests a superior microwave attenuation capability due to its special porous structure,good impedance matching,and large dielectric loss induced from heterojunction interfacial polarization.The minimum reflection loss of flower-like NiO/SiCw is up to-56.8 dB with a thickness of 1.9 mm,and the maximum effective absorption bandwidth(EAB)reaches 5.17 GHz.The as-prepared flower-like NiO/SiCw with strong absorption,thin thickness,and width EAB can meet the potential requirements for microwave absorption materials under oxidation environments.展开更多
Fibers reinforced composite materials offer a combination of strength and modulus that are either comparable to or better than many traditional metallic materials.The research on natural fiber based composite material...Fibers reinforced composite materials offer a combination of strength and modulus that are either comparable to or better than many traditional metallic materials.The research on natural fiber based composite materials fit well into this ecological image.This paper reports the conduction mechanism and ac conductivity,activation energy behavior of Polypropylene and banana fiber reinforced thermoplastic composites.Polypropylene[-CH_(2)-CH_(2)-CH_(2)-]n and different fiber content(wt.%)of polypropylene-banana fibers(natural fiber)composites were fabricated using a hot-press molding system.The optimum fabrication parameters were established(initial pressure,temp.etc.).These composite test samples were fabricated so the short fibers were randomly oriented in the matrix.The detail investigation of the a.c.conductivity and conduction mechanism of polymer composites would provide information about the relaxation processes,activation energy etc.which are dependent on frequency,temperature and time.The activation energy involved in the above processes can also be estimated from this study.The measurements were performed over a wide range of frequency of 60 Hz to 3 MHz and temperature range from 30℃(303°K)to 110℃(383°K).Experimental results of the ac properties of pure polypropylene and polypropylene-natural banana fiber composites were compared.It has been established that the fabricated composition changes its insulating property after adding the natural fibers and gives the better conductivity properties.展开更多
The aggregation/dispersion of ultrafine particles is of interest for both fundamental and practical perspective. These behaviors of ultrafine silica in flotagent solution and the heter coagulation of silica and alumin...The aggregation/dispersion of ultrafine particles is of interest for both fundamental and practical perspective. These behaviors of ultrafine silica in flotagent solution and the heter coagulation of silica and alumina were examined using particle size analyzer, electrokinetic potential, contact angle measurements. The flotation reagents have a pronounced effect on the aggregation or dispersion behaviors of ultrafine silica suspensions. Collector dodecylamine chloride renders silica surfaces hydrophobic and the aggregation between silica particles takes place. Modifier tripolyphosphate makes the silica surface completely hydrophilic and enhances the stability of silica suspension. These experimental results can be explained based on the extended DLVO theory by considering polar interfacial interaction between particle surfaces.展开更多
Carbonized metallic organic frameworks(CMOF)have been attracting attention in microwave absorption(MA)research area because of their diverse structures,tunable compositions,and rich porosity.Herein,structure regulatio...Carbonized metallic organic frameworks(CMOF)have been attracting attention in microwave absorption(MA)research area because of their diverse structures,tunable compositions,and rich porosity.Herein,structure regulation on metal clusters in CMOF is achieved by tuning the interaction strength between metals and ligands to enhance microwave absorption performance.Due to relatively weak interaction among copper cations and ligands,copper nanoclusters(CuNC)can be uniformly formed and embedded within the cobalt/zinc(Co/Zn)CMOF.Firstly,copper cations are added to the Co/Zn bimetallic zeolitic imidazolate frameworks(ZIFs).Secondly,the CMOF composite particles with CuNCs(CuNCs/CoZn-CMOF)were developed by a pyrolysis process.The CuNCs/CoZn-CMOF with an appropriate amount of CuNCs can harmonize both dielectric and magnetic losses.As a result,the minimum reflection loss(RLmin)reaches–45.1 dB at a matching thickness of 2.30 mm and the effective absorption bandwidth(EAB)is 8.80 GHz at a thickness of 3.10 mm.The broadband response to electromagnetic waves is attributed to interfacial polarization at CuNCs surface and heterogeneous interfaces,impedance matching and multiple scattering of electromagnetic waves.This study provides a feasible method to develop CMOF microwave absorption materials with high EAB values.展开更多
Ti_(3)C_(2)T_(x) nanosheets have attracted significant attention for their potential in electromagnetic wave absorption(EWA).However,their inherent self-stacking and exorbitant electrical conductivity inevitably lead ...Ti_(3)C_(2)T_(x) nanosheets have attracted significant attention for their potential in electromagnetic wave absorption(EWA).However,their inherent self-stacking and exorbitant electrical conductivity inevitably lead to serious impedance mismatch,restricting their EWA application.Therefore,the optimization of impedance matching becomes crucial.In this work,we developed polymethyl methacrylate(PMMA)@Ti_(3)C_(2)T_(x)@SiO_(2) composites with a sandwich-like core–shell structure by coating SiO_(2) on PMMA@Ti_(3)C_(2)T_(x).The results demonstrate that the superiority of the SiO_(2) layer in combination with PMMA@Ti_(3)C_(2)T_(x),outperforming other relative graded distribution structures and meeting the requirements of EWA equipment.The resulting PMMA@Ti_(3)C_(2)T_(x)@SiO_(2) composites achieved a minimum reflection loss of-58.08 dB with a thickness of 1.9 mm,and an effective absorption bandwidth of 2.88 GHz.Mechanism analysis revealed that the structural design of SiO_(2) layer not only optimized impedance matching,but also synergistically enhanced multiple loss mechanisms such as interfacial polarization and dipolar polarization.Therefore,this work provides valuable insights for the future preparation of high-performance electromagnetic wave absorbing Ti_(3)C_(2)T_(x)-based composites.展开更多
Vanadium(V)oxides exhibit low electrical conductivity and poor polarization properties,especially in that V_(2)O_(3)has low stability and is easily oxidized to higher valence V oxides.To solve this problem,we herein p...Vanadium(V)oxides exhibit low electrical conductivity and poor polarization properties,especially in that V_(2)O_(3)has low stability and is easily oxidized to higher valence V oxides.To solve this problem,we herein provide a two-step strategy for the synthesis of carbon nanofilm stabilized twisty V_(2)O_(3)nanorods(V_(2)O_(3)@C),including a hydrothermal reaction and a controlled pyrolysis process.Conductivity tests and electron-spin resonance(ESR)spectra indicate that the coating of carbon nanofilm not only enhances the electrical conductivity but also generates abundant defects.The electromagnetic waves absorption(EMA)results suggest that V_(2)O_(3)@C exhibits excellent EMA performance at ultra-low thickness,where the effective absorption bandwidth gets to 7.21 GHz at 1.7 mm and the maximal absorption reaches–56 d B.Enhanced conductivity loss and improved multiple polarization relaxation were used to illustrate the absorbing mechanism of V_(2)O_(3)@C.This work provides new insights into the design of advanced nanocomposites for EMA applications.展开更多
Ti_(3)C_(2)T_(x)MXene shows great potential in the application as microwave absorbers due to its high attenuation ability.However,excessively high permittivity and self-stacking are the main obstacles that constrain i...Ti_(3)C_(2)T_(x)MXene shows great potential in the application as microwave absorbers due to its high attenuation ability.However,excessively high permittivity and self-stacking are the main obstacles that constrain its wide range of applications.To tackle these problems,herein,the microspheres of SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi with the hydrangea-like core-shell structure were designed and prepared by a combinatorial electrostatic assembly and hydrothermal reaction method.These microspheres are constructed by an outside layer of CoNi nanosheets and intermediate Ti_(3)C_(2)T_(x)MXene nanosheets wrapping on the core of modified SiO_(2),engendering both homogenous and heterogeneous interfaces.Such trilayer SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi microspheres are“magnetic microsize supercapacitors”that can not only induce dielectric loss and magnetic loss but also provide multilayer interfaces to enhance the interfacial polarization.The optimized impedance matching and core-shell structure could boost the reflection loss(RL)by electromagnetic synergy.The synthesized SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi microspheres demonstrate outstanding microwave absorption(MA)performance benefited from these advantages.The obtained RL value was-63.95 dB at an ultra-thin thickness of 1.2 mm,corresponding to an effective absorption bandwidth(EAB)of 4.56 GHz.This work demonstrates that the trilayer core-shell structure designing strategy is highly efficient for tuning the MA performance of MXene-based microspheres.展开更多
Exploring a simple,rapid,solvent-free synthetic method for mass production of cheap,broadband mi-crowave absorbers remains the main challenge.Here,a mild solvent-free procedure is reported to syn-thesize zinc oxide na...Exploring a simple,rapid,solvent-free synthetic method for mass production of cheap,broadband mi-crowave absorbers remains the main challenge.Here,a mild solvent-free procedure is reported to syn-thesize zinc oxide nanoparticles(ZnO NPs)embedded in porous carbon derived from mixing sucrose and zinc nitrate hexahydrate.The characteristic morphology and the ZnO NPs distribution in these compos-ites were tuned using the different raw materials proportions.The mesoporous structure of porous car-bon benefits the compositional advantages between carbon foam and ZnO NPs.The optimal synthesized ZnO/C-2 carbon material demonstrates the strongest absorption of-41.7 dB with a frequency of 14.5 GHz at a thin thickness of 2 mm,and its widest effective absorption is close to 6 GHz(12.2-17.8 GHz).This work produces a feasible route for the sensible design of other effective microwave absorbers for large-scale production.展开更多
Electromagnetic wave-absorbing(EMA)materials at high temperatures are limited by poor conduction loss(L_(c)).However,adding conductors simultaneously increases the conduction loss and interfacial polarization loss,lea...Electromagnetic wave-absorbing(EMA)materials at high temperatures are limited by poor conduction loss(L_(c)).However,adding conductors simultaneously increases the conduction loss and interfacial polarization loss,leading to a conflict between impedance matching(Z_(in)/Z_(0))and electromagnetic wave loss.This will prevent electromagnetic waves from entering the EMA materials,finally reducing overall absorbing performance.Here,the effective electrical conductivity(σ)is enhanced by synchronizing particle size and grain number of Ti_(3)AlC_(2) to increase the conduction loss and avoid the conflict between the impedance matching and the electromagnetic wave loss.As a result,the best-absorbing performance with an effective absorption bandwidth(EAB)of 4.8 GHz(10.6–15.4 GHz)at a thickness of only 1.5 mm is realized,which is the best combination of wide absorption bandwidth and small thickness,and the minimum reflection loss(RL_(min))reaches−45.6 dB at 4.1 GHz.In short,this work explores the regulating mechanism of the EMA materials of effective electrical conductivity by simulated calculations using the Vienna ab-initio Simulation Package(VASP)and COMSOL as well as a series of experiments,which provide new insight into a rational design of materials with anisotropic electrical conductivity.展开更多
The microscopic morphology of electromagnetic wave absorbers influences the multiple reflections of electromagnetic waves and impedance matching,determining the absorption properties.Herein,the urchin-shaped bimetalli...The microscopic morphology of electromagnetic wave absorbers influences the multiple reflections of electromagnetic waves and impedance matching,determining the absorption properties.Herein,the urchin-shaped bimetallic nickel-cobalt oxide/carbon(NiCo_(2)O_(4)/C)composites are prepared via a hy-drothermal route,whose absorption properties are investigated by different morphologies regulated by changing calcination temperature.A minimum reflection loss(RL_(min))of-75.26 dB is achieved at a match-ing thickness of 1.5 mm,and the effective absorption bandwidth(EAB)of 8.96 GHz is achieved at 2 mm.Multi-advantages of the synthesized NiCo_(2)O_(4)/C composites contribute to satisfactory absorption proper-ties.First,the interweaving of the needle-like structures increases the opportunities for scattering and multiple reflections of incident electromagnetic waves,and builds up a conductive network to facilitate the enhancement of conductive losses.Second,the carbon component in the NiCo_(2)O_(4)/C composites en-hances the interfacial polarization and reduces the density of the absorber.Besides,generous oxygen va-cancy defects are introduced into the NiCo_(2)O_(4)/C composites,which induces defect polarization and dipole polarization.In summary,the ternary coordination of components,defects and morphology led to out-standing electromagnetic wave absorption,which lightened the path for improving the electromagnetic wave absorption property and enriching the family of NiCo_(2)O_(4) absorbers with excellent performance.展开更多
Developing electromagnetic(EM) wave absorbing materials with low reflection coefficient and optimal operating frequency band is urgently needed on account of the increasingly serious EM pollution. However, the applica...Developing electromagnetic(EM) wave absorbing materials with low reflection coefficient and optimal operating frequency band is urgently needed on account of the increasingly serious EM pollution. However, the applications of common EM absorbing materials are encumbered by poor high-temperature stability, poor oxidation resistance, narrow absorption bandwidth or high density. Herein, the strong EM absorption capability and wide efficient absorption bandwidth of high entropy ceramics are reported for the first time, which are designed by a combination of the novel high entropy(HE) rare earth silicide carbides/rare earth oxides(RE3 Si2 C2/RE2 O3). Three HE powders, i.e., HERSC-1(HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)3 Si2 C2),HERSC-2 HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)3 Si2 C2/HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)2 O3) and HERSC-3(HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)3 Si2 C2/HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)2 O3), are synthesized. Although HERSC-1 exhibits a limited absorption effect(the minimum reflection loss(RLmin) is-11.6 d B at 3.4 mm) and a relatively narrow effective absorption bandwidth(EAB) of 1.7 GHz, the optimal absorption RLminvalue and EAB of HERSC-2 and HERSC-3 are-40.7 d B(at 2.9 mm), 3.4 GHz and-50.9 d B(at 2.0 mm), 4.5 GHz,respectively, demonstrating strong microwave absorption capability and wide absorption bandwidth.Considering the better stability, low density and strong EM absorption effect, HE ceramics are promising as a new type of EM absorbing materials.展开更多
Electromagnetic(EM)absorption is paving the way to overcome the challenges related to conventional shielding strategy against EM pollution through sustainable energy dissipation.As characteristic functional media that...Electromagnetic(EM)absorption is paving the way to overcome the challenges related to conventional shielding strategy against EM pollution through sustainable energy dissipation.As characteristic functional media that can interact with electric or magnetic field branch,EM wave absorption materials(EWAMs)have received extensive attention and realized considerable development in the past two decades,where carbon-based composites are always considered as promising candidates for high-performance EMAWs due to their synergetic loss mechanism as well as diversified composition and microstructure design.Recent progress indicates that there is more and more interest in the fabrication of carbon-based composites with unique core–shell configuration.On one hand,core–shell configuration usually ensures good chemical homogeneity of final products and provides some positive protections for the components with susceptibility to corrosion,on the other hand,it creates enough heterogeneous interfaces between different EM components,which may bring enhanced polarization effect and intensify the consumption of EM energy.In this review,we firstly introduce EM wave absorption theory,and then highlight the advances of core–shell engineering in carbonbased composites in terms of built-in carbon cores and built-out carbon shells.Moreover,we also show some special core–shell carbon-based composites,including carbon/carbon composites,assembled composites,and decorated composites.After analyzing EM absorption performance of some representative composites,we further propose some challenges and perspectives on the development of core–shell carbon-based composites.展开更多
基金supported by Zhejiang Provincial Key Research and Development Program(2021C01004)National Key Research and Development Program of China(No.2021YFE0100500,2021YFB3501504)Zhejiang Provincial Natural Science Foundation(LQ22E030003),Guangdong Basic and Applied Basic Research Foundation(2020A1515110005).
文摘Multi-layer 2D material assemblies provide a great number of interfaces beneficial for electromagnetic wave absorption.However,avoiding agglomeration and achieving layer-by-layer ordered intercalation remain chal-lenging.Here,3D reduced graphene oxide(rGO)/MXene/TiO_(2)/Fe_(2)C lightweight porous microspheres with periodical intercalated structures and pronounced inter-facial effects were constructed by spray-freeze-drying and microwave irradiation based on the Maxwell–Wagner effect.Such approach reinforced interfacial effects via defects introduction,porous skeleton,multi-layer assembly and multi-compo-nent system,leading to synergistic loss mechanisms.The abundant 2D/2D/0D/0D intercalated heterojunctions in the microspheres provide a high density of polari-zation charges while generating abundant polarization sites,resulting in boosted interfacial polarization,which is verified by CST Microwave Studio simulations.By precisely tuning the 2D nanosheets intercalation in the heterostructures,both the polarization loss and impedance matching improve significantly.At a low filler loading of 5 wt%,the polarization loss rate exceeds 70%,and a minimum reflection loss(RLmin)of-67.4 dB can be achieved.Moreover,radar cross-section simulations further confirm the attenuation ability of the optimized porous microspheres.These results not only provide novel insights into understanding and enhancing interfacial effects,but also constitute an attractive platform for implementing heterointerface engineering based on customized 2D hierarchical architectures.
基金supported by the National Natural Science Foundation of China(Nos.51872002 and 52172174)Open Project of Provincial and Ministerial Scientific Research Platform,and Fuyang Normal University(No.FSKFKT009D).
文摘Integrating heterogeneous interface through nanostructure design and interfacial modification is essential to realize strengthened interfacial polarization relaxation in electromagnetic wave absorption.However,an in-depth comprehension of the interfacial polarization behavior at hetero-junction/interface is highly desired but remains a great challenge.Herein,a Mott-Schottky heterojunction consisting of honeycomb-like porous N-doped carbon confined CoP nanoparticles(CoP@HNC)is designed to elevate the interfacial polarization strength.Simultaneously,corresponding electron migration and redistribution between the heterointerface of defective carbon and CoP nanoparticles are revealed.The significant difference in the work function on both sides of heterogeneous interface boosts the interfacial polarization in high frequency region.Furthermore,the relevant spectroscopic characterizations demonstrate that electron spontaneously migrates from CoP to N-doped carbon at the heterointerface,thereby contributing to the accumulation of electron on defective carbon side and the distribution of hole on CoP side.Impressively,benefitting from the synergistic effects of three-dimensional porous conductive carbon skeleton,foreign N heteroatoms,special CoP nanoparticles,and the resultant CoP/N-doped carbon Mott-Schottky heterojunction,the CoP@HNC exhibits remarkable electromagnetic wave absorption performances with minimum reflection loss up to−60.8 dB and the maximum effective absorption bandwidth of 4.96 GHz,which is superior to most of recently reported transition metal phosphides microwave absorbing composites.The present work opens a new avenue for designing heterogeneous interface to realize strengthened microwave absorption capability and also reveals the in-depth influence of interface structure on electromagnetic wave absorption.
文摘Dispersion of ultrafine alumina suspension is examined by using particle size analyzer. The zeta potential and contact angle measurements were used to discuss the electrokinetic behavior and surface wettability of alumina in modifier solution, and to calculate the electrostatic interaction forces and interfacial interaction forces between alumina particles. The aggregation of ultrafine alumina occurs near its PZC. Addition of modifier increases the zeta potential of alumina and its surface hydrophilicity, resulting in increase of electrostatic and hydration repulsion. It makes the suspension of ultrafine alumina completely dispersed. The average particle size of the suspension is decreased from 1.73 μm in absence of modifier to 0.8 μm in the presence of tripolyphosphate. According to polar interfacial interaction approach, the hydration forces responsible for the stability of alumina suspension in the presence of modifier have also been obtained. The extended DLVO theory is successful to describe the dispersion behavior of ultrafine alumina in modifier solution.
基金financial support from the National Natural Science Foundation of China(No.52174066,No.51534007).
文摘Exposing waxy oils to an electric field may significantly improve their cold flowability.Our previous study has shown that interfacial polarization,i.e.,charged particle accumulation on the wax particle surface,is the primary mechanism of the electrorheological behavior of waxy oils.However,the way that charged particles interact with wax particles under an electric field remains unknown.In this study,we found no viscosity and impedance change for two waxy crude oils after their exposure to a high-voltage electric field.However,the yield stresses were reduced obviously.We thus proposed that the collision of colloidal particles such as resins and asphaltenes with the wax particles could be an essential mechanism that the wax particle structure was weakened.To verify this hypothesis,a series of ad hoc experiments were carried out,i.e.,by performing electrorheological tests on model waxy oils containing additives removable under an electric field,including electrically-neutral colloidal particles(Fe3O4),charged colloidal particles(resins),and oil-soluble electrolyte(C22H14CoO4),respectively,and demonstrated that upon application of a high-voltage electric field,charged particles in a waxy oil may move and thus collide with wax particles,and consequently adhere to the wax particle surface.The particle collision results in damage to the wax particle network,and the electrostatic repulsion arising from the adhesion of the charged particle on the wax particle diminishes attraction between wax particles.This study clarifies the process of interfacial polarization.
基金supported by the National Natural Science Foundation of China(No.U2004177)the Henan Province Science and Technology Research and Development Project in 2020,China(No.202300410491)the Key Scientific Research Projects of Provincial Universities in 2021,China(No.21A430045)。
文摘With the gradually increasing protection awareness about electromagnetic pollution,the demand for absorbing materials with renewability and environmental friendliness has attracted widespread attention.In this work,composites consisting of straw-derived biochar combined with NiCo alloy were successfully fabricated through high-temperature carbonization and subsequent hydrothermal reaction.The electromagnetic parameters of the porous biocarbon/NiCo composites can be effectively modified by altering their NiCo content,and their improved absorbing performance can be attributed to the synergy effect of magnetic-dielectric characteristics.An exceptional reflection loss of-27.0 dB at 2.2 mm thickness and an effective absorption bandwidth of 4.4 GHz(11.7-16.1 GHz)were achieved.These results revealed that the porous biocarbon/NiCo composites could be used as a new generation absorbing material because of their low density,light weight,excellent conductivity,and strong absorption.
基金financially supported by the National Natural Science Foundation of China(Nos.51872002 and 52172174)the key research and development projects in Anhui province,China(No.202004a07020026)。
文摘Lightweight and efficient carbon-based microwave absorbents are significant in addressing the increasing severity of electromagnetic pollution.In this study,hierarchical NiO/Ni nanosheets with a tuneable phase and morphology supported on a carbon fiber substrate(CF@NiO/Ni)were fabricated using a hydrothermal approach and post-annealing treatment.As the annealing temperature increases,more metallic Ni is formed,and an apparent porosity appears on the sheet surface.Benefiting from the advantages of a three-dimensional(3D)conducting network,hierarchical porous structure,reinforced dipole/interface polarization,multiple scattering,and good impedance matching,the CF@NiO/Ni-500 composite exhibits an excellent microwave absorption performance even at a filling rate of only 3wt%.Specifically,its minimal reflection loss is-43.92 dB,and the qualified bandwidth is up to 5.64 GHz.In addition,the low radar cross-section area of the CF@NiO/Ni composite coating confirms its strong ability to suppress electromagnetic wave scattering.We expect that this work could contribute to a deeper understanding of the phase and morphology evolution in enhancing microwave absorption.
基金supported by Sichuan Science and Technology Program,Grant No.2022YFG0111the Postdoctoral Innovative Talent Support Program(Grant No.BX20190220)the State Key Laboratory of Polymer Materials Engineering(Grant No.sklpme2019-2-02)for financial support。
文摘In order to obtain the microwave absorption(MA)materials with light weight,high efficiency and tunable properties,the carbonized mesophase pitch(CMP)with the variation in carbonization temperatures and particle sizes were prepared and characterized.The carbonization temperature mainly controlled the graphitization degree of the CMP to affect their conductive loss.The carbon residues were generated on the CMP surface when the temperature was higher than 700℃,which contributed significantly to the polarization loss of the CMP.For scale regulation,the segregation between the particles in the paraffin ring caused by the reduction particles of CMP carbonization at 750℃(750 CMP)resulted in a significant reduction in conductive losses while improving their impedance matching.The 750 CMP over 300 mesh sieved had the strongest MA properties of-53 d B at 3.4 GHz within 5.5 mm.Moreover,the prepared CMPs were multi-layer compounded and optimized by CST microwave studio.The synergistic effect derived from the improved impedance matching and the enhanced interfacial polarization resulted in significant reflection loss in multi-layer CMP.Overall,these findings lead to the systematically regulation of carbon-based materials for MA,showing an attractive application prospect for the preparation of high-performance MA materials.
基金Supported by Program for the National Natural Science Foundation of China (Nos. 51577021 and U1704253)the Fundamental Research Funds for the Central Universities (DUT17GF107)
文摘Crystalline Fe/MnO@C core–shell nanocapsules inlaid in porous amorphous carbon matrix(FMCA)was synthesized successfully with a novel confinement strategy.The heterogeneous Fe/MnO nanocrystals are with approximate single-domain size which gives rise to natural resonance in 2–18 GHz.The addition of MnO2 confines degree of graphitization catalyzed by iron and contributes to the formation of amorphous carbon.The heterogeneous materials composed of crystalline–amorphous structures disperse evenly and its density is significantly reduced on account of porous properties.Meanwhile,adjustable dielectric loss is achieved by interrupting Fe core aggregation and stacking graphene conductive network.The dielectric loss synergistically with magnetic loss endows the FMCA enhanced absorption.The optimal reflection loss(RL)is up to−45 dB,and the effective bandwidth(RL<−10 dB)is 5.0 GHz with 2.0 mm thickness.The proposed confinement strategy not only lays the foundation for designing high-performance microwave absorber,but also offers a general duty synthesis method for heterogeneous crystalline–amorphous composites with tunable composition in other fields.
基金supported by the National Science Foundation for Excellent Young Scholars of China(21922815)National Natural Science Foundation of China(21975275)+1 种基金Scientific Research Foundation for Young Scientists of Shanxi Province(201801D221156)Research Project Supported by Department of Resource and Social Security of Shanxi Province。
文摘Toward the increasingly serious problem of electromagnetic wave pollution,the development of absorbing material with the properties of the light,thin,wide,strong,and multiple applications scenarios is still a huge challenge.Herein,the core-shell nickel oxide/silicon carbide whiskers(NiO/SiCw)with variational NiO morphologies(tulle-,flower,and rod-like)were designed and fabricated via a facile prehydrothermal method and post-annealing process.For the NiO shell morphology,it can effectively be controlled by the proportion of Ni(NO_(3))_(2)·6H_(2)O,NH_(4)Cl,and CO(NH_(2))_(2).The structure of NiO/SiCw samples was investigated by XRD,SEM,XPS,TEM,and N2 absorption-desorption.Compared to other morphologies of NiO,the flower-like NiO/SiCw possess a porous structure and large surface area that can benefit from the multiple reflections and attenuation of the microwave.As an absorber,the composite with the flower-like NiO/SiCw filler loading of 50%manifests a superior microwave attenuation capability due to its special porous structure,good impedance matching,and large dielectric loss induced from heterojunction interfacial polarization.The minimum reflection loss of flower-like NiO/SiCw is up to-56.8 dB with a thickness of 1.9 mm,and the maximum effective absorption bandwidth(EAB)reaches 5.17 GHz.The as-prepared flower-like NiO/SiCw with strong absorption,thin thickness,and width EAB can meet the potential requirements for microwave absorption materials under oxidation environments.
文摘Fibers reinforced composite materials offer a combination of strength and modulus that are either comparable to or better than many traditional metallic materials.The research on natural fiber based composite materials fit well into this ecological image.This paper reports the conduction mechanism and ac conductivity,activation energy behavior of Polypropylene and banana fiber reinforced thermoplastic composites.Polypropylene[-CH_(2)-CH_(2)-CH_(2)-]n and different fiber content(wt.%)of polypropylene-banana fibers(natural fiber)composites were fabricated using a hot-press molding system.The optimum fabrication parameters were established(initial pressure,temp.etc.).These composite test samples were fabricated so the short fibers were randomly oriented in the matrix.The detail investigation of the a.c.conductivity and conduction mechanism of polymer composites would provide information about the relaxation processes,activation energy etc.which are dependent on frequency,temperature and time.The activation energy involved in the above processes can also be estimated from this study.The measurements were performed over a wide range of frequency of 60 Hz to 3 MHz and temperature range from 30℃(303°K)to 110℃(383°K).Experimental results of the ac properties of pure polypropylene and polypropylene-natural banana fiber composites were compared.It has been established that the fabricated composition changes its insulating property after adding the natural fibers and gives the better conductivity properties.
文摘The aggregation/dispersion of ultrafine particles is of interest for both fundamental and practical perspective. These behaviors of ultrafine silica in flotagent solution and the heter coagulation of silica and alumina were examined using particle size analyzer, electrokinetic potential, contact angle measurements. The flotation reagents have a pronounced effect on the aggregation or dispersion behaviors of ultrafine silica suspensions. Collector dodecylamine chloride renders silica surfaces hydrophobic and the aggregation between silica particles takes place. Modifier tripolyphosphate makes the silica surface completely hydrophilic and enhances the stability of silica suspension. These experimental results can be explained based on the extended DLVO theory by considering polar interfacial interaction between particle surfaces.
基金We thank the National Natural Science Foundation of China(No.52173264)for financial support。
文摘Carbonized metallic organic frameworks(CMOF)have been attracting attention in microwave absorption(MA)research area because of their diverse structures,tunable compositions,and rich porosity.Herein,structure regulation on metal clusters in CMOF is achieved by tuning the interaction strength between metals and ligands to enhance microwave absorption performance.Due to relatively weak interaction among copper cations and ligands,copper nanoclusters(CuNC)can be uniformly formed and embedded within the cobalt/zinc(Co/Zn)CMOF.Firstly,copper cations are added to the Co/Zn bimetallic zeolitic imidazolate frameworks(ZIFs).Secondly,the CMOF composite particles with CuNCs(CuNCs/CoZn-CMOF)were developed by a pyrolysis process.The CuNCs/CoZn-CMOF with an appropriate amount of CuNCs can harmonize both dielectric and magnetic losses.As a result,the minimum reflection loss(RLmin)reaches–45.1 dB at a matching thickness of 2.30 mm and the effective absorption bandwidth(EAB)is 8.80 GHz at a thickness of 3.10 mm.The broadband response to electromagnetic waves is attributed to interfacial polarization at CuNCs surface and heterogeneous interfaces,impedance matching and multiple scattering of electromagnetic waves.This study provides a feasible method to develop CMOF microwave absorption materials with high EAB values.
基金supported by the National Natural Science Foundation of China(No.U2004177)Henan Province Key Research Project for Higher Education Institutions(No.23B430017)+1 种基金the Outstanding Youth Fund of Henan Province(No.212300410081)the Science and Technology Innovation Talents in Universities of Henan Province(No.22HASTIT001).
文摘Ti_(3)C_(2)T_(x) nanosheets have attracted significant attention for their potential in electromagnetic wave absorption(EWA).However,their inherent self-stacking and exorbitant electrical conductivity inevitably lead to serious impedance mismatch,restricting their EWA application.Therefore,the optimization of impedance matching becomes crucial.In this work,we developed polymethyl methacrylate(PMMA)@Ti_(3)C_(2)T_(x)@SiO_(2) composites with a sandwich-like core–shell structure by coating SiO_(2) on PMMA@Ti_(3)C_(2)T_(x).The results demonstrate that the superiority of the SiO_(2) layer in combination with PMMA@Ti_(3)C_(2)T_(x),outperforming other relative graded distribution structures and meeting the requirements of EWA equipment.The resulting PMMA@Ti_(3)C_(2)T_(x)@SiO_(2) composites achieved a minimum reflection loss of-58.08 dB with a thickness of 1.9 mm,and an effective absorption bandwidth of 2.88 GHz.Mechanism analysis revealed that the structural design of SiO_(2) layer not only optimized impedance matching,but also synergistically enhanced multiple loss mechanisms such as interfacial polarization and dipolar polarization.Therefore,this work provides valuable insights for the future preparation of high-performance electromagnetic wave absorbing Ti_(3)C_(2)T_(x)-based composites.
基金financially supported by the National Natural Science Foundation of China(No.51702161)。
文摘Vanadium(V)oxides exhibit low electrical conductivity and poor polarization properties,especially in that V_(2)O_(3)has low stability and is easily oxidized to higher valence V oxides.To solve this problem,we herein provide a two-step strategy for the synthesis of carbon nanofilm stabilized twisty V_(2)O_(3)nanorods(V_(2)O_(3)@C),including a hydrothermal reaction and a controlled pyrolysis process.Conductivity tests and electron-spin resonance(ESR)spectra indicate that the coating of carbon nanofilm not only enhances the electrical conductivity but also generates abundant defects.The electromagnetic waves absorption(EMA)results suggest that V_(2)O_(3)@C exhibits excellent EMA performance at ultra-low thickness,where the effective absorption bandwidth gets to 7.21 GHz at 1.7 mm and the maximal absorption reaches–56 d B.Enhanced conductivity loss and improved multiple polarization relaxation were used to illustrate the absorbing mechanism of V_(2)O_(3)@C.This work provides new insights into the design of advanced nanocomposites for EMA applications.
基金supported by the National Natural Science Foundation of China(U2004177)the Outstanding Youth Fund of Henan Province(212300410081)the Support Plan for Scientific and Technological Innovation Talents in Colleges and Universities of Henan Province(22HASTIT001)。
文摘Ti_(3)C_(2)T_(x)MXene shows great potential in the application as microwave absorbers due to its high attenuation ability.However,excessively high permittivity and self-stacking are the main obstacles that constrain its wide range of applications.To tackle these problems,herein,the microspheres of SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi with the hydrangea-like core-shell structure were designed and prepared by a combinatorial electrostatic assembly and hydrothermal reaction method.These microspheres are constructed by an outside layer of CoNi nanosheets and intermediate Ti_(3)C_(2)T_(x)MXene nanosheets wrapping on the core of modified SiO_(2),engendering both homogenous and heterogeneous interfaces.Such trilayer SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi microspheres are“magnetic microsize supercapacitors”that can not only induce dielectric loss and magnetic loss but also provide multilayer interfaces to enhance the interfacial polarization.The optimized impedance matching and core-shell structure could boost the reflection loss(RL)by electromagnetic synergy.The synthesized SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi microspheres demonstrate outstanding microwave absorption(MA)performance benefited from these advantages.The obtained RL value was-63.95 dB at an ultra-thin thickness of 1.2 mm,corresponding to an effective absorption bandwidth(EAB)of 4.56 GHz.This work demonstrates that the trilayer core-shell structure designing strategy is highly efficient for tuning the MA performance of MXene-based microspheres.
基金the State Key Lab of Advanced Technology for Materials Synthesis and Processing(Wuhan Univer-sity of Technology)for financial support.
文摘Exploring a simple,rapid,solvent-free synthetic method for mass production of cheap,broadband mi-crowave absorbers remains the main challenge.Here,a mild solvent-free procedure is reported to syn-thesize zinc oxide nanoparticles(ZnO NPs)embedded in porous carbon derived from mixing sucrose and zinc nitrate hexahydrate.The characteristic morphology and the ZnO NPs distribution in these compos-ites were tuned using the different raw materials proportions.The mesoporous structure of porous car-bon benefits the compositional advantages between carbon foam and ZnO NPs.The optimal synthesized ZnO/C-2 carbon material demonstrates the strongest absorption of-41.7 dB with a frequency of 14.5 GHz at a thin thickness of 2 mm,and its widest effective absorption is close to 6 GHz(12.2-17.8 GHz).This work produces a feasible route for the sensible design of other effective microwave absorbers for large-scale production.
文摘Electromagnetic wave-absorbing(EMA)materials at high temperatures are limited by poor conduction loss(L_(c)).However,adding conductors simultaneously increases the conduction loss and interfacial polarization loss,leading to a conflict between impedance matching(Z_(in)/Z_(0))and electromagnetic wave loss.This will prevent electromagnetic waves from entering the EMA materials,finally reducing overall absorbing performance.Here,the effective electrical conductivity(σ)is enhanced by synchronizing particle size and grain number of Ti_(3)AlC_(2) to increase the conduction loss and avoid the conflict between the impedance matching and the electromagnetic wave loss.As a result,the best-absorbing performance with an effective absorption bandwidth(EAB)of 4.8 GHz(10.6–15.4 GHz)at a thickness of only 1.5 mm is realized,which is the best combination of wide absorption bandwidth and small thickness,and the minimum reflection loss(RL_(min))reaches−45.6 dB at 4.1 GHz.In short,this work explores the regulating mechanism of the EMA materials of effective electrical conductivity by simulated calculations using the Vienna ab-initio Simulation Package(VASP)and COMSOL as well as a series of experiments,which provide new insight into a rational design of materials with anisotropic electrical conductivity.
基金financially supported by the National Natu-ral Science Foundation of China(No.52207249)the Natural Sci-ence Foundation of Shandong Province(No.ZR2022ME089)+2 种基金the research program of Top Talent Project of Yantai University(No.1115/2220001)the Yantai Basic Research Project(No.2022JCYJ04)the Science Fund of Shandong Laboratory of Advanced Ma-terials and Green Manufacturing(No.AMGM2021F11).The au-thors would like to thank the Deanship of Scientific Research at Umm Al-Qura University for supporting this work by Grant Code:22UQU4320141DSR72.
文摘The microscopic morphology of electromagnetic wave absorbers influences the multiple reflections of electromagnetic waves and impedance matching,determining the absorption properties.Herein,the urchin-shaped bimetallic nickel-cobalt oxide/carbon(NiCo_(2)O_(4)/C)composites are prepared via a hy-drothermal route,whose absorption properties are investigated by different morphologies regulated by changing calcination temperature.A minimum reflection loss(RL_(min))of-75.26 dB is achieved at a match-ing thickness of 1.5 mm,and the effective absorption bandwidth(EAB)of 8.96 GHz is achieved at 2 mm.Multi-advantages of the synthesized NiCo_(2)O_(4)/C composites contribute to satisfactory absorption proper-ties.First,the interweaving of the needle-like structures increases the opportunities for scattering and multiple reflections of incident electromagnetic waves,and builds up a conductive network to facilitate the enhancement of conductive losses.Second,the carbon component in the NiCo_(2)O_(4)/C composites en-hances the interfacial polarization and reduces the density of the absorber.Besides,generous oxygen va-cancy defects are introduced into the NiCo_(2)O_(4)/C composites,which induces defect polarization and dipole polarization.In summary,the ternary coordination of components,defects and morphology led to out-standing electromagnetic wave absorption,which lightened the path for improving the electromagnetic wave absorption property and enriching the family of NiCo_(2)O_(4) absorbers with excellent performance.
基金financially supported by the National Natural Science Foundation of China(Nos.51672064 and 51972089)。
文摘Developing electromagnetic(EM) wave absorbing materials with low reflection coefficient and optimal operating frequency band is urgently needed on account of the increasingly serious EM pollution. However, the applications of common EM absorbing materials are encumbered by poor high-temperature stability, poor oxidation resistance, narrow absorption bandwidth or high density. Herein, the strong EM absorption capability and wide efficient absorption bandwidth of high entropy ceramics are reported for the first time, which are designed by a combination of the novel high entropy(HE) rare earth silicide carbides/rare earth oxides(RE3 Si2 C2/RE2 O3). Three HE powders, i.e., HERSC-1(HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)3 Si2 C2),HERSC-2 HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)3 Si2 C2/HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)2 O3) and HERSC-3(HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)3 Si2 C2/HE(Tm0.2 Y0.2 Dy0.2 Gd0.2 Tb0.2)2 O3), are synthesized. Although HERSC-1 exhibits a limited absorption effect(the minimum reflection loss(RLmin) is-11.6 d B at 3.4 mm) and a relatively narrow effective absorption bandwidth(EAB) of 1.7 GHz, the optimal absorption RLminvalue and EAB of HERSC-2 and HERSC-3 are-40.7 d B(at 2.9 mm), 3.4 GHz and-50.9 d B(at 2.0 mm), 4.5 GHz,respectively, demonstrating strong microwave absorption capability and wide absorption bandwidth.Considering the better stability, low density and strong EM absorption effect, HE ceramics are promising as a new type of EM absorbing materials.
基金supported by the National Natural Science Foundation of China(No.21676065).
文摘Electromagnetic(EM)absorption is paving the way to overcome the challenges related to conventional shielding strategy against EM pollution through sustainable energy dissipation.As characteristic functional media that can interact with electric or magnetic field branch,EM wave absorption materials(EWAMs)have received extensive attention and realized considerable development in the past two decades,where carbon-based composites are always considered as promising candidates for high-performance EMAWs due to their synergetic loss mechanism as well as diversified composition and microstructure design.Recent progress indicates that there is more and more interest in the fabrication of carbon-based composites with unique core–shell configuration.On one hand,core–shell configuration usually ensures good chemical homogeneity of final products and provides some positive protections for the components with susceptibility to corrosion,on the other hand,it creates enough heterogeneous interfaces between different EM components,which may bring enhanced polarization effect and intensify the consumption of EM energy.In this review,we firstly introduce EM wave absorption theory,and then highlight the advances of core–shell engineering in carbonbased composites in terms of built-in carbon cores and built-out carbon shells.Moreover,we also show some special core–shell carbon-based composites,including carbon/carbon composites,assembled composites,and decorated composites.After analyzing EM absorption performance of some representative composites,we further propose some challenges and perspectives on the development of core–shell carbon-based composites.