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High Water Resistance and Enhanced Mechanical Properties of Bio-Based Waterborne Polyurethane Enabled by in-situ Construction of Interpenetrating Polymer Network
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作者 Henghui Deng Jingyi Lu +5 位作者 Dunsheng Liang Xiaomin Wang Tongyao Wang Weihao Zhang Jing Wang Chaoqun Zhang 《Journal of Renewable Materials》 SCIE EI 2023年第3期1209-1222,共14页
In this study,acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization.The effects of the content of ... In this study,acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization.The effects of the content of acrylic acid on the properties of the resulting waterborne polyurethane-poly(acrylic acid)(WPU-PAA)dispersion and the films were systematically investigated.The results showed that the cross-linking density of the interpenetrating network polymers was increased and the interlocking structure of the soft and hard phase dislocations in the molecular segments of the double networks was tailored with increasing the content of acrylic acid,leading to enhancement of the mechanical properties and water resistance of WPU-PAA films.Notably,with the increase in content of acrylic acid,the tensile strength,Young’s modulus,and toughness of the WPU-PAA-110 film increased by 3 times,and 8 times,and 2.4 times compared with WPU-PAA-80,respectively.The WPU-PAA-100 film showed the best water resistance,and the water absorption rate at 96 h was only 3.27%.This work provided a new design scheme for constructing bio-based WPU materials with excellent properties. 展开更多
关键词 Bio-based waterborne polyurethane interpenetrating polymer network highly water resistance superior mechanical performance
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Influence of Interpenetrating Polymer Networks (IPN) Microstructure on Underwater Acoustic Stealth Performance
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作者 罗忠 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第2期272-277,共6页
According to the configuration and absorption theory of polymer macromolecule materials, a kind of IPN with wider temperature range and higher damping property was designed and synthesized. By using the spectrum of dy... According to the configuration and absorption theory of polymer macromolecule materials, a kind of IPN with wider temperature range and higher damping property was designed and synthesized. By using the spectrum of dynamic mechanical thermal analysis (DMTA) and acoustic pulse tube device, the microstructure, phase separation degree, phase size and phase continuity of IPN with different components were analyzed. The experimental results show that the nano size grade of phase, the continuous and homogeneous IPN phase can provide higher absorption coefficient. The absorption coefficient of optimized sample I09 is 0.7 in 2 kHz, and the absorption peak is 0.9 in 4 kHz. Then the underwater acoustic properties of modified IPN filled with mica, micro-balloon and nano-SiO2 were discussed respectively to indicate that the inhomogeneous property of filler-modified IPN can improve the underwater acoustic stealth performance effectively, and the micro size grade of these filler-modified IPN can work well in low frequency acoustic stealth. 展开更多
关键词 interpenetrating polymer networks ipn POLYURETHANE DAMPING absorption coefficient FILLERS
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PREPARATION AND PROPERTIES OF GEL POLYMER ELECTROLYTE BASED ON PVDF/ACRYLATE INTERPENETRATING POLYMER NETWORK FOR DYE-SENSITIZED SOLAR CELL
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作者 杨艳 陶杰 +1 位作者 金鑫 秦琦 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2010年第4期353-360,共8页
The gel polymer electrolytes(GPEs)based on poly(vinylidence fluoride)(PVDF)/acrylate interpenetrating polymer network(IPN)are prepared.The micro-phase separation type GPEs are characterized by Fourier transfor... The gel polymer electrolytes(GPEs)based on poly(vinylidence fluoride)(PVDF)/acrylate interpenetrating polymer network(IPN)are prepared.The micro-phase separation type GPEs are characterized by Fourier transform infrared(FTIR)spectroscopy,scanning electron microscope(SEM),respectively.Moreover,the conductivity and the voltage-current curves of the electrolytes are measured by electrochemical workstation.The higher porosity and electrolyte uptake are observed in the membranes prepared at lower crosslinker concentration.The suitable cross-linking acrylate monomer improves the porosity and the electrochemical behavior of GPE.A dye-sensitized solar cell(DSSC)employing PGE based on PVDF/poly(ethylene glycol dimethacrylate)(PEGDMA)IPN yields an open-circuit voltage of 0.674 V,short-circuit current of 8.476 mA·cm-2and the conversion efficiency of 2.710% under 100 mW·cm-2illumination. 展开更多
关键词 solar cells interpenetrating polymer network ploymer films GELS
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Studies on the Morphology of Natural Rubber/Polyacrylate Interpenetrating Polymer Networks 被引量:3
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作者 Llao Kalrong (Institute of Polymer Science, Zhangshan University, Guangzhou)Thomas C. Ward (Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA, USA) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1990年第1期85-89,共5页
The interpenetrating polymer network(IPN) systems have attracted a lot of attention because of their unique two-phase structure and properties. There have been many publications concerning the IPNs in which poly (isop... The interpenetrating polymer network(IPN) systems have attracted a lot of attention because of their unique two-phase structure and properties. There have been many publications concerning the IPNs in which poly (isoprene) (PIP) or polyacrylates (PAC) is formed as one of the networks.In the present study, Four serles of natural rubber(NR)/PAC IPNs were prepared and their morphologies were investigated with dynamic mechanics analysis(DMA) and transmission electron microscopy (TEM). 展开更多
关键词 interpenetrating polymer network Natural rubber POLYACRYLATE
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Preparation,Morphology and Damping Property of PU/UP Interpenetrating Polymer Networks 被引量:1
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作者 Dongyan TANG Liangsheng QIANG +1 位作者 Zheng JIN Liancheng ZHAO 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2005年第4期585-588,共4页
Interpenetrating polymer networks (IPNs) composed of acrylate-modified polyurethane (PU)/unsaturated polyester (UP) resin via simultaneous polymerization with various component ratios of PU/UP were prepared. The... Interpenetrating polymer networks (IPNs) composed of acrylate-modified polyurethane (PU)/unsaturated polyester (UP) resin via simultaneous polymerization with various component ratios of PU/UP were prepared. The polymerization processes of IPNs were traced through infrared spectrum (IR) techniques, by which the phase separation in systems could be controlled effectively. Results for the morphology and miscibility among multiple phases of IPNs, obtained by transmission electron microscope (TEM) indicated that the domains between two phases were constricted in nanometer scales. The dynamic mechanical thermal analyzer (DMTA) detection results revealed that the loss factor (tanS) and loss modulus (E″) increased with the polyurethane amounts in system, and the peak value in curves of tanδ and E″ appeared toward low temperature ranges. Maximum tanδ values of all samples were above 0.3 in the nearly 50℃ ranges. Also, the mechanical properties of PU/UP IPNs were studied in detail. 展开更多
关键词 interpenetrating polymer networks ipns) NANOCOMPOSITES Damping property MORPHOLOGY
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Polymerization Process and Morphology of Polyurethane/Vinyl Ester Resin Interpenetrating Polymer Networks 被引量:1
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作者 Dongyan TANG Xuelian WU Liangsheng QIANG 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2007年第3期423-426,共4页
A series of polyurethane (PU)/vinyl ester resin (VER) simultaneous IPNs (interpenetrating polymer networks) with different component ratios and comonomers types introduced to VER were synthesized and the polymer... A series of polyurethane (PU)/vinyl ester resin (VER) simultaneous IPNs (interpenetrating polymer networks) with different component ratios and comonomers types introduced to VER were synthesized and the polymerization processes were traced by Fourier transform infrared spectroscopy (FTIR) to study the kinetics of IPNs and hydrogen bonding action within multi-component. Furthermore, the relationship of polymerization process with morphology was investigated in detail for the first time by the morphological information given by chemical action between two networks besides physical entanglement, atomic force microscope (AFM) observation and dynamic mechanical analysis (DMA). The results indicated that the degree of hydrogen bonding (Xb,UT,%), calculated from functional group conversional rate and fine structures gained from FT-IR spectra of two networks, were affected by PU/VER weight ratios and comonomer types of VER. The relationship of formation kinetics and morphology showed that the change of Xb,UT (%) values exhibited excellent consistency with that of phase sizes observed by AFM and detected by DMA. 展开更多
关键词 Polyurethane (PU) interpenetrating polymer networks ipns) polymerization process MORPHOLOGY
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Structural characteristics and properties of polyurethane modified TDE-85/MeTHPA epoxy resin with interpenetrating polymer networks 被引量:2
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作者 李芝华 黄耀鹏 +1 位作者 任冬燕 郑子樵 《Journal of Central South University of Technology》 EI 2008年第3期305-308,共4页
Diglycidyl-4,5-epoxycyclohexane-1,2-dicarboxylate(TDE-85)/methyl tetrahydrophthalic anhydride (MeTHPA) epoxy resin was modified with polyurethane(PU) and the interpenetrating polymer networks(IPNs) of PU-modified TDE-... Diglycidyl-4,5-epoxycyclohexane-1,2-dicarboxylate(TDE-85)/methyl tetrahydrophthalic anhydride (MeTHPA) epoxy resin was modified with polyurethane(PU) and the interpenetrating polymer networks(IPNs) of PU-modified TDE-85/MeTHPA resin were prepared. The structural characteristics and properties of PU-modified TDE-85/MeTHPA resin were investigated by Fourier transform infrared(FTIR) spectrum,emission scanning electron microscopy(SEM) and thermogravimetry(TG). The results indicate that epoxy polymer network (Ⅰ) and polyurethane polymer network (Ⅱ) of the modified resin can be obtained and the networks (Ⅰ) and (Ⅱ) interpenetrate and tangle highly each other at the phase interface. The micro morphology presents heterogeneous structure. The integrative properties of PU-modified TDE-85/MeTHPA epoxy resin are improved obviously. The PU-modified TDE-85/ MeTHPA resin's tensile strength reaches 69.39 MPa,the impact strength reaches 23.56 kJ/m,the temperature for the system to lose 1% mass (t1%) is 300 ℃,and that for the system to lose 50% mass (t50%) is 378 ℃. Compared with those of TDE-85/MeTHPA resin,the tensile strength,impact strength,t1% and t50% of the PU-modified resin increases by 48%,115%,30 ℃,11 ℃,respectively. The PU-modified TDE-85/MeTHPA resin has the structure characteristics and properties of interpenetrating polymer networks. 展开更多
关键词 POLYURETHANE epoxy resin interpenetrating polymer networks tensile strength impact strength thermal stability
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Thermoreversible Thickening and Self-assembly Behaviors of pH/Temperature Dually Responsive Microgels with Interpenetrating Polymer Network Structure 被引量:1
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作者 刘晓云 杨军 +1 位作者 闫伟霞 査刘生 《Journal of Donghua University(English Edition)》 EI CAS 2014年第3期312-315,共4页
The pH /temperature dually responsive microgels of interpenetrating polymer network( IPN) structure composed of poly( N-isopropylacrylamide)( PNIPAM) network and poly( acrylic acid)( PAA) network( PNIPAM /PAA IPN micr... The pH /temperature dually responsive microgels of interpenetrating polymer network( IPN) structure composed of poly( N-isopropylacrylamide)( PNIPAM) network and poly( acrylic acid)( PAA) network( PNIPAM /PAA IPN microgels) were synthesized by seed emulsion polymerization. The results obtained by dynamic laser light scattering( DLLS) show that the microgels have good pH /temperature dual sensitivities. The temperature sensitive component and the pH sensitive component inside the microgels have little interference with each other. The rheological properties of the concentrated PNIPAM /PAA IPN microgel dispersions as a function of temperature at pH 4. 0 or 7. 0 were investigated by viscometer,and the results displayed that only at pH 7. 0 the dispersions presented thermoreversible thickening behavior. Then the PNIPAM /PAA fibers were prepared by self-assembly of the PNIPAM /PAA IPN microgels in the ice-crystal templates formed by unidirectional liquid nitrogen freezing method. Field emission scanning electron microscopy( FESEM) images indicate that the PNIPAM /PAA fibers are rounded,randomly orientated and interweaved. 展开更多
关键词 interpenetrating polymer network(ipn) structure pH and temperature sensitivity thermo-thickening self-assembly
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Synthesis and Characterization of Polyurethane and Epoxy Resin Interpenetrating Polymer Network 被引量:1
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作者 吴晓燕 杨晓慧 +1 位作者 刘允航 王新灵 《Journal of Shanghai Jiaotong university(Science)》 EI 2005年第2期193-196,202,共5页
A series of Polyurethane (PU)/bisphenol A based Epoxy Resin(EP) Interpenetrating Polymer Networks(IPN) were synthesized and characterized by SEM, DSC, TGA and DMTA. It was found that IPN shows the best compatibility a... A series of Polyurethane (PU)/bisphenol A based Epoxy Resin(EP) Interpenetrating Polymer Networks(IPN) were synthesized and characterized by SEM, DSC, TGA and DMTA. It was found that IPN shows the best compatibility and damping properties when the ratio of PU/EP is 80 to 20. The results show that chain-extender and higher molecular weight of PPG are able to improve the properties of compatibility, damping and thermal properties. 展开更多
关键词 interpenetrating polymer networks(ipn) POLYURETHANE epoxy resin compatibility damping (properties)
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Fabrication and evaluation of carboxymethyl guar gum-chitosan interpenetrating polymer network (IPN) nanoparticles for controlled drug delivery
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作者 Chandrani Roy Arijit Gandhi +1 位作者 Sreejan Manna Sougata Jana 《Medicine in Novel Technology and Devices》 2024年第2期73-79,共7页
Guar gum(GG)has drawn more interest from researchers in the last several decades for the controlled delivery of drugs.The aim of the research is to fabricate and evaluate an interpenetrating polymer network(IPN)based ... Guar gum(GG)has drawn more interest from researchers in the last several decades for the controlled delivery of drugs.The aim of the research is to fabricate and evaluate an interpenetrating polymer network(IPN)based nanocarriers system employing chemically modified GG to achieve controlled release of drug.In present study,we have reported the synthesis of carboxymethyl GG-chitosan IPN nanoparticles for controlled release of metformin hydrochloride.Carboxymethyl guar gum(CMGG)was synthesized and employed for developing IPN nanoparticles in combination with chitosan in varying polymeric ratios.A cross-linking agent,sodium tripolyphosphate(Na-TPP)was used for the synthesis of IPN colloidal suspension of nanoparticles which was lyophilized to obtain nanoparticles.The carboxymethylation of GG was confirmed through Fourier transform infra-red spectroscopy.The mean particle size was 440.6 nm indicating a polydispersity index of 0.528.The drug entrapment efficiency was found to vary between 67.461.64%to 88.232.02%.The differential scanning calorimetry study revealed the presence of amorphous metformin hydrochloride as a homogenous dispersion in nanoparticles(NPs)matrix.In vitro drug release study indicated controlled release ability of developed IPN matrix.A2 formulation(chitosan:CMGG-1:1)exhibited 78.110.27%release after 8 h.Antidiabetic evaluation performed in alloxan-treated diabetic rat model exhibited a prolonged hypoglycemic efficacy over 6 h,for A2 formulation treated group,compared to the group receiving only metformin HCl,which demonstrated a reduction in blood glucose levels for up to 4 h.The study findings demonstrated the efficacy of the CMGG-chitosan based IPN nanoparticulate system for sustained delivery of therapeutic agents. 展开更多
关键词 Carboxymethyl guar gum CHITOSAN interpenetrating polymer network NANOPARTICLES Controlled release Metformin hydrochloride
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Taste masking of ofloxacin and formation of interpenetrating polymer network beads for sustained release
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作者 A. Michael Rajesh Kiritkumar Mangaldas Popat 《Journal of Pharmaceutical Analysis》 SCIE CAS CSCD 2017年第4期244-251,共8页
The objective of this study was to carry out taste masking of ofloxacin(Ofl) by ion exchange resins(IERs)followed by sustained release of Ofl by forming interpenetrating polymer network(IPN) beads. Drug-resin complexe... The objective of this study was to carry out taste masking of ofloxacin(Ofl) by ion exchange resins(IERs)followed by sustained release of Ofl by forming interpenetrating polymer network(IPN) beads. Drug-resin complexes(DRCs) with three different ratios of Ofl to IERs(1:1, 1:2, 1:4) were prepared by batch method and investigated for in vivo and in vitro taste masking. DRC of methacrylic acid-divinyl benzene(MD) resin and Ofl prepared at a ratio of 1:4 was used to form IPN beads. IPN beads of MD 1:4 were prepared by following the ionic cross-linking method using sodium carboxymethyl xanthan gum(SCMXG) and SCMXG-sodium carboxymethyl cellulose(SCMXG-SCMC). IPN beads were characterized with FT-IR and further studied on sustained release of Ofl at different pH. In vivo taste masking carried out by human volunteers showed that MD 1:4 significantly reduced the bitterness of Ofl. Characterization studies such as FT-IR, DSC, P-XRD and taste masking showed that complex formation took place between drug and resin. In vitro study at gastric pH showed complete release of drug from MD 1:4 within 30 min whereas IPN beads took 5 h at gastric pH and 10 h at salivary pH for the complete release of drug. As the crosslinking increased the release kinetics changed into non-Fickian diffusion to zero-order release mechanism. MD 1:4 showed better performance for the taste masking of Ofl and IPNs beads prepared from it were found useful for the sustained release of Ofl at both the pH, indicating a versatile drug delivery system. 展开更多
关键词 Ion exchange resins OFLOXACIN in vivo & in VITRO TASTE MASKING interpenetrating polymer network SUSTAINED release
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SYNTHESIS,CHARACTERIZATION AND PROPERTIES OF ORGANOCLAYMODIFIED POLYSULFONE/EPOXY INTERPENETRATING POLYMER NETWORK NANOCOMPOSITES
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作者 R.Rajasekaran C.Karikalchozhan M.Alagar 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2008年第6期669-678,共10页
Organoclay-modified hydroxylterminated polysulfone (PSF)/epoxy interpenetrating network nanocomposites (oM-PSF/EP nanocomposites) were prepared by adding organophilic montmorillonite (oMMT) to interpenetrating polymer... Organoclay-modified hydroxylterminated polysulfone (PSF)/epoxy interpenetrating network nanocomposites (oM-PSF/EP nanocomposites) were prepared by adding organophilic montmorillonite (oMMT) to interpenetrating polymer networks (IPNs) of polysulfone and epoxy resin (PSF/EP) using diaminodiphenylmethane (DDM) as curing agent.The mechanical properties like tensile strength,tensile modulus,flexural strength,flexural modulus and impact properties of the nanocomposites were studied as per ASTM standards.Different... 展开更多
关键词 NANOCOMPOSITES Glass transition temperature Impact strength interpenetrating networks ipn Polysulfone.
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SYNTHESIS AND CHARACTERIZATION OF POLYDIMETHYLSILOXANE/POLYSTYRENE SEMIINTERPENETRATING POLYMER NETWORKS
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作者 方世璧 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1999年第6期537-542,共6页
The synthesis of pseudo- and semi-interpenetrating polymer networks (IPNs) based on polydimethylsiloxane (PDMS) and polystyrene (PS) is described. IPNs were obtained by simultaneous and in situ sequential synthesis pr... The synthesis of pseudo- and semi-interpenetrating polymer networks (IPNs) based on polydimethylsiloxane (PDMS) and polystyrene (PS) is described. IPNs were obtained by simultaneous and in situ sequential synthesis procedure. The preliminary studies on IPNs properties such as transition temperature, microphase separation and mechanical behaviors have been carried out by using differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The experimental evidence clearly showed that semi-IPNs obtained by sequential synthesis procedure have higher interpenetrating extent than pseudo-IPNs synthesized by simultaneous procedure. Over the full composition, the PDMS/PS IPNs are immiscible. The pseudo-IPNs microphase separation can be greatly subdued through the formation of grafting bonds between two networks as well as the kinetic rate-matching of the individual network crosslinking. 展开更多
关键词 interpenetrating polymer networks POLYDIMETHYLSILOXANE POLYSTYRENE glass transition temperature MORPHOLOGY mechanical properties
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AN EPOXY/(METHYL METHACRYLATE)INTERPENETRATING POLYMER NETWORK FOR NONLINEAR OPTICS
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作者 张灵志 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1999年第5期435-440,共6页
An interpenetrating polymer networks (IPN) consisting of an epoxy-based polymer network and a polymethyl methacrylate network were synthesized and characterized. The IPN showed only one T-g, and hence a homogeneous-ph... An interpenetrating polymer networks (IPN) consisting of an epoxy-based polymer network and a polymethyl methacrylate network were synthesized and characterized. The IPN showed only one T-g, and hence a homogeneous-phase morphology was suggested. The second-order nonlinear optical coefficient (d(33)) of the IPN was measured to be 1.72 X 10(-7) esu. The study of NLO temporal stability at room temperature and elevated temperature (100 degrees C) indicated that the IPN exhibits a high stability in the dipole orientation due to the permanent entanglements of two component networks in the IPN system. Long-term stability of second harmonic coefficients was observed at room temperature for more than 1000 h. 展开更多
关键词 interpenetrating polymer networks second-order optical nonlinearity epoxy-based polymer polymethyl methacrylate
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Microstrueture and Properties of Fluoroelastomer/Butadiene-Acrylonitrile Rubber Interpenetrating Polymer Networks
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作者 陈春明 XIONG Chuanxi +1 位作者 YANG Jian DONG Lijie 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2008年第1期50-53,共4页
Interpenetrating polymer networks (IPNs) based on fluoroelastomer/butadiene-acrylonitrile rubber (FKM/NBR) by molten blending at a high temperature and chemical cross-linking of two components were prepared. The i... Interpenetrating polymer networks (IPNs) based on fluoroelastomer/butadiene-acrylonitrile rubber (FKM/NBR) by molten blending at a high temperature and chemical cross-linking of two components were prepared. The influence of the two networks component on the mechanical properties and thermostabilities was studied. The experimental results show that the mechanical properties of the IPNs are superior to those of the individual FKM and NBR networks due to forming the case of interpenetrating and intercross-linking between the two networks, the mechanical properties and thermal resistance exhibit higher values when 80/20 (w/w) FKM and NBR is blended and respectively cured simultaneously. The co-continuous morphology of the IPNs in the blends of 80/20 (w/w) FKM/NBR is found by transmission electron microscopy (TEM), the differential scanning calorimetry (DSC) determination shows that the blends of 80/20 (w/w) FKM/NBR have better compatibility, and the glass transition temperature of the elastomer is -21.5 ℃. 展开更多
关键词 FLUOROELASTOMER butadiene-acrylonitrile rubber interpenetrating polymer network BLENDS
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Preparation of Semi-interpenetrating Polymer Network of Silicon Rubber and Poly(methyl methylacrylate) Using Supercritical CO_2
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作者 Zhi Min LIU Jia Qiu WANG +1 位作者 Guan Ying YANG Bu Xing HAN 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第7期683-684,共2页
The heterogeneous free-radical polymerization of methyl methylacrylate (MMA) and divinylbenzene (DVB) as cross-linker within supercritical carbon dioxide-swollen silicon rubber (SR) has been studied as an approach to ... The heterogeneous free-radical polymerization of methyl methylacrylate (MMA) and divinylbenzene (DVB) as cross-linker within supercritical carbon dioxide-swollen silicon rubber (SR) has been studied as an approach to preparing semi-interpenetrating polymer network (semi-IPN) of SR and poly(methyl methylacrylate) (PMMA). The SR/PMMA semi-IPNs were characterized by scanning electron microscopy (SEM) and dynamic mechanical analyzer (DMA). 展开更多
关键词 Supercritical CO2 interpenetrating polymer network silicon rubber poly(methyl methylacrylate) polymerization.
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Gas Permeability and Free Volume Hole Properties of Interpenetrating Polymer Network Studied by Positrons
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作者 QI Ning GONG Wei +3 位作者 WANG Zhifen WANG Bo YANG Yurun HU Chunpu 《Wuhan University Journal of Natural Sciences》 CAS 2007年第2期271-274,共4页
A series of polyurethane/epoxy resin interpenetrating polymer networks (PU/ER IPN) were studied by positron annihilation lifetime spectroscopy (PALS). The effects of epoxy resin type and content on the free volume... A series of polyurethane/epoxy resin interpenetrating polymer networks (PU/ER IPN) were studied by positron annihilation lifetime spectroscopy (PALS). The effects of epoxy resin type and content on the free volume properties in IPN were investigated. We found that in PU/ER IPN, the free volume hole size and fractional free volume showed a negative deviation due to closer segmental chain packing through some chemical bonding between PU and epoxy resin. Direct relationship between the gas permeability and the free volume has been established based on the free volume theory. Experimental results revealed that the free volume plays an important role in determining the gas diffusion and permeability. 展开更多
关键词 interpenetrating polymer network positron annihilation free volume gas permeability
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Interfacial Actions and Adherence of an Interpenetrating Polymer Network Thin Film on Aluminum Substrate
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作者 Weiwei Cui Dongyan Tang +1 位作者 Jie Liu Fan Yang 《Journal of Surface Engineered Materials and Advanced Technology》 2011年第3期89-94,共6页
The interpenetrating polymer networks (IPN) thin film with the –C=O group in one network and the terminal –N=C=O group in another network on an aluminum substrate to reinforce the adherence between IPN and aluminum ... The interpenetrating polymer networks (IPN) thin film with the –C=O group in one network and the terminal –N=C=O group in another network on an aluminum substrate to reinforce the adherence between IPN and aluminum through interfacial reactions, were obtained by dip-pulling the pretreated aluminum substrate into the viscous-controlled IPN precursors and by the following thinning treatment to the IPN film to a suitable thickness. The interfacial actions and the adhesion strengths of the IPN on the pretreated aluminum substrate were investigated by the X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and strain-stress(?-?) measurements. The XPS and FTIR detection results indicated that the elements’ contents of N, O, and Al varied from the depths of IPN. The in-terfacial reaction occurred between the –N=C=O group of IPN and the AlO(OH) of pretreated aluminum. The in-creased force constant for –C=O double bond and the lower frequency shift of –C=O stretching vibration absorption peak both verified the formation of hydrogen bond between the –OH group in AlO(OH) and the –C=O group in IPN. The adherence detections indicated that the larger amount of –N=C=O group in the IPN, the higher shear strengths between the IPN thin film and the aluminum substrate. 展开更多
关键词 INTERFACIAL Action ADHERENCE interpenetrating polymer network (ipn) Aluminum THIN Film
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Biosorption of Toxic Zn(ll) Ion from Water Using Ion Imprinted Interpenetrating Polymer Networks
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作者 Girija p Beena Mathew 《Journal of Chemistry and Chemical Engineering》 2013年第6期508-517,共10页
Toxic Zn(II) ion imprinted interpenetrating polymer networks were synthesized for the selective sorption of Zn(ll) from aqueous solutions using a biopolymer alginic acid. The polymeric biosorbant was prepared usin... Toxic Zn(II) ion imprinted interpenetrating polymer networks were synthesized for the selective sorption of Zn(ll) from aqueous solutions using a biopolymer alginic acid. The polymeric biosorbant was prepared using Zn(II) ion as template, acrylamide as functional monomer, cross linker NNMBA (N,N' Methylene-bis-acrylamide) and potassium persulphate as an initiator. The non-imprinted polymer networks were also prepared without use of the Zn(II) ion. The synthesized interpenetrating networks were characterized by various spectral techniques. Metal ion binding studies were carried out and the factors affecting binding were also optimized. Competitive sorption studies were investigated to determine the selectivity of Zn(II) ion imprinted interpenetrating polymer network. Zinc ion imprinted polymer networks showed good selectivity for the target ion. 展开更多
关键词 interpenetrating polymer network molecular imprinting template metal SELECTIVITY zinc ion.
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Interpenetrating polymers supported on microporous polypropylene membranes for the transport of chromium ions 被引量:2
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作者 Yesid Tapiero Julio Sánchez BernabéL.Rivas 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第7期938-946,共9页
Modifying polypropylene membranes with interpenetrating polymer networks(IPNs) through the incorporation of poly(glycidyl methacrylate-N-methyl-D-glucamine)(P(GMA-NMG)) was performed by in situ synthesis via radical p... Modifying polypropylene membranes with interpenetrating polymer networks(IPNs) through the incorporation of poly(glycidyl methacrylate-N-methyl-D-glucamine)(P(GMA-NMG)) was performed by in situ synthesis via radical polymerization. The surface of the polypropylene membrane was activated by hydrophilic grafted polyelectrolyte, and then, pressure injection was used for the impregnation of the reactive solution in the membrane.Two types of pore-filled membranes were synthesized, chelating interpenetrating homopolymer networks of P(GMA-NMG), and chelating-ion exchange interpenetrating polymer networks(e.g., P(GMA-NMG)/P(AA),P(GMA-NMG)/P(AMPSA), and P(GMA-NMG)/P(Cl VBTA)). After their synthesis, the modified polypropylene membranes were characterized using techniques such as the electrokinetic potential, SEM, FT-IR, and Donnan dialysis to corroborate the chromium ion transport. The P(GMA-NMG) and complex network membranes exhibited a hydrophilic character with a water-uptake capacity between 20% and 35% and a percentage of modification between 4.0% and 7.0% in comparison with the behavior of the unmodified polypropylene membrane.Hexavalent chromium ions were efficiently transported from the food chamber at p H 9.0 when the 65.2%MTA1 P(Cl VBTA) homopolymer IPN membrane and 48.5% MTAG P(GMA-NMG)/P(Cl VBTA) IPN membrane were used. Similarly, hexavalent chromium ions were removed from the food chamber at pH 3.0 when MTAG(63.30%) and MTA1(35.68%) were used in 1 mol·L^(-1)Na Cl solution as the extraction reagent. 展开更多
关键词 POLYPROPYLENE N-methyI-D-glucamine Ion exchange Donnan dialysis interpenetrating polymer networks CHROMIUM
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