Traditional 3D printing is based on stereolithography or standard tessellation language models,which contain many redundant data and have low precision.This paper proposes a slicing and support structure generation al...Traditional 3D printing is based on stereolithography or standard tessellation language models,which contain many redundant data and have low precision.This paper proposes a slicing and support structure generation algorithm for 3D printing directly on boundary representation(B-rep)models.First,surface slicing is performed by efficiently computing the intersection curves between the faces of the B-rep models and each slicing plane.Then,the normals of the B-rep models are used to detect where the support structures should be located and the support structures are generated.Experimental results show the efficiency and stability of our algorithm.展开更多
The photophysics of 3-dimethylamino-2-methyl-propenal （DMAMP） after excitation to the S2 （ππ^＊） electronic state was studied using the resonance Raman spectroscopy and complete active space self-consistent fiel...The photophysics of 3-dimethylamino-2-methyl-propenal （DMAMP） after excitation to the S2 （ππ^＊） electronic state was studied using the resonance Raman spectroscopy and complete active space self-consistent field method calculations. The transition barriers of the ground state tautomerization reactions between DMAMP and its three isomers were determined at B3LYP/6-311＋＋G（d,p） level of theory. The vibrational spectra were assigned. The A- band resonance Raman spectra were obtained in acetonitrile with excitation wavelengths in resonance with the first intense absorption band to probe the structural dynamics of DMAMP. The B3LYP-TD computation was carried out to determine the relative A-band resonance Raman intensities of the fundamental modes, and the result indicated that the vibronic-coupling existed in Franck-Condon region. Complete active space self-consistent field （CASSCF） calculations were carried out to determine the excitation energies of the lower-lying singlet and triplet excited states, the conical intersection points and the intersystem crossing points. The A-band short-time structural dynamics and the corresponding decay dynamics of DMAMP were obtained by analysis of the resonance Raman intensity pattern and CASSCF computations. It was found that a sudden de-conjugation between C1=O6 and C2=C3 occurred at the Franck-Condon region of the S2（ππ^＊） state, while the enhancement of the conjugation interaction between C3 and N（CH3）2, and between C1 and C2 evolutions shortly after the wavepacket leaves away the Pranck-Condon region via the excited state charge redistribution. The de-conjugation interaction between C1=O6 and C2=C3 made the rotation of C3=N（CH3）2 group around the C2-C3 bond much easier, while the enhanced conjugation between C1 and C2, and between C3 and N（CH3）2 made the rotation around the C1-C2 bond and C3-N5 more difficult. It was revealed that the initial structural dynamics of DMAMP was predominantly towards the CI-I（S2/S0） point, while the opportunities towards either CI-2（S2/S0） or CI-3（S2/S0） point were negligible. Two decay channels of DMAMP from S2,FC（ππ^＊） to So or Tl,min via various CIs and ISCs were proposed.展开更多
Intersecting connection plays an important role in the new diagrid structural system for high-rise buildings.To investigate the static behavior of the intersecting connection of concrete-filled steel tubular(CFST)colu...Intersecting connection plays an important role in the new diagrid structural system for high-rise buildings.To investigate the static behavior of the intersecting connection of concrete-filled steel tubular(CFST)columns,a typical reduced-scale planner connection specimen is tested under monotonic axial compression.The failure modes,force mechanism and bearing capacity of intersecting CFST connections are analyzed further in the follow-up numerical simulation,considering influences of intersecting angle,elliptical plate and ring plate.Test and simulation results prove that,intersecting connection can develop fully plastic deformation and provide sufficient bearing capacity.Parametric analysis indicates that bearing capacity of planar intersecting CFST connection mainly depends on intersecting angle and thickness of elliptical plate,while the ring plate affects that little.Capacity estimation method for planar intersecting CFST connection is proposed basing on the capacity of the critical section which is located near intersecting center for a distance of steel tube radius,and the design suggestions is provided in the end of this paper.展开更多
基金This work is was funded by National Natural Science Foundation of China under Grant No.61672307.
文摘Traditional 3D printing is based on stereolithography or standard tessellation language models,which contain many redundant data and have low precision.This paper proposes a slicing and support structure generation algorithm for 3D printing directly on boundary representation(B-rep)models.First,surface slicing is performed by efficiently computing the intersection curves between the faces of the B-rep models and each slicing plane.Then,the normals of the B-rep models are used to detect where the support structures should be located and the support structures are generated.Experimental results show the efficiency and stability of our algorithm.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.21033002 and No.21202032） and the National Basic Research Program of China （No.2013CB834604）.
文摘The photophysics of 3-dimethylamino-2-methyl-propenal （DMAMP） after excitation to the S2 （ππ^＊） electronic state was studied using the resonance Raman spectroscopy and complete active space self-consistent field method calculations. The transition barriers of the ground state tautomerization reactions between DMAMP and its three isomers were determined at B3LYP/6-311＋＋G（d,p） level of theory. The vibrational spectra were assigned. The A- band resonance Raman spectra were obtained in acetonitrile with excitation wavelengths in resonance with the first intense absorption band to probe the structural dynamics of DMAMP. The B3LYP-TD computation was carried out to determine the relative A-band resonance Raman intensities of the fundamental modes, and the result indicated that the vibronic-coupling existed in Franck-Condon region. Complete active space self-consistent field （CASSCF） calculations were carried out to determine the excitation energies of the lower-lying singlet and triplet excited states, the conical intersection points and the intersystem crossing points. The A-band short-time structural dynamics and the corresponding decay dynamics of DMAMP were obtained by analysis of the resonance Raman intensity pattern and CASSCF computations. It was found that a sudden de-conjugation between C1=O6 and C2=C3 occurred at the Franck-Condon region of the S2（ππ^＊） state, while the enhancement of the conjugation interaction between C3 and N（CH3）2, and between C1 and C2 evolutions shortly after the wavepacket leaves away the Pranck-Condon region via the excited state charge redistribution. The de-conjugation interaction between C1=O6 and C2=C3 made the rotation of C3=N（CH3）2 group around the C2-C3 bond much easier, while the enhanced conjugation between C1 and C2, and between C3 and N（CH3）2 made the rotation around the C1-C2 bond and C3-N5 more difficult. It was revealed that the initial structural dynamics of DMAMP was predominantly towards the CI-I（S2/S0） point, while the opportunities towards either CI-2（S2/S0） or CI-3（S2/S0） point were negligible. Two decay channels of DMAMP from S2,FC（ππ^＊） to So or Tl,min via various CIs and ISCs were proposed.
基金The presented work is financially supported by National Science Foundation(NSF,USA)project 90815029 and SLDRCE08-A-04.
文摘Intersecting connection plays an important role in the new diagrid structural system for high-rise buildings.To investigate the static behavior of the intersecting connection of concrete-filled steel tubular(CFST)columns,a typical reduced-scale planner connection specimen is tested under monotonic axial compression.The failure modes,force mechanism and bearing capacity of intersecting CFST connections are analyzed further in the follow-up numerical simulation,considering influences of intersecting angle,elliptical plate and ring plate.Test and simulation results prove that,intersecting connection can develop fully plastic deformation and provide sufficient bearing capacity.Parametric analysis indicates that bearing capacity of planar intersecting CFST connection mainly depends on intersecting angle and thickness of elliptical plate,while the ring plate affects that little.Capacity estimation method for planar intersecting CFST connection is proposed basing on the capacity of the critical section which is located near intersecting center for a distance of steel tube radius,and the design suggestions is provided in the end of this paper.
