The mesoporous molecular sieves MCM-41 were prepared using room tempera-ture ionic liquid (RTIL) synthesized in laboratory and cethytrimethylammonium bromide (CTAB) as compound templates for the first time. They w...The mesoporous molecular sieves MCM-41 were prepared using room tempera-ture ionic liquid (RTIL) synthesized in laboratory and cethytrimethylammonium bromide (CTAB) as compound templates for the first time. They were prepared under low aging temperature and short aging time. Via characterizing by XRD and nitrogen adsorption instrument, MCM-41 synthesized by this new method exhibited good crystal structure and narrow pore distribution. The following pre-paratory conditions was optimal: the molar ratio of RTIL to CTAB was 1.0∶1.0, aging at 80 ℃, for 40 h and calcined at 540 ℃. It is found that the acidified MCM-41 improves its activity as catalyst over the unmodified ones.展开更多
基金supported by the Science Foundation of Hebei Province(B2012402001,D2014402046)Program for One Hundred Innovative Talents in Universities of Hebei Province(BR2-204)and the Science and Technology Foundation of Universities of Hebei Province(Q2012030)~~
基金supported by the National Natural Science Foundation of China(41571464)Education Department of Liaoning Province,China(L2014145)Natural Science Foundation of Liaoning Province,China(201602467)~~
基金supported by the National Natural Science Foundation of China(51204080,51274108,21263007)Natural Science Foundation of Yunnan Province,China(2011FA009)+1 种基金Application Foundation Research of Yunnan Province,China(2011FZ020)Talents Cultivation Foundation of Kunming University of Science and Technology,China(14118441)~~
基金Funded by Zhengzhou Natural Science Foundation (No. 064SJZJ23115)Key Laboratory Catalysis and Materials Science of Southcentral Universityfor Nationalities Foundation
文摘The mesoporous molecular sieves MCM-41 were prepared using room tempera-ture ionic liquid (RTIL) synthesized in laboratory and cethytrimethylammonium bromide (CTAB) as compound templates for the first time. They were prepared under low aging temperature and short aging time. Via characterizing by XRD and nitrogen adsorption instrument, MCM-41 synthesized by this new method exhibited good crystal structure and narrow pore distribution. The following pre-paratory conditions was optimal: the molar ratio of RTIL to CTAB was 1.0∶1.0, aging at 80 ℃, for 40 h and calcined at 540 ℃. It is found that the acidified MCM-41 improves its activity as catalyst over the unmodified ones.