A new class of iron（II） hydrides based on a tetradentate PSNP ligand were synthesized and fully characterized. All the iron（II） complexes feature a folded PSNP ligand with cis reactive sites. The hydrido iron comp...A new class of iron（II） hydrides based on a tetradentate PSNP ligand were synthesized and fully characterized. All the iron（II） complexes feature a folded PSNP ligand with cis reactive sites. The hydrido iron complex [2 H（NCMe[2_TD$IF]1）]（BF4） is capable of catalyzing aldehyde hydroboration by pinacolborane（HBpin） and with extremely high efficiency at room temperature. Aldehydes with various functional groups are compatible.展开更多
基金financial support from the "1000 Youth Talents Plan"the National Natural Science Foundation of China (Nos. 21402107, 91427303)the Natural Science Foundation of Shandong Province (Nos. ZR2014M011)
文摘A new class of iron（II） hydrides based on a tetradentate PSNP ligand were synthesized and fully characterized. All the iron（II） complexes feature a folded PSNP ligand with cis reactive sites. The hydrido iron complex [2 H（NCMe[2_TD$IF]1）]（BF4） is capable of catalyzing aldehyde hydroboration by pinacolborane（HBpin） and with extremely high efficiency at room temperature. Aldehydes with various functional groups are compatible.
