Polyethersulphone(PES)membranes modified with urethane functional groups were prepared through an interfacial reaction using electron beam irradiation.The removal of eight endocrine disrupting chemicals(EDCs)was studi...Polyethersulphone(PES)membranes modified with urethane functional groups were prepared through an interfacial reaction using electron beam irradiation.The removal of eight endocrine disrupting chemicals(EDCs)was studied using both pristine and functionalized PES membranes.The prepared membranes underwent characterization using several techniques,including attenuated total reflectance-Fourier transform infrared(ATR-FTIR)spectroscopy,scanning electron microscopy,contact angle analysis,and measurements of pure water flux.Furthermore,dynamic adsorption experiments were conducted to evaluate the adsorption mechanism of the prepared membrane toward the eight EDCs.The urethane functionalized membranes were hydrophilic(52°contact angle)and maintained a high permeate flux(26000 L/h m^(2) bar)throughout the filtration process.Dynamic adsorption results demonstrated that the introduction of urethane functional groups on the membranes significantly enhanced the removal efficiency of 17β-estradiol,estriol,bisphenol A,estrone,ethinylestradiol,and equilin.The adsorption loading of 17β-estradiol on the functionalized PES membrane was 6.7±0.7 mg/m^(2),exhibiting a 5-fold increase compared to the unmodified PES membrane.The membranes were successfully regenerated and reused for three adsorption cycles without experiencing any loss of adsorption capacity.展开更多
The degradation of aniline, p-nitroaniline and m-chloroaniline by electron beam irradiation was studied. Re- moval of aniline, p-nitroaniline and m-chloroaniline reached 95% at an initial concentration of 0.5mmol/L at...The degradation of aniline, p-nitroaniline and m-chloroaniline by electron beam irradiation was studied. Re- moval of aniline, p-nitroaniline and m-chloroaniline reached 95% at an initial concentration of 0.5mmol/L at 23kGy. The results showed that electron beam irradiation is an effective process for the degradation of aniline and its derivatives.展开更多
采用电子束辐照技术对烤烟烟叶进行处理,探讨其对烟叶化学成分的影响。结果表明,1-7 k Gy剂量的电子束辐照没有影响初烤烟叶中还原糖和总糖的含量,但显著影响了烟碱、总氮、石油醚提取物的含量以及糖碱比、氮碱比等化学指标;1-7 k Gy剂...采用电子束辐照技术对烤烟烟叶进行处理,探讨其对烟叶化学成分的影响。结果表明,1-7 k Gy剂量的电子束辐照没有影响初烤烟叶中还原糖和总糖的含量,但显著影响了烟碱、总氮、石油醚提取物的含量以及糖碱比、氮碱比等化学指标;1-7 k Gy剂量的电子束辐照对复烤烟叶中的还原糖、总糖、烟碱、总氮、石油醚提取物含量以及氮碱比等化学指标无显著影响,〉3 k Gy剂量的电子束辐照对复烤烟叶的糖碱比有一定的影响;而〉1 k Gy剂量的电子束辐照就能有效控制烟叶霉变。因此,采用电子束辐照技术对初烤烟叶进行杀菌防霉是不可行的,而对复烤烟叶是可行的。展开更多
采用剂量率为20 k Gy/h的电子束在空气氛围中对乙烯-四氟乙烯共聚物(Ethylene tetra-fluoro-ethylenecopolymer,ETFE)片材进行辐照,剂量范围0–1600 k Gy,研究了ETFE片材在低剂量率电子束辐照下的化学稳定性。通过机械性能、红外光谱、...采用剂量率为20 k Gy/h的电子束在空气氛围中对乙烯-四氟乙烯共聚物(Ethylene tetra-fluoro-ethylenecopolymer,ETFE)片材进行辐照,剂量范围0–1600 k Gy,研究了ETFE片材在低剂量率电子束辐照下的化学稳定性。通过机械性能、红外光谱、拉曼光谱和扫描量热仪(DSC)等对辐照前后的样品进行了测试和表征。机械性能测试结果表明,随着吸收剂量的增加,断裂伸长率和断裂强度在0–200 k Gy内缓慢下降,超过400 k Gy则急剧下降;红外光谱分析表明,随着吸收剂量的增加,羰基指数增加,样品表面氧化程度严重;拉曼光谱分析结果显示低剂量率电子束的辐照破坏了ETFE分子链结构的对称性;DSC测试结果表明,随着吸收剂量的增加,ETFE的结晶度和熔点逐渐下降,结晶度从43.2%下降到12.6%,熔点从261.3℃下降到233.3℃。展开更多
文摘Polyethersulphone(PES)membranes modified with urethane functional groups were prepared through an interfacial reaction using electron beam irradiation.The removal of eight endocrine disrupting chemicals(EDCs)was studied using both pristine and functionalized PES membranes.The prepared membranes underwent characterization using several techniques,including attenuated total reflectance-Fourier transform infrared(ATR-FTIR)spectroscopy,scanning electron microscopy,contact angle analysis,and measurements of pure water flux.Furthermore,dynamic adsorption experiments were conducted to evaluate the adsorption mechanism of the prepared membrane toward the eight EDCs.The urethane functionalized membranes were hydrophilic(52°contact angle)and maintained a high permeate flux(26000 L/h m^(2) bar)throughout the filtration process.Dynamic adsorption results demonstrated that the introduction of urethane functional groups on the membranes significantly enhanced the removal efficiency of 17β-estradiol,estriol,bisphenol A,estrone,ethinylestradiol,and equilin.The adsorption loading of 17β-estradiol on the functionalized PES membrane was 6.7±0.7 mg/m^(2),exhibiting a 5-fold increase compared to the unmodified PES membrane.The membranes were successfully regenerated and reused for three adsorption cycles without experiencing any loss of adsorption capacity.
文摘The degradation of aniline, p-nitroaniline and m-chloroaniline by electron beam irradiation was studied. Re- moval of aniline, p-nitroaniline and m-chloroaniline reached 95% at an initial concentration of 0.5mmol/L at 23kGy. The results showed that electron beam irradiation is an effective process for the degradation of aniline and its derivatives.
文摘采用电子束辐照技术对烤烟烟叶进行处理,探讨其对烟叶化学成分的影响。结果表明,1-7 k Gy剂量的电子束辐照没有影响初烤烟叶中还原糖和总糖的含量,但显著影响了烟碱、总氮、石油醚提取物的含量以及糖碱比、氮碱比等化学指标;1-7 k Gy剂量的电子束辐照对复烤烟叶中的还原糖、总糖、烟碱、总氮、石油醚提取物含量以及氮碱比等化学指标无显著影响,〉3 k Gy剂量的电子束辐照对复烤烟叶的糖碱比有一定的影响;而〉1 k Gy剂量的电子束辐照就能有效控制烟叶霉变。因此,采用电子束辐照技术对初烤烟叶进行杀菌防霉是不可行的,而对复烤烟叶是可行的。
文摘采用剂量率为20 k Gy/h的电子束在空气氛围中对乙烯-四氟乙烯共聚物(Ethylene tetra-fluoro-ethylenecopolymer,ETFE)片材进行辐照,剂量范围0–1600 k Gy,研究了ETFE片材在低剂量率电子束辐照下的化学稳定性。通过机械性能、红外光谱、拉曼光谱和扫描量热仪(DSC)等对辐照前后的样品进行了测试和表征。机械性能测试结果表明,随着吸收剂量的增加,断裂伸长率和断裂强度在0–200 k Gy内缓慢下降,超过400 k Gy则急剧下降;红外光谱分析表明,随着吸收剂量的增加,羰基指数增加,样品表面氧化程度严重;拉曼光谱分析结果显示低剂量率电子束的辐照破坏了ETFE分子链结构的对称性;DSC测试结果表明,随着吸收剂量的增加,ETFE的结晶度和熔点逐渐下降,结晶度从43.2%下降到12.6%,熔点从261.3℃下降到233.3℃。
