We report here the measurements of valence electron structure for the n-butane (C4H10)using high resolution (E=0.9 eV FWHM, P=0.1 a.u.) (e,2e) spectrometer. The impact energy was 1200eV plus binding energy (i.e. 1206 ...We report here the measurements of valence electron structure for the n-butane (C4H10)using high resolution (E=0.9 eV FWHM, P=0.1 a.u.) (e,2e) spectrometer. The impact energy was 1200eV plus binding energy (i.e. 1206 to 1232 eV) and symmetric non-coplanar kinematics was employed. The inner-and outer-valence energy spectrum is in agreement with published Photoelectron data. The experimental momentum profiles have been compared with calculations obtained using Hartree-Fock method with the minimum basis set and a high-level basis set, and also using density functional theory (DFT) density methods with a high level basis set. The agreement hetween theory and experiment for shape of orbital electron momentum distributions is generallygood.展开更多
We briefly present in this paper the results of 1200eV non-coplanar symmetric (e, 2e) binding energy spectrum of argon and an electron momentum profile of argon 3p.They were measured by a newly constructed spectromete...We briefly present in this paper the results of 1200eV non-coplanar symmetric (e, 2e) binding energy spectrum of argon and an electron momentum profile of argon 3p.They were measured by a newly constructed spectrometer with position-sensitive detectors in USTC. We use non-birming mode to get the Ar3p、 3s and 3s satellites binding energy spectra separately. The experAnental results is well consistent with the available theoretical results.展开更多
The binding energy spectra and momentum profiles for the valence shells of ethane have been measured by using multichannel EMS spectrometer. The results are compared with the available experimental and theoretical res...The binding energy spectra and momentum profiles for the valence shells of ethane have been measured by using multichannel EMS spectrometer. The results are compared with the available experimental and theoretical results. The present result of the experimental momentum profile of 3a1g has an obvious minimum as predicted by the theoretical calculations.展开更多
This paper reports the measurements of valence electron structure for the iso-butane (iso-C4H10) using high resolution （E = 0. 9eV FWHM, p = 0.1a. u） （e, 2e） spectrometer. The impact energy was 1200 eV plus bindin...This paper reports the measurements of valence electron structure for the iso-butane (iso-C4H10) using high resolution （E = 0. 9eV FWHM, p = 0.1a. u） （e, 2e） spectrometer. The impact energy was 1200 eV plus binding energy （i. e. 1205 to 1230 eV） and symmetric non-coplanar kinematics was employed. The experimental momentum Profiles have been compared with those calculated using Hartree -Fock method and Density Funchon Theory.展开更多
文摘We report here the measurements of valence electron structure for the n-butane (C4H10)using high resolution (E=0.9 eV FWHM, P=0.1 a.u.) (e,2e) spectrometer. The impact energy was 1200eV plus binding energy (i.e. 1206 to 1232 eV) and symmetric non-coplanar kinematics was employed. The inner-and outer-valence energy spectrum is in agreement with published Photoelectron data. The experimental momentum profiles have been compared with calculations obtained using Hartree-Fock method with the minimum basis set and a high-level basis set, and also using density functional theory (DFT) density methods with a high level basis set. The agreement hetween theory and experiment for shape of orbital electron momentum distributions is generallygood.
文摘We briefly present in this paper the results of 1200eV non-coplanar symmetric (e, 2e) binding energy spectrum of argon and an electron momentum profile of argon 3p.They were measured by a newly constructed spectrometer with position-sensitive detectors in USTC. We use non-birming mode to get the Ar3p、 3s and 3s satellites binding energy spectra separately. The experAnental results is well consistent with the available theoretical results.
文摘The binding energy spectra and momentum profiles for the valence shells of ethane have been measured by using multichannel EMS spectrometer. The results are compared with the available experimental and theoretical results. The present result of the experimental momentum profile of 3a1g has an obvious minimum as predicted by the theoretical calculations.
文摘This paper reports the measurements of valence electron structure for the iso-butane (iso-C4H10) using high resolution （E = 0. 9eV FWHM, p = 0.1a. u） （e, 2e） spectrometer. The impact energy was 1200 eV plus binding energy （i. e. 1205 to 1230 eV） and symmetric non-coplanar kinematics was employed. The experimental momentum Profiles have been compared with those calculated using Hartree -Fock method and Density Funchon Theory.
