Naphthalimide methylcyclohexane(NMICY)luminogen that features molecular conformation-directed aggregation-induced emission was prepared,and its pure equatorial conformer was isolated and wellcharacterized via various ...Naphthalimide methylcyclohexane(NMICY)luminogen that features molecular conformation-directed aggregation-induced emission was prepared,and its pure equatorial conformer was isolated and wellcharacterized via various techniques,including single-crystal X-ray diffraction(SC-XRD)analysis.In NMICY,the methyl cyclohexane substituent adapted the most stable chair conformation,preventing intermolecularπ-πinteractions among the naphthalimide cores.Careful analysis of the self-assembly behavior indicated that an uncommon J^(*)-aggregation pattern was predominant for NMICY that exhibited∼450 nm emission in crystal as well as in the aggregated state[λmax=455 nm,фPL=23.22%,fw=99.9%in water or water-dimethylformamide mixture].NMICY self-assembled into cube-shaped 2D-nanoarchitecture as characterized by fieldemission scanning electron microscopy,atomic force microscopy,and dynamic light scattering(Zavg=143 nm,∼20 nm height)studies while also displaying unique optical properties in the aggregated state.The supramolecular self-assembly and aggregated state structure-property relationship in aqueous media of NMICY were optimized,and a facile strategy for the detection of melamine in milk and an aqueous solution of milk powder is reported with a limit of detection value of 0.184 ppm(milk)and 0.101 ppm(milk powder),achieved via the rare acceptor-excited photoinduced electron transfer mechanism.Furthermore,a smartphone-based,portable,and uncomplicated sensing platform was developed that simplifies the melamine detection process.展开更多
A semigroup is called completely J（e）-simple if it is isomorphic to some Rees matrix semi- group over a left cancellative monoid and each entry of whose sandwich matrix is in the group of units of the left cancellat...A semigroup is called completely J（e）-simple if it is isomorphic to some Rees matrix semi- group over a left cancellative monoid and each entry of whose sandwich matrix is in the group of units of the left cancellative monoid. It is proved that completely J（e）-simple semigroups form a quasivarity. Moreover, the construction of free completely J（e）simple semigroups is given. It is found that a free completely J（e）-simple semigroup is just a free completely J＊-simple semigroup and also a full subsemigroup of some completely simple semigroups.展开更多
文摘Naphthalimide methylcyclohexane(NMICY)luminogen that features molecular conformation-directed aggregation-induced emission was prepared,and its pure equatorial conformer was isolated and wellcharacterized via various techniques,including single-crystal X-ray diffraction(SC-XRD)analysis.In NMICY,the methyl cyclohexane substituent adapted the most stable chair conformation,preventing intermolecularπ-πinteractions among the naphthalimide cores.Careful analysis of the self-assembly behavior indicated that an uncommon J^(*)-aggregation pattern was predominant for NMICY that exhibited∼450 nm emission in crystal as well as in the aggregated state[λmax=455 nm,фPL=23.22%,fw=99.9%in water or water-dimethylformamide mixture].NMICY self-assembled into cube-shaped 2D-nanoarchitecture as characterized by fieldemission scanning electron microscopy,atomic force microscopy,and dynamic light scattering(Zavg=143 nm,∼20 nm height)studies while also displaying unique optical properties in the aggregated state.The supramolecular self-assembly and aggregated state structure-property relationship in aqueous media of NMICY were optimized,and a facile strategy for the detection of melamine in milk and an aqueous solution of milk powder is reported with a limit of detection value of 0.184 ppm(milk)and 0.101 ppm(milk powder),achieved via the rare acceptor-excited photoinduced electron transfer mechanism.Furthermore,a smartphone-based,portable,and uncomplicated sensing platform was developed that simplifies the melamine detection process.
基金Supported by NSFC(No.11361027)the Natural Science Foundation of Jiangxi Province(No.2014BAB201009)+1 种基金the Science Foundation of the Education Department of Jiangxi Province(No.GJJ14251)the Graduate Innovation Foundation of Jiangxi Province(No,YC2014-S160)
基金Supported by National Natural Science Foundation of China(Grant No.11361027)the Natural Science Foundation of Jiangxi Provincethe Science Foundation of the Education Department of Jiangxi Province,China
文摘A semigroup is called completely J（e）-simple if it is isomorphic to some Rees matrix semi- group over a left cancellative monoid and each entry of whose sandwich matrix is in the group of units of the left cancellative monoid. It is proved that completely J（e）-simple semigroups form a quasivarity. Moreover, the construction of free completely J（e）simple semigroups is given. It is found that a free completely J（e）-simple semigroup is just a free completely J＊-simple semigroup and also a full subsemigroup of some completely simple semigroups.
