The ^(12)C+^(12)C fusion is one of the most important reactions in modern nuclear astrophysics.The trend and magnitude of the reaction rate within the Gamow window strongly influence various astrophysical processes.Ho...The ^(12)C+^(12)C fusion is one of the most important reactions in modern nuclear astrophysics.The trend and magnitude of the reaction rate within the Gamow window strongly influence various astrophysical processes.However,direct measurement of this reaction is extremely difficult,which makes it necessary to develop indirect methods.In this study,the ^(23)Na+p reaction system was used to study the compound nucleus ^(24)Mg.We employed a thick-target inverse kinematics method combined with theγ-charged-particle coincidence technique to measure the proton andα exit channels of ^(24)Mg.Technical details of the ^(23)Na+p thick-target inverse kinematics experiment and analysis are presented herein.展开更多
In recent times, lithium-ion batteries have been widely used owing to their high energy density, extended cycle lifespan, and minimal self-discharge rate. The design of high-speed rechargeable lithium-ion batteries fa...In recent times, lithium-ion batteries have been widely used owing to their high energy density, extended cycle lifespan, and minimal self-discharge rate. The design of high-speed rechargeable lithium-ion batteries faces a significant challenge owing to the need to increase average electric power during charging. This challenge results from the direct influence of the power level on the rate of chemical reactions occurring in the battery electrodes. In this study, the Taguchi optimization method was used to enhance the average electric power during the charging process of lithium-ion batteries. The Taguchi technique is a statistical strategy that facilitates the systematic and efficient evaluation of numerous experimental variables. The proposed method involved varying seven input factors, including positive electrode thickness, positive electrode material, positive electrode active material volume fraction, negative electrode active material volume fraction, separator thickness, positive current collector thickness, and negative current collector thickness. Three levels were assigned to each control factor to identify the optimal conditions and maximize the average electric power during charging. Moreover, a variance assessment analysis was conducted to validate the results obtained from the Taguchi analysis. The results revealed that the Taguchi method was an eff ective approach for optimizing the average electric power during the charging of lithium-ion batteries. This indicates that the positive electrode material, followed by the separator thickness and the negative electrode active material volume fraction, was key factors significantly infl uencing the average electric power during the charging of lithium-ion batteries response. The identification of optimal conditions resulted in the improved performance of lithium-ion batteries, extending their potential in various applications. Particularly, lithium-ion batteries with average electric power of 16 W and 17 W during charging were designed and simulated in the range of 0-12000 s using COMSOL Multiphysics software. This study efficiently employs the Taguchi optimization technique to develop lithium-ion batteries capable of storing a predetermined average electric power during the charging phase. Therefore, this method enables the battery to achieve complete charging within a specific timeframe tailored to a specificapplication. The implementation of this method can save costs, time, and materials compared with other alternative methods, such as the trial-and-error approach.展开更多
The LiMnPO4/C composite material was synthesized via a sol-gel method based on the citric acid. The X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical performance tests were adopted to...The LiMnPO4/C composite material was synthesized via a sol-gel method based on the citric acid. The X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical performance tests were adopted to characterize the properties of LiMnPO4/C. The XRD studies show that the pure olivine phase LiMnPO4 can be obtained at a low temperature of 500 °C. The SEM analyses illustrate that the citric acid used as the chelating reagent and carbon source can restrain the particle size of LiMnPO4/C well. The LiMnPO4/C sample synthesized at 500 °C for 10 h performs the highest initial discharge capacity of 122.6 mA-h/g, retaining 112.4 mA-h/g over 30 cycles at 0.05C rate. The citric acid based sol-gel method is favor to obtain the high electrochemical performance of LiMnPO4/C.展开更多
Nanosphere-like Li2FeSiO4/C was synthesized via a solution method using sucrose as carbon sources under a mild condition of time-saving and energy-saving, followed by sintering at high temperatures for crystallization...Nanosphere-like Li2FeSiO4/C was synthesized via a solution method using sucrose as carbon sources under a mild condition of time-saving and energy-saving, followed by sintering at high temperatures for crystallization. The amount of carbon in the composite is less than 10% (mass fraction), and the X-ray diffraction result confirms that the sample is of pure single phase indexed with the orthorhombic Pmn21 space group. The particle size of the Li2FeSiO4/C synthesized at 700 °C for 9 h is very fine and spherical-like with a size of 200 nm. The electrochemical performance of this material, including reversible capacity, cycle number, and charge-discharge characteristics, were tested. The cell of this sample can deliver a discharge capacity of 166 mA-h/g at C/20 rate in the first three cycles. After 30 cycles, the capacity decreases to 158 mA-h/g, and the capacity retention is up to 95%. The results show that this method can prepare nanosphere-like Li2FeSiO4/C composite with good electrochemical performance.展开更多
以J C 皮特2000年出版的代表作《技术思考:技术哲学的基础》一书为起点,概述了皮特技术哲学思想基本观点以及所引发论争的焦点,分析了"皮特现象",即国际学术界对皮特技术哲学的反响。以此指出,我们应注重技术哲学的基础研究...以J C 皮特2000年出版的代表作《技术思考:技术哲学的基础》一书为起点,概述了皮特技术哲学思想基本观点以及所引发论争的焦点,分析了"皮特现象",即国际学术界对皮特技术哲学的反响。以此指出,我们应注重技术哲学的基础研究以及技术哲学研究的建制化发展。展开更多
The fuzzy integration evaluation method (FIEM) is studied in order to select the best orbital elements from the multi-group initial orbits determined by a satellite TT&C (Tracking, Telemetry and Control) center w...The fuzzy integration evaluation method (FIEM) is studied in order to select the best orbital elements from the multi-group initial orbits determined by a satellite TT&C (Tracking, Telemetry and Control) center with all kinds of data sources. By employing FIEM together with the experience of TT&C experts, the index system to evaluate the selection of the best initial orbits is established after the data sources and orbit determination theories are studied. Besides, the concrete steps in employing the method are presented. Moreover, by taking the objects to be evaluated as evaluation experts, the problem of how to generate evaluation matrices is solved. Through practical application, the method to select the best initial orbital elements has been proved to be flexible and effective The originality of the method is to find a new evaluation criterion (comparing the actually tracked orbits) replacing the traditional one (comparing the nominal orbits) for selecting the best orbital elements.展开更多
3D evaluation method of cutting surface topography for C/Ph composites was established.The cutting surface was measured by Talyscan 150,using 3D non-contact measurement.Through the results of 2D and 3D roughness evalu...3D evaluation method of cutting surface topography for C/Ph composites was established.The cutting surface was measured by Talyscan 150,using 3D non-contact measurement.Through the results of 2D and 3D roughness evaluating for C/Ph composite and Duralumin,the 2D evaluation method of the cutting surface topography of C/Ph composite loses a lot of information,the characteristics of the surface topography of C/Ph composite can be comprehensively and authentically evaluated only by 3D evaluation method.Furthermore,3D amplitude and spatial parameters were adopted to evaluate the surface.The results show that: the topography of the C/Ph composite is anisotropic,there are more valleys in the machined surface of C/Ph than that of duralumin,and there are not obvious feeding textures for C/Ph,which indicates the machining mechanism is different from the metal.In conclusion,the topography of the C/Ph composite cutting surface is anisotropic;the cutting surface of C/Ph composite needs 3D evaluation method.展开更多
The electrocatalysts of Pt/C, PtRu/C and Ru/C were prepared by the impregnation method. The facet characterization, the dispersion and the particle size for the catalysts were determined by means of X ray diffractio...The electrocatalysts of Pt/C, PtRu/C and Ru/C were prepared by the impregnation method. The facet characterization, the dispersion and the particle size for the catalysts were determined by means of X ray diffraction and transmission electron microscopy. X ray photoelectron spectroscopy was also used to analyze the state and the valency of the noble metals. The results show that the particle size was in nanometer range and the binary metals have come into being an alloy. The platinum in the catalysts existed in zero valency. The valency of the ruthenium on the surface is different from that in the body, while the ruthenium on the surface existed in oxide form. PtRu/C and Pt/C are of good activity to the electrooxidation of hydrogen except Ru/C. PtRu/C is more tolerant of CO than Pt/C, and CO is only adsorbed on Pt.展开更多
Effects of cooling methods on stability and methane conversion rate using dielectric-barrier discharges (DBD) were systematically investigated in this article. The results showed that the methane conversion rate was...Effects of cooling methods on stability and methane conversion rate using dielectric-barrier discharges (DBD) were systematically investigated in this article. The results showed that the methane conversion rate was as high as 44.43% in a pure methane system at a flow rate of 100 mL·min^-1 and an input power of 234.2 W with air cooling. A dark greenish and soft film-like carbon was deposited on the outer surface of quartz tube when the outer electrode was watercooled, which decreased the methane conversion. With air cooling of inner electrode the selectivity of C2 hydrocarbons was higher than that with other cooling methods, while the C3 hydrocarbons had higher selectivity with flowing water cooling. Cooling the inner electrode could restrain the carbon deposition, but would decrease the methane conversion rate. The stability of both reaction and plasma operation can be improved through cooling the reactor. From thermodynamic analysis, it was found that the effective collisions frequency among the reactant molecules and free electrons (e^-) increased with temperature, which in turn led to a higher methane conversion rate and a change in the distribution of products.展开更多
Refinery scheduling attracts increasing concerns in both academic and industrial communities in recent years.However, due to the complexity of refinery processes, little has been reported for success use in real world...Refinery scheduling attracts increasing concerns in both academic and industrial communities in recent years.However, due to the complexity of refinery processes, little has been reported for success use in real world refineries. In academic studies, refinery scheduling is usually treated as an integrated, large-scale optimization problem,though such complex optimization problems are extremely difficult to solve. In this paper, we proposed a way to exploit the prior knowledge existing in refineries, and developed a decision making system to guide the scheduling process. For a real world fuel oil oriented refinery, ten adjusting process scales are predetermined. A C4.5 decision tree works based on the finished oil demand plan to classify the corresponding category(i.e. adjusting scale). Then,a specific sub-scheduling problem with respect to the determined adjusting scale is solved. The proposed strategy is demonstrated with a scheduling case originated from a real world refinery.展开更多
[ Objective ] The aim was to select appropriate sterilization methods and explants for tissue culture of Haloxylon ammodendron ( C. A. Mey. ). [Method] H. ammodendron (C. A. Mey. ) seeds were used as experimental ...[ Objective ] The aim was to select appropriate sterilization methods and explants for tissue culture of Haloxylon ammodendron ( C. A. Mey. ). [Method] H. ammodendron (C. A. Mey. ) seeds were used as experimental materials to investigate the sterilization results of different sterilization treatments and the effect of different seed sizes on the survival rate of aseptic seedlings. [ Result] Sterilization of H. ammodendron ( C.A. Mey. ) seeds achieved the best result by using 75% alcohol for 15 min and 0.1% mercuric chloride for 8 min. Seeds with diameter φ 〉 2.0 mm were used as explants and achieved relatively high surviv- al rate of aseptic seedlings, which reached above 65%. [ Conclusion] This study established a surface sterilization method for tissue culture of H. ammodendron ( C. A. Mey. ) Bunge seeds.展开更多
Earthquake early warning (EEW) systems are one of the most effective ways to reduce earthquake disaster. Earthquake magnitude estimation is one of the most important and also the most difficult parts of the entire E...Earthquake early warning (EEW) systems are one of the most effective ways to reduce earthquake disaster. Earthquake magnitude estimation is one of the most important and also the most difficult parts of the entire EEW system. In this paper, based on 142 earthquake events and 253 seismic records that were recorded by the KiK-net in Japan, and aftershocks of the large Wenchuan earthquake in Sichuan, we obtained earthquake magnitude estimation relationships using the τe and Pa methods. The standard variances of magnitude calculation of these two formulas are ±0.65 and ±0.56, respectively. The Pd value can also be used to estimate the peak ground motion of velocity, then warning information can be released to the public rapidly, according to the estimation results. In order to insure the stability and reliability of magnitude estimation results, we propose a compatibility test according to the natures of these two parameters. The reliability of the early warning information is significantly improved though this test.展开更多
Increasing incidences showed that food allergies have attracted more and more attention from researchers.BALB/c mice were sensitized with wheat gluten combined with aluminum hydroxide adjuvant via intraperitoneal inje...Increasing incidences showed that food allergies have attracted more and more attention from researchers.BALB/c mice were sensitized with wheat gluten combined with aluminum hydroxide adjuvant via intraperitoneal injection,transdermal sensitization,and oral gavage sensitization route.Results showed that all the three sensitization methods could induce allergic symptoms;increase the serum antibody(total immunoglobulin E(IgE),specific IgE,IgG,IgA)and histamine content;promote the secretion of Th2 cytokines(interleukin(IL)-4,IL-5,IL-13)and inflammatory factors(IL-6,IL-17 A,IL-10);and inhibit the production of Th1 cytokines(IFN-γ,IL-2).However,the allergic symptoms of mice sensitized by intraperitoneal injection were the most obvious among the three models.The level of serum antibodies in intraperitoneal injection group was significantly higher than control.Subsequently,16 S rRNA sequencing technology was used to analyze the intestinal flora of mice.The results showed that the abundance of Firmicutes in the wheat protein sensitized group was lower than that in the normal group,while the abundance of Bacteroidetes was higher,and Lactobacillus was the difference marker in normal group.Bacterial species diversity analysis showed that the species richness and diversity of intestinal flora in mice were decreased,the difference between mice induced by intraperitoneal injection and normal control group mice was the most significant.Taken together,these results show that among three sensitization methods used to build a mouse model with aluminum hydroxide as adjuvant,intraperitoneal injection is the comparably best way to build a mouse sensitization mode.展开更多
A new method of fabricating C/C composite materials, namely electric heating CVD method, was used, which electrified the carbon fiber directly by using the conductivity of itself. Acetylene was used as the carbon sour...A new method of fabricating C/C composite materials, namely electric heating CVD method, was used, which electrified the carbon fiber directly by using the conductivity of itself. Acetylene was used as the carbon source with nitrogen as dilution gas, and the pyrolytic carbon started to deposit on the carbon fiber surface when the deposition temperature was reached. The morphology of pyrolytic carbon was characterized by SEM, and the surface properties of carbon fibers before and after CVD were characterized by Raman spectroscopy. The experimental results show that the electric heating method is a novel method to fabricate C/C composite materials, which can form a dense C/C composite material in a short time. The order degree and the average crystallite size of the carbon fiber surface were decreased after the experiment.展开更多
The potential energy snrface of a CO2-N2 mixture is determined by using an inversion method, together with a new collision integral correlation [J. Phys. Chem. R@ Data 19 1179 (1990)]. With the new invert potential,...The potential energy snrface of a CO2-N2 mixture is determined by using an inversion method, together with a new collision integral correlation [J. Phys. Chem. R@ Data 19 1179 (1990)]. With the new invert potential, the transport properties of CO2-N2 mixture are presented in a temperature range front 273.15 K to 3273.15 K at low density by employing the Chapman-Enskog scheme and the Wang Chang-Uhlenbeck de Boer theory, consisting of a viscosity coefficient, a thermal conductivity coefficient, a binary diffusion coefficient, and a thermal diffusion factor. The accuracy of the predicted results is estimated to be 2% for viscosity, 5% for thermal conductivity, and 10% for binary diffusion coefficient.展开更多
This paper aims to establish a 3D evaluation method for cutting surface topography of C/C composites. The cutting surface is measured by Talyscan 150, using 3D non-contact measurement. By evaluating 2D and 3D roughnes...This paper aims to establish a 3D evaluation method for cutting surface topography of C/C composites. The cutting surface is measured by Talyscan 150, using 3D non-contact measurement. By evaluating 2D and 3D roughness of C/C composite and Duralumin, the 2D evaluation method of the cutting surface topography of C/C composite loses a lot of information, and the characteristics of the surface topography of C/C composite can be comprehensively and authentically evaluated only by the 3D evaluation method. Furthermore, 3D amplitude and spatial parameters are adopted to evaluate the surface and the results show that: the topography of the C/C composite is anisotropy and there are no obvious feeding textures but abrupt peaks and valleys on surface of the C/C composite, which indicates that the machining mecha- nism is different from that of the metal. In conclusion, The C/C composite surface is evaluated using a 3D evaluation method, the roughness error is small, and the unique topography characteristics earl be au- thentically evaluated.展开更多
A solvothermal assisted ethylene glycol reduction method is a common technology for Pt/C catalysts preparation. Here, the coordination mechanism of the Pt-containing species is deeply studied by innovatively adopting ...A solvothermal assisted ethylene glycol reduction method is a common technology for Pt/C catalysts preparation. Here, the coordination mechanism of the Pt-containing species is deeply studied by innovatively adopting the ultraviolet-visible spectroscopy technology and H+ concentration detector. Moreover, the amount of Na OH that effectively coordinates Pt4+ has been tentatively qualified and the heating parameters during the preparation process of Pt/C have also been optimized. As investigated, the optimized 20-(1/22)-140-2 Pt/C(20 wt%Pt;m(Pt):m(Na OH)=1/22;heating temperature: 140 °C, heating time: 2 h) exhibits higher electrocatalytic activity towards oxygen reduction reaction(ORR) than the commercial 20 wt% Pt/C(E-TEK) in acidic media. This work provides a theoretical reserve and technical accumulation for industrialized mass production of highly efficient Pt/C catalysts for ORR in proton exchange membrane fuel cells.展开更多
Fe-based carbon materials are widely considered promising to replace Pt/C as next-generation electrocatalysts towards oxygen reduction reaction (ORR). However, the preparation of Fe-based carbon materials is still car...Fe-based carbon materials are widely considered promising to replace Pt/C as next-generation electrocatalysts towards oxygen reduction reaction (ORR). However, the preparation of Fe-based carbon materials is still carried out by conventional heating method (CHM). Herein, a novel microwave-assisted carbon bath method (MW-CBM) was proposed, which only took 35 min to synthesize Fe/Fe3C nanoparticles encapsulated in N-doped carbon layers derived from Prussian blue (PB). The catalyst contained large specific surface area and mesoporous structure, abundant Fe-Nx and C–N active sites, unique core-shell structure. Due to the synergistic effects of these features, the as-prepared Fe/Fe3C@NC-2 displayed outstanding ORR activity with onset potential of 0.98 VRHE and halfwave potential of 0.87 VRHE, which were more positive than 20 wt.% Pt/C (0.93 VRHE and 0.82 VRHE). Besides, Fe/Fe3C@NC-2 gave a better stability and methanol tolerance than Pt/C towards ORR in alkaline media, too.展开更多
基金supported by the National Key Research and Development Project (No. 2022YFA1602301)the National Natural Science Foundation of China (Nos. U2267205, 12275361, 12125509, 12222514, 11961141003, and 12005304)+2 种基金the CAST Young Talent Support Planthe CNNC Science Fund for Talented Young Scholarsthe Continuous-Support Basic Scientific Research Project
文摘The ^(12)C+^(12)C fusion is one of the most important reactions in modern nuclear astrophysics.The trend and magnitude of the reaction rate within the Gamow window strongly influence various astrophysical processes.However,direct measurement of this reaction is extremely difficult,which makes it necessary to develop indirect methods.In this study,the ^(23)Na+p reaction system was used to study the compound nucleus ^(24)Mg.We employed a thick-target inverse kinematics method combined with theγ-charged-particle coincidence technique to measure the proton andα exit channels of ^(24)Mg.Technical details of the ^(23)Na+p thick-target inverse kinematics experiment and analysis are presented herein.
文摘In recent times, lithium-ion batteries have been widely used owing to their high energy density, extended cycle lifespan, and minimal self-discharge rate. The design of high-speed rechargeable lithium-ion batteries faces a significant challenge owing to the need to increase average electric power during charging. This challenge results from the direct influence of the power level on the rate of chemical reactions occurring in the battery electrodes. In this study, the Taguchi optimization method was used to enhance the average electric power during the charging process of lithium-ion batteries. The Taguchi technique is a statistical strategy that facilitates the systematic and efficient evaluation of numerous experimental variables. The proposed method involved varying seven input factors, including positive electrode thickness, positive electrode material, positive electrode active material volume fraction, negative electrode active material volume fraction, separator thickness, positive current collector thickness, and negative current collector thickness. Three levels were assigned to each control factor to identify the optimal conditions and maximize the average electric power during charging. Moreover, a variance assessment analysis was conducted to validate the results obtained from the Taguchi analysis. The results revealed that the Taguchi method was an eff ective approach for optimizing the average electric power during the charging of lithium-ion batteries. This indicates that the positive electrode material, followed by the separator thickness and the negative electrode active material volume fraction, was key factors significantly infl uencing the average electric power during the charging of lithium-ion batteries response. The identification of optimal conditions resulted in the improved performance of lithium-ion batteries, extending their potential in various applications. Particularly, lithium-ion batteries with average electric power of 16 W and 17 W during charging were designed and simulated in the range of 0-12000 s using COMSOL Multiphysics software. This study efficiently employs the Taguchi optimization technique to develop lithium-ion batteries capable of storing a predetermined average electric power during the charging phase. Therefore, this method enables the battery to achieve complete charging within a specific timeframe tailored to a specificapplication. The implementation of this method can save costs, time, and materials compared with other alternative methods, such as the trial-and-error approach.
基金Project (0991025) supported by Natural Science Foundation of Guangxi, ChinaProject (51164007) supported by the National Natural Science Foundation of ChinaProject (201101ZD008) supported by Educational Commission of Guangxi, China
文摘The LiMnPO4/C composite material was synthesized via a sol-gel method based on the citric acid. The X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical performance tests were adopted to characterize the properties of LiMnPO4/C. The XRD studies show that the pure olivine phase LiMnPO4 can be obtained at a low temperature of 500 °C. The SEM analyses illustrate that the citric acid used as the chelating reagent and carbon source can restrain the particle size of LiMnPO4/C well. The LiMnPO4/C sample synthesized at 500 °C for 10 h performs the highest initial discharge capacity of 122.6 mA-h/g, retaining 112.4 mA-h/g over 30 cycles at 0.05C rate. The citric acid based sol-gel method is favor to obtain the high electrochemical performance of LiMnPO4/C.
基金Project supported by Ministry of Education Key Laboratory of Synthetic and Natural Functional Molecular Chemistry, China Project (2010JK765) supported by the Education Department of Shaanxi Province, China
文摘Nanosphere-like Li2FeSiO4/C was synthesized via a solution method using sucrose as carbon sources under a mild condition of time-saving and energy-saving, followed by sintering at high temperatures for crystallization. The amount of carbon in the composite is less than 10% (mass fraction), and the X-ray diffraction result confirms that the sample is of pure single phase indexed with the orthorhombic Pmn21 space group. The particle size of the Li2FeSiO4/C synthesized at 700 °C for 9 h is very fine and spherical-like with a size of 200 nm. The electrochemical performance of this material, including reversible capacity, cycle number, and charge-discharge characteristics, were tested. The cell of this sample can deliver a discharge capacity of 166 mA-h/g at C/20 rate in the first three cycles. After 30 cycles, the capacity decreases to 158 mA-h/g, and the capacity retention is up to 95%. The results show that this method can prepare nanosphere-like Li2FeSiO4/C composite with good electrochemical performance.
基金This project was supported by the Evaluate Quality of Satellite TT&C Mission(C0112)
文摘The fuzzy integration evaluation method (FIEM) is studied in order to select the best orbital elements from the multi-group initial orbits determined by a satellite TT&C (Tracking, Telemetry and Control) center with all kinds of data sources. By employing FIEM together with the experience of TT&C experts, the index system to evaluate the selection of the best initial orbits is established after the data sources and orbit determination theories are studied. Besides, the concrete steps in employing the method are presented. Moreover, by taking the objects to be evaluated as evaluation experts, the problem of how to generate evaluation matrices is solved. Through practical application, the method to select the best initial orbital elements has been proved to be flexible and effective The originality of the method is to find a new evaluation criterion (comparing the actually tracked orbits) replacing the traditional one (comparing the nominal orbits) for selecting the best orbital elements.
基金Funded by the National Natural Science Foundation of China(No.50875036)
文摘3D evaluation method of cutting surface topography for C/Ph composites was established.The cutting surface was measured by Talyscan 150,using 3D non-contact measurement.Through the results of 2D and 3D roughness evaluating for C/Ph composite and Duralumin,the 2D evaluation method of the cutting surface topography of C/Ph composite loses a lot of information,the characteristics of the surface topography of C/Ph composite can be comprehensively and authentically evaluated only by 3D evaluation method.Furthermore,3D amplitude and spatial parameters were adopted to evaluate the surface.The results show that: the topography of the C/Ph composite is anisotropic,there are more valleys in the machined surface of C/Ph than that of duralumin,and there are not obvious feeding textures for C/Ph,which indicates the machining mechanism is different from the metal.In conclusion,the topography of the C/Ph composite cutting surface is anisotropic;the cutting surface of C/Ph composite needs 3D evaluation method.
基金Supported by the National 973project(No.G2 0 0 0 0 2 6 4 10 ) and Inovation Funds of Dalian Insitute of Chem icalPhysics
文摘The electrocatalysts of Pt/C, PtRu/C and Ru/C were prepared by the impregnation method. The facet characterization, the dispersion and the particle size for the catalysts were determined by means of X ray diffraction and transmission electron microscopy. X ray photoelectron spectroscopy was also used to analyze the state and the valency of the noble metals. The results show that the particle size was in nanometer range and the binary metals have come into being an alloy. The platinum in the catalysts existed in zero valency. The valency of the ruthenium on the surface is different from that in the body, while the ruthenium on the surface existed in oxide form. PtRu/C and Pt/C are of good activity to the electrooxidation of hydrogen except Ru/C. PtRu/C is more tolerant of CO than Pt/C, and CO is only adsorbed on Pt.
基金National Natural Science Foundation of China(No.20606023)National Key Natural Science Foundation of China(No.20490203)
文摘Effects of cooling methods on stability and methane conversion rate using dielectric-barrier discharges (DBD) were systematically investigated in this article. The results showed that the methane conversion rate was as high as 44.43% in a pure methane system at a flow rate of 100 mL·min^-1 and an input power of 234.2 W with air cooling. A dark greenish and soft film-like carbon was deposited on the outer surface of quartz tube when the outer electrode was watercooled, which decreased the methane conversion. With air cooling of inner electrode the selectivity of C2 hydrocarbons was higher than that with other cooling methods, while the C3 hydrocarbons had higher selectivity with flowing water cooling. Cooling the inner electrode could restrain the carbon deposition, but would decrease the methane conversion rate. The stability of both reaction and plasma operation can be improved through cooling the reactor. From thermodynamic analysis, it was found that the effective collisions frequency among the reactant molecules and free electrons (e^-) increased with temperature, which in turn led to a higher methane conversion rate and a change in the distribution of products.
基金Supported by the National Natural Science Foundation of China(21706282,21276137,61273039,61673236)Science Foundation of China University of Petroleum,Beijing(No.2462017YJRC028)the National High-tech 863 Program of China(2013AA 040702)
文摘Refinery scheduling attracts increasing concerns in both academic and industrial communities in recent years.However, due to the complexity of refinery processes, little has been reported for success use in real world refineries. In academic studies, refinery scheduling is usually treated as an integrated, large-scale optimization problem,though such complex optimization problems are extremely difficult to solve. In this paper, we proposed a way to exploit the prior knowledge existing in refineries, and developed a decision making system to guide the scheduling process. For a real world fuel oil oriented refinery, ten adjusting process scales are predetermined. A C4.5 decision tree works based on the finished oil demand plan to classify the corresponding category(i.e. adjusting scale). Then,a specific sub-scheduling problem with respect to the determined adjusting scale is solved. The proposed strategy is demonstrated with a scheduling case originated from a real world refinery.
基金Supported by Open Project of Key Laboratory of Tarim Animal Husbandry Science and Technology from Xinjiang Production & Construction Crops(HS20901)
文摘[ Objective ] The aim was to select appropriate sterilization methods and explants for tissue culture of Haloxylon ammodendron ( C. A. Mey. ). [Method] H. ammodendron (C. A. Mey. ) seeds were used as experimental materials to investigate the sterilization results of different sterilization treatments and the effect of different seed sizes on the survival rate of aseptic seedlings. [ Result] Sterilization of H. ammodendron ( C.A. Mey. ) seeds achieved the best result by using 75% alcohol for 15 min and 0.1% mercuric chloride for 8 min. Seeds with diameter φ 〉 2.0 mm were used as explants and achieved relatively high surviv- al rate of aseptic seedlings, which reached above 65%. [ Conclusion] This study established a surface sterilization method for tissue culture of H. ammodendron ( C. A. Mey. ) Bunge seeds.
文摘Earthquake early warning (EEW) systems are one of the most effective ways to reduce earthquake disaster. Earthquake magnitude estimation is one of the most important and also the most difficult parts of the entire EEW system. In this paper, based on 142 earthquake events and 253 seismic records that were recorded by the KiK-net in Japan, and aftershocks of the large Wenchuan earthquake in Sichuan, we obtained earthquake magnitude estimation relationships using the τe and Pa methods. The standard variances of magnitude calculation of these two formulas are ±0.65 and ±0.56, respectively. The Pd value can also be used to estimate the peak ground motion of velocity, then warning information can be released to the public rapidly, according to the estimation results. In order to insure the stability and reliability of magnitude estimation results, we propose a compatibility test according to the natures of these two parameters. The reliability of the early warning information is significantly improved though this test.
基金supported by the National Key Research and Development Program of China(2019YFC1605000)the National Natural Science Foundation(1872904)。
文摘Increasing incidences showed that food allergies have attracted more and more attention from researchers.BALB/c mice were sensitized with wheat gluten combined with aluminum hydroxide adjuvant via intraperitoneal injection,transdermal sensitization,and oral gavage sensitization route.Results showed that all the three sensitization methods could induce allergic symptoms;increase the serum antibody(total immunoglobulin E(IgE),specific IgE,IgG,IgA)and histamine content;promote the secretion of Th2 cytokines(interleukin(IL)-4,IL-5,IL-13)and inflammatory factors(IL-6,IL-17 A,IL-10);and inhibit the production of Th1 cytokines(IFN-γ,IL-2).However,the allergic symptoms of mice sensitized by intraperitoneal injection were the most obvious among the three models.The level of serum antibodies in intraperitoneal injection group was significantly higher than control.Subsequently,16 S rRNA sequencing technology was used to analyze the intestinal flora of mice.The results showed that the abundance of Firmicutes in the wheat protein sensitized group was lower than that in the normal group,while the abundance of Bacteroidetes was higher,and Lactobacillus was the difference marker in normal group.Bacterial species diversity analysis showed that the species richness and diversity of intestinal flora in mice were decreased,the difference between mice induced by intraperitoneal injection and normal control group mice was the most significant.Taken together,these results show that among three sensitization methods used to build a mouse model with aluminum hydroxide as adjuvant,intraperitoneal injection is the comparably best way to build a mouse sensitization mode.
基金Funded by the National Natural Science Foundation of China(51165006)
文摘A new method of fabricating C/C composite materials, namely electric heating CVD method, was used, which electrified the carbon fiber directly by using the conductivity of itself. Acetylene was used as the carbon source with nitrogen as dilution gas, and the pyrolytic carbon started to deposit on the carbon fiber surface when the deposition temperature was reached. The morphology of pyrolytic carbon was characterized by SEM, and the surface properties of carbon fibers before and after CVD were characterized by Raman spectroscopy. The experimental results show that the electric heating method is a novel method to fabricate C/C composite materials, which can form a dense C/C composite material in a short time. The order degree and the average crystallite size of the carbon fiber surface were decreased after the experiment.
基金supported by the National Natural Science Foundation of China (Grant No. 51006083)the China Postdoctoral Science Foundation (Grant No. 20110491658)the Fundamental Research Funds for the Central Universities
文摘The potential energy snrface of a CO2-N2 mixture is determined by using an inversion method, together with a new collision integral correlation [J. Phys. Chem. R@ Data 19 1179 (1990)]. With the new invert potential, the transport properties of CO2-N2 mixture are presented in a temperature range front 273.15 K to 3273.15 K at low density by employing the Chapman-Enskog scheme and the Wang Chang-Uhlenbeck de Boer theory, consisting of a viscosity coefficient, a thermal conductivity coefficient, a binary diffusion coefficient, and a thermal diffusion factor. The accuracy of the predicted results is estimated to be 2% for viscosity, 5% for thermal conductivity, and 10% for binary diffusion coefficient.
基金Supported by the National Natural Science Foundation of China (No. 50875036)
文摘This paper aims to establish a 3D evaluation method for cutting surface topography of C/C composites. The cutting surface is measured by Talyscan 150, using 3D non-contact measurement. By evaluating 2D and 3D roughness of C/C composite and Duralumin, the 2D evaluation method of the cutting surface topography of C/C composite loses a lot of information, and the characteristics of the surface topography of C/C composite can be comprehensively and authentically evaluated only by the 3D evaluation method. Furthermore, 3D amplitude and spatial parameters are adopted to evaluate the surface and the results show that: the topography of the C/C composite is anisotropy and there are no obvious feeding textures but abrupt peaks and valleys on surface of the C/C composite, which indicates that the machining mecha- nism is different from that of the metal. In conclusion, The C/C composite surface is evaluated using a 3D evaluation method, the roughness error is small, and the unique topography characteristics earl be au- thentically evaluated.
文摘A solvothermal assisted ethylene glycol reduction method is a common technology for Pt/C catalysts preparation. Here, the coordination mechanism of the Pt-containing species is deeply studied by innovatively adopting the ultraviolet-visible spectroscopy technology and H+ concentration detector. Moreover, the amount of Na OH that effectively coordinates Pt4+ has been tentatively qualified and the heating parameters during the preparation process of Pt/C have also been optimized. As investigated, the optimized 20-(1/22)-140-2 Pt/C(20 wt%Pt;m(Pt):m(Na OH)=1/22;heating temperature: 140 °C, heating time: 2 h) exhibits higher electrocatalytic activity towards oxygen reduction reaction(ORR) than the commercial 20 wt% Pt/C(E-TEK) in acidic media. This work provides a theoretical reserve and technical accumulation for industrialized mass production of highly efficient Pt/C catalysts for ORR in proton exchange membrane fuel cells.
基金supported by the National Natural Science Foundation of China (U1303291)the Program for Changjiang Scholars and Innovative Research Team in University (No. IRT_15R46)
文摘Fe-based carbon materials are widely considered promising to replace Pt/C as next-generation electrocatalysts towards oxygen reduction reaction (ORR). However, the preparation of Fe-based carbon materials is still carried out by conventional heating method (CHM). Herein, a novel microwave-assisted carbon bath method (MW-CBM) was proposed, which only took 35 min to synthesize Fe/Fe3C nanoparticles encapsulated in N-doped carbon layers derived from Prussian blue (PB). The catalyst contained large specific surface area and mesoporous structure, abundant Fe-Nx and C–N active sites, unique core-shell structure. Due to the synergistic effects of these features, the as-prepared Fe/Fe3C@NC-2 displayed outstanding ORR activity with onset potential of 0.98 VRHE and halfwave potential of 0.87 VRHE, which were more positive than 20 wt.% Pt/C (0.93 VRHE and 0.82 VRHE). Besides, Fe/Fe3C@NC-2 gave a better stability and methanol tolerance than Pt/C towards ORR in alkaline media, too.