Microperoxidase 11(MP 11) was immobilized on the surface of a silanized glass carbon electrode by means of the covalent bond with glutaraldehyde. The measurements of cyclic voltammetry demonstrated that the formal r...Microperoxidase 11(MP 11) was immobilized on the surface of a silanized glass carbon electrode by means of the covalent bond with glutaraldehyde. The measurements of cyclic voltammetry demonstrated that the formal redox potential of immobilized MP 11 was -170 mV, which is significantly more positive than that of MP 11 in a solution or immobilized on the surface of electrodes prepared with other methods. This MP 11 modified electrode showed a good electrocatalytic activity and stability for the reduction of oxygen and hydrogen peroxide.展开更多
This paper presents a combined control and modulation technique to enhance the power quality(PQ)and power reliability(PR)of a hybrid energy system(HES)through a single-phase 11-level cascaded H-bridge inverter(11-CHBI...This paper presents a combined control and modulation technique to enhance the power quality(PQ)and power reliability(PR)of a hybrid energy system(HES)through a single-phase 11-level cascaded H-bridge inverter(11-CHBI).The controller and inverter specifically regulate the HES and meet the load demand.To track optimum power,a Modified Perturb and Observe(MP&O)technique is used for HES.Ultra-capacitor(UCAP)based energy storage device and a novel current control strategy are proposed to provide additional active power support during both voltage sag and swell conditions.For an improved PQ and PR,a two-way current control strategy such as the main controller(MC)and auxiliary controller(AC)is suggested for the 11-CHBI operation.MC is used to regulate the active current component through the fuzzy controller(FC),and AC is used to regulate the dc-link voltage of CHBI through a neural network-based PI controller(ANN-PI).By tracking the reference signals fromMC and AC,a novel hybrid pulse widthmodulation(HPWM)technique is proposed for the 11-CHBI operation.To justify and analyze the MATLAB/Simulink software-based designed model,the robust controller performance is tested through numerous steady-state and dynamic state case studies.展开更多
Surface reactable modified silver nanoparticles were prepared by NaBH4 reduced silver ion in the aquenous solvent, in the presence of the double group modifying agent, O,O′-di(11-bromic undecane)dithiophosphonic acid...Surface reactable modified silver nanoparticles were prepared by NaBH4 reduced silver ion in the aquenous solvent, in the presence of the double group modifying agent, O,O′-di(11-bromic undecane)dithiophosphonic acid. The morphology and structure of the product were characterized using Transmission Electron Microscope(TEM), UV-Visible Absorption(UV-Vis) spectra, Fourier Transform Infrared(FTIR) spectra. The result indicate that the products are spherical shape and no aggregation, C-Br functional groups are on the outermost portion of the silver nanoparticles. The nanoparticles were well dispersed in organic solution, such as chloroform, petroleum ether, toluene etc. The analysis of the sample which reacted with trimethylamine by X-ray photoelectron spectra(XPS) shows the silver nanoparticles can undergo many reactions.展开更多
To synthesize a series of 3-, 4-, and/or 11-trihydroxy modified bergenin derivatives and evaluated their cytotoxic activity in vitro. The phenolic hydroxyl groups of bergenin were protected by benzyl groups with benzy...To synthesize a series of 3-, 4-, and/or 11-trihydroxy modified bergenin derivatives and evaluated their cytotoxic activity in vitro. The phenolic hydroxyl groups of bergenin were protected by benzyl groups with benzyl bromide. Treatment of dibenzyl bergenin with the corresponding acid in the presence of EDC·HCl and DMAP in CH2Cl2, followed by hydrogenation over Pd/C catalysts, afforded derivatives of bergenin esters. All of the target compounds were identified by IR, MS, and 1H NMR. Twenty-six novel and three known derivatives of bergenin esters were synthesized. Their cytotoxicity values were evaluated by the MTT assay on the inhibition of DU-145 and BGC-823 cells in vitro. Several triply-substituted(3a, 4a, 5a, 6a, 7a) and doublysubstituted(8b, 9b) bergenin derivatives exhibited higher cytotoxic activity than bergenin. The result showed that the size of substituents and the lipophilicity of the bergenin esters displayed an important role on their cytotoxic activity.展开更多
基金Supported by"973" Project(No. G2 0 0 0 0 2 6 4 0 8) the National Natural Science Foundation of China(No.2 99730 15 ) the Natural Science Foundation of Heilongjiang Province(B2 0 0 0 - 0 6 ) and the Natural Science Foundation of Eduction Comm it-
文摘Microperoxidase 11(MP 11) was immobilized on the surface of a silanized glass carbon electrode by means of the covalent bond with glutaraldehyde. The measurements of cyclic voltammetry demonstrated that the formal redox potential of immobilized MP 11 was -170 mV, which is significantly more positive than that of MP 11 in a solution or immobilized on the surface of electrodes prepared with other methods. This MP 11 modified electrode showed a good electrocatalytic activity and stability for the reduction of oxygen and hydrogen peroxide.
基金Assistance provided by Council of scientific and industrial research(CSIR),Government of India,under the acknowledgment number 143460/2K19/1(File:09/969(0013)/2020-EMR-I)and Siksha O Anusandhan(Deemed to be University).
文摘This paper presents a combined control and modulation technique to enhance the power quality(PQ)and power reliability(PR)of a hybrid energy system(HES)through a single-phase 11-level cascaded H-bridge inverter(11-CHBI).The controller and inverter specifically regulate the HES and meet the load demand.To track optimum power,a Modified Perturb and Observe(MP&O)technique is used for HES.Ultra-capacitor(UCAP)based energy storage device and a novel current control strategy are proposed to provide additional active power support during both voltage sag and swell conditions.For an improved PQ and PR,a two-way current control strategy such as the main controller(MC)and auxiliary controller(AC)is suggested for the 11-CHBI operation.MC is used to regulate the active current component through the fuzzy controller(FC),and AC is used to regulate the dc-link voltage of CHBI through a neural network-based PI controller(ANN-PI).By tracking the reference signals fromMC and AC,a novel hybrid pulse widthmodulation(HPWM)technique is proposed for the 11-CHBI operation.To justify and analyze the MATLAB/Simulink software-based designed model,the robust controller performance is tested through numerous steady-state and dynamic state case studies.
文摘Surface reactable modified silver nanoparticles were prepared by NaBH4 reduced silver ion in the aquenous solvent, in the presence of the double group modifying agent, O,O′-di(11-bromic undecane)dithiophosphonic acid. The morphology and structure of the product were characterized using Transmission Electron Microscope(TEM), UV-Visible Absorption(UV-Vis) spectra, Fourier Transform Infrared(FTIR) spectra. The result indicate that the products are spherical shape and no aggregation, C-Br functional groups are on the outermost portion of the silver nanoparticles. The nanoparticles were well dispersed in organic solution, such as chloroform, petroleum ether, toluene etc. The analysis of the sample which reacted with trimethylamine by X-ray photoelectron spectra(XPS) shows the silver nanoparticles can undergo many reactions.
基金supported by the Natural Science Foundation of China(Nos.81274064 and 81373956)the National Fund for Fostering Talents of Basic Science(NFFTBS)(No.J1030830)the Science and Technology Supporting Project of Xinjiang(No.201291160)
文摘To synthesize a series of 3-, 4-, and/or 11-trihydroxy modified bergenin derivatives and evaluated their cytotoxic activity in vitro. The phenolic hydroxyl groups of bergenin were protected by benzyl groups with benzyl bromide. Treatment of dibenzyl bergenin with the corresponding acid in the presence of EDC·HCl and DMAP in CH2Cl2, followed by hydrogenation over Pd/C catalysts, afforded derivatives of bergenin esters. All of the target compounds were identified by IR, MS, and 1H NMR. Twenty-six novel and three known derivatives of bergenin esters were synthesized. Their cytotoxicity values were evaluated by the MTT assay on the inhibition of DU-145 and BGC-823 cells in vitro. Several triply-substituted(3a, 4a, 5a, 6a, 7a) and doublysubstituted(8b, 9b) bergenin derivatives exhibited higher cytotoxic activity than bergenin. The result showed that the size of substituents and the lipophilicity of the bergenin esters displayed an important role on their cytotoxic activity.
