We describe a janusarene derivative PyJ,which forms micrometer-scale one-dimensional metallo-supramolecular polymer through coordination driven self-assembly.PyJ is a well-preorganized dodecatopic pyridyl ligand built...We describe a janusarene derivative PyJ,which forms micrometer-scale one-dimensional metallo-supramolecular polymer through coordination driven self-assembly.PyJ is a well-preorganized dodecatopic pyridyl ligand built on a hexaphenylbenzene platform.The two-face structural feature of PyJ allows for a delicate control over multiple Py-Ag^(+)-Py coordination interactions,leading to assembled structure of PyJ-Ag^(+),which was characterized by dynamic light scattering,atomic force microscopy,and transmission electron microscopy.展开更多
基金supported by the National Natural Science Foundation of China(Nos.21871298,91956118)the Sun Yat-sen University。
文摘We describe a janusarene derivative PyJ,which forms micrometer-scale one-dimensional metallo-supramolecular polymer through coordination driven self-assembly.PyJ is a well-preorganized dodecatopic pyridyl ligand built on a hexaphenylbenzene platform.The two-face structural feature of PyJ allows for a delicate control over multiple Py-Ag^(+)-Py coordination interactions,leading to assembled structure of PyJ-Ag^(+),which was characterized by dynamic light scattering,atomic force microscopy,and transmission electron microscopy.
