Photocatalytic discoloration kinetics of Reactive Black 5 (RB5), a vinylsulfone dye, has been studied spectrophotometrically by following the decrease in dye concentration with time at ambient conditions using a flow ...Photocatalytic discoloration kinetics of Reactive Black 5 (RB5), a vinylsulfone dye, has been studied spectrophotometrically by following the decrease in dye concentration with time at ambient conditions using a flow loop reactor. UV lump, Black Light Blue (BLB) emitting at maximum wavelength of 365 nm and Ahlstrom Research Service paper consistent of TiO2 P500 coated on non woven paper was used respectively as source of UV light and photocatalyst. At natural pH, the result shows that photolysis of RB5 and its adsorption in the presence of photocatalyst was negligible while the photocatalytic oxidation (PCO) permits 30.8% of RB5 degradation. The degradation of dye was studied under a variety of conditions such as volumetric flow rate, initial pH, photocatalyst reuse, and in the presence of electron acceptor such as sodium persulphate ((Na)2S2O8). The degradation rates were found to be strongly influenced by all the above parameters. The circulation flow rate of 108 L/h was the best. The rate constant calculated when the initial pH was varied shows that pH 3 was more favorable for RB5 removal. Peroxydisulphate ions have the strong effect on RB5 discoloration even in dark without and with photocatalyst. When UV light was used in the presence of photocatalyst, 50 min was enough for quasi-total removal of RB5 with (0.2 M).展开更多
Two induction magnetometers have been installed at Chinese Zhongshan Station and Australia Davis Station, Antarctica respectively. We adopt the cross spectral analysis technique to analyze the data of the two inducti...Two induction magnetometers have been installed at Chinese Zhongshan Station and Australia Davis Station, Antarctica respectively. We adopt the cross spectral analysis technique to analyze the data of the two induction magnetometers, in June, September, December 1996 and March 1997, and to investigate Pc5 frequency range pulsation (150 600 s) occurrence and propagation in cusp latitude. The results are summarized as follows: At Zhongshan Davis Station, the magnetic pulsations in Pc5 frequency band can occurs over a wide time, but more frequently at pre local magnetic noon and pre local magnetic midnight. The Pc5 pulsations have no significant seasonal variation in the amplitude, occurrence and propagation. The amplitude has a small peak at pre local magnetic noon and large value sometimes at pre local magnetic midnight. In daytime, the Pc5 pulsations propagate westward in morning and eastward in afternoon, and reversal at local magnetic noon. In nighttime, the Pc5 pulsations propagate westward before 20:00 MLT and eastward after 20:00 MLT. Near dusk time, the Pc5 pulsations propagate irregularly. These characteristics indicate that the Pc5 pulsations have different source at different local magnetic time.展开更多
为了降低车联网(Long Term Evolution-Vehicle to Everything,LTE-V)终端间的相互干扰并提升通信的可靠性,提出通过资源分配和拥塞控制来解决资源碰撞的问题。依据信道忙率(Channel Busy Ratio,CBR)划分拥塞等级,融合资源分配与拥塞控...为了降低车联网(Long Term Evolution-Vehicle to Everything,LTE-V)终端间的相互干扰并提升通信的可靠性,提出通过资源分配和拥塞控制来解决资源碰撞的问题。依据信道忙率(Channel Busy Ratio,CBR)划分拥塞等级,融合资源分配与拥塞控制提出相应的方案,形成资源碰撞避免机制。为了减少重选资源时发生的碰撞,提出了资源重选竞争退避机制以降低重选带来的不确定性;针对拥塞导致的碰撞,改变调制编码策略从而优化资源占用。仿真结果表明,与标准中基于感知的半持续调度(Semi-persistent Scheduling,SPS)相比,所提出的机制在传输距离为300 m时可以实现0.85以上的数据包投递率,有效减少资源碰撞,提升传输可靠性。展开更多
Nomadic Vehicular Cloud(NVC)is envisaged in this work.The predo-minant aspects of NVC is,it moves along with the vehicle that initiates it and functions only with the resources of moving vehicles on the heavy traffic ...Nomadic Vehicular Cloud(NVC)is envisaged in this work.The predo-minant aspects of NVC is,it moves along with the vehicle that initiates it and functions only with the resources of moving vehicles on the heavy traffic road without relying on any of the static infrastructure and NVC decides the initiation time of container migration using cell transmission model(CTM).Containers are used in the place of Virtual Machines(VM),as containers’features are very apt to NVC’s dynamic environment.The specifications of 5G NR V2X PC5 interface are applied to NVC,for the feature of not relying on the network coverage.Nowa-days,the peak traffic on the road and the bottlenecks due to it are inevitable,which are seen here as the benefits for VC in terms of resource availability and residual in-network time.The speed range of high-end vehicles poses the issue of dis-connectivity among VC participants,that results the container migration failure.As the entire VC participants are on the move,to maintain proximity of the containers hosted by them,estimating their movements plays a vital role.To infer the vehicle movements on the road stretch and initiate the container migration prior enough to avoid the migration failure due to vehicles dynamicity,this paper proposes to apply the CTM to the container based and 5G NR V2X enabled NVC.The simulation results show that there is a significant increase in the success rate of vehicular cloud in terms of successful container migrations.展开更多
文摘Photocatalytic discoloration kinetics of Reactive Black 5 (RB5), a vinylsulfone dye, has been studied spectrophotometrically by following the decrease in dye concentration with time at ambient conditions using a flow loop reactor. UV lump, Black Light Blue (BLB) emitting at maximum wavelength of 365 nm and Ahlstrom Research Service paper consistent of TiO2 P500 coated on non woven paper was used respectively as source of UV light and photocatalyst. At natural pH, the result shows that photolysis of RB5 and its adsorption in the presence of photocatalyst was negligible while the photocatalytic oxidation (PCO) permits 30.8% of RB5 degradation. The degradation of dye was studied under a variety of conditions such as volumetric flow rate, initial pH, photocatalyst reuse, and in the presence of electron acceptor such as sodium persulphate ((Na)2S2O8). The degradation rates were found to be strongly influenced by all the above parameters. The circulation flow rate of 108 L/h was the best. The rate constant calculated when the initial pH was varied shows that pH 3 was more favorable for RB5 removal. Peroxydisulphate ions have the strong effect on RB5 discoloration even in dark without and with photocatalyst. When UV light was used in the presence of photocatalyst, 50 min was enough for quasi-total removal of RB5 with (0.2 M).
文摘Two induction magnetometers have been installed at Chinese Zhongshan Station and Australia Davis Station, Antarctica respectively. We adopt the cross spectral analysis technique to analyze the data of the two induction magnetometers, in June, September, December 1996 and March 1997, and to investigate Pc5 frequency range pulsation (150 600 s) occurrence and propagation in cusp latitude. The results are summarized as follows: At Zhongshan Davis Station, the magnetic pulsations in Pc5 frequency band can occurs over a wide time, but more frequently at pre local magnetic noon and pre local magnetic midnight. The Pc5 pulsations have no significant seasonal variation in the amplitude, occurrence and propagation. The amplitude has a small peak at pre local magnetic noon and large value sometimes at pre local magnetic midnight. In daytime, the Pc5 pulsations propagate westward in morning and eastward in afternoon, and reversal at local magnetic noon. In nighttime, the Pc5 pulsations propagate westward before 20:00 MLT and eastward after 20:00 MLT. Near dusk time, the Pc5 pulsations propagate irregularly. These characteristics indicate that the Pc5 pulsations have different source at different local magnetic time.
文摘为了降低车联网(Long Term Evolution-Vehicle to Everything,LTE-V)终端间的相互干扰并提升通信的可靠性,提出通过资源分配和拥塞控制来解决资源碰撞的问题。依据信道忙率(Channel Busy Ratio,CBR)划分拥塞等级,融合资源分配与拥塞控制提出相应的方案,形成资源碰撞避免机制。为了减少重选资源时发生的碰撞,提出了资源重选竞争退避机制以降低重选带来的不确定性;针对拥塞导致的碰撞,改变调制编码策略从而优化资源占用。仿真结果表明,与标准中基于感知的半持续调度(Semi-persistent Scheduling,SPS)相比,所提出的机制在传输距离为300 m时可以实现0.85以上的数据包投递率,有效减少资源碰撞,提升传输可靠性。
文摘Nomadic Vehicular Cloud(NVC)is envisaged in this work.The predo-minant aspects of NVC is,it moves along with the vehicle that initiates it and functions only with the resources of moving vehicles on the heavy traffic road without relying on any of the static infrastructure and NVC decides the initiation time of container migration using cell transmission model(CTM).Containers are used in the place of Virtual Machines(VM),as containers’features are very apt to NVC’s dynamic environment.The specifications of 5G NR V2X PC5 interface are applied to NVC,for the feature of not relying on the network coverage.Nowa-days,the peak traffic on the road and the bottlenecks due to it are inevitable,which are seen here as the benefits for VC in terms of resource availability and residual in-network time.The speed range of high-end vehicles poses the issue of dis-connectivity among VC participants,that results the container migration failure.As the entire VC participants are on the move,to maintain proximity of the containers hosted by them,estimating their movements plays a vital role.To infer the vehicle movements on the road stretch and initiate the container migration prior enough to avoid the migration failure due to vehicles dynamicity,this paper proposes to apply the CTM to the container based and 5G NR V2X enabled NVC.The simulation results show that there is a significant increase in the success rate of vehicular cloud in terms of successful container migrations.
