Exploring the potential of olivine-containing copper-nickel slag for carbon dioxide mineralization in cementitious materials

Water-quenched copper-nickel metallurgical slag enriched with olivine minerals exhibits promising potential for the production of CO_(2)-mineralized cementitious materials.In this work,copper-nickel slag-based cementitious material(CNCM)was synthesized by using different chemical activation methods to enhance its hydration reactivity and CO_(2) mineralization capacity.Different water curing ages and carbonation conditions were explored related to their carbonation and mechanical properties development.Meanwhile,thermogravimetry differential scanning calorimetry and X-ray diffraction methods were applied to evaluate the CO_(2) adsorption amount and carbonation products of CNCM.Microstructure development of carbonated CNCM blocks was examined by backscattered electron imaging(BSE)with energy-dispersive X-ray spectrometry.Results showed that among the studied samples,the CNCM sample that was subjected to water curing for 3 d exhibited the highest CO_(2) sequestration amount of 8.51wt%at 80℃and 72 h while presenting the compressive strength of 39.07 MPa.This result indicated that 1 t of this CNCM can sequester 85.1 kg of CO_(2) and exhibit high compressive strength.Although the addition of citric acid did not improve strength development,it was beneficial to increase the CO_(2) diffusion and adsorption amount under the same carbonation conditions from BSE results.This work provides guidance for synthesizing CO_(2)-mineralized cementitious materials using large amounts of metallurgical slags containing olivine minerals.

GEOCHEMICAL CHARACTERISTICS OF PLATINUM GROUP ELEMENTS IN JINCHUAN SUPER-LARGE SULFIDE COPPER-NICKEL DEPOSIT, JINCHANG CITY, GANSU PROVINCE, CHINA

The platinum-group element geochemistry of rocks and ores from Jinchuan super-large copper-nickel sulfide deposit is systemically studied in this paper. The Cu/Pd mean ratio of Jinchuan intrusion is lower than that of original mantle magma, which indicates that these ultrabasic rocks were crystallized from magma that lost Pd in the form of melting segregation of sulfides. The PGE of the rocks show trend of partial melting, similar to that of mantle peridotite, which shows that magma formation occurs during rock-forming and ore-forming processes. The chondrite normalized PGE patterns of the rocks and ores are well related to each other, which signifies the signatures of multi-episode magmatic intrusion, melting and differentiation in the formation processes of rocks and ores. In addition, analyses about the relation between PGE and S, and study on Re-Os isotopes indicate that few contamination of the crustal substances occurred during the magmatic intrusion and the formation of deposit. However, contamination by crustal substances helps to supply part of the S for the enrichment of PGE. Meanwhile, the hydrothermal process is also advantageous for the enrichment of PGE, especially lbr Pt and Pd, due to deep melting segregation. The characteristic parameters （such as Pt/（Pt＋Pd）, （Pt＋Pd）/（Ru＋Ir＋Os）, Pd/Ir, Cu/（Ni＋Cu）, and so on.） for platinum-group elements for Jinchuan sulfide copper-nickel deposit show the same features as those for sulfide copper-nickel deposit related to basic magma, which also illustrates its original magma property representative of Mg-high tholeiite. Therefore, it is the marie （not ultramafic） magma that resulted in the formation of the superlarge sulfide copper-nickel deposit enriched in Cu and PGE. To sum up, the geochemical characteristics of platinum-group elements in rocks and ores from Jinchuan copper-nickel sulfide deposit are constrained by the continental rift tectonic environment, the parent magma features, the enriched mantel magma source, the complex metallogenesis and PGE geochemical signatures, and this would be rather significant for the study about the genetic mechanism of copper-nickel sulfide deposits.

Corrosion behavior of B10 copper-nickel alloy beneath a deposit caused by sulfate-reducing bacteria with carbon source starvation in marine environments

Copper-nickel alloys can suffer severe localized corrosion in marine environments containing sulfate-reducing bacteria(SRB),but the effect of SRB on the under-deposit corrosion of copper-nickel alloys is unknown.In this work,the corrosion behavior of B10 copper-nickel alloy beneath a deposit caused by SRB with carbon source starvation in artificial seawater was studied based on electrochemical measurements and surface analysis.Results demonstrate that SRB with an organic carbon starvation can survive in artificial water but most SRB cells have died.The survived SRB cells can attach to the bare and deposit-covered B10 copper-nickel alloy,leading to the corrosion acceleration.Due to the limitation of organic carbon source,the pitting corrosion of B10 copper-nickel alloy caused by SRB is not serious.However,serious pitting corrosion of the deposit-covered B10 copper-nickel alloy can be found both in abiotic and biotic conditions,and the pitting corrosion and uniform corrosion are further accelerated by SRB.There is a galvanic effect between the bare and deposit-covered specimens in the presence of SRB in the early stage but the galvanic effect after 5 d of testing can be neglected due to the low OCP difference values.

Acute Toxicity of Jinchuan Formula Plum Wine Extract and Its Protective Effect on Mice with Liver Injury

[Objectives]To investigate the acute toxicity and hepatoprotective effect of Jinchuan formula plum wine extract on mice,determine its safety range,and evaluate its hepatoprotective effect.[Methods]The median lethal dose(LD_(50))was determined by acute toxicity test with the toxic reaction and mortality of mice as indexes.Sixty Kunming mice were randomly divided into 6 groups:normal control group,model group(ConA-induced liver injury model),Jinchuan formula plum wine high,medium and low dose groups(1.0,0.5,0.25 g/kg)and silybin group(0.1 g/kg).The levels of ALT,AST,LDH in serum and TG,VLDL in liver were measured.After HE staining,the pathological changes of liver tissue in mice were observed,and the liver protective effect of Jinchuan formula plum wine extract was analyzed and evaluated.[Results]LD_(50)was 11.18 g/kg,and the 95%confidence limit of LD_(50)was 10.31-12.05 g/kg.The high-dose group of Jinchuan formula plum wine extract could significantly reduce the serum ALT and AST activities of ConA-induced liver injury mice(P<0.05).[Conclusions]Jinchuan formula plum wine extract is relatively safe,and also has a protective effect on liver injury.

Geochemical Characteristics,Genesis of Concealed Cu-rich Ore Body in the Jinchuan Deposit,Northwestern China,and Its Prospecting

The Jinchuan deposit is hosted by the olivine-rich ultramafic rock body, which is the thirdlargest magmatic sulfide Ni-Cu deposit in the world currently being exploited. Seeking new relaying resources in the deep and the border of the deposit becomes more and more important. The ore body, ore and geochemistry characteristics of the concealed Cu-rich ore body are researched. Through spatial analysis and comparison with the neighboring II1 main ore body, the mineralization rule of the concealed Cu-rich ore body is summed up. It is also implied that Cu-rich magma may exist between Nirich magma and ore pulp during liquation differentiation in deep-stage chambers, which derives from deep-mantle Hi-MgO basalt magma. It is concluded that the type of ore body has features of both magmatic liquation and late reconstruction action. It has experienced three stages： deep liquation and pulsatory injection of the Cu- and PPGE-rich magma, concentration of tectonic activation, and the later magma hydrothermal superimposition. In addition, the Pb and S isotopes indicate the magma of I6 concealed Cu-rich ore body originates predominantly from mantle; however, it is interfused by minute crust material. Finally, it is inferred that the genesis of the Cu-Ni sulfide deposit is complex and diverse, and the prospect of seeking new deep ore bodies within similar deposits is promising, especially Cu-rich ore bodies.

Stress Measurement with an Improved Hollow Inclusion Technique In Jinchuan Nickel Mine

Borehole overcoring stress measurement with an improved hollow inclusion technique was carried out at 10 points on 3 levels in Jinchuan nickel mine which is situated in north-west of China. Through the measurement, 3-D in situ stress state at the measuring points and distribution characteristics of the stress field in the mine were obtained. The stress state in Jinchuan mine is dominated by the horizontal tectonic stress field. The maximum principal stress is horizontal which is about twice the weight of the overburden and its orientation is approximately vertical to the regional tectonic line. The difference between two horizontal principal stresses is quite large which is an important reason to cause failure of underground excavations.

Process mineralogy of copper-nickel sulphide flotation by a cyclonic-static micro-bubble flotation column

In our study we investigated a refractory copper-nickel sulfide ore separation by using a cyclonic-static micro-bubble flotation column (FCSMC). The process mineralogy of the main products was studied. Using a scanning electron microscope-energy dispersive system (SEM-EDS) and an X-ray spectrometer the mineral category and content of samples were analyzed. By using a mineral liberation analyzer (MLA) the mineral liberation characteristics were revealed. It is shown that in roughing feed the monomers liberation degree of nickel pyrite and chalcopyrite take up 84.11% and 88.82%, respectively. In tailings, the lost nickel pyrite and chalcopyrite are mainly monomers. Therefore, strengthening the micro-fine particle recovery capacity is the key to increase recovery.

Processing Map of C71500 Copper-nickel Alloy and Application in Production Practice

The isothermal compression tests of C71500 copper-nickel alloy at different temperatures (1 073-1 273 K) and strain rates (0.01-10 s^-1) were carried out on Gleeble-3500 thermo-mechanical simulator.The real stress-strain data were obtained.On the basis of dynamic material model,the power dissipation was established.The peak efficiency of the power dissipation is 57%.At the same time,Prasad’s,Murty’s and Babu’s instability criteria based on Ziegler’s expectant rheology theory,and Gegel’s and Malas’s instability criteria based on Lyaponov’s function theory,were used to predict the unstable regions in the processing map.The maximum entropy generation rate and large plastic deformation principle are more in line with the hot deformation process of C71500 alloy,so the accuracy of Prasad’s instability criterion is much better.According to the obtained macro-crack and micro-metallographic structure morphologies,the temperature range of 1 098-1 156 K and the strain rate range of 2.91-10 s^-1,and the temperature range of 1 171-1 273 K and the strain rate range of 0.01-0.33 s^-1 are more suitable for the processing area of C71500 alloy.The accuracy of the above conclusions were verified by the forging of materials and the analysis of hot piercing tubes.The significance of this paper is to provide theoretical basis and technological conditions for hot-press processing of C71500 alloy.

Feasibility Study on Continuous Mining Method in Deep Position of Jinchuan Nickel Mine, China

Jinchuan nickel mine is the largest nickel mine in China. Cut-and-fill mining method with high density cementing materials is used in the mine. The original mining design divided the mining operation into two steps. The first step stopped the mining rooms and the second step stopped the pillars. Because the two-step method made big trouble for finally mining pillars and strongly limited the mining speed and production, it was successfully changed to a continuous cut-and-fill method without pillars. However, the mining operation in the mine has been down to 800 m and the mining condition is getting worse and more complicated. Through systematical field investigations and 3-D FEM analysis, it is proved that the mining method without pillars is feasible for mining deeper orebodies in Jinchuan nickel mine.

Geophysical prospecting of copper-nickel deposits in Beishan rift zone, Xinjiang

The Beishan rift zone in Xinjiang Uygur Autonomous Region was formed due to strong activities of faults on the basement of the Tarim continental crust.Despite the fact that many geological research results of the rift zone have been achieved,only a few studies have been conducted on its regional geophysical characteristics.In this paper,the gravity and magnetic anomalies of the rift zone were highlighted through specific data processing of 1∶50000 high-precision aeromagnetic data and gravity data with a grid spacing of 2 km×2 km.Based on this,the geophysical evidence for the scope and internal structures of the Beishan rift zone was obtained for the first time.The distinct characteristics of magnetic and gravity fields in the areas to the north and south of the Beishan rift zone reveal that deep faults exist between the Beishan rift zone and the geological units on the southern and northern sides.Furthermore,the faults on the two areas contain the bidirectional thrusts and have flower-shaped structures according to the characteristics of the magnetic and gravity fields.The Beishan rift zone can be divided into two tectonomagmatic zones,namely the Zhongposhan-Bijiashan-Cihai-Baishanliang zone(the northern zone)and the Bayiquan-Qixin-Baishan zone(the southern zone).The northern zone can be further subdivided into three comet-shaped anomaly groups(tectonomagmatic areas),while the southern zone can be further subdivided into two tectonomagmatic areas.According to the characteristics of aeromagnetic anomalies and gravity field,19 mafic-ultramafic complexes were delineated.The known Pobei,Hongshishan,and Qixin complexes are all located within the inferred complexes,with estimates of total explored resources of Ni,Cu,and Au of 3×10^(6) t,10×10^(3) t and 10 t,respectively.The prospecting of high-grade copper-nickel deposits should focus on the periphery and deep parts of the known and inferred mafic-ultramafic complexes.Among them,the peripheral strata of the complexes specifically have great prospecting potential of large-scale high-grade copper-nickel deposits of magma injection type.Finally,this paper analyzed the application effects of the rapid airborne-ground-drilling synergetic exploration method in the prospecting of copper-nickel deposits in Qixin,Beishan,Xinjiang,which will provide references for further exploration of copper-nickel deposits in Beishan area,Xinjiang.

High Slope Stability of Diversion Power System Intake of Jinchuan Hydropower Station

The excavated height of the left bank slope of the diversion power system intake in Jinchuan hydropower station is about 16o m. The stability and safety of the slope during construction and its operation/utilization become one of the most important geological engineering problems. At the same time, it is also crucial to select a safe and economic excavation gradient for the construction. We studied the problem of how to select a safe and economic slope ratio by analyzing the geological condition of the high slope, including the lithology, slope structure, structural surface and their combinations, rock weathering and unloading, hydrology, and the natural gradient. The study results showed that the use of an excavation gradient larger than the gradient observed during site investigation and the gradient recommended in standards and field practice manuals is feasible. Then, we used the finite element method and rigid limit equilibrium method to evaluate the stability of the excavation slope under natural, rainstorm and earthquake conditions. The calculated results showed that the excavated slope only has limited failure, but its stability is greatly satisfactory. The research findings can be useful in excavation and slope stabilization projects.

Structures, stabilities and magnetic moment of small copper-nickel clusters

This paper obtains the lowest-energy geometric structures and the electronic and magnetic properties of small CuNiN clusters by using all-electron density functional theory. The calculated results reveal that the Cu atom prefers to occupy the apical site when N ≤ 9 and for the clusters with N = 10, the Cu atom starts to encapsulate in the cage. The CuNi7 and CuNi9 are magic clusters. The magnetism correlates closely with the symmetry of the clusters. For these clusters, the charge tends to transfer from the nickel atoms to the copper atoms. It finds that the doping of Cu atom decreases the stability of pure NiN clusters.

The Inhibitive Effect of 3-Methyl 4-Amino 1,2,4 Triazole on the Corrosion of Copper-Nickel 70 - 30 in NaCl 3% Solution

The effect of 3-methyl 4-amino 1,2,4 triazole (MATA) on the corrosion behaviour of copper-nickel 70 - 30 (Monel) in NaCl 3% solution is investigated at 298 K by weight loss measurements, potentiodynamic polarisation and impedance spectroscopy (EIS′) methods. Preliminary screening of the inhibition efficiency (ECR) was carried out with using weight- loss measurements. Polarization measurements showed that the organic compound investigated is mixed type inhibitor (it acts on the cathodic and the cathodic reactions), inhibiting the corrosion of Monel by blocking the active sites of the metal surface. Changes in the impedance parameters charge transfer resistance (Rct) and double layer capacitance (Cdl) are related to adsorption of organic inhibitor of the metal surface, leading to the formation of protective film, which grows with increasing exposure time. Inhibition efficiencies obtained from cathodic Tafel plots, gravimetric and EIS methods are in good agreement. Results obtained shows that the (MATA) is good inhibitor for copper – nickel, and its efficiency reaches more than 95% at 60 ppm after 30 mn of immersion.

Fluctuation of Body Size and Body Weight of Jinchuan Female Yak within One Year

To understand the exact changes in body size and body weight of Jinchuan female yaks within one year,the body size and body weight of 30 Jinchuan female yaks were measured from July 2015 to July 2016. The results showed that the body weight of Jinchuan female yak declined continuously since October 2015,and the weight loss in November 2015 was the largest. The body weight started to increase in May 2016,and the body weight increased significantly in June and July of 2016.

Nano-sized Mineral Phases in Copper-nickel Ores of the Central Pai-Khoi(Nenets Autonomous District,Russia)

The characteristics of previously determined and a number of new,unknown before,mineral phases are presented.On this area in sulphide ores of the Central the Pai-Khoi dolerite bodies.In the process of intrusion formation and sulphidic magma crystallization the subtraction of such elements as lead, stibium,cobalt,arsenic,and accordingly migration and concentration of minerals of platinum

A Genetic Model for Ore Magma of the Chibaisong Copper-Nickel Sulphide Deposit, Jilin

In the early 1980's, the author proposed his view that copper-nickel sulphide deposts are of ore magma origin. For more than ten years, this view has aroused attention of his colleagues at home and abroad. In this paper an attempt is made to deal with the genetic model for ore magma of copper-nickel sulphide deposits in more details on the basis of geological, geochemical, petrophysico - chemical and thermodynamic studies of the Chibaisong copper-nickel sulphide deposit in the Changbai Mountains, Jilin province.

Exhumation and Preservation of the Jinchuan Ni-Cu-PGE Deposit under the East Longshou Mountain Thermal Evolution,Revealed by Apatite Fission Track Thermochronology

Uplift and exhumation are important factors affecting the preservation of deposits.The anatomy of uplift-cooling evolution and exhumation in the East Longshou Mountain is of significant research value in understanding changes in the Jinchuan Ni-Cu-PGE deposit since its formation.This study uses apatite fission track(AFT)thermochronology to reconstruct the thermal history of the East Longshou Mountain,including the Jinchuan mine,revealing the uplift and exhumation history of the East Longshou Mountain and elucidating the preservation status of the Jinchuan deposit.The AFT ages in the East Longshou Mountain are distributed from 62.3±3.0 Ma to 214.7±14 Ma,with significant differences in ages in distinct areas,the central and pooled ages being consistent within the margin of error.Inverse thermal history models reveal two rapid cooling events associated with exhumation from the Early Jurassic to the Early Cretaceous(200–100 Ma)and since the Miocene(15–0 Ma),the former attributable to the far-afield response to the closure of the PaleoTethys Ocean and plate assembly at the southern margin of Eurasia,the latter associated with the initial India-Eurasia plate collision.A slow cooling event from the Early Cretaceous to the Miocene(100–15 Ma)is thought to be related to the arid environment in northwest China since the Cretaceous.These cooling events have diverse responses and cooling rates in different blocks of the East Longshou Mountain:the southwest and centre of which are mainly cooled over 200–120 Ma and 120–0 Ma,with cooling rates of~0.25 and~0.33°C/Ma(~1.25 and~0.33°C/Ma in the centre);the Jinchuan mine primarily cooled over 160–100 Ma,100–15 Ma and 15–0 Ma,with cooling rates of~1.33,~0.25 and~2.00°C/Ma.These differentiated coolings imply that the uplift of the East Longshou Mountain before the Miocene(~15 Ma)was integral.Strong uplift then occurred in the vicinity of the mining area,which is a critical period for the uplift of the Jinchuan deposit to the surface,meaning that the Jinchuan deposit was exposed no earlier than the Miocene(~15 Ma).Based on mineralization depth information obtained by previous researchers,in conjunction with the calculation and simulation results of this study,it can be seen that the bulk of the Jinchuan intrusion may still be preserved at depth.

Dynamic Magma Conduit System Related to the Jinchuan Ni-Cu Sulfide Deposit,NW China

The Jinchuan Ni-Cu sulfide deposits,NW China,are hosted in small ultramafic intrusions that were emplaced into Paleoproterozoic metamorphic rocks. The ultramafic intrusions were previously thought to be the segments of a single elongate intrusion that was dismembered by late faults into eastern and western portions,each of which have distinct stratigraphic sequences.

甘肃金川铜镍硫化物矿床成岩成矿构造观测及解析

甘肃金川超大型铜镍硫化物矿床形成于新元古代,从其母岩浆侵位到后期构造叠加改造,该矿床经历了复杂的地质演化过程。尽管前人开展了相关研究,但是关于该矿床的矿区构造研究仍然存在较大争议。此外,厘清矿区控岩控矿构造对探讨岩浆侵入与就位过程、矿床深部找矿等具有重要意义。本次研究根据矿区构造分类、配套、交切关系与成岩成矿时序组合等,划分出成矿前、成矿期和成矿后构造系统,借助断裂、共轭节理产状统计分析了矿区构造应力场,确定主压应力方向分别为N-S向、NE-SW向和NNE-SSW向。最后将矿区构造与区域大地构造演化相结合,总结归纳出成矿前、成矿期与成矿后构造演化过程:成矿前经历吕梁运动阶段,该区发生强烈褶皱和变质作用。成矿期晋宁运动阶段,金川赋矿岩体的母岩浆沿着吕梁期形成的褶皱构造虚脱空间侵入就位。成矿后,加里东运动阶段,龙首山地区发生陆内造山,大量基性岩脉侵入;海西运动阶段,推覆造山运动强烈,形成泥盆纪地层,发育一系列同斜紧闭褶皱;燕山运动阶段,挤压-走滑作用占主导形成东西向展布的山前拉分盆地和北东向展布的断陷盆地;喜马拉雅运动阶段,急剧隆升和剥蚀,金川矿床从深部被抬升到了地表。研究成果为金川矿床深、边部找矿提供了新思路。

镍渣—全尾砂混合骨料配比试验研究

为实现固废循环利用,降低尾砂和镍渣的固废堆存,开展了镍渣—全尾砂混合骨料配比试验。通过扫描电镜和X射线荧光光谱测定(XRF)方法分析了镍渣和全尾砂的粒级分布和化学成分,利用骨料堆积密实度理论确定了镍渣—尾砂的配比优化范围为4∶6、5∶5和6∶4;考虑料浆的流动性、和易性及充填体强度,最终推荐镍渣—全尾砂的最优配合比为5∶5,料浆的质量浓度为77%~79%,水泥添加量为310 kg/m^(3);针对镍渣—全尾砂充填,镍渣利用量最高不超过50%,最大质量浓度为79%,对应的剪切应力为112.634 Pa,黏度为0.938 Pa·s。