Total 138 coal samples and 14 parting samples were taken from the No. 6 Seam of the Jungar Coalfield, Inner Mongolia. These samples were analysed by optical microscopy, sequential chemical extraction procedure （SCEP...Total 138 coal samples and 14 parting samples were taken from the No. 6 Seam of the Jungar Coalfield, Inner Mongolia. These samples were analysed by optical microscopy, sequential chemical extraction procedure （SCEP）, inductively coupled plasma mass spectrometry （ICP-MS）, X-ray powder diffraction （XRD）, and scanning electron microscope in conjunction with an energy-dispersive X-ray spectrometer （SEM-EDX） analysis. The results indicate that the Li contents have reached the industrial grade of the coal associated Li deposit, and the total Li reserves have reached 2406600 tons, that is, 5157000 tons Li2O in the No. 6 seam in the Jungar Coalfield. The sequential chemical extraction procedure results suggest that the Li concentration is mainly related to inorganic matter. The minerals in the coals consist of kaolinite, boehmite, chlorite-group mineral, quartz, calcite, pyrite, siderite and amorphous clay material. Some Li could be absorbed by clay minerals in the Li-bearing coal seam. The chlorite phase？could be？most likely the host for a part of Li. The Yinshan Oldland should be the most possible source of Li of the coal.展开更多
We collected eleven bench samples of No. 6 coal from the Heidaigou Surface Mine, Jungar Coalfield, Inner Mongolia, China, and four samples from the affiliated coal preparation plant. Based on these samples, we used in...We collected eleven bench samples of No. 6 coal from the Heidaigou Surface Mine, Jungar Coalfield, Inner Mongolia, China, and four samples from the affiliated coal preparation plant. Based on these samples, we used inductively coupled-plasma mass spectroscopy, X-ray diffraction, scanning electron microscope with an energy-dispersive X-ray spectrometer techniques, and borehole exploration data, to investigate the distribution, occurrence and enrichment causes of gallium (Ga) in the coals. Our results show: (1) Gallium is significantly enriched in the coal seams from the study area, with an average content of 18.8-26.0 ppm. Gallium is distributed heterogeneously in the coals, and reaches ore-forming scales only in No. 6 coal of Heidaigou Surface Mine, not in the other mining districts of Jungar Coalfield. (2) On the horizontal plane, Ga is enriched in the main minable coals from the northern and middle part of the coalfield. In the vertical profile, Ga content in the coal seams is higher at the base of Taiyuan Formation (Nos. 8 and 9) and Shanxi Formation (Nos. 3 and 4) than at the top of the Taiyuan Formation. Within the identical coal seam, Ga content is higher in the benches near the roof and floor than in the middle section. (3) Gallium in the coals is associated mainly with kaolinite and boehmite. Additionally, Ga may be adsorbed to some extent by humic acid, resulting in a high level in weathering coal. (4) Geological factors affect Ga enrichment in coal, such as the property of parent rocks in the source area, the sedimentary environment, organic matter, structure, and past magmatic hydrothermal activity. Especially, Ga content in parent rocks plays a leading role. (5) The mobility and precipitation of trace elements like Ga are controlled principally by the geochemical behavior of the major element Al. Terrestrial and transgressive environments can cause the precipitation of bauxite, whereas marine-continental depositional environments may cause the separation of Ga from Al. In addition, Ga may migrate in the form of gas, and may be affected by the ground temperature. Thus, it is relatively enriched in high-volatile coal.展开更多
It is known that the exploitation of opencast coal mines has seriously damaged the environments in the semi-arid areas.Vegetation status can reliably reflect the ecological degeneration and restoration in the opencast...It is known that the exploitation of opencast coal mines has seriously damaged the environments in the semi-arid areas.Vegetation status can reliably reflect the ecological degeneration and restoration in the opencast mining areas in the semi-arid areas.Long-time series MODIS NDVI data are widely used to simulate the vegetation cover to reflect the disturbance and restoration of local ecosystems.In this study, both qualitative(linear regression method and coefficient of variation(CoV)) and quantitative(spatial buffer analysis, and change amplitude and the rate of change in the average NDVI) analyses were conducted to analyze the spatio-temporal dynamics of vegetation during 2000–2017 in Jungar Banner of Inner Mongolia Autonomous Region, China, at the large(Jungar Banner and three mine groups) and small(three types of functional areas: opencast coal mining excavation areas, reclamation areas and natural areas) scales.The results show that the rates of change in the average NDVI in the reclamation areas(20%–60%) and opencast coal mining excavation areas(10%–20%) were considerably higher than that in the natural areas(<7%).The vegetation in the reclamation areas experienced a trend of increase(3–5 a after reclamation)-decrease(the sixth year of reclamation)-stability.The vegetation in Jungar Banner has a spatial heterogeneity under the influences of mining and reclamation activities.The ratio of vegetation improvement area to vegetation degradation area in the west, southwest and east mine groups during 2000–2017 was 8:1, 20:1 and 33:1, respectively.The regions with the high CoV of NDVI above 0.45 were mainly distributed around the opencast coal mining excavation areas, and the regions with the CoV of NDVI above 0.25 were mostly located in areas with low(28.8%) and medium-low(10.2%) vegetation cover.The average disturbance distances of mining activities on vegetation in the three mine groups(west, southwest and east) were 800, 800 and 1000 m, respectively.The greater the scale of mining, the farther the disturbance distances of mining activities on vegetation.We conclude that vegetation reclamation will certainly compensate for the negative impacts of opencast coal mining activities on vegetation.Sufficient attention should be paid to the proportional allocation of plant species(herbs and shrubs) in the reclamation areas, and the restored vegetation in these areas needs to be protected for more than 6 a.Then, as the repair time increased, the vegetation condition of the reclamation areas would exceed that of the natural areas.展开更多
基金financially supported by the National Science Fundamental of China Projects(Nos.41072115 and 51174262)the project of the Science Foundation of Hebei(No.D2011402034)
文摘Total 138 coal samples and 14 parting samples were taken from the No. 6 Seam of the Jungar Coalfield, Inner Mongolia. These samples were analysed by optical microscopy, sequential chemical extraction procedure （SCEP）, inductively coupled plasma mass spectrometry （ICP-MS）, X-ray powder diffraction （XRD）, and scanning electron microscope in conjunction with an energy-dispersive X-ray spectrometer （SEM-EDX） analysis. The results indicate that the Li contents have reached the industrial grade of the coal associated Li deposit, and the total Li reserves have reached 2406600 tons, that is, 5157000 tons Li2O in the No. 6 seam in the Jungar Coalfield. The sequential chemical extraction procedure results suggest that the Li concentration is mainly related to inorganic matter. The minerals in the coals consist of kaolinite, boehmite, chlorite-group mineral, quartz, calcite, pyrite, siderite and amorphous clay material. Some Li could be absorbed by clay minerals in the Li-bearing coal seam. The chlorite phase？could be？most likely the host for a part of Li. The Yinshan Oldland should be the most possible source of Li of the coal.
基金supported by National Natural Science Foundation of China (Grant Nos. 40772102 and 40730422)Program for New Century Excellent Talents in University (Grant No. NCET-08-0839)+2 种基金National Key Basic Research and Development Program of China (Grant No. 2007CB209400)the Fundamental Research Funds for the Central Universities (Grant No. 2010LKDZ02)Sci-Tech Project "Evaluation of coal resources in first batch national planning mining areas" of the Ministry of Land and Resources
文摘We collected eleven bench samples of No. 6 coal from the Heidaigou Surface Mine, Jungar Coalfield, Inner Mongolia, China, and four samples from the affiliated coal preparation plant. Based on these samples, we used inductively coupled-plasma mass spectroscopy, X-ray diffraction, scanning electron microscope with an energy-dispersive X-ray spectrometer techniques, and borehole exploration data, to investigate the distribution, occurrence and enrichment causes of gallium (Ga) in the coals. Our results show: (1) Gallium is significantly enriched in the coal seams from the study area, with an average content of 18.8-26.0 ppm. Gallium is distributed heterogeneously in the coals, and reaches ore-forming scales only in No. 6 coal of Heidaigou Surface Mine, not in the other mining districts of Jungar Coalfield. (2) On the horizontal plane, Ga is enriched in the main minable coals from the northern and middle part of the coalfield. In the vertical profile, Ga content in the coal seams is higher at the base of Taiyuan Formation (Nos. 8 and 9) and Shanxi Formation (Nos. 3 and 4) than at the top of the Taiyuan Formation. Within the identical coal seam, Ga content is higher in the benches near the roof and floor than in the middle section. (3) Gallium in the coals is associated mainly with kaolinite and boehmite. Additionally, Ga may be adsorbed to some extent by humic acid, resulting in a high level in weathering coal. (4) Geological factors affect Ga enrichment in coal, such as the property of parent rocks in the source area, the sedimentary environment, organic matter, structure, and past magmatic hydrothermal activity. Especially, Ga content in parent rocks plays a leading role. (5) The mobility and precipitation of trace elements like Ga are controlled principally by the geochemical behavior of the major element Al. Terrestrial and transgressive environments can cause the precipitation of bauxite, whereas marine-continental depositional environments may cause the separation of Ga from Al. In addition, Ga may migrate in the form of gas, and may be affected by the ground temperature. Thus, it is relatively enriched in high-volatile coal.
基金supported by the National Key Research and Development Program of China (2016YFC0501107)the Project of Ordos Science and Technology Program (2017006)the Special Project of Science and Technology Basic Work of Ministry of Science and Technology of China (2014FY110800)
文摘It is known that the exploitation of opencast coal mines has seriously damaged the environments in the semi-arid areas.Vegetation status can reliably reflect the ecological degeneration and restoration in the opencast mining areas in the semi-arid areas.Long-time series MODIS NDVI data are widely used to simulate the vegetation cover to reflect the disturbance and restoration of local ecosystems.In this study, both qualitative(linear regression method and coefficient of variation(CoV)) and quantitative(spatial buffer analysis, and change amplitude and the rate of change in the average NDVI) analyses were conducted to analyze the spatio-temporal dynamics of vegetation during 2000–2017 in Jungar Banner of Inner Mongolia Autonomous Region, China, at the large(Jungar Banner and three mine groups) and small(three types of functional areas: opencast coal mining excavation areas, reclamation areas and natural areas) scales.The results show that the rates of change in the average NDVI in the reclamation areas(20%–60%) and opencast coal mining excavation areas(10%–20%) were considerably higher than that in the natural areas(<7%).The vegetation in the reclamation areas experienced a trend of increase(3–5 a after reclamation)-decrease(the sixth year of reclamation)-stability.The vegetation in Jungar Banner has a spatial heterogeneity under the influences of mining and reclamation activities.The ratio of vegetation improvement area to vegetation degradation area in the west, southwest and east mine groups during 2000–2017 was 8:1, 20:1 and 33:1, respectively.The regions with the high CoV of NDVI above 0.45 were mainly distributed around the opencast coal mining excavation areas, and the regions with the CoV of NDVI above 0.25 were mostly located in areas with low(28.8%) and medium-low(10.2%) vegetation cover.The average disturbance distances of mining activities on vegetation in the three mine groups(west, southwest and east) were 800, 800 and 1000 m, respectively.The greater the scale of mining, the farther the disturbance distances of mining activities on vegetation.We conclude that vegetation reclamation will certainly compensate for the negative impacts of opencast coal mining activities on vegetation.Sufficient attention should be paid to the proportional allocation of plant species(herbs and shrubs) in the reclamation areas, and the restored vegetation in these areas needs to be protected for more than 6 a.Then, as the repair time increased, the vegetation condition of the reclamation areas would exceed that of the natural areas.
