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Increasing Threat of Scarcity Prompts Rise in Water Recycling
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作者 Chris Palmer 《Engineering》 SCIE EI CAS CSCD 2024年第2期6-8,共3页
In January 2018,construction wrapped on Salesforce Tower(Fig.1),a 61-story office building that now dominates the skyline of San Francisco,CA,USA.In addition to being the tallest building in the city,Salesforce Tower ... In January 2018,construction wrapped on Salesforce Tower(Fig.1),a 61-story office building that now dominates the skyline of San Francisco,CA,USA.In addition to being the tallest building in the city,Salesforce Tower is the largest structure in the world with an onsite water recycling system.Built by the Australian com-pany Aquacell(Milton,NSW,Australia),the system cleans 113 m^(3)of sewage,sink,shower,and other wastewater each day for use in irrigation and flushing toilets,saving an estimated 35000 m?of water anmually[1].The building is just one of dozens in San Fran-cisco outitted with their own water recycling systems,thanks to a city mandate enacted in 2015[1]. 展开更多
关键词 cycling WASTEWATER recycling
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TuBG1 promotes hepatocellular carcinoma via ATR/P53-apoptosis and cycling pathways
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作者 Yan Zhang Zhen-Zhen Wang +4 位作者 An-Qi Han Ming-Ya Yang Li-Xin Zhu Fa-Ming Pan Yong Wang 《Hepatobiliary & Pancreatic Diseases International》 SCIE CAS CSCD 2024年第2期195-209,共15页
Background:As reported,γ-tubulin(TuBG1)is related to the occurrence and development of various types of malignant tumors.However,its role in hepatocellular cancer(HCC)is not clear.The present study was to investigate... Background:As reported,γ-tubulin(TuBG1)is related to the occurrence and development of various types of malignant tumors.However,its role in hepatocellular cancer(HCC)is not clear.The present study was to investigate the relationship between TuBG1 and clinical parameters and survival in HCC patients.Methods:The correlation between TuBG1 and clinical parameters and survival in HCC patients was ex-plored by bioinformatics analysis.Immunohistochemistry was used for the verification.The molecular function of TuBG1 was measured using colony formation,scratch assay,trans-well assay and flow cytometry.Gene set enrichment analysis(GSEA)was used to pick up the enriched pathways,followed by investigating the target pathways using Western blotting.The tumor-immune system interactions and drug bank database(TISIDB)was used to evaluate TuBG1 and immunity.Based on the TuBG1-related immune genes,a prognostic model was constructed and was further validated internally and externally.Results:The bioinformatic analysis found high expressed TuBG1 in HCC tissue,which was confirmed us-ing immunohistochemistry and Western blotting.After silencing the TuBG1 in HCC cell lines,more G1 arrested cells were found,cell proliferation and invasion were inhibited,and apoptosis was promoted.Furthermore,the silence of TuBG1 increased the expressions of Ataxia-Telangiectasia and Rad-3(ATR),phospho-P38 mitogen-activated protein kinase(P-P38MAPK),phospho-P53(P-P53),B-cell lymphoma-2 associated X protein(Bax),cleaved caspase 3 and P21;decreased the expressions of B-cell lymphoma-2(Bcl-2),cyclin D1,cyclin E2,cyclin-dependent kinase 2(CDK2)and CDK4.The correlation analysis of immunohistochemistry and clinical parameters and survival data revealed that TuBG1 was negatively corre-lated with the overall survival.The constructed immune prognosis model could effectively evaluate the prognosis.Conclusions:The increased expression of TuBG1 in HCC is associated with poor prognosis,which might be involved in the occurrence and development of HCC. 展开更多
关键词 TuBG1 Hepatocellular carcinoma APOPTOSIS Cell cycling IMMUNOMODULATORS
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Enhanced High-Temperature Cycling Stability of Garnet-Based All Solid-State Lithium Battery Using a Multi-Functional Catholyte Buffer Layer
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作者 Leqi Zhao Yijun Zhong +2 位作者 Chencheng Cao Tony Tang Zongping Shao 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第7期59-73,共15页
The pursuit of safer and high-performance lithium-ion batteries(LIBs)has triggered extensive research activities on solid-state batteries,while challenges related to the unstable electrode-electrolyte interface hinder... The pursuit of safer and high-performance lithium-ion batteries(LIBs)has triggered extensive research activities on solid-state batteries,while challenges related to the unstable electrode-electrolyte interface hinder their practical implementation.Polymer has been used extensively to improve the cathode-electrolyte interface in garnet-based all-solid-state LIBs(ASSLBs),while it introduces new concerns about thermal stability.In this study,we propose the incorporation of a multi-functional flame-retardant triphenyl phos-phate additive into poly(ethylene oxide),acting as a thin buffer layer between LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)cathode and garnet electro-lyte.Through electrochemical stability tests,cycling performance evaluations,interfacial thermal stability analysis and flammability tests,improved thermal stability(capacity retention of 98.5%after 100 cycles at 60℃,and 89.6%after 50 cycles at 80℃)and safety characteristics(safe and stable cycling up to 100℃)are demonstrated.Based on various materials characterizations,the mechanism for the improved thermal stability of the interface is proposed.The results highlight the potential of multi-functional flame-retardant additives to address the challenges associated with the electrode-electrolyte interface in ASSLBs at high temperature.Efficient thermal modification in ASSLBs operating at elevated temperatures is also essential for enabling large-scale energy storage with safety being the primary concern. 展开更多
关键词 Solid-state battery Cathode electrolyte interlayer Flame-retardant additive cycling stability Interfacial stability
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Cycling performance of layered oxide cathode materials for sodium-ion batteries
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作者 Jinpin Wu Junhang Tian +1 位作者 Xueyi Sun Weidong Zhuang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第7期1720-1744,共25页
Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity,high operating voltage,and simple synthesis.Cycling performance is an important criterion for evaluating the applicat... Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity,high operating voltage,and simple synthesis.Cycling performance is an important criterion for evaluating the application prospects of batteries.However,facing challenges,including phase transitions,ambient stability,side reactions,and irreversible anionic oxygen activity,the cycling performance of layered oxide cathode materials still cannot meet the application requirements.Therefore,this review proposes several strategies to address these challenges.First,bulk doping is introduced from three aspects:cationic single doping,anionic single doping,and multi-ion doping.Second,homogeneous surface coating and concentration gradient modification are reviewed.In addition,methods such as mixed structure design,particle engineering,high-entropy material construction,and integrated modification are proposed.Finally,a summary and outlook provide a new horizon for developing and modifying layered oxide cathode materials. 展开更多
关键词 sodium-ion battery layered oxide materials cycling performance bulking doping surface coating concentration gradient mixed structure high-entropy
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Interconnected and high cycling stability polypyrrole supercapacitors using cellulose nanocrystals and commonly used inorganic salts as dopants 被引量:1
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作者 Zuxin Sun Wim Thielemans 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第1期165-174,I0005,共11页
Polypyrrole(PPy)is wildly used as electrode material in supercapacitors due to its high conductivity,low cost,ease of handling,and ease of fabrication.However,limited capacitance and poor cycling stability hinder its ... Polypyrrole(PPy)is wildly used as electrode material in supercapacitors due to its high conductivity,low cost,ease of handling,and ease of fabrication.However,limited capacitance and poor cycling stability hinder its practical application.After developing carboxylated cellulose nanocrystals(CNC-COO^(-))as immobile dopants for PPy to improve its cycling stability,we investigated the effect of different commonly used salts(KCl,NaCl,KBr,and NaClO_(4))as dopants during electrode fabrication by electropolymerization.The film’s capacitance increased from 160.6 to 183.4 F g^(-1)after adding a combination of KCl and NaClO_(4) into the electrodeposition electrolyte.More importantly,the porous and interconnected PPy/CNC-COO^(-)-Cl-(Cl O_(4)^(-))_0.5 electrode film exhibited an excellent capacitance of 125.0 F g^(-1)(0.78 F cm^(-2))at a high current density of 2.0 Ag^(-1)(20 m A cm^(-2),allowing charging in less than 1 min),increasing almost 204%over PPy/CNC-COO-films.A symmetric PPy/CNC-COO^(-)-Cl-(ClO_(4)^(-))_0.5 supercapacitor retained its full capacitance after 5000 cycles,and displayed a high energy density of 5.2 Wh kg^(-1)at a power density of 25.4 W kg^(-1)(34.5μWh cm^(-2) at 1752.3μW cm^(-2)).These results reveal that the porous structure formed by doping with CNC-COO-and inorganic salts opens up more active reaction areas to store charges in PPy-based films as the stiff and ribbon-like CNC-COO-as permanent dopants improve the strength and stability of PPy-based films.Our demonstration provides a simple and practical way to deposit PPy based supercapacitors with high capacitance,fast charging,and excellent cycling stability. 展开更多
关键词 POLYPYRROLE Cellulose nanocrystals cycling stability Inorganic salts SUPERCAPACITOR
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Hydrogen absorption/desorption cycling performance of Mg-based alloys with in-situ formed Mg_(2)Ni and LaH_(x)(x=2,3)nanocrystallines 被引量:1
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作者 Fenghai Guo Tiebang Zhang +1 位作者 Limin Shi Lin Song 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第4期1180-1192,共13页
Aiming to elucidate the hydrogen absorption/desorption cycling properties of Mg-based alloys with in-situ formed Mg_(2)Ni and LaH_(x)(x=2,3)nanocrystallines,the hydrogen storage cycle stability,hydriding/dehydriding c... Aiming to elucidate the hydrogen absorption/desorption cycling properties of Mg-based alloys with in-situ formed Mg_(2)Ni and LaH_(x)(x=2,3)nanocrystallines,the hydrogen storage cycle stability,hydriding/dehydriding cycling kinetics and thermodynamic stability of the experimental alloys have been investigated in detail.The results show that the Mg-Ni-La alloys exhibit improved hydrogen storage cycling properties and can remain storage hydrogen above 5.5 wt%after 200 cycles.With the increase of cycling numbers,the dehydrogenation rates of the experimental samples increase firstly and then gradually decrease,and eventually maintain relative stable state.Microstructure observation reveals that powders sintering and hydrogen decrepitation both exist during hydrogen absorption/desorption cycles due to repeated volume expansion and contraction.Meanwhile,the in-situ formed LaH_(x)(x=2,3)and Mg_(2)Ni nanocrystallines stabilize the microstructures of the particles and hinder the powders sintering.After 200 cycles,the average particle size of the experimental samples decreases and the specific surface area apparently increases,which leads to the decomposition temperatures of MgH_(2)and Mg_(2)NiH_(4)slightly shift to lower temperatures.Moreover,Mg_(2)Ni and LaH_(x)(x=2,3)have been proven to be stable catalysts during long-term cycling,which can still uniformly distribute within the powders after 200 cycles. 展开更多
关键词 Mg-based hydrogen storage alloys cycle stability Microstructure evolution Catalyst stability THERMODYNAMICS
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普通烟草外向整流Shaker K^(+)通道NtSKOR1的组织表达分析
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作者 农童嘉 徐方正 +8 位作者 袁佳苹 向海英 王学瑛 袁光 OLUWASEYI Setonji Hunpatin 崔萌萌 宁扬 王倩 戴培刚 《中国烟草科学》 CSCD 北大核心 2024年第2期90-98,共9页
外向整流Shaker K^(+)通道SKOR(Stelar K^(+)outward rectifier)是一类定位于植物根部中柱细胞质膜的外向整流Shaker K^(+)通道。为探究普通烟草NtSKOR1的启动子活性和不同时期组织表达情况,克隆该基因上游2439 bp的启动子序列,创制启... 外向整流Shaker K^(+)通道SKOR(Stelar K^(+)outward rectifier)是一类定位于植物根部中柱细胞质膜的外向整流Shaker K^(+)通道。为探究普通烟草NtSKOR1的启动子活性和不同时期组织表达情况,克隆该基因上游2439 bp的启动子序列,创制启动子驱动β-葡萄糖苷酸酶基因(GUS)的烟草材料并进行组织化学染色,通过RT-qPCR验证该基因的表达。结果表明NtSKOR1启动子含有光响应、逆境胁迫和激素等相关的顺式作用元件;转ProNtSKOR1::GUS烟草的组织化学染色试验表明:萌发期至子叶展平期未检测到GUS活性;小十字期,在真叶叶脉和茎尖分生组织开始检测到GUS活性;生根期,除茎和叶脉的维管组织外,在根部维管组织也开始检测到明显GUS活性,且活性随烟株生长而逐渐增强;盛花期,主要在烟草的根、茎和叶脉维管组织检测到活性,且上部叶叶脉中的GUS活性高于下部叶叶脉。RT-qPCR与GUS活性检测结果基本一致。综上可知,NtSKOR1主要在烟草小十字期及后续发育阶段的根、茎、叶的维管组织中表达,烟草进入盛花期后,该基因在光合作用较强的上部叶中的表达高于下部叶,推测该基因可能参与烟草K^(+)转运和同化产物协同运输。 展开更多
关键词 NtSKOR1 Shaker K^(+)通道 GUS活性 烟草 基因表达
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低盐水体Na^(+)/K^(+)对凡纳滨对虾生长、体成分与肝胰腺、鳃组织结构的影响
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作者 祝华萍 苏家齐 +4 位作者 张子军 朱长波 张博 李婷 陈素文 《水产学报》 CAS CSCD 北大核心 2024年第3期87-95,共9页
缺钾在内陆低盐度盐碱水中经常发生,为探究低盐水体中不同钾缺乏程度对凡纳滨对虾生长、存活、体成分以及鳃和肝胰腺组织结构的影响,实验参照海水离子组成配置盐度为2的低盐度水体,在Na^(+)/K^(+)(mg/mg)比值为27、47、67、87、107 (分... 缺钾在内陆低盐度盐碱水中经常发生,为探究低盐水体中不同钾缺乏程度对凡纳滨对虾生长、存活、体成分以及鳃和肝胰腺组织结构的影响,实验参照海水离子组成配置盐度为2的低盐度水体,在Na^(+)/K^(+)(mg/mg)比值为27、47、67、87、107 (分别记为A、B、C、D、E组)的条件下,对体重为(1.04±0.23) g的凡纳滨对虾幼虾开展了为期60 d的养殖实验。结果显示,E组对虾的存活率为44.64%±20.95%,显著低于A、B、D三组;E组体重为(4.86±0.66) g,显著低于其他4组;A~D组之间的湿重、增重率、特定生长率差异不显著,但均大于E组且差异显著;在饲料系数上,E组最高并与A、D组差异显著。在体成分上,各组全虾钾含量、灰分含量差异不显著,E组的水分含量高于其他组,并与A、B组差异显著;E组粗蛋白含量最低,且与B组差异显著。E组对虾鳃组织角质层明显受损,红细胞数量减少,空泡增多,肝胰腺B细胞及其内部转运泡体积增大,肝小管结构受损。研究表明,低盐条件下严重缺钾引起了对虾鳃和肝胰腺损伤,降低了对虾的存活率和生长率;水体缺钾在前期即可对对虾的生长产生明显影响,而对存活的影响随养殖时间的增加而增大。实验结果有助于为内陆低盐度盐碱水养殖凡纳滨对虾提供理论依据。 展开更多
关键词 凡纳滨对虾 Na^(+)/K^(+) 生长 体成分 组织结构
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K^(+)掺杂双钙钛矿Cs_(2)AgInCl_(6)的发光性质
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作者 徐锦锃 高辉 +2 位作者 陈国庆 王可可 胡金辉 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第2期405-411,共7页
采用固相球磨法制备了K^(+)掺杂双钙钛矿Cs_(2)AgInCl_(6)纳米材料,该方法无需配体辅助,绿色环保。通过X射线衍射和拉曼光谱对晶体结构进行研究,通过激发光谱、发射光谱和时间分辨光谱对其发光性能进行研究。结果表明,Cs_(2)AgInCl_(6)... 采用固相球磨法制备了K^(+)掺杂双钙钛矿Cs_(2)AgInCl_(6)纳米材料,该方法无需配体辅助,绿色环保。通过X射线衍射和拉曼光谱对晶体结构进行研究,通过激发光谱、发射光谱和时间分辨光谱对其发光性能进行研究。结果表明,Cs_(2)AgInCl_(6)为立方晶体,属于Fm3m空间群,由于宇称禁戒跃迁,其荧光量子产率(PLQY)低,小于0.1%。低于60%的K^(+)掺杂主要取代Ag^(+)的位置,引起Cs_(2)AgInCl_(6)的晶格膨胀,消除了晶格结构的反演对称性,打破了宇称禁戒跃迁,掺杂后Cs_(2)AgInCl_(6)的光致发光强度显著增强。K^(+)的最佳掺杂比例为40%,Cs_(2)Ag_(0.6)K_(0.4)InCl_(6)材料发射中心波长为640 nm,半高宽为180 nm,平均荧光寿命达到29.2 ns,PLQY达到10.5%。当K^(+)掺杂比例超过60%,K^(+)开始取代Cs+的位置,产物发生相变,出现立方相的Cs_(2-x)K_(1+x+y)AgyInCl_(6)和单斜相的Cs_(2-x)K_(1+x)InCl_(6)产物,这些产物由于强电子-声子耦合,非辐射复合占据主导地位。 展开更多
关键词 双钙钛矿 K^(+)掺杂 宇称禁戒跃迁 球磨法
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基于Cycling探针的实时荧光聚合酶链式反应检测河鲀鱼中掺杂的横纹东方鲀成分
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作者 李治儒 吴涵 +2 位作者 杨莉莉 张晓波 曹际娟 《食品安全质量检测学报》 CAS 北大核心 2023年第18期94-102,共9页
目的开发基于Cycling探针实时荧光聚合酶链式反应(real-time fluorescent polymerase chain reaction,RT-PCR)用于检测河鲀鱼中横纹东方鲀(Takifugu oblongus,T.oblongus)成分。方法基于细胞色素C氧化酶亚型I(cytochrome C oxidase subu... 目的开发基于Cycling探针实时荧光聚合酶链式反应(real-time fluorescent polymerase chain reaction,RT-PCR)用于检测河鲀鱼中横纹东方鲀(Takifugu oblongus,T.oblongus)成分。方法基于细胞色素C氧化酶亚型I(cytochrome C oxidase subunit I,COI)基因为靶标设计RT-PCR引物及Cycling探针,开发横纹东方鲀成分检测方法,评价方法的特异性、扩增效率、灵敏度和稳定性。结果横纹东方鲀成分与密切相关的其他8种河鲀鱼、4种其他鱼类物种DNA无交叉反应,具有很好的特异性;方法扩增效率为93.47%;方法重复18次均给出阳性报告的最小稀释点(limitofdetection6,LOD6)为14.64pg/μL(相对应的质量含量为0.1%),95%置信水平条件下检出限为34.41 pg/μL(11.59~119.05 pg/μL,LOD_(95%)),稳定性分析(P=0.152)表明该方法可转移到其他实验室以及在常规分析中使用。结论本研究开发的Cycling探针RT-PCR方法可对河鲀鱼食品中掺杂0.1%的横纹东方鲀成分进行可靠追溯。 展开更多
关键词 河鲀鱼 食品真实性 横纹东方鲀 cycling探针 实时荧光聚合酶链式反应
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Effect of Thermal-cold Cycling Treatment on Mechanical Properties and Microstructure of 6061 Aluminum Alloy
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作者 王会敏 LI Yanguang +2 位作者 GUO Chaobo CUI Guoming HUANG Shiquan 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第3期677-681,共5页
The influence of thermal-cold cycling treatment on mechanical properties and microstructure of 6061 aluminum alloy was investigated by means of tensile test, optical microscopy(OM), X-ray diffraction(XRD) and transmis... The influence of thermal-cold cycling treatment on mechanical properties and microstructure of 6061 aluminum alloy was investigated by means of tensile test, optical microscopy(OM), X-ray diffraction(XRD) and transmission electron microscopy(TEM). The cryogenic treatment mechanism of the alloys was discussed. The results show that thermal-cold cycling treatment is beneficial since it produces a large number of dislocations and accelerates the ageing process of the alloy and yields the finer dispersed β" precipitates in the matrix. This variation of microstructural changes leads to more favorable mechanical properties than the other investigated states, while grain boundary precipitation is coarse and distributed discontinuously along grain boundaries, with a lower precipitation free zone(PEZ) on the both sides of precipitated phase. As a result, the tensile strength, elongation and conductivity of 6061 aluminum alloy after thermal-cold cycling treatment are 373.37 MPa, 17.2% and 28.2 MS/m, respectively. Compared with conventional T6 temper, the mechanical properties are improved significantly. 展开更多
关键词 thermal-cold cycling treatment MICROSTRUCTURES tensile properties aluminum alloys
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Green recycling of short-circuited garnet-type electrolyte for high-performance solid-state lithium batteries
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作者 Yongxian Huang Zhiwei Qin +6 位作者 Cheng Shan Yuming Xie Xiangchen Meng Delai Qian Gang He Dongxin Mao Long Wan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第5期492-500,I0012,共10页
Solid-state lithium batteries(SSLBs)solve safety issues and are potentially energy-dense alternatives to next-generation energy storage systems.Battery green recycling routes are responsible for the widespread use of ... Solid-state lithium batteries(SSLBs)solve safety issues and are potentially energy-dense alternatives to next-generation energy storage systems.Battery green recycling routes are responsible for the widespread use of SSLBs due to minimizing environmental contamination,reducing production costs,and providing a sustainable solution for resources,e.g.,saving rare earth elements(La,Ta,etc.).Herein,a solid-state recycling strategy is proposed to achieve green recycling of the crucial component solidstate electrolytes(SSEs)in spent SSLBs.The short-circuited garnet Li_(6.5)La_(3)Zr_(1.5)Ta_(0.5)O_(12)(LLZTO)is broken into fine particles and mixed with fresh particles to improve sintering activity and achieve high packing density.The continuous Li absorption process promotes sufficient grain fusion and guarantees the transformation from tetragonal phase to pure cubic phase for high-performance recycled LLZTO.The Li-ion conductivity reaches 5.80×10^(-4)S cm-1with a relative density of 95.9%.Symmetric Li cell with asrecycled LLZTO shows long-term cycling stability for 700 h at 0.3 mA cm^(-2)without any voltage hysteresis.Full cell exhibits an excellent cycling performance with a discharge capacity of 141.5 mA h g^(-1)and a capacity retention of 92.1%after 400 cycles(0.2C).This work develops an environmentally friendly and economically controllable strategy to recycle SSE from spent SSLBs,guiding future directions of SSLBs large-scale industrial application and green recycling study. 展开更多
关键词 Solid-state electrolytes Li-garnet Green recycling Solid-state lithium batteries cycling stability
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Effect of drying-wetting cycles on pore characteristics and mechanical properties of enzyme-induced carbonate precipitation-reinforced sea sand 被引量:1
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作者 Ming Huang Kai Xu +2 位作者 Zijian Liu Chaoshui Xu Mingjuan Cui 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第1期291-302,共12页
Enzyme-induced carbonate precipitation(EICP)is an emanating,eco-friendly and potentially sound technique that has presented promise in various geotechnical applications.However,the durability and microscopic character... Enzyme-induced carbonate precipitation(EICP)is an emanating,eco-friendly and potentially sound technique that has presented promise in various geotechnical applications.However,the durability and microscopic characteristics of EICP-treated specimens against the impact of drying-wetting(D-W)cycles is under-explored yet.This study investigates the evolution of mechanical behavior and pore charac-teristics of EICP-treated sea sand subjected to D-W cycles.The uniaxial compressive strength(UCS)tests,synchrotron radiation micro-computed tomography(micro-CT),and three-dimensional(3D)recon-struction of CT images were performed to study the multiscale evolution characteristics of EICP-reinforced sea sand under the effect of D-W cycles.The potential correlations between microstructure characteristics and macro-mechanical property deterioration were investigated using gray relational analysis(GRA).Results showed that the UCS of EICP-treated specimens decreases by 63.7% after 15 D-W cycles.The proportion of mesopores gradually decreases whereas the proportion of macropores in-creases due to the exfoliated calcium carbonate with increasing number of D-W cycles.The micro-structure in EICP-reinforced sea sand was gradually disintegrated,resulting in increasing pore size and development of pore shape from ellipsoidal to columnar and branched.The gray relational degree suggested that the weight loss rate and UCS deterioration were attributed to the development of branched pores with a size of 100-1000 m m under the action of D-W cycles.Overall,the results in this study provide a useful guidancee for the long-term stability and evolution characteristics of EICP-reinforced sea sand under D-W weathering conditions. 展开更多
关键词 Enzyme-induced carbonate precipitation(EICP) Plant-based urease Drying-wetting(D-W)cycles Microstructure
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Pore evolution and shear characteristics of a soil-rock mixture upon freeze-thaw cycling
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作者 LiYun Tang ShiYuan Sun +4 位作者 JianGuo Zheng Long Jin YongTang Yu Tao Luo Xu Duan 《Research in Cold and Arid Regions》 CSCD 2023年第4期179-190,共12页
The changes in pore structure within soil-rock mixtures under freeze-thaw cycles in cold regions result in strength deterioration,leading to instability and slope failure.However,the existing studies mainly provided q... The changes in pore structure within soil-rock mixtures under freeze-thaw cycles in cold regions result in strength deterioration,leading to instability and slope failure.However,the existing studies mainly provided qualitative analysis of the changes in pore or strength of soil-rock mixture under freeze-thaw cycles.In contrast,few studies focused on the quantitative evaluation of pore change and the relationship between the freeze-thaw strength deterioration and pore change of soil-rock mixture.This study aims to explore the correlation between the micro-pore evolution characteristics and macro-mechanics of a soil-rock mixture after frequent freeze-thaw cycles during the construction and subsequent operation in a permafrost region.The pore characteristics of remolded soil samples with different rock contents(i.e.,25%,35%,45%,and 55%)subjected to various freeze-thaw cycles(i.e.,0,1,3,6,and 10)were quantitatively analyzed using nuclear magnetic resonance(NMR).Shear tests of soil-rock samples under different normal pressures were carried out simultaneously to explore the correlation between the soil strength changes and pore characteristics.The results indicate that with an increase in the number of freeze-thaw cycles,the cohesion of the soil-rock mixture generally decreases first,then increases,and finally decreases;however,the internal friction angle shows no apparent change.With the increase in rock content,the peak shear strength of the soil-rock mixture rises first and then decreases and peaks when the rock content is at 45%.When the rock content remains constant,as the number of freeze-thaw cycles rises,the shear strength of the sample reaches its peak after three freeze-thaw cycles.Studies have shown that with an increase in freeze-thaw cycles,the medium and large pores develop rapidly,especially for pores with a size of 0.2–20μm.Freeze-thaw cycling affects the internal pores of the soil-rock mixture by altering its skeleton and,therefore,impacts its macro-mechanical characteristics. 展开更多
关键词 Freeze-thaw cycling Soil-rock mixture NMR Pore change Shear strength
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Effects of Al and Co doping on the structural stability and high temperature cycling performance of LiNi_(0.5)Mn_(1.5)O_(4) spinel cathode materials
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作者 Jianfeng Cheng Meixuan Li +4 位作者 Yutong Wang Jiexiang Li Jiawei Wen Chunxia Wang Guoyong Huang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第9期201-209,共9页
The poor structural stability and capacity retention of the high-voltage spinel-type LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)limits their further application.Herein,Al and Co were doped in LNMO materials for a more stable struct... The poor structural stability and capacity retention of the high-voltage spinel-type LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)limits their further application.Herein,Al and Co were doped in LNMO materials for a more stable structure and capacity.The LNMO,LiNi_(0.45)Al_(0.05)Mn_(1.5)O_(4)(LNAMO)and LiNi_(0.45)Co_(0.05)Mn_(1.5)O_(4)(LNCMO)were synthesized by calcination at 900℃ for 8 h,which was called as solid-phase method and applied universally in industry.XRD,FT-IR and CV test results showed the synthesized samples have cation disordering Fd-3m space group structures.Moreover,the incorporation of Al and Co increased the cation disordering of LNMO,thereby increasing the transfer rate of Li+.The SEM results showed that the doped samples performed more regular and ortho-octahedral.The EDS elemental analysis confirmed the uniform distribution of each metal element in the samples.Moreover,the doped samples showed better electrochemical properties than undoped LNMO.The LNAMO and LNCMO samples were discharged with specific capacities of 116.3 mA·h·g^(-1)and 122.8 mA·h·g^(-1)at 1 C charge/discharge rate with good capacity retention of 95.8% and 94.8% after 200 cycles at room temperature,respectively.The capacity fading phenomenon of the doped samples at 50℃ and 1 C rate was significantly improved.Further,cations doping also enhanced the rate performance,especially for the LNCMO,the discharge specific capacity of 117.9 mA·h·g^(-1)can be obtained at a rate of 5 C. 展开更多
关键词 High voltage spinel Al/Co doping High temperature cycling stability
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有向图上基于层次树索引的最大cycle truss社区搜索
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作者 宗传玉 张纯鹤 夏秀峰 《计算机应用》 CSCD 北大核心 2024年第1期190-198,共9页
社区搜索旨在从信息网络中找出包含用户查询顶点的高内聚连通子图,cycle truss是一种基于cycle三角形的社区搜索模型,而现有的基于索引的cycle truss社区搜索方法存在索引空间大、搜索效率低、社区内聚性低的缺点。为了解决这一问题,提... 社区搜索旨在从信息网络中找出包含用户查询顶点的高内聚连通子图,cycle truss是一种基于cycle三角形的社区搜索模型,而现有的基于索引的cycle truss社区搜索方法存在索引空间大、搜索效率低、社区内聚性低的缺点。为了解决这一问题,提出一种基于层次树索引的最大cycle truss社区搜索方法。首先,提出了k-cycle truss分解算法,并引入了两个重要的概念:cycle三角连通与k-层次等价。基于k-层次等价设计了层次树索引TreeCIndex与表结构索引SuperTable,在此基础上,并基于这两个新的索引,提出了两个高效的cycle truss社区搜索算法。在4个真实数据集上与已有的基于TrussIndex与EquiTruss的社区搜索算法进行了比较,实验结果表明,TreeCIndex与SuperTable比TrussIndex与EquiTruss节省至少41.5%的空间,索引构建的时间节省8.2%至98.3%,且搜索最大cycle truss社区的效率分别高出了一个和两个数量级。 展开更多
关键词 有向图 社区搜索 cycle truss cycle三角形 层次等价 层次树索引
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Radicals on the silica surface:probes for studying dynamics by means of fast field cycling relaxometry and dynamic nuclear polarization
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作者 Bulat Gizatullin Carlos Mattea Siegfried Stapf 《Magnetic Resonance Letters》 2023年第3期256-265,I0004,共11页
Determining the dynamics of adsorbed liquids on nanoporous materials is crucial for a detailed understanding of interactions and processes on the solid-liquid interface in many materials and porous systems.Knowledge o... Determining the dynamics of adsorbed liquids on nanoporous materials is crucial for a detailed understanding of interactions and processes on the solid-liquid interface in many materials and porous systems.Knowledge of the influence of the presence of paramagnetic species on the surface or within the porous matrices is essential for fundamental studies and industrial processes such as catalysts.Magnetic resonance methods,such as electron paramagnetic resonance(EPR),nuclear magnetic resonance(NMR)and dynamic nuclear polarization(DNP),are powerful tools to address these questions and to quantify dy-namics,electron-nuclear interaction features and their relation to the physical-chemical parameters of the system.This paper presents an NMR study of the dynamics of polar and nonpolar adsorbed liquids,represented by water,n-decane,deuterated water and nonane-d20,on the native silica surface as well as silica modified with vanadyl porphyrins.The analysis of the frequency dependence of the nuclear spin-lattice relaxation time is carried out by separating the intra-and intermolecular contributions,which were analyzed using reorientations mediated by translational displacements(RMTD)and force-free-hard-sphere(FFHS)models,respectively. 展开更多
关键词 NMR relaxation Fast field cycling Porous media DNP PORPHYRINS
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Adaptive Route Sink Relocation Using Cluster Head Chain Cycling Model in WSN
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作者 M.Sudha P.Shanmugapriya +1 位作者 Rami Q.Malik Ahmed Alkhayyat 《Intelligent Automation & Soft Computing》 SCIE 2023年第5期1811-1826,共16页
Wireless Sensor Networks(WSN)have revolutionized the processes involved in industrial communication.However,the most important challenge faced by WSN sensors is the presence of limited energy.Multiple research inves-t... Wireless Sensor Networks(WSN)have revolutionized the processes involved in industrial communication.However,the most important challenge faced by WSN sensors is the presence of limited energy.Multiple research inves-tigations have been conducted so far on how to prolong the energy in WSN.This phenomenon is a result of inability of the network to have battery powered-sensor terminal.Energy-efficient routing on packetflow is a parallel phenomenon to delay nature,whereas the primary energy gets wasted as a result of WSN holes.Energy holes are present in the vicinity of sink and it is an important efficient-routing protocol for WSNs.In order to solve the issues discussed above,an energy-efficient routing protocol is proposed in this study named as Adaptive Route Decision Sink Relocation Protocol using Cluster Head Chain Cycling approach(ARDSR-CHC2H).The proposed method aims at improved communica-tion at sink-inviting routes.At this point,Cluster Head Node(CHN)is selected,since it consumes low energy and permits one node to communicate with others in two groups.The main purpose of the proposed model is to reduce energy con-sumption and define new interchange technology.A comparison of simulation results demonstrates that the proposed algorithm achieved low cluster creation time,better network error and high Packet Delivery Rate with less network failure. 展开更多
关键词 Cluster head energy-efficient routing chain routing cycling approach sink relocation adaptive routing WSN
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Dynamic simulation analysis of molten salt reactor-coupled air-steam combined cycle power generation system
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作者 Jing-Lei Huang Guo-Bin Jia +3 位作者 Li-Feng Han Wen-Qian Liu Li Huang Zheng-Han Yang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第2期222-233,共12页
A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the mol... A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the molten salt reactor and power system.This model considers the impact of thermal properties of fluid variation on accuracy and has been validated with Simulink.This study reveals the capability of the control system to compensate for anomalous situations and maintain shaft stability in the event of perturbations occurring in high-temperature molten salt tank outlet parameters.Meanwhile,the control system’s impact on the system’s dynamic characteristics under molten salt disturbance is also analyzed.The results reveal that after the disturbance occurs,the controlled system benefits from the action of the control,and the overshoot and disturbance amplitude are positively correlated,while the system power and frequency eventually return to the initial values.This simulation model provides a basis for utilizing molten salt reactors for power generation and maintaining grid stability. 展开更多
关键词 Molten salt reactor Combined cycle Dynamic characteristic CONTROL
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THE LIMIT CYCLE BIFURCATIONS OF A WHIRLING PENDULUM WITH PIECEWISE SMOOTH
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作者 杨纪华 《Acta Mathematica Scientia》 SCIE CSCD 2024年第3期1115-1144,共30页
This paper deals with the problem of limit cycles for the whirling pendulum equation x=y,y=sin x(cosx-r)under piecewise smooth perturbations of polynomials of cos x,sin x and y of degree n with the switching line x=0.... This paper deals with the problem of limit cycles for the whirling pendulum equation x=y,y=sin x(cosx-r)under piecewise smooth perturbations of polynomials of cos x,sin x and y of degree n with the switching line x=0.The upper bounds of the number of limit cycles in both the oscillatory and the rotary regions are obtained using the Picard-Fuchs equations,which the generating functions of the associated first order Melnikov functions satisfy.Furthermore,the exact bound of a special case is given using the Chebyshev system.At the end,some numerical simulations are given to illustrate the existence of limit cycles. 展开更多
关键词 whirling pendulum limit cycle Melnikov function Picard-Fuchs equation Chebyshev system
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