K-Ar dating of synkinematic illite is increasingly recognized as a central method to constrain the timing of shallow crustal faulting.Methods of efficient sample preparation and quantitative identification of illite p...K-Ar dating of synkinematic illite is increasingly recognized as a central method to constrain the timing of shallow crustal faulting.Methods of efficient sample preparation and quantitative identification of illite polytypes are critical to acquiring K-Ar isotope data for authigenic clays.In this respect,we compared the commonly used clay size separation method through centrifugation with vacuum filtration technology,showing that the former is prone to extract fractions with finer particle sizes under similar conditions,thus improving the error in the authigenic end-member age.Additionally,we demonstrated that the side-packed mounting method for X-ray diffraction analysis can significantly enhance the randomness in powder samples,thus improving the quantification accuracy compared with the front-packed and back-packed methods.The validity of our quantification method was confirmed by comparing Profex■modeling patterns with a suite of synthetic mixtures of known compositions,yielding an average analytical error of 3%.Dating results of these artificial mixtures and the reference materials indicated that a large range in percentages of detrital illite and a sufficient amount of age data will produce reliable results for ages of both extrapolated end-members.However,if the range is limited,the extrapolated age close to those of datasets is still reliable.展开更多
Based on K-Ar isotope analyses, Mesozoic mafic (and alkali ultramafic) dikes from western and eastern Shandong Province, China, are dated at 88.2±1.70 Ma to 169.5±3.7 Ma with the majority of ages ranging fro...Based on K-Ar isotope analyses, Mesozoic mafic (and alkali ultramafic) dikes from western and eastern Shandong Province, China, are dated at 88.2±1.70 Ma to 169.5±3.7 Ma with the majority of ages ranging from 90 Ma to 140 Ma. The emplacement of the dikes suggests a major Yanshanian (Cretaceous) crustal extension in Shandong province. Together with other available age data, this study suggests four periods of crustal extension at about 80 Ma, 100 Ma, 120 Ma and 140 Ma, respectively. Besides the effect of collapse of the Yanshanian orogenic belt on the emplacement of the mafic dikes in Shandong in the Cretaceous, the mantle plume and the extensive left-lateral advection and extension of the Tanlu fault also have controlled the crustal extension and the emplacement of the mafic dikes in eastern Shandong and western Shandong, respectively.展开更多
The major elements, trace elements. K-Ar age and Sr-Nd-Pb isotopie systems ofthe Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province aremeasured. The volcanic rocks ( olivine-nephelinite...The major elements, trace elements. K-Ar age and Sr-Nd-Pb isotopie systems ofthe Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province aremeasured. The volcanic rocks ( olivine-nephelinite and nephcline-basanite ) in Daheishan Islanderupted periodically in an interval of 0.32 Ma, from 8.72 Ma. 8.39 Ma. 8.08 Ma to 7.73 Ma. Thevolcanic rocks arc all rich in light REEs. They are similar to the OIB-type alkali basalt in thetrace elements normalized model by primordial mantle: rich in high field elements such as Nb and Ta,and imcompatible elements such as Cs. Rb, Ba, Th. U. The volcanic rocks show a depletion of K andRb elements. It is suggested by the trace elements that the olivine-nephelinite in Daheishan Islandis originated from deep resources under the continental mantle. ε Nd (0) values of the volcanicrocks in Daheishan Island and Cishan are 5.31~8.51 and 7.33 respectively, suggesting that thevolcanic rocks are from the depleted mantle resources, which have higher Sm/Nd ratios than the CHUR.^(143)Nd /^(144)Nd ratios ot Daheishan Island olivine-nephelinite and Cishan alkali basalts are0.512 910~0.513 074 and 0.513 014 respectively. The ^(87)Sr /^(86)Sr of Daheishan Island volcanicrocks are lower than that of Cishan, 0.703 427 ~0.703 482 and 0.703 895 respectively. The DaheishanIsland olivine-nephelinite has the Pb isotopie values as follows: ^(206)Pb/^(204)Pb= 18.028 9~17.972 8. ^(207)Pb / ^(204)Pb = 15.435 8 ~15.402 2 and ^(208)Pb /^(204)Pb = 38.087 6~37.997 5.lower than those of Cishan basanite. The Cishan basanite has ^(206)Pb/^(204)Pb= 18.240 1. ^(207)Pb/^(204)Pb= 15.564 5 and ^(208)Pb /^(204)Pb = 38.535. The authors suggest that theolivine-nephelinite in Daheishan Island is similar to the E-type MORB or Hawaii OIB, and the alkalibasalts in Cishan similar to the Kerguelen OIB. The dominant mantle components of DM+PREMA andperhaps DM ( Dupal type ) are the dominant mantle components for volcanic rocks in Daheishan Islandand Cishan. The PREMA component plays an important role.展开更多
The Dashuigou tellurium deposit found in 1991 in Shimian County, Sichuan Province of China, is the first and only independent tellurium deposit in the world. The deposit is located on the western margin of the Yangtze...The Dashuigou tellurium deposit found in 1991 in Shimian County, Sichuan Province of China, is the first and only independent tellurium deposit in the world. The deposit is located on the western margin of the Yangtze Platform. The tellurium ore bodies taking vein and lentiform shapes filled the N-S fractures in the pyrrhotite veins in hornblende schists at the northern limb of the Middle and Lower Triassic metamorphic arch. The main wallrock alterations are biotitization, sericitization, greisenization, dolomitization,展开更多
基金funded by the National Natural Science Foundation of China(Nos.42072240 and 41602218)Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory(No.GML2019ZD0201)the Fund from the Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources,Chinese Academy of Geological Sciences(Nos.J1901-30 and J1908)。
文摘K-Ar dating of synkinematic illite is increasingly recognized as a central method to constrain the timing of shallow crustal faulting.Methods of efficient sample preparation and quantitative identification of illite polytypes are critical to acquiring K-Ar isotope data for authigenic clays.In this respect,we compared the commonly used clay size separation method through centrifugation with vacuum filtration technology,showing that the former is prone to extract fractions with finer particle sizes under similar conditions,thus improving the error in the authigenic end-member age.Additionally,we demonstrated that the side-packed mounting method for X-ray diffraction analysis can significantly enhance the randomness in powder samples,thus improving the quantification accuracy compared with the front-packed and back-packed methods.The validity of our quantification method was confirmed by comparing Profex■modeling patterns with a suite of synthetic mixtures of known compositions,yielding an average analytical error of 3%.Dating results of these artificial mixtures and the reference materials indicated that a large range in percentages of detrital illite and a sufficient amount of age data will produce reliable results for ages of both extrapolated end-members.However,if the range is limited,the extrapolated age close to those of datasets is still reliable.
文摘Based on K-Ar isotope analyses, Mesozoic mafic (and alkali ultramafic) dikes from western and eastern Shandong Province, China, are dated at 88.2±1.70 Ma to 169.5±3.7 Ma with the majority of ages ranging from 90 Ma to 140 Ma. The emplacement of the dikes suggests a major Yanshanian (Cretaceous) crustal extension in Shandong province. Together with other available age data, this study suggests four periods of crustal extension at about 80 Ma, 100 Ma, 120 Ma and 140 Ma, respectively. Besides the effect of collapse of the Yanshanian orogenic belt on the emplacement of the mafic dikes in Shandong in the Cretaceous, the mantle plume and the extensive left-lateral advection and extension of the Tanlu fault also have controlled the crustal extension and the emplacement of the mafic dikes in eastern Shandong and western Shandong, respectively.
基金supported by the National Major Fundamental Research and Development Project(No.G2000046703).
文摘The major elements, trace elements. K-Ar age and Sr-Nd-Pb isotopie systems ofthe Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province aremeasured. The volcanic rocks ( olivine-nephelinite and nephcline-basanite ) in Daheishan Islanderupted periodically in an interval of 0.32 Ma, from 8.72 Ma. 8.39 Ma. 8.08 Ma to 7.73 Ma. Thevolcanic rocks arc all rich in light REEs. They are similar to the OIB-type alkali basalt in thetrace elements normalized model by primordial mantle: rich in high field elements such as Nb and Ta,and imcompatible elements such as Cs. Rb, Ba, Th. U. The volcanic rocks show a depletion of K andRb elements. It is suggested by the trace elements that the olivine-nephelinite in Daheishan Islandis originated from deep resources under the continental mantle. ε Nd (0) values of the volcanicrocks in Daheishan Island and Cishan are 5.31~8.51 and 7.33 respectively, suggesting that thevolcanic rocks are from the depleted mantle resources, which have higher Sm/Nd ratios than the CHUR.^(143)Nd /^(144)Nd ratios ot Daheishan Island olivine-nephelinite and Cishan alkali basalts are0.512 910~0.513 074 and 0.513 014 respectively. The ^(87)Sr /^(86)Sr of Daheishan Island volcanicrocks are lower than that of Cishan, 0.703 427 ~0.703 482 and 0.703 895 respectively. The DaheishanIsland olivine-nephelinite has the Pb isotopie values as follows: ^(206)Pb/^(204)Pb= 18.028 9~17.972 8. ^(207)Pb / ^(204)Pb = 15.435 8 ~15.402 2 and ^(208)Pb /^(204)Pb = 38.087 6~37.997 5.lower than those of Cishan basanite. The Cishan basanite has ^(206)Pb/^(204)Pb= 18.240 1. ^(207)Pb/^(204)Pb= 15.564 5 and ^(208)Pb /^(204)Pb = 38.535. The authors suggest that theolivine-nephelinite in Daheishan Island is similar to the E-type MORB or Hawaii OIB, and the alkalibasalts in Cishan similar to the Kerguelen OIB. The dominant mantle components of DM+PREMA andperhaps DM ( Dupal type ) are the dominant mantle components for volcanic rocks in Daheishan Islandand Cishan. The PREMA component plays an important role.
文摘The Dashuigou tellurium deposit found in 1991 in Shimian County, Sichuan Province of China, is the first and only independent tellurium deposit in the world. The deposit is located on the western margin of the Yangtze Platform. The tellurium ore bodies taking vein and lentiform shapes filled the N-S fractures in the pyrrhotite veins in hornblende schists at the northern limb of the Middle and Lower Triassic metamorphic arch. The main wallrock alterations are biotitization, sericitization, greisenization, dolomitization,