A series of BUC-21/N-K2Ti4O9 composites(B1NX)were facilely fabricated from BUC-21 and N-K2Ti4O9 via ball-milling,and they were fully characterized using various techniques.The photocatalytic reduction of Cr(Ⅵ)over th...A series of BUC-21/N-K2Ti4O9 composites(B1NX)were facilely fabricated from BUC-21 and N-K2Ti4O9 via ball-milling,and they were fully characterized using various techniques.The photocatalytic reduction of Cr(Ⅵ)over the B1NX composites was investigated systematically under various conditions,including different light sources,pH values,hole scavengers,and inorganic ions,in both real lake water and tap water.The BUC-21/N-K2Ti4O9 composites demonstrated remarkable photocatalytic Cr(Ⅵ)reduction performance,good reusability,and stability under both UV and white light irradiation.The introduction of N-K2Ti4O9 into BUC-21 not only broadened its light absorption region to white light,but also strongly inhibited the recombination of the photo-generated electrons and holes.Mechanisms of photocatalytic Cr(Ⅵ)reduction under both UV light and white light were proposed and verified by electrochemical measurements,active species capture experiments,and ESR measurements.展开更多
Photocatalyst CoPcS/TiO2 was prepared by sol-gel method. Composite CoPcS/TiO2/K2Ti4O9 was prepared by dipping. It was incandesced at various temperatures and modification effect was compared. The results showed that o...Photocatalyst CoPcS/TiO2 was prepared by sol-gel method. Composite CoPcS/TiO2/K2Ti4O9 was prepared by dipping. It was incandesced at various temperatures and modification effect was compared. The results showed that optical absorption of sample incandesce at 423K occurred significant red-shift. Light absorption width extended from ultraviolet region to visible region, especially there was an intensive absorption between 600 nm and 680 nm. X-ray diffraction spectrogram showed that TiO2 in sample still maintained anatase crystal form. Under the illumination of visible light, photocatalysis degradation experiment was taken with Eosin B as simulated pollutants. Decoloration rate of Eosin B was much improved. The rate can reach 80% in 300 minutes.展开更多
In order to realize the photocatalysis of TiO2 in the sunlight and directly apply it to waste water treatment, the Gd-doped TiO2 nanofibre was synthesized using two-step synthesis method as follows: Firstly, potassium...In order to realize the photocatalysis of TiO2 in the sunlight and directly apply it to waste water treatment, the Gd-doped TiO2 nanofibre was synthesized using two-step synthesis method as follows: Firstly, potassium carbonate, titanium dioxide and proper gadolinium oxide （dopant） were calcined in the muffle at high temperature and the doped gadolinium K2Ti4O9 fibres were obtained; secondly, the fibre was heated using glycerol as solvent until Gd-doped TiO2 nanofibres were obtained. The synthesized samples were characterized using scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The results show that Gd-doped TiO2 nanofibre heat-treated by glycerol solvent can inhibit the agglomeration, so the grain diameter of the fibre is smaller than that without heat-treated with glycerol. Meanwhile, the diameter of the fibre decreases with the increase of the heating temperature and time. 97% 98% of Gd-doped TiO2 nanofibre is anatase. The photocatalysis results showed that the photocatalysis activity of Gd-doped TiO2 nanofibre is just a little lower than that of TiO2 powder.展开更多
The K2Ti4O9 whiskers were chosen for the catalyst carrier, TiO2/potassium titanate photocatalyst was prepared by Sol-gel method. The product was characterated by X-ray diffraction and SEM. EDS shows that, the main pec...The K2Ti4O9 whiskers were chosen for the catalyst carrier, TiO2/potassium titanate photocatalyst was prepared by Sol-gel method. The product was characterated by X-ray diffraction and SEM. EDS shows that, the main peck included Ti, O, and K in potassium titanate whisker. The main peak of K disappeared and the peaks of Ti, O stayed after whisker was covered. It directed that the surface of sample was covered by TiO2. XRD shows that diffraction peak appeared, which was corresponded to the peak of anatase TiO2. In the reaction device of photochemistry, using middle-pressure mercury lamp as illumination, rhodamine B as simulant pollutant, the photocatalytic performance of TiO2/potassium titanate was studied. Under the same conditions, the lower pH, the larger illuminance, the higher temperature, the greater aeration quantum and the lower initial concentration of rhodamine B, the higher decoloration rate was got. Under our experiment conditions: pH 6, the illuminance of 250W, the temperature of 313K, and the aeration quantum of 2.0L/min. When the concentration of rhodamine B was 8mg/L The photocatalyst of TiO2/potassium titanate was 0.01g/L. The decoloration rate of TiO2/potassium titanate dealt with the rhodamine B reach over 95% in 160min, and compare with TiO2, the decoloration rate of rhodamine B was improved 0.50~1.91 multiple. TiO2/potassium titanate can be used to treatment of dye wastewater.展开更多
In order to decrease cutting fluid and improve environment, the cutting fluid was replaced by solid lubricant. Four kinds of solid lubricants were tested on a high temperature friction tester, from which nano K 2Ti ...In order to decrease cutting fluid and improve environment, the cutting fluid was replaced by solid lubricant. Four kinds of solid lubricants were tested on a high temperature friction tester, from which nano K 2Ti 4O 9 whisker enhanced solid lubrication film was chosen. It was coated on the surface of cutters and tested on a CA6140 lathe. At the rate of 400r/min, the wear of the tool flank with solid lubrication film is 1/6 of that without the film, and it is even lower than that using cutting fluid. With the increase of cutting speed, the wear of the tool flank with solid lubrication film is still lower than that without film, but it is higher than that using cutting fluid. Surface analyses by AFM, SEM and EDX reveal that the solid lubrication film can prevent Fe element of chips from diffusing the cutter surface; adhesion of the cutter and chips is abated and the wear of the tool flank is obviously decreased.展开更多
文摘A series of BUC-21/N-K2Ti4O9 composites(B1NX)were facilely fabricated from BUC-21 and N-K2Ti4O9 via ball-milling,and they were fully characterized using various techniques.The photocatalytic reduction of Cr(Ⅵ)over the B1NX composites was investigated systematically under various conditions,including different light sources,pH values,hole scavengers,and inorganic ions,in both real lake water and tap water.The BUC-21/N-K2Ti4O9 composites demonstrated remarkable photocatalytic Cr(Ⅵ)reduction performance,good reusability,and stability under both UV and white light irradiation.The introduction of N-K2Ti4O9 into BUC-21 not only broadened its light absorption region to white light,but also strongly inhibited the recombination of the photo-generated electrons and holes.Mechanisms of photocatalytic Cr(Ⅵ)reduction under both UV light and white light were proposed and verified by electrochemical measurements,active species capture experiments,and ESR measurements.
基金Acknowledgements： This project is supported by the fund of the Plan of Postgraduate Scientific Research Innovation of Jiangsu Province （No. CX07B_175z） and the Natural Science Foundation of Henan Province （No. 0624720029）.
文摘Photocatalyst CoPcS/TiO2 was prepared by sol-gel method. Composite CoPcS/TiO2/K2Ti4O9 was prepared by dipping. It was incandesced at various temperatures and modification effect was compared. The results showed that optical absorption of sample incandesce at 423K occurred significant red-shift. Light absorption width extended from ultraviolet region to visible region, especially there was an intensive absorption between 600 nm and 680 nm. X-ray diffraction spectrogram showed that TiO2 in sample still maintained anatase crystal form. Under the illumination of visible light, photocatalysis degradation experiment was taken with Eosin B as simulated pollutants. Decoloration rate of Eosin B was much improved. The rate can reach 80% in 300 minutes.
文摘In order to realize the photocatalysis of TiO2 in the sunlight and directly apply it to waste water treatment, the Gd-doped TiO2 nanofibre was synthesized using two-step synthesis method as follows: Firstly, potassium carbonate, titanium dioxide and proper gadolinium oxide （dopant） were calcined in the muffle at high temperature and the doped gadolinium K2Ti4O9 fibres were obtained; secondly, the fibre was heated using glycerol as solvent until Gd-doped TiO2 nanofibres were obtained. The synthesized samples were characterized using scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The results show that Gd-doped TiO2 nanofibre heat-treated by glycerol solvent can inhibit the agglomeration, so the grain diameter of the fibre is smaller than that without heat-treated with glycerol. Meanwhile, the diameter of the fibre decreases with the increase of the heating temperature and time. 97% 98% of Gd-doped TiO2 nanofibre is anatase. The photocatalysis results showed that the photocatalysis activity of Gd-doped TiO2 nanofibre is just a little lower than that of TiO2 powder.
基金The Innovation Foundation of the Ministry of Science and Technology of China (No. 03C26213200932)the Natural Science Foundation of Henan Province (No.0624720029).
文摘The K2Ti4O9 whiskers were chosen for the catalyst carrier, TiO2/potassium titanate photocatalyst was prepared by Sol-gel method. The product was characterated by X-ray diffraction and SEM. EDS shows that, the main peck included Ti, O, and K in potassium titanate whisker. The main peak of K disappeared and the peaks of Ti, O stayed after whisker was covered. It directed that the surface of sample was covered by TiO2. XRD shows that diffraction peak appeared, which was corresponded to the peak of anatase TiO2. In the reaction device of photochemistry, using middle-pressure mercury lamp as illumination, rhodamine B as simulant pollutant, the photocatalytic performance of TiO2/potassium titanate was studied. Under the same conditions, the lower pH, the larger illuminance, the higher temperature, the greater aeration quantum and the lower initial concentration of rhodamine B, the higher decoloration rate was got. Under our experiment conditions: pH 6, the illuminance of 250W, the temperature of 313K, and the aeration quantum of 2.0L/min. When the concentration of rhodamine B was 8mg/L The photocatalyst of TiO2/potassium titanate was 0.01g/L. The decoloration rate of TiO2/potassium titanate dealt with the rhodamine B reach over 95% in 160min, and compare with TiO2, the decoloration rate of rhodamine B was improved 0.50~1.91 multiple. TiO2/potassium titanate can be used to treatment of dye wastewater.
文摘In order to decrease cutting fluid and improve environment, the cutting fluid was replaced by solid lubricant. Four kinds of solid lubricants were tested on a high temperature friction tester, from which nano K 2Ti 4O 9 whisker enhanced solid lubrication film was chosen. It was coated on the surface of cutters and tested on a CA6140 lathe. At the rate of 400r/min, the wear of the tool flank with solid lubrication film is 1/6 of that without the film, and it is even lower than that using cutting fluid. With the increase of cutting speed, the wear of the tool flank with solid lubrication film is still lower than that without film, but it is higher than that using cutting fluid. Surface analyses by AFM, SEM and EDX reveal that the solid lubrication film can prevent Fe element of chips from diffusing the cutter surface; adhesion of the cutter and chips is abated and the wear of the tool flank is obviously decreased.
