Two systems of La_(2-x)Sr_xCuO_(4±λ) and La_(2-x)Th_xCuO_(4±λ) mixed oxides with K_2NiF_4structure were synthesized.The compositions and structures of the catalysts were characterized by means of XRD,XPS,c...Two systems of La_(2-x)Sr_xCuO_(4±λ) and La_(2-x)Th_xCuO_(4±λ) mixed oxides with K_2NiF_4structure were synthesized.The compositions and structures of the catalysts were characterized by means of XRD,XPS,chemical analysis and so on.The catalytic behavior for the direct decomposition of NO has been investigated.The results show that the catalytic activity is closely related to the oxygen vacancy and lower valence metallic ion in the direct decomposition of NO.The presence of oxygen vacancy is necessary for mixed oxide to have steady activity in NO decomposition.展开更多
文摘Two systems of La_(2-x)Sr_xCuO_(4±λ) and La_(2-x)Th_xCuO_(4±λ) mixed oxides with K_2NiF_4structure were synthesized.The compositions and structures of the catalysts were characterized by means of XRD,XPS,chemical analysis and so on.The catalytic behavior for the direct decomposition of NO has been investigated.The results show that the catalytic activity is closely related to the oxygen vacancy and lower valence metallic ion in the direct decomposition of NO.The presence of oxygen vacancy is necessary for mixed oxide to have steady activity in NO decomposition.
