For dividing-wall distillation columns(DWDCs) separating a heavy-component dominated and wide boiling-point ternary(HCDWBT) mixture, a significant amount of excessive heat exists inevitably in stripping the heavy-comp...For dividing-wall distillation columns(DWDCs) separating a heavy-component dominated and wide boiling-point ternary(HCDWBT) mixture, a significant amount of excessive heat exists inevitably in stripping the heavy-component from the intermediate-component and it can be employed to initiate the development of vapor recompression heat pump(VRHP) assisted DWDC(VRHP-DWDC). Despite dividing wall may locate in the top, middle, and bottom, the optimum VRHP-DWDC is found to involve uniformlytwo VRHP circles. While the first one serves to compress and transform the excessive heat resulted from the separation of the heavy-component from the intermediate-component, the second one to compress and transform the overhead vapor stream of the light-component pre-heated sequentially with the condensate from the first one and the bottom product stream of the heavy-component, both releasing the temperature-elevated latent heat to the pre-fractionator's or common stripping section. The processing of two HCDWBT mixtures of benzene/toluene/o-xylene and n-pentane/n-hexane/n-heptane are selected to assess the derived optimum topological configurations of the VRHP-DWDC and their optimality is confirmed through detailed comparisons with the DWDC and two VRHP-DWDCs involving only one VRHP circle. The proposed strategy helps to tap the full potential of the VRHP-DWDC with considerably alleviated complication in process development.展开更多
The mass and thermal coupling makes the control of the reactive double dividing-wall distillation column(R-DDWDC) an especially challenging issue with a highly interactive nature. With reference to the separation of a...The mass and thermal coupling makes the control of the reactive double dividing-wall distillation column(R-DDWDC) an especially challenging issue with a highly interactive nature. With reference to the separation of an ideal endothermic quaternary reversible reaction with the most unfavorable ranking of relative volatilities(A + B ■ C + D with α_(A)>α_(C)>α_(D)>α_(B)), the operation rationality of the R-DDWDC is studied in this contribution. The four-point single temperature control system leads to great steady-state discrepancies in the compositions of products C and D and the reason stems essentially from the failure in keeping strictly the stoichiometric ratio between reactants A and B. A temperature plus temperature cascade control scheme is then employed to reinforce the stoichiometric ratio control and helps to secure a substantial abatement in the steady-state discrepancies. A temperature difference plus temperature cascade control scheme is finally synthesized and leads even to better performance than the most effective double temperature difference control scheme. These outcomes reveal not only the operation feasibility of the R-DDWDC but also the general significance of the proposed temperature difference plus temperature cascade control scheme to the inferential control of any other complicated distillation columns.展开更多
Reactive dividing-wall column(RDWC) technology plays a critical role in the energy saving and high efficiency of chemical process.In this article, the process of co-producing ethyl acetate(EA) and n-butyl acetate(BA) ...Reactive dividing-wall column(RDWC) technology plays a critical role in the energy saving and high efficiency of chemical process.In this article, the process of co-producing ethyl acetate(EA) and n-butyl acetate(BA) with RDWC was studied.BA was not only the product, but also acted as entrainer to remove the water generated by the two esterification reactions.Experiments and simulations of the co-production process were carried out.It was found that the experimental results were in good agreement with the simulation results.Two kinds of RDWC structures(RDWC-FC and RDWC-RS) were proposed, and the co-production process operating parameters of the two types of RDWC were optimized by Aspen Plus respectively.The optimal operating parameters of the RDWC-FC were determined as follows: 0.6 of the reflux ratio of aqueous phase(RR), 0.66 of the vapor split(R_V) and 0.51 of the liquid split(R_L).And the optimal operating parameters of the RDWC-RS were shown as follows: RR was 0.295 and R_V was 0.61.Furthermore, the energy saving analysis of the co-production process was based on the annual output of 10000 tons of EA, compared with the traditional reaction distillation(RD) to prepare EA and BA, the reboiler duty of the RDWC-FC column could save 20.4%, TAC saving 23.6%; RDWC-RS reboiler energy consumption could save 17.0%, TAC 22.2%.展开更多
Due to the topological structure of double columns and multiple separating sections in dividing-wall distillation columns(DWDCs),the development of vapor recompressed dividing-wall distillation columns(DWDC-VRHPs)repr...Due to the topological structure of double columns and multiple separating sections in dividing-wall distillation columns(DWDCs),the development of vapor recompressed dividing-wall distillation columns(DWDC-VRHPs)represents a challenging issue with great complexities and tediousness.For the separations of light-component dominated and wide boiling-point ternary mixtures,because the purification of the light-component from the intermediate-and heavy-components incurs the primary energy dissipation,the application of vapor recompressed heat pumps(VRHP)should be aimed to reduce the irreversibility and this leads to the generation of the optimum topological structures of the DWDC-VRHPs,i.e.,a DWDC plus a two-stage VRHP.The first-stage VRHP is to preheat feed,not only taking the advantages of the small temperature elevation available but also favoring the mass transfer between the vapor and liquid phases through feed splitting.The second-stage VRHP is to reduce further separation irreversibility.The philosophy can be applied to any DWDCs no matter where the dividing wall locates.Two case studies on the separations of ternary mixtures of benzene,toluene,and o-xylene and n-pentane,n-hexane,and n-heptane demonstrate the economic optimality of the proposed DWDC-VRHPs and reveal the inherent interplay between internal and external process integration.展开更多
The extractive dividing-wall column(EDWC)is one of the most efficient technologies for separation of azeotropic or close boiling-point mixtures,but its design is fairly challenging.In this paper we extend the hybrid f...The extractive dividing-wall column(EDWC)is one of the most efficient technologies for separation of azeotropic or close boiling-point mixtures,but its design is fairly challenging.In this paper we extend the hybrid feasible path optimisation algorithm(Ma Y,McLaughlan M,Zhang N,Li J.Computers&Chemical Engineering,2020,143:107058)for such optimal design.The tolerances-relaxation integration method is refined to allow for long enough integration time that can ensure the solution of the pseudo-transient continuation simulation close to the steady state before the required tolerance is used.To ensure the gradient and Jacobian information available for optimisation,we allow a relaxed tolerance for the simulation in the sensitivity analysis mode when the simulation diverges under small tolerance.In addition,valid lower bounds on purity of the recycled entrainer and the vapour flow rate in column sections are imposed to improve computational efficiency.The computational results demonstrate that the extended hybrid algorithm can achieve better design of the EDWC compared to those in literature.The energy consumption can be reduced by more than 20%compared with existing literature report.In addition,the optimal design of the heat pump assisted EDWC is achieved using the improved hybrid algorithm for the first time.展开更多
Dividing-wall columns(DWCs)are widely used in the separation of ternary mixtures,but rarely seen in the separation of petroleum fractions.This work develops two novel and energy-efficient designs of lubricant-type vac...Dividing-wall columns(DWCs)are widely used in the separation of ternary mixtures,but rarely seen in the separation of petroleum fractions.This work develops two novel and energy-efficient designs of lubricant-type vacuum distillation process(LVDP)for the separation of hydroisomerization fractions(HIF)of a hydrocracking tail oil(HTO).First,the HTO hydroisomerization reaction is investigated in an experimental fixed-bed reactor to achieve the optimum liquid HIF by analyzing the impact of the operating conditions.A LVDP used for HIF separation is proposed and optimized.Subsequently,two thermal coupling intensified technologies,including side-stream(SC)and dividing-wall column(DWC),are combined with the LVDP to develop side-stream vacuum distillation process(SC-LVDP)and dividing-wall column vacuum distillation process(DWC-LVDP).The performance of LVDP,SC-LVDP,and DWC-LVDP are evaluated in terms of energy consumption,capital cost,total annual cost,product yields,and stripping steam consumption.The results demonstrates that the intensified processes,SC-LVDP and DWC-LVDP significantly decreases the energy consumption and capital cost compared with LVDP.DWC-LVDP further decreases in capital cost due to the removal of the side stripper and narrows the overlap between the third lube oils and fourth lube oils.This study attempts to combine DWC structure into the separation of petroleum fractions,and the proposed approach and the results presented provide an incentive for the industrial implementation of high-quality utilization of HTO through intensified LVDP.展开更多
基金The financial support from National Natural Science Foundation of China (21878011)。
文摘For dividing-wall distillation columns(DWDCs) separating a heavy-component dominated and wide boiling-point ternary(HCDWBT) mixture, a significant amount of excessive heat exists inevitably in stripping the heavy-component from the intermediate-component and it can be employed to initiate the development of vapor recompression heat pump(VRHP) assisted DWDC(VRHP-DWDC). Despite dividing wall may locate in the top, middle, and bottom, the optimum VRHP-DWDC is found to involve uniformlytwo VRHP circles. While the first one serves to compress and transform the excessive heat resulted from the separation of the heavy-component from the intermediate-component, the second one to compress and transform the overhead vapor stream of the light-component pre-heated sequentially with the condensate from the first one and the bottom product stream of the heavy-component, both releasing the temperature-elevated latent heat to the pre-fractionator's or common stripping section. The processing of two HCDWBT mixtures of benzene/toluene/o-xylene and n-pentane/n-hexane/n-heptane are selected to assess the derived optimum topological configurations of the VRHP-DWDC and their optimality is confirmed through detailed comparisons with the DWDC and two VRHP-DWDCs involving only one VRHP circle. The proposed strategy helps to tap the full potential of the VRHP-DWDC with considerably alleviated complication in process development.
基金the financial support from National Natural Science Foundation of China (21878011)。
文摘The mass and thermal coupling makes the control of the reactive double dividing-wall distillation column(R-DDWDC) an especially challenging issue with a highly interactive nature. With reference to the separation of an ideal endothermic quaternary reversible reaction with the most unfavorable ranking of relative volatilities(A + B ■ C + D with α_(A)>α_(C)>α_(D)>α_(B)), the operation rationality of the R-DDWDC is studied in this contribution. The four-point single temperature control system leads to great steady-state discrepancies in the compositions of products C and D and the reason stems essentially from the failure in keeping strictly the stoichiometric ratio between reactants A and B. A temperature plus temperature cascade control scheme is then employed to reinforce the stoichiometric ratio control and helps to secure a substantial abatement in the steady-state discrepancies. A temperature difference plus temperature cascade control scheme is finally synthesized and leads even to better performance than the most effective double temperature difference control scheme. These outcomes reveal not only the operation feasibility of the R-DDWDC but also the general significance of the proposed temperature difference plus temperature cascade control scheme to the inferential control of any other complicated distillation columns.
基金Supported by the National Key R&D Program of China(2017YFB0602500)the Key Basic Research Items in Application Basic Research Program of Hebei Province,China(16964502D)
文摘Reactive dividing-wall column(RDWC) technology plays a critical role in the energy saving and high efficiency of chemical process.In this article, the process of co-producing ethyl acetate(EA) and n-butyl acetate(BA) with RDWC was studied.BA was not only the product, but also acted as entrainer to remove the water generated by the two esterification reactions.Experiments and simulations of the co-production process were carried out.It was found that the experimental results were in good agreement with the simulation results.Two kinds of RDWC structures(RDWC-FC and RDWC-RS) were proposed, and the co-production process operating parameters of the two types of RDWC were optimized by Aspen Plus respectively.The optimal operating parameters of the RDWC-FC were determined as follows: 0.6 of the reflux ratio of aqueous phase(RR), 0.66 of the vapor split(R_V) and 0.51 of the liquid split(R_L).And the optimal operating parameters of the RDWC-RS were shown as follows: RR was 0.295 and R_V was 0.61.Furthermore, the energy saving analysis of the co-production process was based on the annual output of 10000 tons of EA, compared with the traditional reaction distillation(RD) to prepare EA and BA, the reboiler duty of the RDWC-FC column could save 20.4%, TAC saving 23.6%; RDWC-RS reboiler energy consumption could save 17.0%, TAC 22.2%.
基金financial financial support from National Natural Science Foundation of China(218780112167601121808007)。
文摘Due to the topological structure of double columns and multiple separating sections in dividing-wall distillation columns(DWDCs),the development of vapor recompressed dividing-wall distillation columns(DWDC-VRHPs)represents a challenging issue with great complexities and tediousness.For the separations of light-component dominated and wide boiling-point ternary mixtures,because the purification of the light-component from the intermediate-and heavy-components incurs the primary energy dissipation,the application of vapor recompressed heat pumps(VRHP)should be aimed to reduce the irreversibility and this leads to the generation of the optimum topological structures of the DWDC-VRHPs,i.e.,a DWDC plus a two-stage VRHP.The first-stage VRHP is to preheat feed,not only taking the advantages of the small temperature elevation available but also favoring the mass transfer between the vapor and liquid phases through feed splitting.The second-stage VRHP is to reduce further separation irreversibility.The philosophy can be applied to any DWDCs no matter where the dividing wall locates.Two case studies on the separations of ternary mixtures of benzene,toluene,and o-xylene and n-pentane,n-hexane,and n-heptane demonstrate the economic optimality of the proposed DWDC-VRHPs and reveal the inherent interplay between internal and external process integration.
基金The authors would like to thank the financial support from China Scholarship Council-The University of Manchester Joint scholarship(Grant No.201809120005)Cuiwen Cao would like to thank the financial support from the National Natural Science Foundation of China(Grant No.61673175).
文摘The extractive dividing-wall column(EDWC)is one of the most efficient technologies for separation of azeotropic or close boiling-point mixtures,but its design is fairly challenging.In this paper we extend the hybrid feasible path optimisation algorithm(Ma Y,McLaughlan M,Zhang N,Li J.Computers&Chemical Engineering,2020,143:107058)for such optimal design.The tolerances-relaxation integration method is refined to allow for long enough integration time that can ensure the solution of the pseudo-transient continuation simulation close to the steady state before the required tolerance is used.To ensure the gradient and Jacobian information available for optimisation,we allow a relaxed tolerance for the simulation in the sensitivity analysis mode when the simulation diverges under small tolerance.In addition,valid lower bounds on purity of the recycled entrainer and the vapour flow rate in column sections are imposed to improve computational efficiency.The computational results demonstrate that the extended hybrid algorithm can achieve better design of the EDWC compared to those in literature.The energy consumption can be reduced by more than 20%compared with existing literature report.In addition,the optimal design of the heat pump assisted EDWC is achieved using the improved hybrid algorithm for the first time.
基金funded by Shanghai Sailing Program (No.19YF1410800)National Natural Science Foundation of China(No. 21908056)。
文摘Dividing-wall columns(DWCs)are widely used in the separation of ternary mixtures,but rarely seen in the separation of petroleum fractions.This work develops two novel and energy-efficient designs of lubricant-type vacuum distillation process(LVDP)for the separation of hydroisomerization fractions(HIF)of a hydrocracking tail oil(HTO).First,the HTO hydroisomerization reaction is investigated in an experimental fixed-bed reactor to achieve the optimum liquid HIF by analyzing the impact of the operating conditions.A LVDP used for HIF separation is proposed and optimized.Subsequently,two thermal coupling intensified technologies,including side-stream(SC)and dividing-wall column(DWC),are combined with the LVDP to develop side-stream vacuum distillation process(SC-LVDP)and dividing-wall column vacuum distillation process(DWC-LVDP).The performance of LVDP,SC-LVDP,and DWC-LVDP are evaluated in terms of energy consumption,capital cost,total annual cost,product yields,and stripping steam consumption.The results demonstrates that the intensified processes,SC-LVDP and DWC-LVDP significantly decreases the energy consumption and capital cost compared with LVDP.DWC-LVDP further decreases in capital cost due to the removal of the side stripper and narrows the overlap between the third lube oils and fourth lube oils.This study attempts to combine DWC structure into the separation of petroleum fractions,and the proposed approach and the results presented provide an incentive for the industrial implementation of high-quality utilization of HTO through intensified LVDP.
