A novel fluorimetric method for determination of laccase activity in organic solvents is proposed, based on the oxidation ofo-phenylenediamine (1,2-diaminobenzene, OPDA) catalyzed by laccase yielding 2,3-diaminophenaz...A novel fluorimetric method for determination of laccase activity in organic solvents is proposed, based on the oxidation ofo-phenylenediamine (1,2-diaminobenzene, OPDA) catalyzed by laccase yielding 2,3-diaminophenazine. The optimal conditions for laccase in organic media areT=55°C, pH=6.5, 1.0×10?2mol/L OPDA, 1.25 mL ethanol, 1.25 mL 1,4-dioxane and 1.25 mL acetone. The linear range of the method proposed in ethanol, 1,4-dioxane and acetone media were 0.44–19.33, 0.11–20.85, 0.38–21.05 U with the detection limit of 0.088, 0.022, 0.076 U, respectively. The proposed method has been applied to the analysis of laccase activity of real samples with more accurate and sensitive than that of the previous method reported.展开更多
Six glucoside compounds have been synthesized by means of phase-transfer catalytic method and deacetylation from the starting material ferrocene. Their structures have been confirmed by elementary analysis, IR,1HNMR a...Six glucoside compounds have been synthesized by means of phase-transfer catalytic method and deacetylation from the starting material ferrocene. Their structures have been confirmed by elementary analysis, IR,1HNMR and MS. The antianemic activities of some compounds have also been tested. Results indicate that these glucoside compounds possess the antianemic activities and therefore, the further study is well worth making.展开更多
Improving the Quality of Service (QoS) of Internet traffic is widely recognized as a critical issue for the next-generation networks. In this paper, we present a new algorithm for the active queue management, namely R...Improving the Quality of Service (QoS) of Internet traffic is widely recognized as a critical issue for the next-generation networks. In this paper, we present a new algorithm for the active queue management, namely RED-DTB. This buffer control technique is used to enforce approximate fairness among a large number of concurrent Internet flows. Like RED (Random Early Detection) algorithm, the RED-DTB mechanism can be deployed to actively respond to the gateway congestion, keep the gateway in a healthy state, and protect the fragile flows from being stolen bandwidth by greedy ones. The algorithm is based on the so-called Dual Token Bucket (DTB) pattern. That is, on the one hand, every flow is rate-limited by its own token bucket, to ensure that it can not consume more than its fair share of bandwidth; On the other hand, to make some compensations to less aggressive flows, such as connections with larger round trip time or smaller sending window, and to gain a relatively higher system utilization coefficient, all flows, depending on their individual behavior, may have a chance to fetch tokens from the public token bucket when they run out of their own share of tokens. The algorithm is analyzed and evaluated by simulations, and is proved to be effective in protecting the gateway buffer and controlling the fair allocation of bandwidth among flows.展开更多
文摘A novel fluorimetric method for determination of laccase activity in organic solvents is proposed, based on the oxidation ofo-phenylenediamine (1,2-diaminobenzene, OPDA) catalyzed by laccase yielding 2,3-diaminophenazine. The optimal conditions for laccase in organic media areT=55°C, pH=6.5, 1.0×10?2mol/L OPDA, 1.25 mL ethanol, 1.25 mL 1,4-dioxane and 1.25 mL acetone. The linear range of the method proposed in ethanol, 1,4-dioxane and acetone media were 0.44–19.33, 0.11–20.85, 0.38–21.05 U with the detection limit of 0.088, 0.022, 0.076 U, respectively. The proposed method has been applied to the analysis of laccase activity of real samples with more accurate and sensitive than that of the previous method reported.
文摘Six glucoside compounds have been synthesized by means of phase-transfer catalytic method and deacetylation from the starting material ferrocene. Their structures have been confirmed by elementary analysis, IR,1HNMR and MS. The antianemic activities of some compounds have also been tested. Results indicate that these glucoside compounds possess the antianemic activities and therefore, the further study is well worth making.
基金the National Natural Science Foundation of China(60132030)and the National Education Department Doctorial Foundation Project(RFDP1999048602)
文摘Improving the Quality of Service (QoS) of Internet traffic is widely recognized as a critical issue for the next-generation networks. In this paper, we present a new algorithm for the active queue management, namely RED-DTB. This buffer control technique is used to enforce approximate fairness among a large number of concurrent Internet flows. Like RED (Random Early Detection) algorithm, the RED-DTB mechanism can be deployed to actively respond to the gateway congestion, keep the gateway in a healthy state, and protect the fragile flows from being stolen bandwidth by greedy ones. The algorithm is based on the so-called Dual Token Bucket (DTB) pattern. That is, on the one hand, every flow is rate-limited by its own token bucket, to ensure that it can not consume more than its fair share of bandwidth; On the other hand, to make some compensations to less aggressive flows, such as connections with larger round trip time or smaller sending window, and to gain a relatively higher system utilization coefficient, all flows, depending on their individual behavior, may have a chance to fetch tokens from the public token bucket when they run out of their own share of tokens. The algorithm is analyzed and evaluated by simulations, and is proved to be effective in protecting the gateway buffer and controlling the fair allocation of bandwidth among flows.
