L-lactic acid (L-LA) based copolymer/hydroxylation vermiculites composites (PLLA-co-bis A/HVMTs) were prepared by in situ reaction among L-LA, adipic acid, and hydroxylation lamellar vermiculites (HVMTs) using bisphen...L-lactic acid (L-LA) based copolymer/hydroxylation vermiculites composites (PLLA-co-bis A/HVMTs) were prepared by in situ reaction among L-LA, adipic acid, and hydroxylation lamellar vermiculites (HVMTs) using bisphenol-A epoxy resin as chain extending agent. HVMTs were obtained by sulfuric acid-leaching of lamellar vermiculites (VMTs). The effects of sulfuric acid leaching on the VMTs structure were characterized by X-ray diffraction (XRD), 29Si magic-angle spinning nuclear magnetic resonance(29Si NMR), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), and thermogravimetric analysis (TGA). FTIR, FE-SEM, and TGA were used to characterize the reaction activity of HVMTs. The results indicated that VMTs with increased hydroxyl groups had been successfully obtained and could react with -COOH of the reaction system. The amount of L-LA based copolymer grafted on the surface of HVMTs was more than 22%. The onset decomposition temperature of L-LA based copolymer grafted on the surface of HVMTs was 30℃ higher than that of free L-LA based copolymer.展开更多
Starling with the L- and D,L-lactide copolymer (L:DL = 9:1) [P(L-DL)LA] of M-W = 32.1 x 10(4), rods were obtained through a two stage process: (1) melt-extrusion at 155 degreesC, and (2) hot-drawing at 90 degreesC to ...Starling with the L- and D,L-lactide copolymer (L:DL = 9:1) [P(L-DL)LA] of M-W = 32.1 x 10(4), rods were obtained through a two stage process: (1) melt-extrusion at 155 degreesC, and (2) hot-drawing at 90 degreesC to various drawing ratios. The molecular weight of P(L-DL)LA fell to 9.3 x 10(4) as a consequence of the production process. The crystallization and molecular orientation of P(L-DL)LA developed as a result of the hot-drawing. The mechanical strengths of the rods increase with the drawing ratio; The maximum for tensile strength, bending strength, bending modulus, and shear strength are 329 MPa, 237 MPa, 8.8 GPa, and 157 MPa, respectively.展开更多
为探究劣化道砟力学特性及其循环利用机理,分别针对清洗后掺加不同比例新道砟的劣化道砟,结合洛杉矶磨耗试验仪和应变控制式直剪仪,开展了不同比例新旧道砟混合体的直剪试验,探讨了不同垂压(50、100、200 k Pa)下不同比例新旧道砟混合...为探究劣化道砟力学特性及其循环利用机理,分别针对清洗后掺加不同比例新道砟的劣化道砟,结合洛杉矶磨耗试验仪和应变控制式直剪仪,开展了不同比例新旧道砟混合体的直剪试验,探讨了不同垂压(50、100、200 k Pa)下不同比例新旧道砟混合体应力应变特征.研究结果表明:劣化道砟抗剪强度随新道砟含量增多而增大,如100 k Pa垂压下,新道砟含量为50%和100%的样本抗剪强度分别为143.4 k Pa和176.7 k Pa,比劣化道砟抗剪强度分别提高了24.0%和52.9%;劣化道砟剪胀现象随新道砟含量增多而越不明显,如100 k Pa垂压下,新道砟含量为50%和100%的样本最大剪胀量分别为9.842 mm和7.969 mm,比劣化道砟最大剪胀量分别降低了25.8%和39.9%;清洗后劣化道砟力学性能与新道砟差别较小,在一定条件下可与新道砟混合重复使用.展开更多
基金National High-Tech Research and Development Program of China ( 863 Program ) ( No. 2007AA03Z336) Program for New Century Excellent Talents in University,China ( No. NCET-07-0174) +1 种基金National Natural Science Foundations of China ( No. 21074021,No.50673018) The Fundamental Research Funds for the Central Universities ( No. 2011D10543)
文摘L-lactic acid (L-LA) based copolymer/hydroxylation vermiculites composites (PLLA-co-bis A/HVMTs) were prepared by in situ reaction among L-LA, adipic acid, and hydroxylation lamellar vermiculites (HVMTs) using bisphenol-A epoxy resin as chain extending agent. HVMTs were obtained by sulfuric acid-leaching of lamellar vermiculites (VMTs). The effects of sulfuric acid leaching on the VMTs structure were characterized by X-ray diffraction (XRD), 29Si magic-angle spinning nuclear magnetic resonance(29Si NMR), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), and thermogravimetric analysis (TGA). FTIR, FE-SEM, and TGA were used to characterize the reaction activity of HVMTs. The results indicated that VMTs with increased hydroxyl groups had been successfully obtained and could react with -COOH of the reaction system. The amount of L-LA based copolymer grafted on the surface of HVMTs was more than 22%. The onset decomposition temperature of L-LA based copolymer grafted on the surface of HVMTs was 30℃ higher than that of free L-LA based copolymer.
文摘Starling with the L- and D,L-lactide copolymer (L:DL = 9:1) [P(L-DL)LA] of M-W = 32.1 x 10(4), rods were obtained through a two stage process: (1) melt-extrusion at 155 degreesC, and (2) hot-drawing at 90 degreesC to various drawing ratios. The molecular weight of P(L-DL)LA fell to 9.3 x 10(4) as a consequence of the production process. The crystallization and molecular orientation of P(L-DL)LA developed as a result of the hot-drawing. The mechanical strengths of the rods increase with the drawing ratio; The maximum for tensile strength, bending strength, bending modulus, and shear strength are 329 MPa, 237 MPa, 8.8 GPa, and 157 MPa, respectively.
文摘为探究劣化道砟力学特性及其循环利用机理,分别针对清洗后掺加不同比例新道砟的劣化道砟,结合洛杉矶磨耗试验仪和应变控制式直剪仪,开展了不同比例新旧道砟混合体的直剪试验,探讨了不同垂压(50、100、200 k Pa)下不同比例新旧道砟混合体应力应变特征.研究结果表明:劣化道砟抗剪强度随新道砟含量增多而增大,如100 k Pa垂压下,新道砟含量为50%和100%的样本抗剪强度分别为143.4 k Pa和176.7 k Pa,比劣化道砟抗剪强度分别提高了24.0%和52.9%;劣化道砟剪胀现象随新道砟含量增多而越不明显,如100 k Pa垂压下,新道砟含量为50%和100%的样本最大剪胀量分别为9.842 mm和7.969 mm,比劣化道砟最大剪胀量分别降低了25.8%和39.9%;清洗后劣化道砟力学性能与新道砟差别较小,在一定条件下可与新道砟混合重复使用.
