A novel thiocyanate-controlled copper(Ⅱ)-L-arginine complex with the formula of Cu(Arg)(SCN)2(1,Arg:L-arginine) has been obtained from aqueous solution and structurally characterized by single-crystal X-ray ...A novel thiocyanate-controlled copper(Ⅱ)-L-arginine complex with the formula of Cu(Arg)(SCN)2(1,Arg:L-arginine) has been obtained from aqueous solution and structurally characterized by single-crystal X-ray diffraction method.Crystal data:orthorhombic,space group P212121,a = 6.0156(5),b = 12.1905(11),c = 18.4203(16) A°,V = 1350.8(2) A°3,Z = 4,μ = 1.933mm^(-1),F(000) = 724,S = 1.084,the final R = 0.0410,wR = 0.0754 for 1893 observed reflections with I 〉 2σ(I),and R = 0.0559,wR = 0.0820 for all reflections.In addition,elemental analysis,IR,TG-DTG and magnetism characterization are presented.展开更多
基金the National Natural Science Foundation of China(No.21203160)Education Department Foundation of Shaanxi Province(No.12JK0631)+1 种基金Natural Science Foundation of Shaanxi Province(No.2013JM2013)Special Research Fund of Xianyang Normal University(No.11XSYK204,11XSYK205)
文摘A novel thiocyanate-controlled copper(Ⅱ)-L-arginine complex with the formula of Cu(Arg)(SCN)2(1,Arg:L-arginine) has been obtained from aqueous solution and structurally characterized by single-crystal X-ray diffraction method.Crystal data:orthorhombic,space group P212121,a = 6.0156(5),b = 12.1905(11),c = 18.4203(16) A°,V = 1350.8(2) A°3,Z = 4,μ = 1.933mm^(-1),F(000) = 724,S = 1.084,the final R = 0.0410,wR = 0.0754 for 1893 observed reflections with I 〉 2σ(I),and R = 0.0559,wR = 0.0820 for all reflections.In addition,elemental analysis,IR,TG-DTG and magnetism characterization are presented.