An improvement in the corrosion resistance of alloys at elevated temperature is a factor for their potential use in gas turbines. In this study, Co Ni Cr Al Y has been coated on the L605 alloy using air plasma spray(A...An improvement in the corrosion resistance of alloys at elevated temperature is a factor for their potential use in gas turbines. In this study, Co Ni Cr Al Y has been coated on the L605 alloy using air plasma spray(APS) and high-velocity oxygen fuel(HVOF) coating techniques to enhance its corrosion resistance. Hot corrosion studies were conducted on uncoated and coated samples in a molten salt environment at 850°C under cyclic conditions. Thermogravimetric analysis was used to determine the corrosion kinetics. The samples were subjected to scanning electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction for further investigation. In coated samples, the formation of Al2O3 and Cr2O3 in the coating acts as a diffusion barrier that could resists the inward movement of the corrosive species present in the molten salt. Coated samples showed very less spallation, lower weight gain, less porosity, and internal oxidation as compared to uncoated sample.HVOF-coated sample showed greater corrosion resistance and inferred that this is the best technique under these conditions.展开更多
In this work,the stability of passive film for long-time immersed Cu-bearing L605(L605-Cu) alloy in the phosphate buffer solution(PBS) was studied by potentiodynamic polarization and electrochemical impedance spectros...In this work,the stability of passive film for long-time immersed Cu-bearing L605(L605-Cu) alloy in the phosphate buffer solution(PBS) was studied by potentiodynamic polarization and electrochemical impedance spectroscopy.The results showed that the impedance of passive film for L605-Cu alloy experienced an initial increase and subsequent stabilization with the increase in the immersion time.In addition,the plate count method was employed to assess the antibacterial durability of L605-Cu alloy against Escherichia coli after long-time immersion.The results indicated that the antibacterial rate of L605-Cu alloy presented a declining tendency with the immersion time prolonging.X-ray photoelectron spectroscopy(XPS) was used to analyze the change of the chemical composition in the passive film on L605-Cu alloy immersed in the PBS for different time.The results showed that Cu content and its compounds in the passive film gradually increased with the immersion time prolonging,hinting declined activity of Cu ions penetrating into the passive film,which resulted in a decrease in the antibacterial performance.展开更多
The current study investigates the behavior of wire electric discharge machining （WEDM） of the super alloy Udimet-L605 by employing sophisticated machine learning approaches. The experimental work was designed on th...The current study investigates the behavior of wire electric discharge machining （WEDM） of the super alloy Udimet-L605 by employing sophisticated machine learning approaches. The experimental work was designed on the basis of the Taguchi orthogonal L27 array, consid- ering six explanatory variables and evaluating their influ- ences on the cutting speed, wire wear ratio （WWR）, and dimensional deviation （DD）. A support vector machine （SVM） algorithm using a normalized poly-kernel and a radial-basis flow kernel is recommended for modeling the wire electric discharge machining process. The grey rela- tional analysis （GRA） approach was utilized to obtain the optimal combination of process variables simultaneously, providing the desirable outcome for the cutting speed, WWR, and DD. Scanning electron microscope and energy dispersive X-ray analyses of the samples were performed for the confirmation of the results. An SVM based on the radial-basis kernel model dominated the normalized poly- kernel model. The optimal combination of process vari- ables for a mutually desirable outcome for the cutting speed, WWR, and DD was determined as Ton1, Toffa, Ip1, WT3, SV1, and WF3. The pulse-on time is the significant variable influencing the cutting speed, WWR, and DD. The largest percentage of copper （8.66%） was observed at the highest cutting speed setting 7.05% of copper at the low of the machine compared to cutting speed setting of the machine.展开更多
文摘An improvement in the corrosion resistance of alloys at elevated temperature is a factor for their potential use in gas turbines. In this study, Co Ni Cr Al Y has been coated on the L605 alloy using air plasma spray(APS) and high-velocity oxygen fuel(HVOF) coating techniques to enhance its corrosion resistance. Hot corrosion studies were conducted on uncoated and coated samples in a molten salt environment at 850°C under cyclic conditions. Thermogravimetric analysis was used to determine the corrosion kinetics. The samples were subjected to scanning electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction for further investigation. In coated samples, the formation of Al2O3 and Cr2O3 in the coating acts as a diffusion barrier that could resists the inward movement of the corrosive species present in the molten salt. Coated samples showed very less spallation, lower weight gain, less porosity, and internal oxidation as compared to uncoated sample.HVOF-coated sample showed greater corrosion resistance and inferred that this is the best technique under these conditions.
基金financially supported by the National Natural Science Foundation of China (Nos.51771199, 51631009 and 51501188)the National Key Research and Development Program (No.2016YFB0300205)。
文摘In this work,the stability of passive film for long-time immersed Cu-bearing L605(L605-Cu) alloy in the phosphate buffer solution(PBS) was studied by potentiodynamic polarization and electrochemical impedance spectroscopy.The results showed that the impedance of passive film for L605-Cu alloy experienced an initial increase and subsequent stabilization with the increase in the immersion time.In addition,the plate count method was employed to assess the antibacterial durability of L605-Cu alloy against Escherichia coli after long-time immersion.The results indicated that the antibacterial rate of L605-Cu alloy presented a declining tendency with the immersion time prolonging.X-ray photoelectron spectroscopy(XPS) was used to analyze the change of the chemical composition in the passive film on L605-Cu alloy immersed in the PBS for different time.The results showed that Cu content and its compounds in the passive film gradually increased with the immersion time prolonging,hinting declined activity of Cu ions penetrating into the passive film,which resulted in a decrease in the antibacterial performance.
文摘The current study investigates the behavior of wire electric discharge machining （WEDM） of the super alloy Udimet-L605 by employing sophisticated machine learning approaches. The experimental work was designed on the basis of the Taguchi orthogonal L27 array, consid- ering six explanatory variables and evaluating their influ- ences on the cutting speed, wire wear ratio （WWR）, and dimensional deviation （DD）. A support vector machine （SVM） algorithm using a normalized poly-kernel and a radial-basis flow kernel is recommended for modeling the wire electric discharge machining process. The grey rela- tional analysis （GRA） approach was utilized to obtain the optimal combination of process variables simultaneously, providing the desirable outcome for the cutting speed, WWR, and DD. Scanning electron microscope and energy dispersive X-ray analyses of the samples were performed for the confirmation of the results. An SVM based on the radial-basis kernel model dominated the normalized poly- kernel model. The optimal combination of process vari- ables for a mutually desirable outcome for the cutting speed, WWR, and DD was determined as Ton1, Toffa, Ip1, WT3, SV1, and WF3. The pulse-on time is the significant variable influencing the cutting speed, WWR, and DD. The largest percentage of copper （8.66%） was observed at the highest cutting speed setting 7.05% of copper at the low of the machine compared to cutting speed setting of the machine.
