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A review of liquid crystal spatial light modulators:devices and applications 被引量:4
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作者 Yiqian Yang Andrew Forbes Liangcai Cao 《Opto-Electronic Science》 2023年第8期1-29,共29页
Spatial light modulators,as dynamic flat-panel optical devices,have witnessed rapid development over the past two decades,concomitant with the advancements in micro-and opto-electronic integration technology.In partic... Spatial light modulators,as dynamic flat-panel optical devices,have witnessed rapid development over the past two decades,concomitant with the advancements in micro-and opto-electronic integration technology.In particular,liquid-crystal spatial light modulator(LC-SLM)technologies have been regarded as versatile tools for generating arbitrary optical fields and tailoring all degrees of freedom beyond just phase and amplitude.These devices have gained significant interest in the nascent field of structured light in space and time,facilitated by their ease of use and real-time light manipulation,fueling both fundamental research and practical applications.Here we provide an overview of the key working principles of LC-SLMs and review the significant progress made to date in their deployment for various applications,covering topics as diverse as beam shaping and steering,holography,optical trapping and tweezers,measurement,wavefront coding,optical vortex,and quantum optics.Finally,we conclude with an outlook on the potential opportunities and technical challenges in this rapidly developing field. 展开更多
关键词 liquid crystal spatial light modulators liquid crystal devices structured light HOLOGRAPHY APPLICATIONS
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Diffractive characteristics of the liquid crystal spatial light modulator 被引量:3
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作者 曹召良 穆全全 +2 位作者 胡立发 刘永刚 宣丽 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第6期1665-1671,共7页
The liquid crystal spatial light modulator (LC SLM) is very suitable for wavefront correction and optical testing and can produce a wavefront with large phase change and high accuracy. The LC SLM is composed of thou... The liquid crystal spatial light modulator (LC SLM) is very suitable for wavefront correction and optical testing and can produce a wavefront with large phase change and high accuracy. The LC SLM is composed of thousands of pixels and the pixel size and shape have effects on the diffractive characteristics of the LC SLM. This paper investigates the pixel effect on the phase of the wavefront with the scalar diffractive theory. The results show that the maximum optical path difference modulation is 41μm to produce the paraboloid wavefront with the peak to valley accuracy better than λ/10. Effects of the mismatch between the pixel and the period, and black matrix on the diffraction efficiency of the LC SLM are also analysed with the Fresnel phase lens model. The ability of the LC SLM is discussed for optical testing and wavefront correction based on the calculated results. It shows that the LC SLM can be used as a wavefront corrector and a compensator. 展开更多
关键词 liquid crystal spatial light modulator diffraction efficiency PIXEL WAVEFRONT
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Fast generation of controllable equal-intensity four beams based on isosceles triangle multilevel phase grating realized by liquid crystal spatial light modulator 被引量:1
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作者 刘翔 张健 +1 位作者 吴丽莹 甘雨 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第2期287-294,共8页
Liquid crystal spatial light modulator (LCSLM) realizing equal-intensity multiple beams often has some features, i.e., phase valley between two adjacent pixels, flybaek region when phase decreases immediately from 2... Liquid crystal spatial light modulator (LCSLM) realizing equal-intensity multiple beams often has some features, i.e., phase valley between two adjacent pixels, flybaek region when phase decreases immediately from 2~r to 0, and inevitable backplane curvature, which are different from those of most conventional diffractive optical elements (DOEs), such as static DOEs. For optimal intensity uniformity, equal-intensity multi-beam generation must be considered for these artifacts. We present a tunable-grating method in which the intensity uniformity can be improved by considering the LCSLM artifacts. For instance, tuning phase modulation depth of the grating, called isosceles triangle multilevel phase grating (ITMPG), can be used not only to improve the intensity uniformity, but also to fast steer four beams with narrow beamwidths, determined by the same effective aperture of ITMPG. Improved intensity uniformity and high relative diffraction efficiency are demonstrated through experiments with phase-only LCSLM. 展开更多
关键词 liquid crystal spatial light modulator phase grating SPLITTER
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Research progress of cholesteric liquid crystals with broadband reflection characteristics in application of intelligent optical modulation materials 被引量:1
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作者 张兰英 高延子 +9 位作者 宋平 武晓娟 苑晓 何宝凤 陈兴武 胡望 郭仁炜 丁杭军 肖久梅 杨槐 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第9期13-23,共11页
Cholesteric liquid crystals(CLCs) have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architec... Cholesteric liquid crystals(CLCs) have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architecture and their excellent selective reflection of light based on the Bragg relationship.Nowadays,by the virtue of building the self-organized nanostructures with pitch gradient or non-uniform pitch distribution,extensive work has already been performed to obtain CLC films with a broad reflection band.Based on authors' many years' research experience,this critical review systematically summarizes the physical and optical background of the CLCs with broadband reflection characteristics,methods to obtain broadband reflection of CLCs,as well as the application in the field of intelligent optical modulation materials.Combined with the research status and the advantages in the field,the important basic and applied scientific problems in the research direction are also introduced. 展开更多
关键词 cholesteric liquid crystals soft matter materials broadband reflection characteristics intelligent optical modulation materials
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A high-contrast imaging coronagraph for segmented-mirror large aperture telescopes using a spatial light modulator
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作者 Jiangpei Dou Huanyu Dong 《Astronomical Techniques and Instruments》 CSCD 2024年第3期166-170,共5页
The primary mirrors of current and future large telescopes always employ a segmented mirror configuration.The small but non-negligible gaps between neighboring segments cause additional diffraction,which restricts the... The primary mirrors of current and future large telescopes always employ a segmented mirror configuration.The small but non-negligible gaps between neighboring segments cause additional diffraction,which restricts the performance of high-contrast coronagraph.To solve this problem,we propose a coronagraph system based on a single liquid crystal spatial light modulator(SLM).This spatial light modulator is used for amplitude apodization,and its feasibility and potential performance are demonstrated using a laboratory setup using the stochastic parallel gradient descent(SPGD)algorithm to control the spatial light modulator,which is based on point spread function(PSF)sensing and evaluation and optimized for maximum contrast in the discovery working area as a merit function.The system delivers a contrast in the order of 10−6,and shows excellent potential to be used in current and future large aperture telescopes,both on the ground and in space. 展开更多
关键词 liquid crystal spatial light modulator Amplitude apodized pupil Large aperture telescopes
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Magneto and Electro-Optic Intensity Modulator Based on Liquid Crystal and Magnetic Fluid Filled Photonic Crystal Fiber
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作者 Yue-Lan Lu Fei-Ru Wang +4 位作者 Chi Zhang ai-Wen Yin Yu Huang Wei-min Sun Yong-Jun Liu 《Chinese Physics Letters》 SCIE CAS CSCD 2018年第10期36-39,共4页
We propose a novel light intensity modulator based on magnetic fluid and liquid crystal(LC) filled photonic crystal fibers(PCFs). The influences of electric and magnetic fields on the transmission intensity are th... We propose a novel light intensity modulator based on magnetic fluid and liquid crystal(LC) filled photonic crystal fibers(PCFs). The influences of electric and magnetic fields on the transmission intensity are theoretically and experimentally analyzed and investigated. Both the electric and magnetic fields can manipulate the molecular arrangement of LC to array a certain angle without changing the refractive index of the LC. Therefore, light loss in the PCF varies with the electric and magnetic fields whereas the peak wavelengths remain constant. The experimental results show that the transmission intensity decreases with the increase of the electric and magnetic fields. The cut-off electric field is 0.899 V/um at 20 Hz and the cut-off magnetic field is 195 m T. This simple and compacted optical modulator will have a great prospect in sensing applications. 展开更多
关键词 PCF LC Magneto and Electro-Optic Intensity modulator Based on liquid crystal and Magnetic Fluid Filled Photonic crystal Fiber
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Liquid Crystal Television Spatial Light Modulator
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作者 SHIHongju SHIYongji 《Semiconductor Photonics and Technology》 CAS 1998年第4期197-208,234,共13页
The liquid crystal television spatial light modulator (LCTVSLM) characterized is usable in optical processing applications,e.g.,optical pattern recognition,associative memory, optical computing,correlation detection a... The liquid crystal television spatial light modulator (LCTVSLM) characterized is usable in optical processing applications,e.g.,optical pattern recognition,associative memory, optical computing,correlation detection and optical data processing systems.The array performance and real-time optical correlation applications are reviewed. 展开更多
关键词 Associative Memory Correlation Detection liquid crystal Television Optical Computing Optical Data Optical Pattern Recognition Spatial Light modulator
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Holographic Polymer Nanocomposites with High Refractive Index Modulation by Doping Liquid Crystal E6M
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作者 Meng-Yun Wang Yue Zhang +5 位作者 Dan Wang Ming Yao Yi-Xuan Wang Xing-Ping Zhou Hai-Yan Peng Xiao-Lin Xie 《Chinese Journal of Polymer Science》 SCIE EI CAS CSCD 2024年第7期926-935,I0006,共11页
Holographic optical elements(HOEs)based on polymer composites have become a research hot spot in recent years for augmented reality(AR)due to the significant improvement of optical performance,dynamic range,ease of pr... Holographic optical elements(HOEs)based on polymer composites have become a research hot spot in recent years for augmented reality(AR)due to the significant improvement of optical performance,dynamic range,ease of processing and high yield rate.Nevertheless,it remains a formidable challenge to obtain a large field of view(FOV)and brightness due to the limited refractive index modulation.Herein,we report an effective method to tackle the challenge by doping an epoxy liquid crystal termed E6M,which enables a large refractive index modulation of 0.050@633 nm and low haze of 5.0%at a doping concentration of 5 wt%.This achievement may be ascribed to the improved molecular ordering of liquid crystals within the holographic polymer composites.The high refractive index modulation can endow transmission-type holographic polymer composites with a high diffraction efficiency of 96.2%at a small thickness of 5μm,which would promise the design of thin and lightweight AR devices. 展开更多
关键词 Polymer nanocomposites HOLOGRAPHY AR/VR Refractive index modulation liquid crystal
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Research on Phase Detection of Liquid Crystal Optical Device
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作者 Mingliang Shi Ruofu Yang +2 位作者 Chunping Yang Mingwu Ao Hongzhou Dong 《Journal of Applied Mathematics and Physics》 2014年第12期1099-1104,共6页
The technology for phase detection of liquid crystal optical device is a difficult research in current domestic and overseas. However, for the existing liquid crystal optical device, aiming at the poor anti-vibration ... The technology for phase detection of liquid crystal optical device is a difficult research in current domestic and overseas. However, for the existing liquid crystal optical device, aiming at the poor anti-vibration capability and poor versatile of phase detection, the complexity of phase retrieval algorithm, we propose a new phase measurement principle and experimental methods of liquid crystal optical device. It is a phase measurement method based on the combination of phase- shifting interferometer and phase conjugation technology. The deflection characteristics of the liquid crystal device means the device can implement phase modulation to only one direction of polarized light while is completely transparent to orthogonal polarized light. We put forward the phase shift of the orthogonal polarization phase shift interferometer method, using phase shifting interference as well as the combination of phase conjugate means to achieve its phase measurement. So we can retrieves devices modulation phase simply and efficiently combines with phase- shifting interferometer technology. 展开更多
关键词 liquid crystal Optical Device modulation PHASE Detection ORTHOGONAL PHASE SHIFTING CONJUGATE Interference PHASE RETRIEVAL Algorithm
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Nonlinear Liquid Crystal Polymer and Its Applications
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作者 SHI Yongji(Luoyang Technology College, Luoyang 471003,CHN) 《Semiconductor Photonics and Technology》 CAS 1996年第2期112-117,共6页
The transparent solid medium of a thermotropic liquid crystal polymer have a comb structure of mesogenic side chains which exhibit a nonlinear optical response of electronic origin.The main chain of the liquid crystal... The transparent solid medium of a thermotropic liquid crystal polymer have a comb structure of mesogenic side chains which exhibit a nonlinear optical response of electronic origin.The main chain of the liquid crystal polymers can be selected from a number of suitable polymerized monomeric and comonomeric structures such as polyvinyl,polysiloxane,polyoxyalkylene, polyester etc.The electrooptic light modulator is provided,which have potential to using in the systems of laser modulation and deflection,and information control in optical circuitry etc. 展开更多
关键词 Nonlinear Optics liquid crystal Polymer Electrooptic Light modulator
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Kerr effect and Kerr constant enhancement in vertically aligned deformed helix ferroelectric liquid crystals
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作者 Liangyu Shi Abhishek Kumar Srivastava +1 位作者 Vladimir G Chigrinov Hoi-Sing Kwok 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第9期9-12,共4页
In this article,we review recently achieved Kerr effect progress in novel liquid crystal(LC) material:vertically aligned deformed helix ferroelectric liquid crystal(VADHFLC).With an increasing applied electric fi... In this article,we review recently achieved Kerr effect progress in novel liquid crystal(LC) material:vertically aligned deformed helix ferroelectric liquid crystal(VADHFLC).With an increasing applied electric field,the induced inplane birefringence of LCs shows quadratic nonlinearity.The theoretical calculations and experimental details are illustrated.With an enhanced Kerr constant to 130 nm/V2,this VADHFLC cell can achieve a 2π modulation by a small efficient electric field with a fast response around 100 μs and thus can be employed in both display and photonics devices. 展开更多
关键词 Kerr effect deformed helix ferroelectric liquid crystal phase modulation of light
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聚合物分散液晶器件概述、发展趋势及应用研究进展
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作者 吴菁 李佳 +2 位作者 黄金华 宋伟杰 谭瑞琴 《材料导报》 EI CAS CSCD 北大核心 2024年第21期261-268,共8页
本文概述了聚合物分散液晶器件的基本结构、原理和制备方法,重点介绍了目前聚合物分散液晶器件(包括基于二色性染料的彩色器件以及基于柔性透明电极的柔性器件)的发展现状和趋势,总结了聚合物分散液晶在智能窗、防窥和传感器等方面的应... 本文概述了聚合物分散液晶器件的基本结构、原理和制备方法,重点介绍了目前聚合物分散液晶器件(包括基于二色性染料的彩色器件以及基于柔性透明电极的柔性器件)的发展现状和趋势,总结了聚合物分散液晶在智能窗、防窥和传感器等方面的应用,最后对聚合物分散液晶器件色彩和柔性化方面的问题进行陈述,并对其研究方向进行了展望。 展开更多
关键词 聚合物分散液晶 染料 颜色调控 柔性透明电极
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计算全息综合性光电教学实验设计
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作者 刘珂瑄 朱昊 +2 位作者 何泽浩 李玉和 曹良才 《实验室研究与探索》 CAS 北大核心 2024年第2期132-134,168,共4页
基于傅里叶光学原理实现对目标光场进行精确重建,设计了从显示目标绘制,相应计算全息图生成到光学重建的综合性教学实验。具体的实验流程包含基于Visio的显示目标设计,基于MATLAB的相位型计算全息图生成算法编写和基于相位型液晶空间光... 基于傅里叶光学原理实现对目标光场进行精确重建,设计了从显示目标绘制,相应计算全息图生成到光学重建的综合性教学实验。具体的实验流程包含基于Visio的显示目标设计,基于MATLAB的相位型计算全息图生成算法编写和基于相位型液晶空间光调制器的目标重建光路搭建。实验设计结合了光学、数字电路和计算机软件技术,具有流程清晰、易于教学、学生参与度高和获得感强的优势,可有效增强学生对计算全息技术与光电信息技术的理论理解与实操能力。 展开更多
关键词 实验教学 计算全息 光场重建 液晶空间光调制器
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液晶调控下的亚波长金光栅反射相位
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作者 李韵九 韦穗 +3 位作者 郝学锋 葛博群 沈川 屈磊 《液晶与显示》 CAS CSCD 北大核心 2024年第11期1445-1453,共9页
空间光调制器(Spatial Light Modulator,SLM)是实现光场调控的关键器件。本文研究了一种将亚波长金光栅嵌入硅基液晶(Liquid Crystal on Silicon,LCoS)构成的SLM(G-LCoS)器件模型的反射相位特性,该器件模型以ITO透明导电层和液晶构成G-L... 空间光调制器(Spatial Light Modulator,SLM)是实现光场调控的关键器件。本文研究了一种将亚波长金光栅嵌入硅基液晶(Liquid Crystal on Silicon,LCoS)构成的SLM(G-LCoS)器件模型的反射相位特性,该器件模型以ITO透明导电层和液晶构成G-LCoS中亚波长金光栅的非对称边界。首先运用散射矩阵原理给出了亚波长金光栅反射相位的计算表达式,其次给出了下表面液晶的有效折射率计算公式。在此基础上,利用TechWiz 3D软件模拟加电情况下金光栅下表面液晶指向矢的变化,给出金光栅下表面液晶有效折射率的变化值。将得到的有效折射率数据导入到FDTD Solutions软件,对该器件结构开展了相关的仿真实验和结果分析。综合考虑了上表面的ITO色散情况、金光栅高度变化以及不同电压下液晶有效折射率值,实现了可见光范围内多波长的近2π相位调制。本文研究的器件也为AR/VR显示系统以及全息视频显示的优化提供了一种新思路。 展开更多
关键词 亚波长金属光栅 散射矩阵 液晶有效折射率 相位调制 空间光调制器
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QuEChERS结合气相色谱-串联质谱法测定室内灰尘中的37种液晶单体化合物
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作者 李辉 施致雄 《分析测试学报》 CAS CSCD 北大核心 2024年第3期405-412,共8页
建立了一种简单易行且灵敏准确的测定室内灰尘中液晶单体化合物(Liquid crystal monomers,LCMs)的方法。灰尘样品中加入^(13)C-多氯联苯和^(13)C-多溴联苯醚作为内标,采用二氯甲烷进行提取,萃取液加入无水硫酸钠后采用混合吸附剂(N-丙... 建立了一种简单易行且灵敏准确的测定室内灰尘中液晶单体化合物(Liquid crystal monomers,LCMs)的方法。灰尘样品中加入^(13)C-多氯联苯和^(13)C-多溴联苯醚作为内标,采用二氯甲烷进行提取,萃取液加入无水硫酸钠后采用混合吸附剂(N-丙基乙二胺和十八烷基键合硅胶)净化,随后采用气相色谱-串联质谱在动态多反应监测(dMRM)模式下测定,内标法定量。对仪器分析参数、提取溶剂和吸附剂进行了优化。结果显示在优化条件下,37种液晶单体在0.1~50 ng/mL范围内线性良好,方法检出限为0.02~1.56 ng/g;在两加标水平下的平均回收率为65.3%~137%,相对标准偏差(RSD)为0.90%~24%。通过对实际样本的检测,发现在北京所采集的室内灰尘中有22种LCMs的检出率在50%以上,表明室内环境已普遍存在LCMs污染。该方法操作简单,溶剂消耗少,灵敏度和稳定性良好,可用于大规模室内环境污染监测。 展开更多
关键词 液晶单体 灰尘 QUECHERS 气相色谱-串联质谱 新污染物
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基于液晶空间光调制器的附面层效应模拟
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作者 景刚 刘智 +2 位作者 林鹏 刘树通 蒋青芳 《光子学报》 EI CAS CSCD 北大核心 2024年第2期232-243,共12页
为了给航空动平台激光通信的附面层效应校正系统提供验证条件,设计了一种基于液晶空间光调制器来模拟附面层效应的模拟器。首先,从几何光学的角度分析附面层效应,将其等效为负透镜。然后,利用计算机对不同飞行条件下附面层效应与等效负... 为了给航空动平台激光通信的附面层效应校正系统提供验证条件,设计了一种基于液晶空间光调制器来模拟附面层效应的模拟器。首先,从几何光学的角度分析附面层效应,将其等效为负透镜。然后,利用计算机对不同飞行条件下附面层效应与等效负透镜焦距之间的关系进行数值分析仿真。之后在液晶空间光调制器上导入不同焦距透镜的相位灰度图以实现变焦透镜的功能,通过改变变焦透镜的焦距来模拟航空平台不同飞行条件下的附面层效应。最后通过实验验证模拟的准确性,在环境温度下,模拟附面层效应的液晶空间光调制器得到的光斑图像由红外相机拍摄,之后进行图像处理分析实际光斑大小,并与理论计算光斑大小比较,得出误差曲线图。研究结果显示,基于液晶空间光调制器模拟附面层效应引起散斑效应的理论光斑大小与实际光斑大小的均方根误差为0.04375,验证了所提出的方法的可行性和有效性。 展开更多
关键词 光通信 附面层效应 光斑分析 液晶空间光调制器 液晶变焦透镜 模拟器
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贝塞尔双光子光片显微镜在活体生物成像中的应用
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作者 卜庆盼 罗芳琳 张杏云 《液晶与显示》 CAS CSCD 北大核心 2024年第11期1477-1482,共6页
双光子光片显微镜具有分辨率高、光漂白低等优势,在生物学领域有着广泛的应用。但由于照明光片厚度与长度之间的取舍矛盾问题,导致轴向分辨率和成像视场无法兼顾,因此在应用中受到限制。为了解决这一问题,本文采用液晶空间光调制器将普... 双光子光片显微镜具有分辨率高、光漂白低等优势,在生物学领域有着广泛的应用。但由于照明光片厚度与长度之间的取舍矛盾问题,导致轴向分辨率和成像视场无法兼顾,因此在应用中受到限制。为了解决这一问题,本文采用液晶空间光调制器将普通高斯照明光束调制为贝塞尔光束,利用贝塞尔光束的“无衍射”特性实现了大且薄的光片照明,光片长度与厚度之比达到了163。在此基础上,设计并搭建了一套贝塞尔双光子光片显微镜,在310μm的视场范围内实现了横向440 nm、轴向1.9μm的三维高分辨率成像。本文成功实现了斑马鱼胚胎的活体成像,可以做到血液细胞流速的测量和脊柱骨细胞的分割计数,验证了贝塞尔双光子光片显微镜在活体生物成像中的应用潜力。 展开更多
关键词 液晶空间光调制器 双光子光片显微镜 贝塞尔光束 活体成像
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向列相液晶器件光调制性能研究
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作者 王萧 鲁小鑫 +2 位作者 张雪凤 王浪 乌日娜 《沈阳理工大学学报》 CAS 2024年第1期91-96,共6页
液晶的折射率易受外加电压和温度的影响,据此可获得电场和温度可调制器件。为改善液晶器件对光的调制性能,制备了向列相液晶器件,并对其调制性能进行理论模拟和实验研究。首先研究液晶器件的透过光强和相位延迟随电压变化关系,结果显示... 液晶的折射率易受外加电压和温度的影响,据此可获得电场和温度可调制器件。为改善液晶器件对光的调制性能,制备了向列相液晶器件,并对其调制性能进行理论模拟和实验研究。首先研究液晶器件的透过光强和相位延迟随电压变化关系,结果显示,相同电压下,增大器件厚度,光强调制曲线的峰谷数增多,相位调制量增大,其中电压在0.8~3 V范围内,相位延迟曲线变化较明显,厚度为4、6和10μm的器件可分别获得约1.21π、1.87π和3.19πrad的相位调制量。其次对厚度为4μm的器件进行温度可调制性能的研究,结果显示,温度从20℃升至45℃时,获得的温度可调制量约为0.29πrad。改变电场或温度均能引起液晶的折射率变化,从而实现对光的调控,适当增加液晶器件厚度可获得较大的相位调制量。研究结果对液晶光调制器件的性能改善及应用具有重要参考意义。 展开更多
关键词 液晶光调制器 向列相液晶 光强调制 相位调制
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液晶显示模块LCM12832ZK与飞利浦80C552单片机的接口应用 被引量:1
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作者 卢军 王峰 党新安 《机械设计与制造》 北大核心 2005年第4期44-46,共3页
涉及液晶显示模块(LCM12832ZK)在单片机系统中的应用,说明其功能作用及其与单片机的接口的软硬件实现方法。
关键词 液晶显示模块 单片机 接口
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Atmospheric fate of typical liquid crystal monomers in the tropospheric gas,liquid,and granular phases
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作者 Yanru Huo Zexiu An +5 位作者 Mingxue Li Jinchan Jiang Yuxin Zhou Ju Xie Jianguo Zhang Maoxia He 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2024年第2期348-360,共13页
Mineral aerosol particles significantly impact environmental risk prediction of liquid crystal monomers(LCMs).In this work,we investigated the reaction mechanisms and kinetics of three typical LCMs(4-cyano-3,5-difluor... Mineral aerosol particles significantly impact environmental risk prediction of liquid crystal monomers(LCMs).In this work,we investigated the reaction mechanisms and kinetics of three typical LCMs(4-cyano-3,5-difluorophenyl 4-ethylbenzoate(CEB-2F),4-cyano-3-fluorophenyl 4-ethylbenzoate(CEB-F),and 4-cyanophenyl 4-ethylbenzoate(CEB))with ozone(O_(3))in the atmospheric gas,liquid,and particle phases employing density functional theory(DFT).Here,O_(3)is prone to add to the benzene ring without F atom(s)in the selected LCMs.The ozonolysis products are aldehydes,carboxylic acids,epoxides,and unsaturated hydrocarbons containing aromatic rings.Those products undergo secondary ozonolysis to generate small molecular compounds such as glyoxal,which is beneficial for generating secondary organic aerosol(SOA).Titanium dioxide(TiO_(2)),an essential component of mineral aerosol particles,has good adsorption properties for LCMs;however,it slightly reduces the reactivity with O_(3).At 298 K,the reaction rate constant of the selected LCMs reacting with O_(3)in the gas and atmospheric liquid phases is(2.74–5.53)×10^(-24)cm^(3)/(mol·sec)and 5.58×10^(-3)–39.1 L/(mol·sec),while CEB-2F reacting with O_(3)on(TiO_(2))_(6)cluster is 1.84×10^(-24)cm^(3)/(mol·sec).The existence of TiO_(2)clusters increases the persistence and long-distance transportability of LCMs,which enlarges the contaminated area of LCMs. 展开更多
关键词 liquid crystal monomers(lcms) OZONOLYSIS TiO_(2)clusters Adsorption Toxicity assessment
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