This article discusses and analyzes the law of nitrogen increase in liquid steel and the main factors affect-ing the nitrogen increasing of molten steel,through the way of adding nitrogen to molten steel by bottom blo...This article discusses and analyzes the law of nitrogen increase in liquid steel and the main factors affect-ing the nitrogen increasing of molten steel,through the way of adding nitrogen to molten steel by bottom blowing nitrogen gas in LF refining process.It is considered that the main factors affecting the nitrogen increasing instability of molten steel are the initial temperature of LF refining,nitrogen relative element,surface active elements[O]and[S]of steel liquid,and bottom blowing rate of ladle.The large-scale production practice shows that T[O]not more than 50×10-6 and[S]is not more than 0.020 in LF refining at the initial temperature of not less than 1570.The liquid steel nitrogen enrichment test is carried out by ladle bottom blowing nitrogen gas after 20 min of refining,the flow rate is set as(6.0~7.0)NL/min per ton,and it is turned to 2 NL/min at 6 min before the end of refining,the nitrogen increasing rate of liquid steel is basically stable at(5~6)×10-6 per minute.展开更多
18CrNiMo7-6钢（/%：0.17C,0.57Mn,0.24Si,0.012P,0.003S,1.70Cr,1.49Ni,0.28Mo）的冶金流程为60 t EAF-LF-VD-2.1 t铸锭。取样分析了EAF铝锭预脱氧,LF铝粒和碳化硅混合脱氧剂扩散脱氧（LF初渣成分/%：57～60CaO,20.5～22.0Al_2O_3,9.9...18CrNiMo7-6钢（/%：0.17C,0.57Mn,0.24Si,0.012P,0.003S,1.70Cr,1.49Ni,0.28Mo）的冶金流程为60 t EAF-LF-VD-2.1 t铸锭。取样分析了EAF铝锭预脱氧,LF铝粒和碳化硅混合脱氧剂扩散脱氧（LF初渣成分/%：57～60CaO,20.5～22.0Al_2O_3,9.9～11.3SiO_2,8.8～10.6MgO,0.7～1.1FeO,0.7～0.9MnO）,VD后和软吹后钢中夹杂物数量、尺寸和组成的变化。结果表明,精炼过程1～10μm夹杂物数量降低16.67%,〉10μm夹杂物数量降低50%,≥30μm夹杂物基本去除;精炼过程中生成的夹杂主要为镁铝钙的复合夹杂物和CaS,MgS,MnS等硫化物;成品材中主要为Mg-Al的氧化物夹杂,硫化物以MgS为主,有少量MnS、CaS。应进一步优化冶炼工艺,控制中小型夹杂物的形成。展开更多
26CrMoNbTiB钢由45 t EAF-LF(VD)-Φ80～180mm管坯HCC流程冶炼。该钢各工序的洁净度试验结果表明,LF-VD后钢中氧含量为(8～18)×10^(-6),平均夹杂物数量最低为2.31个/mm^2,连铸坯平均夹杂物数量为3.66个/mm^2,≥50μm大型夹杂物平...26CrMoNbTiB钢由45 t EAF-LF(VD)-Φ80～180mm管坯HCC流程冶炼。该钢各工序的洁净度试验结果表明,LF-VD后钢中氧含量为(8～18)×10^(-6),平均夹杂物数量最低为2.31个/mm^2,连铸坯平均夹杂物数量为3.66个/mm^2,≥50μm大型夹杂物平均含量为4.08 mg/10 kg。加强钢包到中间包长水口的密封保护和采用钢包下渣检测装置,提高中间包容量和采用挡渣墙是进一步提高铸坯洁净度的关键工艺措施。展开更多
试验了45 t LF精炼渣的碱度、喂硫线和脱氧工艺对28MnCr5钢(％:0.25～0.30C、0.60～0.80Mn、0.020～0.035S、0.80～1.00Cr)硫含量的控制、氧化物含量和钢中硫化物的影响。结果表明,LF精炼渣碱度控制在2.8～5.1喂硫线,VD后硫的回收率达8...试验了45 t LF精炼渣的碱度、喂硫线和脱氧工艺对28MnCr5钢(％:0.25～0.30C、0.60～0.80Mn、0.020～0.035S、0.80～1.00Cr)硫含量的控制、氧化物含量和钢中硫化物的影响。结果表明,LF精炼渣碱度控制在2.8～5.1喂硫线,VD后硫的回收率达80％～90％;钢中氧化物级别≤1.5级;精炼结束喂适量CaSi线可改善钢中硫化物的形貌。展开更多
通过研究安钢150 t LF-VD工艺流程下不同钢种的脱硫工艺及其脱硫效果,为采用该工艺流程生产不同成品硫含量要求的钢种提供了操作依据。研究结果表明,通过控制LF炉的精炼渣碱度、LF精炼目标硫含量,以及VD处理抽真空模式、极限真空度和真...通过研究安钢150 t LF-VD工艺流程下不同钢种的脱硫工艺及其脱硫效果,为采用该工艺流程生产不同成品硫含量要求的钢种提供了操作依据。研究结果表明,通过控制LF炉的精炼渣碱度、LF精炼目标硫含量,以及VD处理抽真空模式、极限真空度和真空处理时底吹氩气流量,可以获得良好的脱气和脱硫效果。对产品标准要求成品硫含量分别不超过0.005%、0.010%和0.015%的钢种,采用不同的钢水脱硫工艺控制后,其钢中硫含量可分别达到0.001%左右、0.006%以下和0.009%以下,LF-VD工艺总平均脱硫率为92.31%、86.22%和80.39%;VD后试验钢中氢含量可达0.0001%以下,氮含量平均为0.0040%,均能满足钢种要求。展开更多
文摘This article discusses and analyzes the law of nitrogen increase in liquid steel and the main factors affect-ing the nitrogen increasing of molten steel,through the way of adding nitrogen to molten steel by bottom blowing nitrogen gas in LF refining process.It is considered that the main factors affecting the nitrogen increasing instability of molten steel are the initial temperature of LF refining,nitrogen relative element,surface active elements[O]and[S]of steel liquid,and bottom blowing rate of ladle.The large-scale production practice shows that T[O]not more than 50×10-6 and[S]is not more than 0.020 in LF refining at the initial temperature of not less than 1570.The liquid steel nitrogen enrichment test is carried out by ladle bottom blowing nitrogen gas after 20 min of refining,the flow rate is set as(6.0~7.0)NL/min per ton,and it is turned to 2 NL/min at 6 min before the end of refining,the nitrogen increasing rate of liquid steel is basically stable at(5~6)×10-6 per minute.
文摘18CrNiMo7-6钢（/%：0.17C,0.57Mn,0.24Si,0.012P,0.003S,1.70Cr,1.49Ni,0.28Mo）的冶金流程为60 t EAF-LF-VD-2.1 t铸锭。取样分析了EAF铝锭预脱氧,LF铝粒和碳化硅混合脱氧剂扩散脱氧（LF初渣成分/%：57～60CaO,20.5～22.0Al_2O_3,9.9～11.3SiO_2,8.8～10.6MgO,0.7～1.1FeO,0.7～0.9MnO）,VD后和软吹后钢中夹杂物数量、尺寸和组成的变化。结果表明,精炼过程1～10μm夹杂物数量降低16.67%,〉10μm夹杂物数量降低50%,≥30μm夹杂物基本去除;精炼过程中生成的夹杂主要为镁铝钙的复合夹杂物和CaS,MgS,MnS等硫化物;成品材中主要为Mg-Al的氧化物夹杂,硫化物以MgS为主,有少量MnS、CaS。应进一步优化冶炼工艺,控制中小型夹杂物的形成。
文摘26CrMoNbTiB钢由45 t EAF-LF(VD)-Φ80～180mm管坯HCC流程冶炼。该钢各工序的洁净度试验结果表明,LF-VD后钢中氧含量为(8～18)×10^(-6),平均夹杂物数量最低为2.31个/mm^2,连铸坯平均夹杂物数量为3.66个/mm^2,≥50μm大型夹杂物平均含量为4.08 mg/10 kg。加强钢包到中间包长水口的密封保护和采用钢包下渣检测装置,提高中间包容量和采用挡渣墙是进一步提高铸坯洁净度的关键工艺措施。
文摘试验了45 t LF精炼渣的碱度、喂硫线和脱氧工艺对28MnCr5钢(％:0.25～0.30C、0.60～0.80Mn、0.020～0.035S、0.80～1.00Cr)硫含量的控制、氧化物含量和钢中硫化物的影响。结果表明,LF精炼渣碱度控制在2.8～5.1喂硫线,VD后硫的回收率达80％～90％;钢中氧化物级别≤1.5级;精炼结束喂适量CaSi线可改善钢中硫化物的形貌。
文摘通过研究安钢150 t LF-VD工艺流程下不同钢种的脱硫工艺及其脱硫效果,为采用该工艺流程生产不同成品硫含量要求的钢种提供了操作依据。研究结果表明,通过控制LF炉的精炼渣碱度、LF精炼目标硫含量,以及VD处理抽真空模式、极限真空度和真空处理时底吹氩气流量,可以获得良好的脱气和脱硫效果。对产品标准要求成品硫含量分别不超过0.005%、0.010%和0.015%的钢种,采用不同的钢水脱硫工艺控制后,其钢中硫含量可分别达到0.001%左右、0.006%以下和0.009%以下,LF-VD工艺总平均脱硫率为92.31%、86.22%和80.39%;VD后试验钢中氢含量可达0.0001%以下,氮含量平均为0.0040%,均能满足钢种要求。
