A liquefied petroleum gas （LPG） sensor with high selectivity, sensitivity and low power consumption has been developed based on indium oxide with very low resistance. Nanocrystalline In203 gas sensing materials were...A liquefied petroleum gas （LPG） sensor with high selectivity, sensitivity and low power consumption has been developed based on indium oxide with very low resistance. Nanocrystalline In203 gas sensing materials were directly synthesized through a one-step controllable solvothermal process at 210 ℃ for 24 h, using InCI3.4H2O as the starting material, cetyltrimethyl ammonium bromide （CTAB） as additive and ethanol as the solvent. The obtained samples were characterized by X-ray diffraction （XRD）, and transmission electron microscopy （TEM）. The results showed that indium oxide takes on uniform cubic shape with range size of 10~30 nm and fine dispersivity. Gas sensitivity was measured in a mixing static gas. The results indicated that 3.0 V is the best working voltage of the sensor to LPG. Sensitivity is 12.6. The response-time and recovery-time are 3 s and 10 s respectively. Power consumption is only around 200 mW.展开更多
This paper presents a quantitative risk analysis of liquefied petroleum gas(LPG)transportation.An accident that happened on June 13,2020,on the highway near Wenling,China is studied as a case.In this accident,LPG carr...This paper presents a quantitative risk analysis of liquefied petroleum gas(LPG)transportation.An accident that happened on June 13,2020,on the highway near Wenling,China is studied as a case.In this accident,LPG carried by a tank truck on the highway leaked and caused a large explosion,which led to 20 deaths.Different methods are combined to calculate the consequence of the accident.Multi-energy model and rupture of vessel model are employed to calculate the overpressure;the simulation result of the multi-energy model is closer to the damage caused by the accident.The safety distances in accidents of LPG transport storage tanks of different capacities are calculated in this study;the results show that the damage of explosion will increase with the filling degree of the tank.Even though the filling degree is 90%(value required by law),the 99%fatality rate range will reach 42 m,which is higher than regulated distance between road and building.The social risk of the tank truck has also been calculated and the results show that the risk is not acceptable.The calculating method used in this study could evaluate the risk of LPG tanker more accurately,which may contribute to the establishment of transportation regulation so that losses from similar accidents in the future could be reduced.展开更多
In this study, the quality characteristics and residue analysis in circulated LPG fuel were investigated experimentally in Korea. Quality characteristics in circulated LPG fuel were examined with samples of LPG in the...In this study, the quality characteristics and residue analysis in circulated LPG fuel were investigated experimentally in Korea. Quality characteristics in circulated LPG fuel were examined with samples of LPG in the supply chain (refinery, petrochemical, and imported LPG), transport, gas stations, and vehicles. The experimental results showed that quality of all circulated LPG was well within the quality standard guideline of LPG in Korea. Especially, it has shown average 13 wt ppm in sulfur content over the full circulated LPG. The residue samples in LPG fuel were extracted on 2 L scale with acetonitrile and analyzed by gas chromatography-mass spectrometry (GC-MS). The components of residues in LPG were composed of 62 organic chemicals with C3 ~ C28 and the main ingredients of residue were plasticizers ((di-octyl phalate (DOP), di-octyl adiphate (DOA) etc.), lubricant oil and amine compounds. It was also showed that mass of residue in vehicles was increasing compared with supply (refinery, petrochemical, and imported LPG). It was presumed that this residue had been originated from automotive LPG fuel, vehicle components, and lubricant oil in infrastructure.展开更多
Oxide-Zeolite(OX-ZEO) bifunctional catalyst design concept has been exemplified in several processes to direct conversion syngas to value-added chemicals and fuels such as mixed light olefins, ethylene, aromatics and ...Oxide-Zeolite(OX-ZEO) bifunctional catalyst design concept has been exemplified in several processes to direct conversion syngas to value-added chemicals and fuels such as mixed light olefins, ethylene, aromatics and gasoline.Herein we demonstrate that the product can be steered toward liquefied petroleum gas(LPG) with a selectivity up to 89% in hydrocarbons especially propane selectivity reaching 80% at CO conversion of 63% using ZnCrOx-H-SSZ-39 catalyst.Interestingly, the quantity of the acid sites of SSZ-39 does not influence obviously the hydrocarbon distribution but the strength is crucial for selective formation of propane.This finding provides an alternative route of LPG synthesis from a variety of carbon resources via syngas.展开更多
Underground storage in rock caverns is widely used in Norway for many different petroleum products,such as crude oil,fuel,propane and butane.Basically,the caverns for such storages are unlined,i.e.containment is ensur...Underground storage in rock caverns is widely used in Norway for many different petroleum products,such as crude oil,fuel,propane and butane.Basically,the caverns for such storages are unlined,i.e.containment is ensured without using any steel lining or membrane.The main basis for the storage technology originates from the extensive hydropower development in Norway.As part of this activity,about 4500 km of tunnels and shafts have been excavated,and around 200 large powerhouse caverns have been constructed.The hydropower tunnels are mainly unlined,with hydrostatic water pressure on unlined rock of up to 1000 m.Some of the projects also include air cushion chambers with volumes of up to 1×10^(5)m^(3)and air pressure up to 7.7 MPa.Many lessons which are valuable also for underground oil and gas storage have been learnt from these projects.For a storage project to become successful,systematic,well planned design and ground investigation procedures are crucial.The main steps of the design procedure are first to define the optimum location of the project,and then to optimize orientation,shape/geometry and dimensions of caverns and tunnels.As part of the procedure,ground investigations have to be carried out at several steps integrated with the progress of design.The investigation and design procedures,and the great significance of these for the project to become successful will be discussed.Case examples of oil and gas storage in unlined rock caverns are given,illustrating the relevancy of experience from high-pressure hydropower projects for planning and design of unlined caverns for oil and gas storage.展开更多
With the widespread application of liquefied petroleum gas (LPG),the safety of LPG cylinder has received more and more attention.For the safety of LPG cylinder,we conduct a safety risk assessment of cylinder using the...With the widespread application of liquefied petroleum gas (LPG),the safety of LPG cylinder has received more and more attention.For the safety of LPG cylinder,we conduct a safety risk assessment of cylinder using the failure mode and effect analysis (FMEA) method.Taking the most influential inflatable fatigue under normal conditions as the research object,we use FE-safe software to analyze the fatigue failure.The risk compliance coefficients of various failure modes are calculated and classified according to the risk level.In this way,the service life of the LPG cylinder weld is determined.The presented method improves the safety risk assessment process of LPG cylinder and provides a good theoretical and practical basis for similar pressure vessel risk assessment.展开更多
基金supported by the National Natural Science Foundation of China （Grant No.20471055）
文摘A liquefied petroleum gas （LPG） sensor with high selectivity, sensitivity and low power consumption has been developed based on indium oxide with very low resistance. Nanocrystalline In203 gas sensing materials were directly synthesized through a one-step controllable solvothermal process at 210 ℃ for 24 h, using InCI3.4H2O as the starting material, cetyltrimethyl ammonium bromide （CTAB） as additive and ethanol as the solvent. The obtained samples were characterized by X-ray diffraction （XRD）, and transmission electron microscopy （TEM）. The results showed that indium oxide takes on uniform cubic shape with range size of 10~30 nm and fine dispersivity. Gas sensitivity was measured in a mixing static gas. The results indicated that 3.0 V is the best working voltage of the sensor to LPG. Sensitivity is 12.6. The response-time and recovery-time are 3 s and 10 s respectively. Power consumption is only around 200 mW.
基金the Research Project of National Engineering Research Center for Petroleum Refining Technology and Catalyst(RIPP,SINOPEC)the National Key Research and Development Program of China(No.2018YFC0808600)。
文摘This paper presents a quantitative risk analysis of liquefied petroleum gas(LPG)transportation.An accident that happened on June 13,2020,on the highway near Wenling,China is studied as a case.In this accident,LPG carried by a tank truck on the highway leaked and caused a large explosion,which led to 20 deaths.Different methods are combined to calculate the consequence of the accident.Multi-energy model and rupture of vessel model are employed to calculate the overpressure;the simulation result of the multi-energy model is closer to the damage caused by the accident.The safety distances in accidents of LPG transport storage tanks of different capacities are calculated in this study;the results show that the damage of explosion will increase with the filling degree of the tank.Even though the filling degree is 90%(value required by law),the 99%fatality rate range will reach 42 m,which is higher than regulated distance between road and building.The social risk of the tank truck has also been calculated and the results show that the risk is not acceptable.The calculating method used in this study could evaluate the risk of LPG tanker more accurately,which may contribute to the establishment of transportation regulation so that losses from similar accidents in the future could be reduced.
文摘In this study, the quality characteristics and residue analysis in circulated LPG fuel were investigated experimentally in Korea. Quality characteristics in circulated LPG fuel were examined with samples of LPG in the supply chain (refinery, petrochemical, and imported LPG), transport, gas stations, and vehicles. The experimental results showed that quality of all circulated LPG was well within the quality standard guideline of LPG in Korea. Especially, it has shown average 13 wt ppm in sulfur content over the full circulated LPG. The residue samples in LPG fuel were extracted on 2 L scale with acetonitrile and analyzed by gas chromatography-mass spectrometry (GC-MS). The components of residues in LPG were composed of 62 organic chemicals with C3 ~ C28 and the main ingredients of residue were plasticizers ((di-octyl phalate (DOP), di-octyl adiphate (DOA) etc.), lubricant oil and amine compounds. It was also showed that mass of residue in vehicles was increasing compared with supply (refinery, petrochemical, and imported LPG). It was presumed that this residue had been originated from automotive LPG fuel, vehicle components, and lubricant oil in infrastructure.
基金supported by the Ministry of Science and Technology of China (No.2017YFB0602201)the Chinese Academy of Sciences (XDA21020400)+2 种基金the National Natural Science Foundation of China (Grant nos.91645204, 21425312 and 21621063)the Youth Innovation Promotion Association of Chinese Academy of Sciences (2019184)the INCOE (International Network of Centers of Excellence) project coordinated by BASF SE
文摘Oxide-Zeolite(OX-ZEO) bifunctional catalyst design concept has been exemplified in several processes to direct conversion syngas to value-added chemicals and fuels such as mixed light olefins, ethylene, aromatics and gasoline.Herein we demonstrate that the product can be steered toward liquefied petroleum gas(LPG) with a selectivity up to 89% in hydrocarbons especially propane selectivity reaching 80% at CO conversion of 63% using ZnCrOx-H-SSZ-39 catalyst.Interestingly, the quantity of the acid sites of SSZ-39 does not influence obviously the hydrocarbon distribution but the strength is crucial for selective formation of propane.This finding provides an alternative route of LPG synthesis from a variety of carbon resources via syngas.
文摘Underground storage in rock caverns is widely used in Norway for many different petroleum products,such as crude oil,fuel,propane and butane.Basically,the caverns for such storages are unlined,i.e.containment is ensured without using any steel lining or membrane.The main basis for the storage technology originates from the extensive hydropower development in Norway.As part of this activity,about 4500 km of tunnels and shafts have been excavated,and around 200 large powerhouse caverns have been constructed.The hydropower tunnels are mainly unlined,with hydrostatic water pressure on unlined rock of up to 1000 m.Some of the projects also include air cushion chambers with volumes of up to 1×10^(5)m^(3)and air pressure up to 7.7 MPa.Many lessons which are valuable also for underground oil and gas storage have been learnt from these projects.For a storage project to become successful,systematic,well planned design and ground investigation procedures are crucial.The main steps of the design procedure are first to define the optimum location of the project,and then to optimize orientation,shape/geometry and dimensions of caverns and tunnels.As part of the procedure,ground investigations have to be carried out at several steps integrated with the progress of design.The investigation and design procedures,and the great significance of these for the project to become successful will be discussed.Case examples of oil and gas storage in unlined rock caverns are given,illustrating the relevancy of experience from high-pressure hydropower projects for planning and design of unlined caverns for oil and gas storage.
文摘With the widespread application of liquefied petroleum gas (LPG),the safety of LPG cylinder has received more and more attention.For the safety of LPG cylinder,we conduct a safety risk assessment of cylinder using the failure mode and effect analysis (FMEA) method.Taking the most influential inflatable fatigue under normal conditions as the research object,we use FE-safe software to analyze the fatigue failure.The risk compliance coefficients of various failure modes are calculated and classified according to the risk level.In this way,the service life of the LPG cylinder weld is determined.The presented method improves the safety risk assessment process of LPG cylinder and provides a good theoretical and practical basis for similar pressure vessel risk assessment.
