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Will the Historic Southeasterly Wind over the Equatorial Pacific in March 2022 Trigger a Third-year La Niña Event? 被引量:2
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作者 Xianghui FANG Fei ZHENG +9 位作者 Kexin LI Zeng-Zhen HU Hongli REN Jie WU Xingrong CHEN Weiren LAN Yuan YUAN Licheng FENG Qifa CAI Jiang ZHU 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2023年第1期6-13,共8页
Based on the updates of the Climate Prediction Center and International Research Institute for Climate and Society(CPC/IRI)and the China Multi-Model Ensemble(CMME)El Niño-Southern Oscillation(ENSO)Outlook issued ... Based on the updates of the Climate Prediction Center and International Research Institute for Climate and Society(CPC/IRI)and the China Multi-Model Ensemble(CMME)El Niño-Southern Oscillation(ENSO)Outlook issued in April 2022,La Niña is favored to continue through the boreal summer and fall,indicating a high possibility of a three-year La Niña(2020-23).It would be the first three-year La Niña since the 1998-2001 event,which is the only observed three-year La Niña event since 1980.By examining the status of air-sea fields over the tropical Pacific in March 2022,it can be seen that while the thermocline depths were near average,the southeasterly wind stress was at its strongest since 1980.Here,based on a quaternary linear regression model that includes various relevant air-sea variables over the equatorial Pacific in March,we argue that the historic southeasterly winds over the equatorial Pacific are favorable for the emergence of the third-year La Niña,and both the anomalous easterly and southerly wind stress components are important and contribute~50%of the third-year La Niña growth,respectively.Additionally,the possible global climate impacts of this event are discussed. 展开更多
关键词 El niño-Southern Oscillation three-year la niña strongest southeasterly wind air-sea interaction
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Southern Hemisphere Volcanism Triggered Multi-year La Niñas during the Last Millennium
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作者 Shangrong ZHOU Fei LIU 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第4期587-592,共6页
To explain the recent three-year La Niña event from 2020 to 2022,which has caused catastrophic weather events worldwide,Fasullo et al.(2023)demonstrated that the increase in biomass aerosol resulting from the 201... To explain the recent three-year La Niña event from 2020 to 2022,which has caused catastrophic weather events worldwide,Fasullo et al.(2023)demonstrated that the increase in biomass aerosol resulting from the 2019-20 Australian wildfire season could have triggered this multi-year La Niña.Here,we present compelling evidence from paleo-proxies,utilizing a substantial sample size of 26 volcanic eruptions in the Southern Hemisphere(SH),to support the hypothesis that ocean cooling in the SH can lead to a multi-year La Niña event.This research highlights the importance of focusing on the Southern Ocean,as current climate models struggle to accurately simulate the Pacific response driven by the Southern Ocean. 展开更多
关键词 volcanic eruptions multi-year la niñas Australian wildfire southern ocean cooling
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La-Y-Ni体系储氢合金的电化学性能的研究
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作者 袁芳雪 杨智勇 《山东化工》 CAS 2024年第6期38-41,共4页
主要研究了La_(0.5)Nd_(0.5)Y_(2)Ni_(9.5)Mn_(0.5)Al_(0.5)贮氢合金的结构及其电化学性能。使用真空电弧熔炼法制备合金,通过X射线衍射测试(XRD测试)测试其结构,用DC-5型电池测试仪测定合金的电化学性能。合金电极的放电容量最大可达到... 主要研究了La_(0.5)Nd_(0.5)Y_(2)Ni_(9.5)Mn_(0.5)Al_(0.5)贮氢合金的结构及其电化学性能。使用真空电弧熔炼法制备合金,通过X射线衍射测试(XRD测试)测试其结构,用DC-5型电池测试仪测定合金的电化学性能。合金电极的放电容量最大可达到265.5 mAh·g^(-1)。由La_(0.5)Nd_(0.5)Y_(2)Ni_(9.5)Mn_(0.5)Al_(0.5)合金的循环关系曲线可以清楚地看出,当循环达到第60个周期时,此合金电极的电容量保持率S60仍能达到70.5%,这说明了此种储氢合金在303 K的温度下,有着良好的循环稳定性。储氢合金电极的高倍率性能随着温度的升高逐渐降低。高倍率放电性能在303 K时La_(0.5)Nd_(0.5)Y_(2)Ni_(9.5)Mn_(0.5)Al_(0.5)储氢合金的表现最为突出。尽管随着温度的升高,合金电极的高倍率放电性能在逐渐降低,但是减缓的程度也在逐渐降低。结果说明,La_(0.5)Nd_(0.5)Y_(2)Ni_(9.5)Mn_(0.5)Al_(0.5)合金具有较高的研究意义,在低成本La-Y-Ni系储氢合金成功应用并大量投入生产后,其应用前景将非常广阔。 展开更多
关键词 贮氢合金 la-Y-ni体系 镍氢电池
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时效处理对Ni-Ti-La合金微结构、相变及力学性能的影响
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作者 王晶 李维雅 赵春旺 《内蒙古工业大学学报(自然科学版)》 2024年第1期18-22,共5页
时效处理是调节合金微结构,影响合金性能的有效方法。用实验的方法分析了Ni-Ti-La合金的微结构,研究了合金的相变行为,测定了合金的维氏硬度。实验结果表明,用La元素替代Ni元素形成的Ti_(50)Ni_(49.5)La_(0.5)合金,经时效处理后合金由N... 时效处理是调节合金微结构,影响合金性能的有效方法。用实验的方法分析了Ni-Ti-La合金的微结构,研究了合金的相变行为,测定了合金的维氏硬度。实验结果表明,用La元素替代Ni元素形成的Ti_(50)Ni_(49.5)La_(0.5)合金,经时效处理后合金由NiTi基体、NiLa沉淀相和Ti_(2)Ni沉淀相组成,并且沉淀相的数量随着时效温度升高而减少,合金在加热和冷却的过程中均为一步相变B2↔B19',合金相变开始温度随时效温度的升高而增大,合金的硬度随时效温度的升高而增大。用La元素替代Ti元素形成的Ti_(49.5)Ni_(50)La_(0.5)合金,经时效处理后合金由NiTi基体、NiLa沉淀相组成,并且沉淀相的数量随时效温度的升高而增加,合金在加热和冷却的过程中呈现一步相变B2↔B19',相变开始温度随时效温度的升高而增大,合金的维氏硬度随时效温度的升高而减小。时效处理对Ti_(50)Ni_(49.5)La_(0.5)合金和Ti_(49.5)Ni_(50)La_(0.5)合金的微结构产生了影响,进而影响了合金的相变行为和力学性能。 展开更多
关键词 ni-Ti-la合金 微观结构 相变行为 维氏硬度 时效处理
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La-Mg-Ni系A_(2)B_(7)型合金相结构与储氢性能研究进展
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作者 李媛 陈康莉 +2 位作者 王文凤 张璐 韩树民 《中国材料进展》 CAS CSCD 北大核心 2023年第1期30-38,共9页
氢的燃烧热值高、储量丰富、燃烧产物零污染,被认为是理想的能源载体。氢能的发展对“双碳”目标的实现具有重要的支撑作用,而氢能的发展又离不开高密度、低成本的储氢材料。La-Mg-Ni系A_(2)B_(7)型储氢合金是在La-Ni二元合金的基础上... 氢的燃烧热值高、储量丰富、燃烧产物零污染,被认为是理想的能源载体。氢能的发展对“双碳”目标的实现具有重要的支撑作用,而氢能的发展又离不开高密度、低成本的储氢材料。La-Mg-Ni系A_(2)B_(7)型储氢合金是在La-Ni二元合金的基础上发展起来的一类新型储氢合金,具有储氢容量高、原料成本低等优势。Mg加入到La-Ni合金后进入到[A_(2)B_(4)]亚单元中,抑制了氢致非晶化现象,使结构保持稳定,加速了合金的实用化进程。La-Mg-Ni系A_(2)B_(7)型储氢合金本征储氢容量可达到1.80%以上(质量分数),显著高于已经商品化的AB_(5)型储氢合金。La-Mg-Ni系A_(2)B_(7)型储氢合金的晶体结构可调控性强,并且容易受到组成与制备条件细微变化的影响。基于以上认识,重点关注了关于La-Mg-Ni系A_(2)B_(7)型储氢合金组成与制备技术等相关的研究报道,较为系统地综述了元素取代和制备技术等对La-Mg-Ni系A_(2)B_(7)型储氢合金相结构与储氢性能及电化学性能的影响,总结了合金发展中尚需解决的问题,为制备性能优良的合金提供了思路与依据,并对合金未来的发展趋势进行了展望。 展开更多
关键词 储氢合金 la-Mg-ni系合金 超晶格合金 相结构 储氢性能
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Processes Leading to Second-Year Cooling of the 2010–12 La Ni?a Event,Diagnosed Using GODAS 被引量:5
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作者 FENG Licheng ZHANG Rong-Hua +1 位作者 WANG Zhanggui CHEN Xingrong 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2015年第3期424-438,共15页
Isopycnal analyses were performed on the Global Ocean Data Assimilation System (GODAS) to determine the oceanic processes leading to so-called second-year cooling of the La Nina event.In 2010-12,a horseshoe-like pat... Isopycnal analyses were performed on the Global Ocean Data Assimilation System (GODAS) to determine the oceanic processes leading to so-called second-year cooling of the La Nina event.In 2010-12,a horseshoe-like pattern was seen,connecting negative temperature anomalies off and on the Equator,with a dominant influence from the South Pacific.During the 2010 La Nina event,warm waters piled up at subsurface depths in the western tropical Pacific.Beginning in early 2011,these warm subsurface anomalies propagated along the Equator toward the eastern basin,acting to reverse the sign of sea surface temperature (SST) anomalies (SSTAs) there and initiate a warm SSTA.However,throughout early 2011,pronounced negative anomalies persisted off the Equator in the subsurface depths of the South Pacific.As isopycnal surfaces outcropped in the central equatorial Pacific,negative anomalies from the subsurface spread upward along with mean circulation pathways,naturally initializing a cold SSTA.In the summer,a cold SSTA reappeared in the central basin,which subsequently strengthened due to the off-equatorial effects mostly in the South Pacific.These SSTAs acted to initiate local coupled air-sea interactions,generating atmospheric-oceanic anomalies that developed and evolved with the second-year cooling in the fall of 2011.However,the cooling tendency in mid-2012 did not develop into another La Nina event,since the cold anomalies in the South Pacific were not strong enough.An analysis of the 2007-09 La Nina event revealed similar processes to the 2010-12 La Nina event. 展开更多
关键词 la ni(n)a second-year cooling off-equatorial effects isopycnal analyses circulation pathways GODAS
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La_(2)Mg(Ni_(1-x)Al_(x))^_(9)(x=0.1,0.2)合金的相组成及储氢性能研究
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作者 邢磊 杨玉红 +1 位作者 刘建辉 李一鸣 《内蒙古科技大学学报》 CAS 2023年第4期311-316,326,共7页
研究了Al替代对AB 3型La_(2)Mg(Ni_(1-x)Al_(x))_(9)(x=0.1,0.2)合金相组成、储氢性能和失效行为的影响.表明Al在常温下促进La(Ni,Al)_(5)相含量的提高和LaMg_(2)Ni相的形成,并导致合金放氢困难和电化学放电容量的降低.由于La_(2)MgNi_... 研究了Al替代对AB 3型La_(2)Mg(Ni_(1-x)Al_(x))_(9)(x=0.1,0.2)合金相组成、储氢性能和失效行为的影响.表明Al在常温下促进La(Ni,Al)_(5)相含量的提高和LaMg_(2)Ni相的形成,并导致合金放氢困难和电化学放电容量的降低.由于La_(2)MgNi_(2)和LaMg_(2)Ni相含量的增加,合金耐KOH的腐蚀性降低.腐蚀产物主要为La(OH)_(3),La_(2)O_(3)和Mg(OH)_(2).通过Al替代改善合金电化学放电和循环稳定性的关键在于优化其中的相组成类型. 展开更多
关键词 la-Mg-ni系合金 AB_(3)型 Al元素替代 失效行为
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TYPHOON ACTIVITY IN NORTHWEST PACIFIC IN RELATION WITH EL NINO AND LA NINA EVENTS 被引量:2
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作者 何敏 宋文玲 陈兴芳 《Journal of Tropical Meteorology》 SCIE 1999年第2期153-162,共10页
Statistic and typical-year composition methods are used to study the northwest Pacific typhoonactivities in relation with the El Nino and La Nina events. The result indicates that the typhoon tends to be inactive in t... Statistic and typical-year composition methods are used to study the northwest Pacific typhoonactivities in relation with the El Nino and La Nina events. The result indicates that the typhoon tends to be inactive in the El Nino years and active in the La Nina years and it is also dependent on the onset and ending time andintensity of the events and areas of genesis of typhoons. With statistic features of the frequency of typhoon activity in the EI Nino and La Nina years and the time-lag correlation between the frequency and sea surface temperature (SST), useful information is provided for the prediction of typhoon occurrence. In addition, the singularvalues disassemble (SVD) method is applied to study the correlation between the geopotential field and SST fief(l.The result shows that the air-sea coupling in the EI Nino years is unfavorable for the typhoon to develop. whichtake place with a smaller number. Opposite situations are found with the La Nina years. 展开更多
关键词 TYPHOON EI nino and la niNA eventS SINGUlaR VALUES disassemble
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La/Y比对A_(2)B_(7)型La⁃Y⁃Ni储氢合金性能的影响
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作者 刘雯雯 赖华生 +1 位作者 王玉香 周有池 《矿冶工程》 CAS 北大核心 2023年第2期149-153,共5页
采用真空熔炼法制备了不同La/Y比的A_(2)B_(7)型La_(x)Y_(3-x)Ni_(9.7)Mn_(0.5)Al_(0.3)(x=0.2,0.4,0.6,0.8,1.0)储氢合金。通过XRD、SEM、气相PCT曲线和电化学充放电循环曲线测试等方法,系统研究了A侧Y元素部分替代La元素对合金相结构... 采用真空熔炼法制备了不同La/Y比的A_(2)B_(7)型La_(x)Y_(3-x)Ni_(9.7)Mn_(0.5)Al_(0.3)(x=0.2,0.4,0.6,0.8,1.0)储氢合金。通过XRD、SEM、气相PCT曲线和电化学充放电循环曲线测试等方法,系统研究了A侧Y元素部分替代La元素对合金相结构和合金性能的影响。结果表明,制备的合金主相为Ce_(2)Ni_(7)相,同时还含有少量Gd2Co7相、PuNi_(3)相和LaNi_(5)相。主相Ce_(2)Ni_(7)相丰度随着La/Y比增加而逐渐增大,当La/Y比为1∶2时,LaY_(2)Ni_(9.7)Mn_(0.5)Al_(0.3)合金吸氢量最大,为1.317%。经过150次充放电循环,LaY_(2)Ni_(9.7)Mn0.5 Al0.3合金容量保持率最高,为54.2%。 展开更多
关键词 储氢合金 la/Y比 la⁃Y⁃ni储氢合金 A2B7型 吸氢量
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La_(0.7)Mg_(0.3)Ni_(2.5-x)Co_(0.6)Mn_(0.4)Cu_(x)(x=0~0.20)储氢合金的制备及电化学性能研究
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作者 王姗姗 裴婷 +2 位作者 张新庄 窦倩 张妮娜 《石油化工应用》 CAS 2023年第9期96-98,102,共4页
采用共沉淀还原扩散法获得了La-Mg-Ni系A2B7型La_(0.7)Mg_(0.3)Ni_(2.5-x)Co_(0.6)Mn_(0.4)Cu_(x)(x=0~0.20)系列储氢合金,并深入探讨其电化学、动力学性能及结构特征。结果发现,合金的最大放电容量和循环稳定性能有很大程度的改善,动... 采用共沉淀还原扩散法获得了La-Mg-Ni系A2B7型La_(0.7)Mg_(0.3)Ni_(2.5-x)Co_(0.6)Mn_(0.4)Cu_(x)(x=0~0.20)系列储氢合金,并深入探讨其电化学、动力学性能及结构特征。结果发现,合金的最大放电容量和循环稳定性能有很大程度的改善,动力学性能也相应的提升,活化性能并未受到影响,因Cu与Ni原子半径相近,其结构并没有因Cu的取代而发生改变,合金相结构主要由(La,Mg)2Ni7和LaNi5相组成。 展开更多
关键词 储氢合金 电化学 la-Mg-ni A2B7
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Ni-La双掺LiMn_(2)O_(4)截角八面体正极材料的制备及电化学性能
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作者 李燕 张俊杰 郭俊明 《材料导报》 CSCD 北大核心 2023年第14期16-23,共8页
采用溶液燃烧法合成了一种具有{111}和{100}晶面的截角八面体LiNi_(0.05)La_(0.04)Mn_(1.91)O_(4)正极材料。结果表明,Ni-La复合掺杂促进了尖晶石型LiMn_(2)O_(4)晶体的{111}及{100}晶面择优生长,形成了亚微米级截角八面体晶粒形貌的正... 采用溶液燃烧法合成了一种具有{111}和{100}晶面的截角八面体LiNi_(0.05)La_(0.04)Mn_(1.91)O_(4)正极材料。结果表明,Ni-La复合掺杂促进了尖晶石型LiMn_(2)O_(4)晶体的{111}及{100}晶面择优生长,形成了亚微米级截角八面体晶粒形貌的正极材料。在1C下,其首次放电比容量为128.5 mA·h/g,1000次循环后保持率为65.48%;10C倍率下,放电比容量为108.2 mA·h/g,1500次循环后容量保持率为75.8%;在更高倍率15C和20C下,经2000次长循环后保持率分别为74.76%和76.16%,说明LiNi_(0.05)La_(0.04)Mn_(1.91)O_(4)材料充放电倍率越高,容量保持率越优。该材料具有较大的锂离子扩散系数与较小的表观活化能。Ni-La共掺杂与截角八面体形貌联合调控策略可有效抑制Jahn-Teller畸变,减少Mn溶解及增加Li^(+)迁移通道数量,稳定晶体结构,提升尖晶石型LiMn_(2)O_(4)正极材料的倍率性能和循环寿命。 展开更多
关键词 LiMn_(2)O_(4) ni-la复合掺杂 截角八面体 JAHN-TELLER畸变 Mn溶解 正极材料 锂离子电池
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The Predictability of Ocean Environments that Contributed to the 2020/21 Extreme Cold Events in China:2020/21 La Niña and 2020 Arctic Sea Ice Loss 被引量:2
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作者 Fei ZHENG Ji-Ping LIU +6 位作者 Xiang-Hui FANG Mi-Rong SONG Chao-Yuan YANG Yuan YUAN Ke-Xin LI Ji WANG Jiang ZHU 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2022年第4期658-675,共18页
Several consecutive extreme cold events impacted China during the first half of winter 2020/21,breaking the low-temperature records in many cities.How to make accurate climate predictions of extreme cold events is sti... Several consecutive extreme cold events impacted China during the first half of winter 2020/21,breaking the low-temperature records in many cities.How to make accurate climate predictions of extreme cold events is still an urgent issue.The synergistic effect of the warm Arctic and cold tropical Pacific has been demonstrated to intensify the intrusions of cold air from polar regions into middle-high latitudes,further influencing the cold conditions in China.However,climate models failed to predict these two ocean environments at expected lead times.Most seasonal climate forecasts only predicted the 2020/21 La Niña after the signal had already become apparent and significantly underestimated the observed Arctic sea ice loss in autumn 2020 with a 1-2 month advancement.In this work,the corresponding physical factors that may help improve the accuracy of seasonal climate predictions are further explored.For the 2020/21 La Niña prediction,through sensitivity experiments involving different atmospheric-oceanic initial conditions,the predominant southeasterly wind anomalies over the equatorial Pacific in spring of 2020 are diagnosed to play an irreplaceable role in triggering this cold event.A reasonable inclusion of atmospheric surface winds into the initialization will help the model predict La Niña development from the early spring of 2020.For predicting the Arctic sea ice loss in autumn 2020,an anomalously cyclonic circulation from the central Arctic Ocean predicted by the model,which swept abnormally hot air over Siberia into the Arctic Ocean,is recognized as an important contributor to successfully predicting the minimum Arctic sea ice extent. 展开更多
关键词 extreme cold event PREDICTABILITY la niña Arctic sea ice loss
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Impact of Pacific Decadal Oscillation on Frequency Asymmetry of El Nio and La Nia Events 被引量:1
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作者 Soon-Il AN 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2018年第5期493-494,共2页
El Nio-Southern Oscillation(ENSO)is an abnormal sea surface warming or cooling phenomenon over the tropical Pacific,which also has severe global impact.
关键词 EL o and la ni a events la
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U-Pb Dating of Volcanic Rocks and Granites along the Wuyishan Belt:Constraints on Timing of Late Mesozoic Tectonic Events in Southeast China 被引量:14
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作者 XU Xianbing ZHANG Yueqiao +1 位作者 JIA Dong SHU Liangshu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2011年第1期130-144,共15页
Five volcanic rock samples and two granite samples taken from the volcanic basins in western Fujian and southern Jiangxi were dated by using the zircon laser albation-inductively coupled plasma mass spectrometry U-Pb ... Five volcanic rock samples and two granite samples taken from the volcanic basins in western Fujian and southern Jiangxi were dated by using the zircon laser albation-inductively coupled plasma mass spectrometry U-Pb method. Together with previously dated ages, the dates obtained provide important constraints on the timing of late Mesozoic tectonic events in SE China. The volcanic rock samples yield ages of 183.1±3.5 Ma, ca. 141 Ma to 135.8±1.1 Ma, 100.4±1.5 to 97.6±1.1 Ma, confirming three episodes of late Mesozoic volcanic activities, which peaked at 180±5 Ma, 140±5 Ma and 100±5 Ma, respectively, along the Wuyishan belt. Moreover, based on field investigations of these volcano-sedimentary basins, we have recognized two compressional tectonic events along this belt. The early one was characterized by Upper Triassic to Middle Jurassic NNE-trending folds that were intruded by late Jurassic granites; and the late one caused the Lower Cretaceous volcano-sedimentary layer to be tilted. The dated age 152.9±1.4 Ma of the granitic samples from the Hetian granitic pluton in the Changting Basin and that from the Baishiding granitic pluton, 100.2±1.8 Ma, in the Jianning Basin, give the upper boundaries of these two tectonic events respectively. Hence, the late Mesozoic tectonic evolution of SE China was alternated between extension and compression. 展开更多
关键词 late Mesozoic volcanic rocks la-ICP-MS U-Pb compressional events Wuyishan Belt SE China
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Differential cognitive responses to guqin music and piano music in Chinese subjects: an event-related potential study 被引量:8
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作者 Wei-Na ZHU Jun-Jun ZHANG +3 位作者 Hai-Wei LIU Xiao-Jun DING Yuan-Ye MA Chang-Le ZHOU 《Neuroscience Bulletin》 SCIE CAS CSCD 2008年第1期21-28,共8页
比较 guqin (最旧的中国仪器) 的认知效果的目的音乐和钢琴音乐。在一项标准二刺激的听觉的古怪任务的方法行为、事件相关的潜力(ERP ) 数据被记录并且分析。这研究复制了的结果文化熟悉的音乐的以前的结果在汉语上完成题目:在在文化... 比较 guqin (最旧的中国仪器) 的认知效果的目的音乐和钢琴音乐。在一项标准二刺激的听觉的古怪任务的方法行为、事件相关的潜力(ERP ) 数据被记录并且分析。这研究复制了的结果文化熟悉的音乐的以前的结果在汉语上完成题目:在在文化熟悉的音乐环境的额区的更大的 P300 振幅。同时, guqin 音乐之间的差别和钢琴音乐在 N1 和以后的积极建筑群被观察(LPC:包括 P300 和 P500 ) :在中国题目的恰好前时间的区域的相对更高的参予。结果建议的结论对 guqin 音乐的 ERP 回答的特殊特征是中国音调的语言环境的结果,这给 Guqin 的音调和官员的类似词汇音调。 展开更多
关键词 钢琴 认知过程 中国 电位 心理过程
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不同Mn含量对A_(2)B_(7)型La-Y-Ni储氢合金性能的影响
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作者 郑波 刘雯雯 +6 位作者 任权兵 赖华生 冯兰 皮雄 李荣华 钟鸣 林昊 《有色金属(冶炼部分)》 CAS 北大核心 2023年第8期82-88,共7页
采用真空熔炼法制备了不同Mn含量的A_(2)B_(7)型LaY_(2)Ni_(10.2-x)Mn_(x)Al_(0.3)(x=0.1、0.2、0.3、0.4、0.5)储氢合金。通过物相性能测试、气态储氢性能测试和电化学充放电循环性能测试等方法,系统研究了B侧Mn元素部分替代Ni元素对... 采用真空熔炼法制备了不同Mn含量的A_(2)B_(7)型LaY_(2)Ni_(10.2-x)Mn_(x)Al_(0.3)(x=0.1、0.2、0.3、0.4、0.5)储氢合金。通过物相性能测试、气态储氢性能测试和电化学充放电循环性能测试等方法,系统研究了B侧Mn元素部分替代Ni元素对合金相结构和性能的影响。结果表明:制备的合金为多相结构,其中,主相为Ce_(2)Ni_(7),副相为Gd_(2)Co_(7)、PuNi_(3)和LaNi_(5)。随着Mn含量的增加,Ce_(2)Ni_(7)相含量先增大后减小。当x=0.3时,LaY_(2)Ni_(9.9)Mn_(0.3)Al_(0.3)合金有最大吸氢量,为1.132%。经过150次充放电循环,x=0.3时,合金的容量保持率最高,为58.0%。 展开更多
关键词 MN含量 la-Y-ni储氢合金 相结构 最大吸氢量
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LA-ICP-MS U-Pb Geochronology of Detrital Zircons in Eastern Liaoning Province: An Early Paleozoic Formation Associated with the Gondwana Supercontinent Event 被引量:2
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作者 DONG Xiaojie LIU Zhenghong +2 位作者 XU Zhongyuan LIU Yongjun LIU Jiexun 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2018年第3期1262-1264,共3页
Objective The Liao-Ji orogenic belt is a famous Paleoproterozoic orogenic belt in the East Block of the North China Craton(NCC),which extend in NE-SW direction.The geological mass in the Paleoproterozoic Liao-Ji belt ... Objective The Liao-Ji orogenic belt is a famous Paleoproterozoic orogenic belt in the East Block of the North China Craton(NCC),which extend in NE-SW direction.The geological mass in the Paleoproterozoic Liao-Ji belt is mainly composed of the Liaoji granites and metamorphic volcanic-sedimentary rocks of the Liaohe group(and its 展开更多
关键词 la-ICP-MS U-Pb Geochronology of Detrital Zircons Eastern Liaoning Province the Gondwana Supercontinent event
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Late onsets of tropical cyclones in the decaying years of super El Niño events
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作者 Zhiqiang Li Runyu Zhang +2 位作者 Kai Liu Changling Zheng Zhikun Chen 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2019年第7期67-73,共7页
The 2015/2016 El Nino event reached the threshold of super El Nino event,and was comparable to the super events in 1982/1983 and 1997/1998.Interestingly,the tropical cyclones(TCs)were found to have very late onsets in... The 2015/2016 El Nino event reached the threshold of super El Nino event,and was comparable to the super events in 1982/1983 and 1997/1998.Interestingly,the tropical cyclones(TCs)were found to have very late onsets in the decaying years of the super El Nino events.This study discusses the causes of late TC onsets related with atmospheric circulation,disturbance sources and trigger mechanisms.The analysis shows that the western North Pacific subtropical high(WNPSH)from January–June during the decaying years of the super El Nino events were stronger than the climatic mean,which resulted in a relatively stable atmospheric state by inhibiting deep convection.As a disturbance source,the April–June intertropical convergence zone(ITCZ)during the decaying years of the super El Nino events were significantly weaker than its climatic mean.The cross-equatorial flow and monsoon trough,as important TC generation triggers,were weaker from April–June during the decaying years of the super El Nino events,which further reduced the probability of TC generation.As for the late TC onsets,the role of atmospheric circulation anomalies(i.e.,subtropical-high,the ITCZ,cross-equatorial flow,and monsoon trough)were more important.The cross-equatorial flow may take as predictor of TC onsets in the decaying years of the super El Nino events. 展开更多
关键词 super El niño event TC generation disturbance source trigger mechanism
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快淬La-Mg-Ni系贮氢合金的电化学性能及微观结构 被引量:7
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作者 张羊换 李保卫 +3 位作者 蔡颖 董小平 任江远 王新林 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2007年第1期108-112,共5页
采用铸造及快淬工艺制备了La—Mg-Ni系(PuNi3型)贮氢合金La0.7Mg0.3Ni2.55-Co0.45Cux(x=0~0.4),分析测试了铸态及快淬态合金的电化学性能与微观结构,研究了Cu替代Ni及快淬工艺对合金微观结构及电化学性能的影响。结果表明:铸... 采用铸造及快淬工艺制备了La—Mg-Ni系(PuNi3型)贮氢合金La0.7Mg0.3Ni2.55-Co0.45Cux(x=0~0.4),分析测试了铸态及快淬态合金的电化学性能与微观结构,研究了Cu替代Ni及快淬工艺对合金微观结构及电化学性能的影响。结果表明:铸态及快淬态合金具有多相结构,包括(La,Mg)Ni3相和LaNi5相和一定量的LaNi2相。快淬处理对合金的相组成没有影响,但使合会的衍射峰趋于均匀一致。Cu替代Ni使合金的电化学容量下降,但使合金的循环稳定性及放电电压特性得到改善。快淬可提高合金的循环稳定性,但使合金的容量下降。 展开更多
关键词 Cu替代ni la—Mg-ni系贮氢台金 微观结构 电化学性能
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Ni-La/γ-Al_2O_3·SiO_2催化剂上乙醇水蒸气重整制氢 被引量:11
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作者 张利峰 王一平 黄群武 《化工进展》 EI CAS CSCD 北大核心 2008年第10期1605-1609,1623,共6页
制备了不同La含量的Ni-La/γ-Al2O3·SiO2催化剂,采用XRD、TPR和XPS等对催化剂进行了表征,结果显示,催化剂中加入La之后,能提高Ni的分散度。分别考察了水醇比和温度对La质量分数为5%的催化剂性能的影响,发现当水醇摩尔比为4.0时,氢... 制备了不同La含量的Ni-La/γ-Al2O3·SiO2催化剂,采用XRD、TPR和XPS等对催化剂进行了表征,结果显示,催化剂中加入La之后,能提高Ni的分散度。分别考察了水醇比和温度对La质量分数为5%的催化剂性能的影响,发现当水醇摩尔比为4.0时,氢气选择性650℃时达到99.0%,CO选择性400℃时只有0.7%。还对该催化剂进行了稳定性测试,结果表明,在整个100h稳定性测试过程中不产生乙烯,氢气的选择性保持在67.2%左右,总积炭量仅仅为8.6mg/(gcat·h),具有良好的稳定性和抗积炭性能。 展开更多
关键词 ni la γ-Al2O3·SiO2 乙醇 氢气
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