The effect of wheel speed on phase formation and magnetic properties of （Ndo.4La0.6）lsFeTzsBzs and （Ndo.4La0.6）13.4Fe79.9B6.7 ribbons prepared by melt-spinning method was investigated experimentally. Based on X-ra...The effect of wheel speed on phase formation and magnetic properties of （Ndo.4La0.6）lsFeTzsBzs and （Ndo.4La0.6）13.4Fe79.9B6.7 ribbons prepared by melt-spinning method was investigated experimentally. Based on X-ray diffraction results, all melt-spun ribbons consist of the main phase with the tetragonal 2：14：1 type structure and the minor α-Fe phase. Magnetic measurements show the maximum magnetic energy product （（BH）max） and the remanence （Mr） increases firstly and then decreases with the increase of wheel speed, while the coercivity （Hci） increases, resulting from the variation of the average volume fraction of the ^-Fe phase and the average grain size in the melt-spun ribbons. Using Henkel plots, the interaction between the 2：14：1 phase and the ^-Fe phase in the melt-spun ribbons was analyzed and the intergranular exchange coupling is manifested. Optimal magnetic properties of Hci - 7.27 kOe, Mr - 90.94 emu/g and （BH）max -- 12.10 MGOe are achieved in the （Ndo.4La0.6）lsFeTzsBT.s ribbon with the wheel speed of 26 m/s. It indicates that magnetic properties of Nd-Fe-B melt-spun ribbons with highly abundant rare earth element La can be improved by optimizing alloy composition and preparation process.展开更多
基金Project supported by the National Basic Research Program of China(973 Program)(2014CB643703)the National Key Research and Development Program of China(2016YFB0700901)+1 种基金the National Natural Science Foundation of China(51761008,51461013)the Guangxi Natural Science Foundation(2016GXNSFDA380015,2016GXNSFGA380001)
文摘The effect of wheel speed on phase formation and magnetic properties of （Ndo.4La0.6）lsFeTzsBzs and （Ndo.4La0.6）13.4Fe79.9B6.7 ribbons prepared by melt-spinning method was investigated experimentally. Based on X-ray diffraction results, all melt-spun ribbons consist of the main phase with the tetragonal 2：14：1 type structure and the minor α-Fe phase. Magnetic measurements show the maximum magnetic energy product （（BH）max） and the remanence （Mr） increases firstly and then decreases with the increase of wheel speed, while the coercivity （Hci） increases, resulting from the variation of the average volume fraction of the ^-Fe phase and the average grain size in the melt-spun ribbons. Using Henkel plots, the interaction between the 2：14：1 phase and the ^-Fe phase in the melt-spun ribbons was analyzed and the intergranular exchange coupling is manifested. Optimal magnetic properties of Hci - 7.27 kOe, Mr - 90.94 emu/g and （BH）max -- 12.10 MGOe are achieved in the （Ndo.4La0.6）lsFeTzsBT.s ribbon with the wheel speed of 26 m/s. It indicates that magnetic properties of Nd-Fe-B melt-spun ribbons with highly abundant rare earth element La can be improved by optimizing alloy composition and preparation process.
