La0.8Sr0.2FeO3-δ is a new kind of cathode material for intermediate SOFC, but its electrochemical activity is relative poor for the lanthanum gallate based solid oxide fuel cell. In this paper, a novel composite cath...La0.8Sr0.2FeO3-δ is a new kind of cathode material for intermediate SOFC, but its electrochemical activity is relative poor for the lanthanum gallate based solid oxide fuel cell. In this paper, a novel composite cathode of La0.8Sr0.2FeO3-δ/La0.9Sr0.1Ga0.8Mg0.2O3-δ was prepared on the LSGM electrolyte substrate by screen-printing method. The results of cathodic polarization measurements show that the overpotential decreases significantly when the composite cathode is used instead of the La0.8Sr0.2FeO3-δ single layer cathode. The cathodic overpotential of the composite La0.8Sr0.2FeO3-δ/La0.9Sr0.1Ga0.8Mg0.2O3-δ cathode is 150 mV at the current density of 0.2 A·cm-2 at 800 ℃, while the cathodic overpotential of the La0.8Sr0.2FeO3-δ single layer cathode is higher than 260 mV at the same condition. The electrochemical impedance spectroscopy was employed to investigate the polarization resistance of the cathode. The polarization resistance of the composite cathode is 1.20 Ω·cm2 in open circuit condition, while the value of the single La0.8Sr0.2FeO3-δ cathode is 1.235 Ω·cm2.展开更多
文章采用柠檬酸络合法制备了La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-δ)钙钛矿,采用低温N_2物理吸附、X-射线衍射(X-ray diffraction,XRD)、氢气程序升温还原(hydrogen temperature programmed reduction,H_2-TPR)、氧气程序升温脱附(ox...文章采用柠檬酸络合法制备了La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-δ)钙钛矿,采用低温N_2物理吸附、X-射线衍射(X-ray diffraction,XRD)、氢气程序升温还原(hydrogen temperature programmed reduction,H_2-TPR)、氧气程序升温脱附(oxygen temperature programmed desorption,O_2-TPD)和X-射线光电子能谱(X-ray photoelectron spectroscopy,XPS)表征了其物理化学性质,并考察了甲烷催化燃烧活性。结果表明,当柠檬酸/金属离子摩尔比(citric acid to metal ions molar ratio,CMMR)为1.25时,所制得的催化剂催化活性最佳。XRD表征结果表明,CMMR为1.25或1.50时,形成的钙钛矿晶型更完整。H_2-TPR表征结果表明,CMMR为1.25时,催化剂中的Fe^(4+)和Co^(3+)的还原温度较低,还原性能好。XPS表征结果表明,CMMR为1.25时,催化剂表面上吸附氧晶格氧之比最大。O_2-TPD表征结果表明,随着CMMR增加,催化剂中可移动晶格氧量减小,脱附温度增加,非化学计量比显著减小。CMMR为1.25时,催化剂表面吸附氧较易活化,形成活性物种。展开更多
基金This work was financially supported by the National Natural Science Foundation of China (No. 90510006) and the National High-Tech Research and Development of China (No. 2003AA302440).
文摘La0.8Sr0.2FeO3-δ is a new kind of cathode material for intermediate SOFC, but its electrochemical activity is relative poor for the lanthanum gallate based solid oxide fuel cell. In this paper, a novel composite cathode of La0.8Sr0.2FeO3-δ/La0.9Sr0.1Ga0.8Mg0.2O3-δ was prepared on the LSGM electrolyte substrate by screen-printing method. The results of cathodic polarization measurements show that the overpotential decreases significantly when the composite cathode is used instead of the La0.8Sr0.2FeO3-δ single layer cathode. The cathodic overpotential of the composite La0.8Sr0.2FeO3-δ/La0.9Sr0.1Ga0.8Mg0.2O3-δ cathode is 150 mV at the current density of 0.2 A·cm-2 at 800 ℃, while the cathodic overpotential of the La0.8Sr0.2FeO3-δ single layer cathode is higher than 260 mV at the same condition. The electrochemical impedance spectroscopy was employed to investigate the polarization resistance of the cathode. The polarization resistance of the composite cathode is 1.20 Ω·cm2 in open circuit condition, while the value of the single La0.8Sr0.2FeO3-δ cathode is 1.235 Ω·cm2.
文摘文章采用柠檬酸络合法制备了La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-δ)钙钛矿,采用低温N_2物理吸附、X-射线衍射(X-ray diffraction,XRD)、氢气程序升温还原(hydrogen temperature programmed reduction,H_2-TPR)、氧气程序升温脱附(oxygen temperature programmed desorption,O_2-TPD)和X-射线光电子能谱(X-ray photoelectron spectroscopy,XPS)表征了其物理化学性质,并考察了甲烷催化燃烧活性。结果表明,当柠檬酸/金属离子摩尔比(citric acid to metal ions molar ratio,CMMR)为1.25时,所制得的催化剂催化活性最佳。XRD表征结果表明,CMMR为1.25或1.50时,形成的钙钛矿晶型更完整。H_2-TPR表征结果表明,CMMR为1.25时,催化剂中的Fe^(4+)和Co^(3+)的还原温度较低,还原性能好。XPS表征结果表明,CMMR为1.25时,催化剂表面上吸附氧晶格氧之比最大。O_2-TPD表征结果表明,随着CMMR增加,催化剂中可移动晶格氧量减小,脱附温度增加,非化学计量比显著减小。CMMR为1.25时,催化剂表面吸附氧较易活化,形成活性物种。
