In this paper, any two of the three anticorrosion agents, that is emulsifier (OP-10), soluble glass (Na2O·nSiO2) and glycerin (C3H8O3), were treated simultaneously on the surface of amorphous (a-) MgNi+5% Ml2Mg17...In this paper, any two of the three anticorrosion agents, that is emulsifier (OP-10), soluble glass (Na2O·nSiO2) and glycerin (C3H8O3), were treated simultaneously on the surface of amorphous (a-) MgNi+5% Ml2Mg17 (Ml denotes the lanthanum-rich mish metal) electrode and the electrolyte. Effect of the synergistic anticorrosion treatment on charging/discharging cycle stability of the electrode was investigated. Contrasted with single treatment method, the cycling stability of the electrodes was further improved. The desirable synergistic anticorrosion method was that the electrode was treated by the soluble glass, and that OP-10 was added into the electrolyte. The cyclic voltammogram (CV) results of the electrode show clearly that the anticorrosion agent can change the electrochemical activity and mechanism of the electrode. The concentration of the anticorrosion agent in the electrolyte treated by the synergistic anticorrosion method was also investigated. The appropriate concentration of the anticorrosion agents in the electrolyte is 0.143%.展开更多
The structure and hydriding/dehydriding behaviors ofLa2Mgl7-10 wt.%Ni composite prepared by mechanical milling were investigated. Compared with the tin-milled sample, the as-milled alloys were ready to be activated an...The structure and hydriding/dehydriding behaviors ofLa2Mgl7-10 wt.%Ni composite prepared by mechanical milling were investigated. Compared with the tin-milled sample, the as-milled alloys were ready to be activated and the kinetics of hydrogen ab- sorption was relatively fast even at environmental temperature. The composite milled for 10 h absorbed 3.16 wt.% hydrogen within 100 s at 290 K. The kinetic mechanisms ofhydriding/dehydriding reactions were analyzed by using a new model. The results showed that hydrogenation processes for all composites were controlled by hydrogen diffusion and the minimum activation energy was 15.3 kJ/mol H2 for the composite milled for 10 h. Mechanical milling changed the dehydriding reaction rate-controlling step from surface penetration to diffusion and reduced the activation energy from 204.6 to 87.4 kJ/mol H2. The optimum milled duration was 5 h for desorption in our trials.展开更多
Nanocrystalline and amorphous La_（2–x）Sm_xMg_（16）Ni＋200wt.% Ni（x=0, 0.1, 0.2, 0.3, 0.4） alloys were prepared by mechanical milling technology. The structures of as-cast and milled alloys were investigated by X...Nanocrystalline and amorphous La_（2–x）Sm_xMg_（16）Ni＋200wt.% Ni（x=0, 0.1, 0.2, 0.3, 0.4） alloys were prepared by mechanical milling technology. The structures of as-cast and milled alloys were investigated by X-ray diffraction（XRD）, scanning electron microscopy（SEM） and transmission electron microscopy（TEM）. Electrochemical performance of the alloy was studied by using an automatic galvanostatic system. The electrochemical impedance spectra（EIS） and Tafel polarization curves were measured by electrochemical workstation. The results indicated that the structures of the as-cast and milled alloys presented a multiphase structure with nanocrystalline and amorphous phase, moreover, transforming from nanocrystalline to amorphous phase with Sm doping. With the increase of Sm content, the maximum discharge capacity of the alloy was decreased from 922.6 to 649.1 m Ah/g, the high-rate discharge ability（HRD） was decreased, the cycle stability was strengthened, and the alloy exhibited excellent electrochemical kinetics. In addition, the charge-transfer resistance（R_（ct）） of alloy was lessened from 0.05874 to 0.02953 ？ and the limiting current density（I_L） was descended from 2.08366 to 1.04592 A/g with increasing Sm content.展开更多
基金Project supported by the National Natural Science Foundation of China (20363001) the Project in Specific Technological R & D Fund Program for Research Institutes from Ministry of Science and Technology of the PRC (2004EG113030)the Key Project in International Science and Technology Cooperation from Ministry of Science and Technology of the PRC (2005DFA50250)
文摘In this paper, any two of the three anticorrosion agents, that is emulsifier (OP-10), soluble glass (Na2O·nSiO2) and glycerin (C3H8O3), were treated simultaneously on the surface of amorphous (a-) MgNi+5% Ml2Mg17 (Ml denotes the lanthanum-rich mish metal) electrode and the electrolyte. Effect of the synergistic anticorrosion treatment on charging/discharging cycle stability of the electrode was investigated. Contrasted with single treatment method, the cycling stability of the electrodes was further improved. The desirable synergistic anticorrosion method was that the electrode was treated by the soluble glass, and that OP-10 was added into the electrolyte. The cyclic voltammogram (CV) results of the electrode show clearly that the anticorrosion agent can change the electrochemical activity and mechanism of the electrode. The concentration of the anticorrosion agent in the electrolyte treated by the synergistic anticorrosion method was also investigated. The appropriate concentration of the anticorrosion agents in the electrolyte is 0.143%.
基金Project supported by the Guizhou Nomarch Fund Project of Excellent Technology and Education Talents (201019)Specialties Projects funded for the Scientific Research Condition of Guizhou High-Level Talents (TZJF200927)
文摘The structure and hydriding/dehydriding behaviors ofLa2Mgl7-10 wt.%Ni composite prepared by mechanical milling were investigated. Compared with the tin-milled sample, the as-milled alloys were ready to be activated and the kinetics of hydrogen ab- sorption was relatively fast even at environmental temperature. The composite milled for 10 h absorbed 3.16 wt.% hydrogen within 100 s at 290 K. The kinetic mechanisms ofhydriding/dehydriding reactions were analyzed by using a new model. The results showed that hydrogenation processes for all composites were controlled by hydrogen diffusion and the minimum activation energy was 15.3 kJ/mol H2 for the composite milled for 10 h. Mechanical milling changed the dehydriding reaction rate-controlling step from surface penetration to diffusion and reduced the activation energy from 204.6 to 87.4 kJ/mol H2. The optimum milled duration was 5 h for desorption in our trials.
基金Project supported by National Natural Science Foundation of China(51371094,51471054)Young Teachers'Training Project,School of Materials and Metallurgy,Inner Mongolia University of Science and Technology(214CY012)
文摘Nanocrystalline and amorphous La_（2–x）Sm_xMg_（16）Ni＋200wt.% Ni（x=0, 0.1, 0.2, 0.3, 0.4） alloys were prepared by mechanical milling technology. The structures of as-cast and milled alloys were investigated by X-ray diffraction（XRD）, scanning electron microscopy（SEM） and transmission electron microscopy（TEM）. Electrochemical performance of the alloy was studied by using an automatic galvanostatic system. The electrochemical impedance spectra（EIS） and Tafel polarization curves were measured by electrochemical workstation. The results indicated that the structures of the as-cast and milled alloys presented a multiphase structure with nanocrystalline and amorphous phase, moreover, transforming from nanocrystalline to amorphous phase with Sm doping. With the increase of Sm content, the maximum discharge capacity of the alloy was decreased from 922.6 to 649.1 m Ah/g, the high-rate discharge ability（HRD） was decreased, the cycle stability was strengthened, and the alloy exhibited excellent electrochemical kinetics. In addition, the charge-transfer resistance（R_（ct）） of alloy was lessened from 0.05874 to 0.02953 ？ and the limiting current density（I_L） was descended from 2.08366 to 1.04592 A/g with increasing Sm content.
