Red long lasting phosphorescence（LLP） was firstly observed in LaA103：Eu3＋ phosphor synthesized by solid state method at 1773 K. It reveals that the Eu3＋ ions occupy the asymmetric La3＋ sites, resulting in the or...Red long lasting phosphorescence（LLP） was firstly observed in LaA103：Eu3＋ phosphor synthesized by solid state method at 1773 K. It reveals that the Eu3＋ ions occupy the asymmetric La3＋ sites, resulting in the orange-red emission of Eu3＋. The LLP of the optimum LaA103：0.6%Eu3＋ sample can come to about 2000 s according to a definition of 0.32 mcd/m2. The LLP decay curve can not be fitted even by a function of three exponential terms, due to the complicated retrapping process of carriers. The result of a classical multi-peak fitting method on thermo- luminescence reveals that the excellent LLP performance of LaA103：Eu3＋ material originates from the rich distribu- tion of shallow traps（E=0.7875 eV）.展开更多
基金the National Natural Science Foundation of China（No. 11264033） and the Science Research Foundation of Tianshui Normal University, China（No.TSA 1108）.
文摘Red long lasting phosphorescence（LLP） was firstly observed in LaA103：Eu3＋ phosphor synthesized by solid state method at 1773 K. It reveals that the Eu3＋ ions occupy the asymmetric La3＋ sites, resulting in the orange-red emission of Eu3＋. The LLP of the optimum LaA103：0.6%Eu3＋ sample can come to about 2000 s according to a definition of 0.32 mcd/m2. The LLP decay curve can not be fitted even by a function of three exponential terms, due to the complicated retrapping process of carriers. The result of a classical multi-peak fitting method on thermo- luminescence reveals that the excellent LLP performance of LaA103：Eu3＋ material originates from the rich distribu- tion of shallow traps（E=0.7875 eV）.
