The ceramics La0.85Cr0.15TiOx and La0.7Cr0.3TiOx are prepared by conventional solid-state reaction method. The dielectric properties of Cr-doped La TiOx as a function of frequency(0.1 k Hz ≤ f ≤ 1 MHz) and tempera...The ceramics La0.85Cr0.15TiOx and La0.7Cr0.3TiOx are prepared by conventional solid-state reaction method. The dielectric properties of Cr-doped La TiOx as a function of frequency(0.1 k Hz ≤ f ≤ 1 MHz) and temperature(77 K ≤ T ≤360 K) are studied. The blocks are then annealed in a flowing O2 or Ar/H2 to convert their oxygen content and the tests mentioned above are performed. The highly oxygenated samples exhibit extremely high low-frequency dielectric constants at room temperature(~10^6). The results show that the oxygen stoichiometry could significantly influence the dielectric properties of Cr-doped LaTiOx.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.51571006)
文摘The ceramics La0.85Cr0.15TiOx and La0.7Cr0.3TiOx are prepared by conventional solid-state reaction method. The dielectric properties of Cr-doped La TiOx as a function of frequency(0.1 k Hz ≤ f ≤ 1 MHz) and temperature(77 K ≤ T ≤360 K) are studied. The blocks are then annealed in a flowing O2 or Ar/H2 to convert their oxygen content and the tests mentioned above are performed. The highly oxygenated samples exhibit extremely high low-frequency dielectric constants at room temperature(~10^6). The results show that the oxygen stoichiometry could significantly influence the dielectric properties of Cr-doped LaTiOx.