An investigation of roof runoff during rain events at the Royal Military College of Canada and potential discharge to Lake Ontario

The Royal Military College of Canada, located on the north eastern shore of Lake Ontario, possesses an abundance of copper roofs and lacks surface water treatment prior to discharge into Lake Ontario. Rainwater, roof runoff and soil samples were collected and analyzed for copper and other parameters. Copper was consistently detected in runoff samples with average concentrations of 3200 ± 2100 μg/L. Multivariable linear regression analysis for a dependant copper runoff concentration yielded an adjusted R 2 value of 0.611, based on an independent variable model using minimum temperature, maximum temperature, total precipitation, and wind speed. Lake water samples taken in the vicinity of storm water outfalls draining areas with copper roofs ranged from 2.0 to 40 μg/L copper. Such data exceed the 2.0 μg/L Canadian Water Quality Guidelines for the Protection of Aquatic Life as outlined by the Canadian Council of Ministers of the Environment （CCME）. Analysis of raw, filtered and digested forms suggested that the majority of copper present in runoff and lake water samples was in a dissolved form. The majority of soils taken in this study displayed copper concentrations below the 63 μg/g CCME residential/parkland land use limits. These findings suggested that ion exchange processes between runoff water and soil do not occur to a sufficient extent to elevate copper levels in soil. It may therefore be concluded that the eventual fate of copper, which is not discharged via storm water outfalls, is lost to the water table and Lake Ontario through the sub-soil.

St Lawrence Seaway: Eastern Great Lakes, the Niagara River and Welland Canal Replacement, Maintenance and Protection

The Eastern Great Lakes region covers 51,000 square km of land, and is home to 15 million people. This region is rich in natural resources, industry and agriculture, and forms the heartland of both Canada and the United States. The development of this region has a history that is closely tied to waterways, and the development of canals that promoted growth and prosperity. The St. Lawrence Seaway connects Western and Eastern Great Lakes to the St Lawrence River and the Gulf of Saint Lawrence. The New York State Canal and the St. Lawrence Seaway were linked by the Oswego canal and provided a shorter route for cargo via barges to New York City. The New York State (NYS) Barge Canal and the St. Lawrence Seaway provided pathways for the settlement of the Eastern Great Lakes. Lake Erie drains into Lake Ontario via the Niagara River but the river was not navigable due to the obstacles of Niagara Falls and the Niagara Escarpment. Until the 1820s ships could not travel into Lake Erie. It was not possible to engineer a bypass of Niagara Falls with a series of locks due to the 100 m high Niagara escarpment. This escarpment obstacle to Niagara River navigation was overcome in 1829 with the completion of the first of four Welland Canals with locks 40 kilometers west of the Niagara River through the glacial till and alluvium that overlays the Niagara Escarpment. This permitted ocean going ships to enter Lake Erie and to continue on to Lake Michigan, Lake Huron and Lake Superior. The Eastern Great Lake shorelines, river banks and canals are actively eroding as a consequence of high surface water levels and flooding. The settlement of millions of people into the Eastern Great Lakes via the NYS Barge Canal and St. Lawrence Seaway migration pathways have created environmental and natural resource risks and challenges. These challenges and risks include deterioration of the Fourth Welland Canal and the need to replace it with the Fifth Welland Canal, industrial and urban wastewater disposal, shoreline, river bank and canal erosion as results of high water levels, the building of structures on the shoreline banks, invasive species and flooding.

Polychlorinated biphenyls and omega-3 fatty acid exposure from fish consumption,and thyroid cancer among New York anglers

Fish from the Great Lakes contain polychlorinated biphenyls（PCBs）which have been shown to disrupt endocrine function and mimic thyroid hormones,but they also contain beneficial omega-3 fatty acids that may offer protection against endocrine cancers.The purpose of this study was to examine the effects of Lake Ontario fish consumption and the estimated consumption of PCBs and omega-3 fatty acids on the risk of thyroid cancer in a group of sport fishermen.Anglers from the New York State Angler Cohort Study were followed for cancer incidence from 1991–2008.Twenty-seven cases of incident thyroid cancer and 108 controls were included in the analyses.Total estimated fish consumption,estimated omega-3 fatty acid consumption,and estimated PCB consumption from Lake Ontario fish were examined for an association with the incidence of thyroid cancer,while matching on sex,and controlling for age and smoking status.Results from logistic regression indicate no significant associations between fish consumption,short-term estimated omega-3 fatty acids,or estimated PCB consumption from Great Lakes fish and the development of thyroid cancer,but it was suggested that long-term omega-3 fatty acid from Great Lakes fish may be protective of the development of thyroid cancer.In conclusion,fish consumption,with the possible concomitant PCBs,from the Great Lakes does not appear to increase the risk of thyroid cancer in New York anglers.Further research is needed in order to separate the individual health effects of PCBs from omega-3 fatty acids contained within the fish.