THE FLUX OF LAND-BASED SOURCE POLLUTANTS FROM TUMEN RIVER SYSTEM ENTERING THE SEA OF JAPAN

The influence of land based source pollutants to marine ecological environment is principally in coastal or enclosed sea waters. Flux of land based source pollutants into the sea will be effected due to social and economic development in the Tumen River basin. Pollutant type and primary pollution factor of the Tumen River in Northeast China is described by weighted coefficient method in this paper. The results indicate that the river is organic pollution type and primary pollution factor is COD. Fresh water fraction proves that the estuary is not affected by tide cycle. COD annual flux entering the Sea of Japan calculated by zero dimension model in 1993 was 90.50 ×10 3 tons. It is estimated with emission coefficient method that the COD will be 176.4 ×10 3 and 458.6 ×10 3 tons for the years of 2000 and 2010 respectively.

Unsustainable Land-Based Source Pollution in a Climate of Change: A Roadblock to the Conservation and Recovery of Elkhorn Coral <i>Acropora palmata</i>(Lamarck 1816)

Chronic eutrophication and turbidity are critical detrimental factors impacting coral reef ecosystems, adversely affecting their ecological functions, services, benefits, and resilience across multiple spatial scales and over prolonged periods of time. Inadequate land use practices and lack of appropriate sewage treatment can adversely contribute to increase land-based source pollution (LBSP) impacts in coastal waters and to magnify impacts by sea surface warming trends associated to climate change. Fringing coral reefs off Vega Baja, Puerto Rico, support extensive remnant patches of Elkhorn coral Acropora palmata (Lamarck 1816), which was listed in 2006 as a threatened species under the US Endangered Species Act. Chronic impacts by LBSP have significantly affected local downstream fringing reefs. We characterized the spatial extent of a water quality stress gradient across 12 reefs along the Vega Baja coast through monthly measurements of multiple physico-chemical parameters. Most parameters, particularly PO4, , chlorophyll-a, and the concentration of optical brighteners (OABs), showed a statistically significant increase (PERMANOVA, p < 0.05) in waters close to the main pollution sources, but also in waters adjacent to Cibuco River effluents. Dissolved oxygen also declined and turbidity increased on polluted sites. PO4, , and chlorophyll-a, exceeded recommended concentrations for coral reef ecosystems by factors of 7 - 50 times, 600 - 1240 times, and 17 - 83 times, respectively, depending on the source of the effluents and the distance from sewage pollution sources. Also, water turbidity exceeded 4 - 10 times the recommended value for pristine coral reefs. Coral reefs showed significant decline in close proximity to the polluted zone, showing a significantly different benthic community structure (PERMANOVA, p < 0.0001) dominated by non-reef building taxa (i.e., macroalgae, algal turf) and bare substrate. Percent coral cover and abundance of A. palmata, showed a significant increase with distance. Coral species richness, species diversity index, and the variance in taxonomic distinctness were very low on reef patches adjacent to the polluted zone, increased at a moderate distance with increasing coral cover and co-existence of multiple species, and declined far from the pollution source due to dominance exerted by A. palmata. This study suggests that chronic LBSP resulted in a major decline of one of the largest and most dense remnant stands of A. palmata across the northeastern Caribbean and that nutrient and chlorophyll-a concentrations were unsustainable for coral reefs. This situation requires immediate solution to prevent further damage to these unprecedented resources. It further suggests that chronic LBSP may synergistically magnify sea-surface warming impacts driving corals to an increased state of risk in face of forecasted climate change impacts. Actions to mitigate and adapt to climate change impacts on coral reefs must require a priori controls of LBSP to be effective.

Spatial Distribution Assessment and Source Apportionment of Land-Based Pollutant Yield from Qingdao, China

The spatial distribution of chemical oxygen demand(COD) and total nitrogen(TN) yield from Qingdao are studied by comparing pollutant yield amount, densities and spatial aggregation(Getis-Ord indexes) among the land-based pollutant source regions(PSRs) entering the three sub-seas(i.e. the Jiaozhou Bay(JZB), other coastal area in the Yellow Sea(OCAYS) and Laizhou Bay(LZB), respectively). Industrial composition of the loads are also studied by comparing pollutant yield among the sources of agriculture, rural domesticity, industry, urban domesticity and service, and calculation of Gini coefficient. Results show that spatial distribution of COD and TN yield from Qingdao are extremely unbalanced. The JZB, with less than 3% of the total coastal sea area of Qingdao, received 62% COD load and 65% TN yield from Qingdao, while the OCAYS, with more than 97% area, only received 23% COD and 20% TN, which consist with the much worsen water quality of JZB than that of OCAYS. On the other hand, the source apportionment of COD and TN loads in the PSRs entering JZB and the OCAYS was similar. The agricultural and domestic sources with high pollution intensity account for more than 80%, while the industrial and service sources with low pollution intensity account for less than 20%. While Gini coefficients, COD 0.81 and TN 0.84 which are much higher than the ‘imbalance' threshold of 0.4, show the uneven industrial structure of Qingdao. These results may be useful in the determination of land-based pollution total amount control at the PSR level.

Pollution source identification methods and remediation technologies of groundwater: A review

Groundwater is an important source of drinking water.Groundwater pollution severely endangers drinking water safety and sustainable social development.In the case of groundwater pollution,the top priority is to identify pollution sources,and accurate information on pollution sources is the premise of efficient remediation.Then,an appropriate pollution remediation scheme should be developed according to information on pollution sources,site conditions,and economic costs.The methods for identifying pollution sources mainly include geophysical exploration,geochemistry,isotopic tracing,and numerical modeling.Among these identification methods,only the numerical modeling can recognize various information on pollution sources,while other methods can only identify a certain aspect of pollution sources.The remediation technologies of groundwater can be divided into in-situ and ex-situ remediation technologies according to the remediation location.The in-situ remediation technologies enjoy low costs and a wide remediation range,but their remediation performance is prone to be affected by environmental conditions and cause secondary pollution.The ex-situ remediation technologies boast high remediation efficiency,high processing capacity,and high treatment concentration but suffer high costs.Different methods for pollution source identification and remediation technologies are applicable to different conditions.To achieve the expected identification and remediation results,it is feasible to combine several methods and technologies according to the actual hydrogeological conditions of contaminated sites and the nature of pollutants.Additionally,detailed knowledge about the hydrogeological conditions and stratigraphic structure of the contaminated site is the basis of all work regardless of the adopted identification methods or remediation technologies.

Numerical Simulation of the Settling Flux of Biodeposition in a Bay with Cage Culture Through Similarity Theory and a Simplified Pollution Source

The settling flux of biodeposition affects the environmental quality of cage culture areas and determines their environmental carrying capacity.Simple and effective simulation of the settling flux of biodeposition is extremely important for determining the spatial distribution of biodeposition.Theoretically,biodeposition in cage culture areas without specific emission rules can be simplified as point source pollution.Fluent is a fluid simulation software that can simulate the dispersion of particulate matter simply and efficiently.Based on the simplification of pollution sources and bays,the settling flux of biodeposition can be easily and effectively simulated by Fluent fluid software.In the present work,the feasibility of this method was evaluated by simulation of the settling flux of biodeposition in Maniao Bay,Hainan Province,China,and 20 sampling sites were selected for determining the settling fluxes.At sampling sites P1,P2,P3,P4,P5,Z1,Z2,Z3,Z4,A1,A2,A3,A4,B1,B2,C1,C2,C3 and C4,the measured settling fluxes of biodeposition were 26.02,15.78,10.77,58.16,6.57,72.17,12.37,12.11,106.64,150.96,22.59,11.41,18.03,7.90,19.23,7.06,11.84,5.19 and 2.57 g d^(−1)m^(−2),respectively.The simulated settling fluxes of biodeposition at the corresponding sites were 16.03,23.98,8.87,46.90,4.52,104.77,16.03,8.35,180.83,213.06,39.10,17.47,20.98,9.78,23.25,7.84,15.90,6.06 and 1.65 g d^(−1)m^(−2),respectively.There was a positive correlation between the simulated settling fluxes and measured ones(R=0.94,P=2.22×10^(−9)<0.05),which implies that the spatial differentiation of biodeposition flux was well simulated.Moreover,the posterior difference ratio of the simulation was 0.38,and the small error probability was 0.94,which means that the simulated results reached an acceptable level from the perspective of relative error.Thus,if nonpoint source pollution is simplified to point source pollution and open waters are simplified based on similarity theory,the setting flux of biodeposition in the open waters can be simply and effectively simulated by the fluid simulation software Fluent.

Ecological Remediation Measures for Non-point Source Pollution Based on Source-Sink Landscape Theory: A Case Study of Huanghou Basin

The growth of society and population has led to a range of water pollution issues.Among these,non-point source pollution assessment and treatment pose a particular challenge due to its formation mechanism.This has become a focal point and challenge in water pollution treatment research.The study area for this research was the Huanghou basin in Guizhou Province,southwest China.The land use type of the basin was analyzed using remote sensing technology,and water quality data was collected by distributing points throughout the basin,based on source-sink landscape theory.The distribution map of the basin’s source-sink landscape and the results of water quality data accurately and efficiently identified the areas with high risk of non-point source pollution in the western and southwestern residential and agricultural areas of the upper basin.Hence,a strategy of“increasing sinks and decreasing sources”was proposed.The strategy was implemented at both macro and micro levels to address non-point source pollution in the basin using ecological remediation techniques.The work to control karst rocky desertification should continue at a macro level.The rocky desertification area in the basin should gradually transform into grassland and forested land,while increasing the overall area of the sink landscape.Ecological restoration techniques,such as slope planting,riparian zone vegetation restoration,increasing plant abundance,and restoring aquatic plants,can effectively control non-point source pollution at the micro level.Compared to traditional control methods,this remediation strategy focuses on source and process control.It is more effective and does not require large-scale water pollution control projects,which can save a lot of environmental control funds and management costs.Therefore,it has greater research significance and application value.

Genotoxicity evaluation and a primary risk assessment of organic pollutants in the drinking water sources of Nanjing, China

An increasing number of industrial, agricultural, and commercial chemicals in the aquatic environment leads to various deleterious effects on organisms, which is becoming an increasingly serious problem in China. In this study, the comet assay was conducted to investigate the genotoxicity to human body caused by organic concentrates in the drinking water sources of Nanjing City from Yangtze River of China, and health and ecology risk due to expose to these organic pollutants were evaluated with the multimedia environmental assessment system （MEAS）. For all the water samples, they were collected from four different locations in the drinking water sourcr samples, es of Nanjing City. The results of the comet assay showed that all the organic concentrates from the water samples could induce different levels DNA damages on human peripheral blood lymphocytes, and a statistically significant difference （p〈0.01） was observed compared with the solvent control, which demonstrated the genotoxicity was in existence. According to the ambient severity （AS） of individual compound, we had sorted out the main organic pollutants in the drinking water source of the four waterworks, and the results showed that there was some potential hazard to human body for all the source water, namely the total ambient severity （TAS） of health for each water source was more than 1. However, the TAS of ecology for each water source was less than 1, which indicated that it was safe to ecology. The results of this investigation demonstrate the application of the comet assay and the MEAS in aquatic environmental monitoring studies, and the comet assay found to be fast, sensitive, and suitable for genotoxicity monitoring programs of drinking water source.

Sources of Particular Pollutants inAmbient Air at a Petrochemical Enterprise

The study on source apportionment of particular pollutants in ambient air at a petrochemical enterprise is the ba-sis of the control over air pollution. Through analyzing particular pollutants in the samples collected from one petrochemi- cal enterprise in northwestern China, the sources of particular pollutants were discussed. The test results showed that con- centrations of particular pollutants in different sites were remarkably different. Results showed that the sampling sites with higher concentrations of particular pollutants, including toluene, xylenes, NH3 and H2S, were located at the boundary of the petrochemical enterprise. Instead, the concentrations of NMHC in the ambient air sampling sites were higher than those at the boundary of the petrochemical enterprise. The sampling sites with higher concentrations of particular pollutants were located in the area that was close to the petrochemical enterprise. The results obtained from the Pearson correlation co- efficients analyses, the factor analyses, and x^2-tests of the particular pollutants had revealed that NH3, H2S, toluene and xylenes at all sampling sites came from the same source, while NMHC might come from some other sources besides the petrochemical enterprise.

Removal of Agricultural Non-Point Source Pollutants by Artificial Aquatic Food Web System: A Study Case of the Control of Cynobacterial Bloom in Jiyu River

An artificial aquatic food web (AAFW) system was designed to remove the non-point source pollutants in eutrophic Jiyu river. A certain amount of Scenedesmus obliquus and Daphnia pulex was cultured in the system for the control of serious cyanobacterial bloom. The AAFW system was a continuous-flow system including one storage basin of 3 m3 capacity with polluted river water (the total nitrogen-TN: 4.49 mg⋅l-1;the total phosphorus-TP: 0.192 mg⋅l-1), one phytoplankton tank of 3 m3 capacity with an initial concentrations of S. obliquus about 5.8 × 103 ind⋅l-1, and one zooplankton growth chamber of 1.5 m3 capacity with an initial abundance of D. pulex about 22.5 ind⋅l-1. The system was optimized by setting hydraulic retention time of phytoplankton tank as 5 days and the experiments were operated for 45 days. Compared with the polluted river, TN and TP were removed about 28% and 47% by the AAFW system, respectively. The biomass of phytoplankton decrease from 6.33 mg⋅l-1 to 1.48 mg⋅l-1 and the percentage of cyanobacteria decrease from 43.93% to 2.36%, the biomass of Crustacean zooplankton increase from 0.34 mg⋅l-1 to 1.53 mg⋅l-1 and the percentage of D. pulex increase from 19.19% to 57.62%. Our results indicated that the AAFW system not only is an efficient, flexible system for reducing nutrient levels in tributary rivers, but also has an ability to control the cyanobacteria bloom and rebuilding the aquatic ecosystem from the polluted river water.

Analysis on the Pollution Load of Non-point Source Pollution and Surface Runoff of A Typical Village in Baiyangdian Lake Basin

[Objective] The characteristic of non-point source pollution of a typical village in Baiyangdian Lake basin was studied.[Method] The discharge of domestic sewage and solid wastes of the typical village was investigated,and both pollutant and nutrient element content were monitored,as well as the water quality and quantity of rainfall runoff.[Result] The non-point source pollution of livestock manure was far more serious than the sum of domestic sewage and domestic waste in this village,and the annual emission of total organic carbon(TOC),total nitrogen(TN) and total phosphorus(TP) was 37 794.0,4 102.9 and 1 923.7 kg,respectively.The event mean concentration(EMC)of chemical oxygen demand COD,TN and TP in rainfall runoff was 44.5,78.8,1.3 mg/L,respectively,and annual pollution load was 7.6,13.4 and 0.2 kg/hm2,respectively,while the annual pollution load of COD accounted for 5.1% of standard farmland,and that of TN and TP occupied 4.5% and 0.49% of slope farmland.[Conclusion] Livestock manure was the main source of non-point source pollution in the village and the annual pollution load of non-point source pollution was obtained.

Seasonal Impact of Agricultural Non-point Source Pollution on Water Environment of Dianshan Lake Basin in Shanghai City

Taken the Dalian lake region as the study area,which represents the typical agriculture production mode and agricultural non-point source pollution （ANSP） in Dianshan lake area in Shanghai City,basis on the characteristics of regional ANSP and combing with the seasonal water quality monitoring of Dalian Lake and reaches of its main influents,the laws of seasonal impact on the water environment were investigated.The results showed that,the seasonal change of TN and COD concentration of regional water had no significant correlation with the local ANSP emissions,while the seasonal changes of TP was consistent with seasonal emissions of regional TP pollution,and it had a significant correlation with Chl.a in four seasons,indicating that regional TP pollutant was the constriction factor influenced the eutrophication degree of Dalian lake.Because more than 80% of TP emissions came from the drainage of intensive pounds in winter,summer and fall,TP pollutant control should be adopted as the control target of regional ANSP control.

Analysis on the Status of Agricultural Non-point Source Pollution in Xinan River Basin

Taking Xinan River basin as research object,the status of agricultural non-point source pollution was analyzed based on field survey,as well as the effect of fertilizer and pesticide leaching and runoff,livestock and poultry breeding and rural domestic pollution on non-point source TN and TP.At last,some technical countermeasures of controlling non-point source pollution were put forward according to the characteristics of agricultural non-point source pollution in Xinan River basin.

Reviews on Agricultural Nonpoint Source Pollution Monitoring Techniques and Methods

Farmland nutrient loss has become one of the main reason causing agri- cultural nonpoint source pollution and water nitrogen, phosphorus eutrophication. Agricultural nonpoint source pollution monitoring techniques and methods are very important in agricultural nonpoint source pollution control. This paper reviews the various monitoring techniques of agricultural non-point source pollution, including runoff pollutant monitoring, leaching pollutant monitoring and on-line monitoring. The runoff pollutant monitoring methods are mainly included artificial simulation of rain- fall runoff method, flow meter method, weir method and volumetric method. The leaching pollutant monitoring methods are mainly included leaching plate method, leaching gutter method, leakage pooling method, pumping filter pipe method and simulating soil column method. Although online monitoring of farmland nutrient loss still exists some technical bottlenecks and economic limitations, it is the future di- rection of development.

Controlling effects of forest belts on non-point source pollution of agricultural lands in Taihu Lake area, China

Taihu Lake area is one of the most developed areas in agricultural production. Application of fertilizers and pesticides in large quantities greatly aggravate environmental pollution of this area, and water pollution has worsened to an unbearable condition. Two sampling farms (respectively 1 hm2) under rape-rice rotation and wheat-rice rotation were selected as studied ecosystem and a 5-yr-old Poplar forest and 8-yr-old Metasequoia forest were chosen in the selected areas. By collecting samples of Nitrogen, Phosphorus in water, crops and underground of forest, the transfer and loss of N and P (main water pollutants) in faming ecosystem were studied, and the effects of forest belts on non-point source pollution of agricultural lands was analyzed. The results indicated that the transfer and loss of N and P vary with means of rotation, types of crops and the amount of fertilizer application. Buffering forest belts betweens farmlands and ditches can effectively stop and purify such elements as N and P in soil runoffs, thus controlling non-point source pollution of agricultural lands. When the width ratio of farmland to forest belt is 100 to 40, 50.05% losing N, 29.37% losing P can be absorbed by forest under rape-rice rotation and 30.98% N, 86.73% P can be absorbed by forest under wheat-rice rotation. When the width ratio of farmland to forest belt is 150 to 40, 33.37% losing N, 19.58% losing P can be absorbed by the forest under rape-rice rotation, and under wheat-rice rotation 20.65% lost N and 57.82% lost P can be absorbed. There is only some purification effect when the width ration of farmland to forest belt is 200 to 40. Based on model of buffering forest belts, the width ratio of farmland to forest is determined between 100 to 40 and 150 to 40, because it not only can purify water, but also occupy less farmland. It is suggested that Poplars, with the characteristics of fast-growing and high value, are suitable to be planted as shelter-forest in Taihu Lake Watershed.

Advances in Microbial Remediation on the Application of Heavy Metal Pollution in Agricultural Water Resources

Heavy metal pollution in agricultural water resources is very serious in re- cent years, resulting in large losses of the agricultural economy and endangering human life and health. Due to the advantages of low cost, high efficiency and less secondary pollution, microbial ramediation technology is widely used in the treatment of heavy metal pollution in agricultural water resources. At present, with the progress of modern biotechnology, microbial remediation of heavy metals in agricul- tural water resources has grown rapidly. The sources and status quo of heavy met- al pollution in agricultural water resources at home and aboard, and the principles of microbial remediation of heavy metals pollution in agricultural water resources were reviewed in this paper, as well as the several common microbial remediation technology of heavy metals in agricultural water resources. Additionally, the further research work of heavy metal contaminated agricultural water resources by microbial ramediation were prospected.

Analysis on Strategic Future of Application of Agricultural Ecological Source in Control on Agricultural Nonpoint Source Pollution in Xi River Area in Guangxi

Non-point source pollution has become a hot issue on aquatic ecological environment at home and abroad. The research analyzed the challenges confronted by Xi River and proposed to construct agricultural ecological source in middle and upper reaches of the Xi River from the perspectives of scientific layout, legal construction, routine monitoring, technology integration, and coordination system in order to promote sustainable development of eco-environment in Xi River.

Determination of pollution point source in parabolic system model

This paper considers an inverse problem for a partial differential equation to identify a pollution point source in a watershed. The mathematical model of the problem is a weakly coupled system of two linear parabolic equations for the concentrations u（x, t） and v（x, t） with an unknown point source F（x, t） = A（ t）δ（x- s） related to the concentration u（x, t）, where s is the point source location and A（t） is the amplitude of the pollution point source. Assuming that source F becomes inactive after time T＊, it is proved that it can be uniquely determined by the indirect measurements { v（0, t）, v（ a, t）, v（ b, t）, v（ l, t）, 0 〈 t ≤ T, T＊ 〈 T}, and, thus, the local Lipschitz stability for this inverse source problem is obtained. Based on the proof of its uniqueness, an inversion scheme is presented to determine the point source. Finally, two numerical examples are given to show the feasibility of the inversion scheme.

A distributed non-point source pollution model: calibration and validation in the Yellow River Basin

The applicability of a non-point source pollution model—SWAT(soil and water assessment tools) in a large river basin with high sediment runoff modulus(770 t/km2 in the Yellow River) was examined. The basic database, which includes DEM, soil and landuse map, weather data, and land management data, was established for the study area using GIS. A two-stage “Brute Force' optimization method was used to calibrate the parameters with the observed monthly flow and sediment data from 1992 to 1997. In the process of calibration automated digital filter technique was used to separate direct runoff and base flow. The direct runoff was firstly calibrated, and the base flow, then the total runoff was matched. The sediment yield was calibrated to match well. Keeping input parameters set during the calibration process unchanged, the model was validated with 1998—1999's observed monthly flow and sediment. The evaluation coefficients for simulated and observed flow and sediment showed that SWAT was successfully applied in the study area: relative error was within 20%, coefficient of determination and Nash-Suttcliffe simulation efficiency were all equal to or above 0.70 during calibration and validation period.

Progress in the research on aquatic environmental nonpoint source pollution in China

In this paper, the authors reviewed the development process of China's research on aquatic environmental nonpoint pollution, and the situation of nonpoint source pollution in east China was also analyzed.

Validation of an agricultural non-point source(AGNPS)pollution model for a catchment in the Jiulong River watershed,China

This study tested and evaluated the agricultural non-point source （AGNPS） model for the Wuchuan catchment, a typical agricultural area in the Jiulong River watershed, Fujian Province, China. The AGNPS model was calibrated and validated for the study area with observed data on ten storms. The data on eight storms in 2002 were used for calibration while data on two storms were used for validation of the model. Considering the lack of water quality data over a long-term series, a novel method, comparing an internal nested catchment with its surrounding catchment, was used to supplement the less long-term series data. Dual calibration and validation of the AGNPS model was obtained by this comparison. The results indicate that the correlation coefficients were 0.99 and 0.98 for runoff, 0.94 and 0.95 for the peak runoff rate of the large catchment and the small catchment, respectively, and 0.76 for the sediment of the small catchment only. Each pair of correlation coefficients is homogeneous for the same event for the two catchments. With the exception of the sediment yield and particulate phosphorus, the peak runoff rate and other nutrients were well predicted. Sensitivity analysis showed that the Soil Conservation Service curve number and rainfall quantity were the most sensitive parameters, which resulted in high output variations. Erosivity and other parameters had little influence on the hydrological and quality outputs.