The new chiral clusters [h5-C5H4C(NR)CH3]RuNiM(CO)5(m3-S) (R = NH-C6H3-2,4- (NO2)2, M = Mo, 3; M = W, 4) were synthesized and the structure of cluster 3 was determined by single-crystal X-ray analysis. Crystal data: C...The new chiral clusters [h5-C5H4C(NR)CH3]RuNiM(CO)5(m3-S) (R = NH-C6H3-2,4- (NO2)2, M = Mo, 3; M = W, 4) were synthesized and the structure of cluster 3 was determined by single-crystal X-ray analysis. Crystal data: C23H16O9N4MoNiRuS, Mr = 780.18, orthorhombic, space group Pbca with the following crystallographic parameters: a = 13.207(4), b = 16.036(5), c = 25.513(8) , Z = 8, V = 5403(3) 3, Dc = 1.918 g/cm3, m = 1.834 mm-1 and F(000) = 3072. The final R = 0.0512 and wR = 0.1132 for 2525 reflections with I > 2.00s(I).展开更多
In this paper,we discuss the mathematical relation determined by the basic physical constant between three types of quarks and the masses of leptons with charges in detail.First,by further theoretical analysis,we wond...In this paper,we discuss the mathematical relation determined by the basic physical constant between three types of quarks and the masses of leptons with charges in detail.First,by further theoretical analysis,we wonderfully see that the result got from the mass empirical formula of quark and charged lepton is identical with the data received by theoretical estimating from the gauge field theory.Second,we also gladly see that the result got from quark and lepton(with charges)mass empirical formula is completely accordant with experiment data.These mass formulas reveal the essential relation between me,mμ,mτ and mq.At the same time,the empirical formula may also derive the mass formula of neu-trinos.As to the mass of neutrinos,at present we only know the square difference of its mass,and so this is meaningful to theoretically estimating the mass.展开更多
基金This work was supported by the National Natural Science Foundation of China
文摘The new chiral clusters [h5-C5H4C(NR)CH3]RuNiM(CO)5(m3-S) (R = NH-C6H3-2,4- (NO2)2, M = Mo, 3; M = W, 4) were synthesized and the structure of cluster 3 was determined by single-crystal X-ray analysis. Crystal data: C23H16O9N4MoNiRuS, Mr = 780.18, orthorhombic, space group Pbca with the following crystallographic parameters: a = 13.207(4), b = 16.036(5), c = 25.513(8) , Z = 8, V = 5403(3) 3, Dc = 1.918 g/cm3, m = 1.834 mm-1 and F(000) = 3072. The final R = 0.0512 and wR = 0.1132 for 2525 reflections with I > 2.00s(I).
基金the State Key Basic Research Project(973Project)of China(Grant No.2006CB605102)the National Natural Science Foundation of China(Grant No.90306016)
文摘In this paper,we discuss the mathematical relation determined by the basic physical constant between three types of quarks and the masses of leptons with charges in detail.First,by further theoretical analysis,we wonderfully see that the result got from the mass empirical formula of quark and charged lepton is identical with the data received by theoretical estimating from the gauge field theory.Second,we also gladly see that the result got from quark and lepton(with charges)mass empirical formula is completely accordant with experiment data.These mass formulas reveal the essential relation between me,mμ,mτ and mq.At the same time,the empirical formula may also derive the mass formula of neu-trinos.As to the mass of neutrinos,at present we only know the square difference of its mass,and so this is meaningful to theoretically estimating the mass.
