Formation mechanism of periodic layered structure in Ni_3Si/Zn system

The formation of periodic layered structure in Ni3Si/Zn diffusion couples with Zn in vapor or liquid state was investigated by SEM-EDS, FESEM and XRD. The results show that the diffusion path in solid-liquid reaction is Ni3Si/（T＋γ）/γ/…T/γ/Ni4Zn12Si3/γ/…Ni4Zn12Si3/γ/Ni4Zn12Si3/δ…/Ni4Zn12Si3/δ/liquid-Zn, and the diffusion path in solid-vapor reaction is Ni3Si/θ/（T＋γ）/γ/…/T/γ/…T/γ/vapor-Zn. With increasing Zn diffusion flux, the diffusion reaction path moves toward the Zn-rich direction, and the distance from the Ni3Si substrate to the periodic layer pair nearest to the interface decreases. In the initial stage of both reactions,γphase nucleates and grows within T matrix phase at first, and then conjuncts together to form a band to reduce the surface energy. Based on the experimental results and diffusion kinetics analysis, the microstructure differences were compared and the formation mechanism of the periodic layered structure in Ni3Si/Zn system was discussed.

Wave localization in randomly disordered periodic layered piezoelectric structures

Considering the mechnoelectrical coupling, the localization of SH-waves in disordered periodic layered piezoelectric structures is studied. The waves propagating in directions normal and tangential to the layers are considered. The transfer matrices between two consecutive unit cells are obtained according to the continuity conditions. The expressions of localization factor and localization length in the disordered periodic structures are presented. For the disordered periodic piezoelectric structures, the numerical results of localization factor and localization length are presented and discussed. It can be seen from the results that the frequency passbands and stopbands appear for the ordered periodic structures and the wave localization phenomenon occurs in the disordered periodic ones, and the larger the coefficient of variation is, the greater the degree of wave localization is. The widths of stopbands in the ordered periodic structures are very narrow when the properties of the consecutive piezoelectric materials are similar and the intervals of stopbands become broader when a certain material parameter has large changes. For the wave propagating in the direction normal to the layers the localization length has less dependence on the frequency, but for the wave propagating in the direction tangential to the layers the localization length is strongly dependent on the frequency.

PROPAGATION BEHAVIORS OF SHEAR HORIZONTAL WAVES IN PIEZOELECTRIC-PIEZOMAGNETIC PERIODICALLY LAYERED STRUCTURES

This paper investigates shear horizontal （SH） waves propagating in a periodically layered structure that consists of piezoelectric （PE） layers perfectly bonded with piezomagnetic （PM） layers alternately. The explicit dispersion relations are derived for the two cases when the propagation directions of SH waves are normal to the interface and parallel to the interface, respectively. The asymptotic expressions for dispersion relations are also given when the wave number is extremely small. Numerical results for stop band effect and phase velocity are presented for a periodic system of alternating BaTiO3 and Terfenol-D layers. The influence of volume fraction on stop band effect and dispersion behaviors is discussed and revealed.

WAVE PROPAGATION IN PIEZOELECTRIC/PIEZOMAGNETIC LAYERED PERIODIC COMPOSITES

This paper is concerned with the dynamic behaviors of wave propagation in layered periodic composites consisting of piezoelectric and piezomagnetic phases. The dispersion relations of Lamb waves axe derived. Dispersion curves and displacement fields are calculated with different piezoelectric volume fractions. Numerical results for BaTiO3/CoFe2O4 composites show that the dispersion curves resemble the symmetric Lamb waves in a plate. Exchange between the longitudinal （i.e. thickness） mode and coupled mode takes place at the crossover point between dispersion curves of the first two branches. With the increase of BaTiO3 volume fraction, the crossover point appears at a lower wave number and wave velocity is higher. These findings are useful for magnetoelectric transducer applications.

DISCRETE SINGULAR CONVOLUTION METHOD WITH PERFECTLY MATCHED ABSORBING LAYERS FOR THE WAVE SCATTERING BY PERIODIC STRUCTURES

A new computational algorithm is introduced for solving scattering problem in periodic structure. The PML technique is used to deal with the difficulty on truncating the unbounded domain while the DSC algorithm is utilized for the spatial discretization. The present study reveals that the method is efficient for solving the problem.

Periodic Layered Structure Formed during Interfacial Reaction

A review of the periodic layered structure （PLS） formed during reactive diffusion was presented. The formation of PLS is a very interesting and complex phenomenon during the reactive diffusion process. It was firstly discovered occasionally. The formation of PLS has been reported in various solid state diffusion couples such as Zn/ Ni3 Si, Mg/SiO2, Zn/Cux Tiy and so on, and some controversial theoretical models and formation mechanism of PLS were put forward. However, there have been few reports about the PLS formed during hot dip. The development of PLS was reviewed, and the recent progress referring to the formation of PLS during the hot dip aluminizing of a no- vel Fe-Cr-B cast steel was especially introduced. However, not all of the borides could form PLS in their interracial reaction with molten Al. PLS only formed at the Cr-rich Fe2B/Al interface, while Mo-rich Fe2B fractured. A general qualitative description for the interracial reaction of Fe-Cr-B cast steel with molten Al was represented. Further inves- tigation on the constituents of the alternating phases and formation mechanism of PLS needs to be done. At last, the development trends of PLS were proposed.

Corrosion resistances of metallic materials in environments containing chloride ions:A review

Corrosion,more specifically,pitting corrosion happening extremely in marine environments,leads to lifespan of materials drastically decreasing in service,which causes enormous economic loss and even environmental disaster and casualties.In the past decade,increasing efforts have been made to study the corrosion behaviors of materials in chloride-containing aqueous environments.Herein,this work provides an overview of recent progress in understanding the degradation mechanism and improving the corrosion resistance and corrosion-wear resistance of materials from bulk metal to surface treatment involving organic coating,metal and its alloy or compound coating.The particular emphasis is given to the periodic layered structures(PLSs),whose anti-corrosion properties outperformed others to some extent,wherever in terms of bulk metal or surface treatment,regardless of aggressive environment(corrosion or corrosion-wear conditions).Numerical simulation based on kinds of models at different scales is introduced to deeply understand the process of corrosion and/or corrosion-wear in chloride-containing aqueous environment.Combined experimental result with numerical simulation,the micro-galvanic corrosion dominated degradation mechanism of PLSs is critically analyzed.Types of setups to realize corrosion-wear in laboratory are also summarized.At last,future research and development are prospected,offering to develop a basic application of PLSs designed by corrosion protection methodology in the near future.