PRECIPITATION BEHAVIOR IN A Cu-Sn-Ni-Zn-P LEAD FRAME MATERIAL

Transmission electron microscopy (TEM) observations were carried out for examining the precipitation behavior in a Cu-Sn-Ni-Zn-P lead frame material. TEM observations revealed that the precipitate is hexagonal Ni5P2 and the orientation relationship between the Cu matrix and Ni$Pi precipitate is (111)fcc//(0001)hcp, [101]fcc//[1120]hcp, where the suffix fcc denotes the Cu matrix and hep denotes the hexagonal Ni5P2 precipitate. The Ni5P2 precipitate is ovoidal in shape at the beginning of aging at lower temperature. By prolonging the aging time or increasing the aging temperature, Ni5P2 precipitate grows and shows a rod-like shape. The Ni added Cu based lead frame material has a comparative mechanical properties with that of TAMAC15 which has been developed and used in electrical industry.

Topology optimization of compliant adaptive wing leading edge with composite materials

An approach for designing the compliant adaptive wing leading edge with composite material is proposed based on the topology optimization. Firstly, an equivalent constitutive relationship of laminated glass fiber reinforced epoxy composite plates has been built based on the symmetric laminated plate theory. Then, an optimization objective function of compliant adaptive wing leading edge was used to minimize the least square error（LSE） between deformed curve and desired aerodynamics shape. After that, the topology structures of wing leading edge of different glass fiber ply-orientations were obtained by using the solid isotropic material with penalization（SIMP） model and sensitivity filtering technique. The desired aerodynamics shape of compliant adaptive wing leading edge was obtained based on the proposed approach. The topology structures of wing leading edge depend on the glass fiber ply-orientation. Finally, the corresponding morphing experiment of compliant wing leading edge with composite materials was implemented, which verified the morphing capability of topology structure and illustrated the feasibility for designing compliant wing leading edge. The present paper lays the basis of ply-orientation optimization for compliant adaptive wing leading edge in unmanned aerial vehicle（UAV） field.

Effect of rolling technologies on the properties of Pb?0.06wt%Ca?1.2wt%Sn alloy anodes during copper electrowinning

The objective of this work was to study the effect of different rolling technologies on the properties of Pb-0.06wt%Ca-1.2wt%Sn anodes during copper electrowinning and to determine the relationship between the properties of the anodes and rolling techniques during copper electrowinning. The anode process was investigated via anodic polarization curves, cyclic voltammetry curves, electrochemical impedance spectra, and corrosion tests. The microscopic morphology and phase composition of the anodic oxide layers were observed by scanning electron microscopy and X-ray diffraction, respectively. Observable variations in the electrocatalytic activity and reaction kinetics of anodes during electrowinning indicated that the electrochemical behavior of the anodes was strongly affected by the rolling technology. An increase in the rolling number tended to decrease the oxygen evolution overpotential and the corrosion rate of the anodes. These trends are contrary to that of the apparent exchange current density. Furthermore, the intensities of diffraction peaks associated with PbO, PbOx, and α-PbO2 tended to increase with increasing rolling number. In addition, the rolled anodes exhibited a more uniform microstructure. Compared with one-way rolled anodes, the eight-time cross rolled anodes exhibited better electrocatalytic activity and improved corrosion resistance.

Lead-free Nb-based dielectric film capacitors for energy storage applications

Dielectric capacitors are the ideal energy storage devices because they have excellent power density,high working voltages,and a long lifespan.With its lower size and better energy storage density,film capacitors make them simpler to incorporate into circuits than traditional dielectric capacitor devices.Lead-free Nb-based perovskite ferroelectric/antiferroelectric films have strong orbital hybridization with O 2p orbitals due to unfilled d orbitals of Nb elements,forming a series of energy storage film materials with potential application value.Here,we provide an overview of the state-of-the-art lead-free Nb-based films for energy storage applications,which include K_(0.5)Na_(0.5)NbO_(3)-based,K_(0.5)Na_(0.5)Bi_(4)NbTi_(3)O_(15)-based,AgNbO_(3)-based and NaNbO_(3)-based films.An overview of the benefits and drawbacks of each kind of Nb-based perovskite ferroelectric/antiferroelectric films is provided,along with a description of the design tactics used to achieve high energy storage performances.

Fabrication of NiO coated SiO_2 and SiO_2 coated NiO for the removal of Pb^(2+) ions

We have prepared silica,SiO2coated NiO and NiO coated SiO2by sol-gel method.The physicochemical properties of the desired materials were investigated by surface charge properties,scanning electron microscopy（SEM）,energy dispersive X-ray（EDX） spectroscopy,surface area measurements and X-ray diffraction（XRD） analyses.The point of zero charge（PZC） of the solid was determined by the salt addition method.In coated materials,two PZC values were noted representing the surface charge of their counterparts.The SEM image of SiO2coated NiO displays a uniform coating of silica on the surface of NiO whereas in case of NiO coated SiO2,a honeycomb like appearance was observed with highly porous structures.In the diffractograms of NiO,the characteristic peaks were suppressed in NiO coated silica however,no diffraction peak could be seen in SiO2coated NiO.Batch adsorption technique was applied for the removal of Pb2＋ions from aqueous solution.The sorption trend for Pb2＋ions was observed in the order of NiO coated SiO2〉 SiO2coated NiO 〉 NiO 〉 SiO2.This trend confirms that the coated materials have more sorption capacities than their parent counterparts.