How does bio-based leather become the favorite of luxury brands?

Artificial leather and synthetic leather products have more than 60 years of development history,because the cost of artificial leather is lower than real leather,the manufacturing process is relatively simple,widely used in textile,automotive and furniture decoration fields.

Covalent and Ionic Bonding between Tannin and Collagen in Leather Making and Shrinking:A MALDI-ToF Study

Collagen powder hydrolysates were reacted with a solution of commercial mimosa bark tannin extract.The mixture was prepared at ambient temperature and prepared at 80°C to determine what reactions,if any,did occur between the collagen protein through its amino acids and the polyphenolic condensed tannin.The reaction products obtained were analyzed by matrix assisted laser desorption ionization time-of-flight(MALDI ToF)mass spectrometry.Reactions between the two materials did appear to occur,with the formation of a relatively small proportion of covalent and ionic linkages at ambient temperature but a considerable proportion of covalent linkages tannin-protein amino acids and the disappearance of ionic bonds.The linkages between the two materials appeared to be by amination of the phenolic–OHs of the tannin by the amino groups of the non-skeletal side chains of arginine,and by esterification by the–COOH groups of glutamic and aspartic acid of the aliphatic alcohol-OH on the C3 site of the flavonoid units heterocycle of the tannin.The proportion of covalent linkages increases markedly and predominate with increasing temperatures.This tightening of the tannin-protein covalent network formed may be an additional contributing factor both to leather wear resistance and performance as well to leather shrinking when this is subjected to excessive temperatures.

Imperial Leather Original皂用香精的仿制

介绍了Imperial Leather Original皂用香精的特点及其香韵组成,详细叙述了如何运用不同香韵的单体原料仿配该香精的过程。讨论了香精的稳定性试验和三角试验。

Light-Dependent Properties of Finishing and Leather Defects

The uniformity of the colour in leathers for the furnishing and automotive sectors is a particularly important feature, especially for white or light-coloured articles, intended to the high-end market;on these articles any colour alteration can be very visible and unpleasant, with possible technical and economic consequences for the producers. In a previous study, we analysed the possible causes behind the formation of some peculiar pink/salmon stains on different kinds of white/beige/light-coloured leather furnishing items, where we focalized our attention on TiO2 properties and its possible interaction with some organic-based antioxidants. In recent years, due to many other similar cases of defects that occurred to tanners and to upholstery traders, we decided to enhance the investigations concerning this topic. More in detail we analysed, defective leathers, powder pigments and chemicals, in order to identify the possible role of some substances in this issue, with particular reference to some antioxidants and aluminosilicates, where several diagnostic techniques have been utilised, as ATR-IR (Attenuated Total Reflectance IR Spectroscopy), SEM-EDX (Scanning Electron Microscopy-Energy Dispersive X-ray Analysis), XRF (X-ray Fluorescence spectrometry), GC-MS (Gas Chromatography-Mass Spectrometry), and DSC/TGA (Differential scanning calorimetry/Thermogravimetry) equipment.

Toward Enhancing Wearability and Fashion of Wearable Supercapacitor with Modified Polyurethane Artificial Leather Electrolyte

Inspired by the sophisticated artificial leather garment industry and toward enhancing wearability of energy storage devices, we demonstrate a polyurethane artificial leather supercapacitor with large sheet electrodes embedded in theleather layer simultaneously working as a polyelectrolyte. This design totally reserves textiles underneath and thus addresses the well-known challenge of wearing comfortability. It provides a revolutionary configuration of wearable supercapacitors: the artificial leather on garment is also a supercapacitor.Unlike the polyvinyl alcohol-based acidic electrolytes, which are widely used, sodium chloride is used to modify the intrinsically fluorescent polyurethane leather for ionic transportation, which has no harm to human. The fluorescent leather supercapacitor is easily transferrable from any arbitrary substrates to form various patterns, enabling multifunctionalities of practical wearability, fashion, and energy storage.

Biodegradation of Leather Waste by Enzymatic Treatment

The treatment of shavings,trimmings and splits of leather waste from tanneries has a potential to generate value-added products. In this study enzymatic treatment of leather waste was performed. This method utilizes alkaline protease produced by Bacillus subtilis in our laboratory by submerged fermentation. Optimum conditions of pH,time duration,temperature and concentration of enzyme were determined for maximum degradation of leather waste. The amount of degradation was measured by the release of amino acid hydroxyproline. Amino acid composition in the hydrolysate obtained by the enzyme hydrolysis was determined. This relative simple biotreatment of leather waste may provide a practical and economical solution.

MECHANICAL BEHAVIOUR OF NATURAL COW LEATHER IN TENSION

We study experimentally the microstructure and mechanical behavior of natural cow leather. Tensile tests are performed using leather strips to observe their deformation, creep and failure. It is found that the microstructure of cow leather is a layered, complicated network of fibers of different sizes from a few to a few hundreds of nanometers in diameter. They show nonlinear stress-strain relations and viscoelastic behavior. The effect of humidity is also examined. A simple theoretical model of a multilayered beam is proposed to describe the most basic behavior in tension.

Sucrose-free hawthorn leathers formulated with fructooligosaccharides and xylooligosaccharides ameliorate high-fat diet induced inflammation, glucose and lipid metabolism in liver of mice

High sucrose content in traditional hawthorn leathers limits the potential consumption, particularly for elders and diabetics. In this study, sucrose-free hawthorn leathers were formulated with 75% fructooligosaccharides(FOS) and 25% xylooligosaccharides(XOS)(HLF75), which exhibited comparable morphology and sensory properties to the traditional ones. Then, the anti-obesity activity of HLF75 was investigated using high-fat diet(HFD) fed C57BL/6J mice. Comparing with traditional hawthorn leathers, HLF75 supplementation in HFD significantly decreased the levels of blood glucose and serum lipid. The histomorphologies of liver and subcutaneous fat tissues were ameliorated by HLF75, as well as the down-regulated m RNA expression levels of IL-1β, Nos2 and Cox-2 in the liver. M oreover, the protein levels of M y D88 and NF-κB in the liver were suppressed by HLF75 treatment with decreased F4/80-positive macrophage number. Ho wever, the expression levels of PI3K, phosphorylated-AKT(Thr308), and phosphorylated-m TOR(Ser2448) proteins related to glucose metabolism were increased in the liver. Moreover, fat synthesis-related gene expression in HLF75-fed mice was suppressed while expressions of lipolysis genes were improved. Thus, HLF75 supplementation alleviated HFD-induced obesity through the alleviation of inflammation and restoration of the disturbed glucose and lipid metabolism. Functional oligosaccharides could be effective sucrose substitutes in hawthorn leathers and enable their potential utilization as functional foods.

Application of Cationic Waterborne Polyurethane as Impregnation Material for Microfiber Synthetic Leather Base

A cationic waterborne polyurethane(CWPU) was synthesized and utilized as impregnation material for manufacturing microfiber synthetic leather base,in an attempt to decrease environmental pollution associated with organic solvents and improve simulation degree relative to genuine leather.The alkali resistance of the CWPU and four manufacture methods were investigated.Meanwhile,the dyeing properties of the microfiber synthetic leather base were studied.It was found that the CWPU displayed enough alkali resistance to endure the alkali deweighting process for microfiber synthetic leather base manufacture.In terms of bending length,bending rigidity,compression elasticity ratio and specific compression elasticity ratio of the resulting base,coagulating the impregnated CWPU with sodium hydroxide before steam treatment was the optimal method.The extent of fiber splitting and the handle of the base from this method were both similar to conventional base filled with solvent-based polyurethane(SPU).The dyeing properties of the microfiber synthetic leather base filled with CWPU were also found superior to the one filled with either anionic waterborne polyurethane(AWPU) or SPU.

Complete III Cranial Nerve Palsy in a Leather Worker: An Unusual Case Report

This case report describes features and surgical management in one patient that developed a worsening total III cranial nerve palsy in his right eye. Our 45 year-old male patient worked for about 25 years in leather tanning industry. He underwent medical history, routine blood test, eye exams that included visual acuity measurement, slit-lamp examination, dilated retinal biomicroscopy and indirect ophthalmoscopy, fundus photography, tonometry, corneal pachymetry, Krimsky test, oculomotor examination and eye deviation surgery. On examination of the fellow eye wasn’t found any disease. Stroke, aneurysm and intracerebral causes of third nerve palsy were excluded, and medical history was negative for diabetes, cardiovascular disease, trauma, neurological disease unless two previous polyneuropathies episodes and one herpetic keratitis episode. Result of any neuroimaging studies were recorded (Our patients performed in hospital CT, MRI and MRI angiography and all the testes were normal). To our knowledge third cranial nerve palsy has never been observed in literature in leather workers. In conclusion, it is important for ophthalmologists to evaluate carefully work history and lifestyle persons and plan the surgical approach focusing the different characteristics of these patients.

Clean Production for Chrome Free Leather by Using a Novel Triazine Compound

Based on a novel triazine compound,the properties of tanned leather and commercial feasibility in pilot scale have been investigated.Then this novel approach tanning was compared with conventional chrome tanning:in the condition of less-salt pickling and chrome free,the physicochemical properties including thermal stability and mechanical strength were analyzed.Meanwhile,the surface roughness and fiber dispersion were evaluated as well.The results show that the thermal stability and mechanical strength of the triazine compound tanned leather are similar to conventional chrome tanned leather,the fiber bundle is well-dispersed and much evener than that of chrome treating.The optimized tanning approach has obvious reduction in environmental impact and leads an excellent biodegradability of tanning liquor.In industrial application,the cost of materials and water treatment are reduced effectively.The production of chrome free leather can encourage the sustainable development of leather industry and protects ecological environment in some extent.

Effect of the Morphology of Leather Surface on the Hydrophobic-Hydrophilic Properties

Natural leathers (split, velour split, nubuck) ware investigated. Solution of fluorine silane in ethanol was applied as the hydrophobic agent. It is shown that the microstructure of the leather surface, provided its structural elements possess hydrophilic properties, determines the wetting regime and duration of the induction period of changeover from heterogeneous to homogeneous wetting. The heterogeneous regime of wetting is distinguished by low rates of spreading and absorbing. The homogeneous wetting is characterized by high rates of spreading and absorbing of a water drop. A necessary condition of the stable heterogeneous wetting regime and achieving hydrophobicity of leather with structurally inhomogeneous face layer is to preserve the microstructure features of their surface at hydrophobic treatment. The morphological peculiarities of split and ground leather ensure stable hydrophobic properties after application of efficient hydrophobizators.

Synthesis and Characterization of Nitrosonaphthol Dyes Based on 1-Naphthol and Their Dyeing Properties on Tanned Leather

Nitrosonaphthol dyes and other corresponding analogues were synthesised from 1-Naphthol. The dyes were applied onto chrome and vegetable tanned leather upon characterization. The results indicate that the dye bath exhaustion was better on chrome tanned leather than on vegetable tanned leather. This may be attributed to the chelating effect of chrome on leather and the higher temperature of dyeing the chrome tanned leather compared with the vegetable tanned leather. The fastness properties of the dyes of washing ranging from (3 - 5), perspiration on acid (4 - 5), alkaline (4 - 5) and light (4 - 7) were impressive on both vegetable and chrome tanned leather respectively.

Shanghai Leather Corporation

The Shanghai Leather Corporation has a production and export history of 40 years. It possesses 32 factories, 17 joint ventures, a research institute of the leather industry and a school for staff and workers. Its factories and joint ventures belong to the three trades, of leather processing, shoe making and leather product making, as well as other trades of chemicals, rubber, hardware and shoe tree production that relate to leather-product manufacture. Its major exports include leather shoes, sports shoes, various gloves, footballs, basketballs, volleyballs, leather garments, leather purses, suitcases and bags. These sell well in dozens of countries and regions, such as Europe, the United States,

The Use of Esterificate for Fattening of Leather for Shoe Uppers

The article presents a new composition for fatliquoring the leather obtained from local secondary products and a stepwise method of fatliquoring process. It was determined that with stepwise fattening, the fatliquoring composition can be added stepwise: in the processes of pickling, tanning, dyeing, retanning and fatliquoring. It was revealed that the introduction of etherification in the composition and stepwise method of fatliquoring of the leather, will allow a uniform distribution of the fatliquoring agents in the skin structure, providing an improvement in the performance properties of the finished product.

Kaifeng Leather Shoes Plant

Kaifeng Leather Shoes Plant used to be No. 1 shoe manufacturer in Henan leather shoe industry. Over the years, the plant has produced various leather shoes, including shoes for special purposes and shoes for export to many countries and regions like Europe and US. Its "Goat" product series, the hot seller on the market, was rated as quality product by the Ministry of Light Industry, and Henan Light Industry Administration.

THE USING OF LEATHER STRAP IN REHABILITATION OF PIP JOINT

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Design and Application of Leather Replacement Tool for Belt Conveyor Seal

In order to solve the problem which may be generated in the case of manual replacement of the belt conveyor sealing leather, such as the operation space is small, the work efficiency is low and the finger is easy to be scratched, Using the principle of simulated bionics, through theoretical analysis and experimental verification,a tool was designed to replace the belt conveyor sealing leather. The tool includes a limit device, feeding device,U-shaped handle three parts, suitable for the replacement of various types and sizes of belt conveyor sealing leather. Use this tool to replace the belt conveyor sealing leather, the results show that： 1） The effect of replace belt conveyor sealing leather is good, belt conveyor sealing leather flat and solid. 2） The replacement proces saveraged 1. 77 min, shorter than the original method of more than 8 min. 3） Direct contact of the fingers and the metal baffle edge was avoided, so as to reduce the chances of a finger injury.

Implementation of Hybrid Genetic Algorithm for CLSC Network Design Problem—A Case Study on Fashion Leather Goods Industry

The implementation of closed loop supply chain system is becoming essential for fashion leather products industry to ensure an economically sustainable business model and eco-friendly industrial practice as demanded by the environmental regulations, consumer awareness and the prevailing social consciousness. In this context, this research work addresses a closed loop supply chain network problem of fashion leather goods industry, with an objective of minimizing the total cost of the entire supply chain and also reducing the total waste from the end of life product returns. The research work commenced with a literature review on the reverse and closed loop supply chain network design problems of fashion and leather goods industry dealt in the past. Then, the identified CLSCND problem is solved using a mathematical model based on Mixed Integer Non-Linear Programme (MINLP) and then a suitable Hybrid Genetic Algorithm (HGA) developed for the CLSCND is implemented for obtaining optimum solution. Both the MINLP model and HGA are customized as per the CLSCND problem chosen and implemented for the industrial case of an Indian Fashion Leather Goods Industry. Finally, the solutions obtained for MINLP model in LINGO 15 and for HGA in VB.NET platform are compared and presented. The optimum solution obtained from the suitable HGA is illustrated as an optimum shipment pattern for the closed loop supply chain network design problem of the fashion leather goods industry case.