The risk of flammability is an unavoidable issue for gel polymer electrolytes(GPEs).Usually,flameretardant solvents are necessary to be used,but most of them would react with anode/cathode easily and cause serious int...The risk of flammability is an unavoidable issue for gel polymer electrolytes(GPEs).Usually,flameretardant solvents are necessary to be used,but most of them would react with anode/cathode easily and cause serious interfacial instability,which is a big challenge for design and application of nonflammable GPEs.Here,a nonflammable GPE(SGPE)is developed by in situ polymerizing trifluoroethyl methacrylate(TFMA)monomers with flame-retardant triethyl phosphate(TEP)solvents and LiTFSI–LiDFOB dual lithium salts.TEP is strongly anchored to PTFMA matrix via polarity interaction between-P=O and-CH_(2)CF_(3).It reduces free TEP molecules,which obviously mitigates interfacial reactions,and enhances flame-retardant performance of TEP surprisingly.Anchored TEP molecules are also inhibited in solvation of Li^(+),leading to anion-dominated solvation sheath,which creates inorganic-rich solid electrolyte interface/cathode electrolyte interface layers.Such coordination structure changes Li^(+)transport from sluggish vehicular to fast structural transport,raising ionic conductivity to 1.03 mS cm^(-1) and transfer number to 0.41 at 30℃.The Li|SGPE|Li cell presents highly reversible Li stripping/plating performance for over 1000 h at 0.1 mA cm^(−2),and 4.2 V LiCoO_(2)|SGPE|Li battery delivers high average specific capacity>120 mAh g^(−1) over 200 cycles.This study paves a new way to make nonflammable GPE that is compatible with Li metal anode.展开更多
Regulation the electronic density of solid-state electrolyte by donor–acceptor(D–A)system can achieve highly-selective Li^(+)transportation and conduction in solid-state Li metal batteries.This study reports a high-...Regulation the electronic density of solid-state electrolyte by donor–acceptor(D–A)system can achieve highly-selective Li^(+)transportation and conduction in solid-state Li metal batteries.This study reports a high-performance solid-state electrolyte thorough D–A-linked covalent organic frameworks(COFs)based on intramolecular charge transfer interactions.Unlike other reported COFbased solid-state electrolyte,the developed concept with D–A-linked COFs not only achieves electronic modulation to promote highly-selective Li^(+)migration and inhibit Li dendrite,but also offers a crucial opportunity to understand the role of electronic density in solid-state Li metal batteries.The introduced strong electronegativity F-based ligand in COF electrolyte results in highlyselective Li^(+)(transference number 0.83),high ionic conductivity(6.7×10^(-4)S cm^(−1)),excellent cyclic ability(1000 h)in Li metal symmetric cell and high-capacity retention in Li/LiFePO_(4)cell(90.8%for 300 cycles at 5C)than substituted C-and N-based ligands.This is ascribed to outstanding D–A interaction between donor porphyrin and acceptor F atoms,which effectively expedites electron transferring from porphyrin to F-based ligand and enhances Li^(+)kinetics.Consequently,we anticipate that this work creates insight into the strategy for accelerating Li^(+)conduction in high-performance solid-state Li metal batteries through D–A system.展开更多
Porous organic cages(POCs)with permanent porosity and excellent host–guest property hold great potentials in regulating ion transport behavior,yet their feasibility as solid-state electrolytes has never been testifie...Porous organic cages(POCs)with permanent porosity and excellent host–guest property hold great potentials in regulating ion transport behavior,yet their feasibility as solid-state electrolytes has never been testified in a practical battery.Herein,we design and fabricate a quasi-solid-state electrolyte(QSSE)based on a POC to enable the stable operation of Li-metal batteries(LMBs).Benefiting from the ordered channels and cavity-induced anion-trapping effect of POC,the resulting POC-based QSSE exhibits a high Li+transference number of 0.67 and a high ionic conductivity of 1.25×10^(−4) S cm^(−1) with a low activation energy of 0.17 eV.These allow for homogeneous Li deposition and highly reversible Li plating/stripping for over 2000 h.As a proof of concept,the LMB assembled with POC-based QSSE demonstrates extremely stable cycling performance with 85%capacity retention after 1000 cycles.Therefore,our work demonstrates the practical applicability of POC as SSEs for LMBs and could be extended to other energy-storage systems,such as Na and K batteries.展开更多
The impact of cryorolling(CR)and room temperature rolling(RTR)followed by artificial aging on the corrosion characteristics of 2195 Al−Li alloy(AA2195)was studied.Transmission electron microscope,scanning electron mic...The impact of cryorolling(CR)and room temperature rolling(RTR)followed by artificial aging on the corrosion characteristics of 2195 Al−Li alloy(AA2195)was studied.Transmission electron microscope,scanning electron microscope,optical microscope,intergranular corrosion experiment,and electrochemical experiment were used.Throughout different stages of aging treatment,the corrosion behavior of both CR and RTR samples exhibited a sequential progression of pitting corrosion,followed by intergranular corrosion,and then pitting corrosion again.The corrosion rates of both samples initially showed an increase,followed by a gradual stabilization over time.The size and density of T1 phase significantly influenced the corrosion performance of the alloy.During the peak aging and over-aging stages,the CR sample exhibited superior corrosion resistance to the RTR sample,attributed to its finer T1 phase.展开更多
Existing empirical methods for interpreting the consolidation yield stress and the overconsolidation ratio （OCR） in clays from piezocone tests are briefly reviewed. It can be seen that no universal correlation exist...Existing empirical methods for interpreting the consolidation yield stress and the overconsolidation ratio （OCR） in clays from piezocone tests are briefly reviewed. It can be seen that no universal correlation exists for all worldwide sites. However, for a given clay deposit, there does exist a most appropriate method to reflect the consolidation yield stress and the OCR based on piezocone test data. Three empirical methods are compared based on the piezocone test data collected on Lixia River lagoonal deposit soil sites in the north of Jiangsu province. The objective of this study is to evaluate the validity of the existing relationships linking the consolidation yield stress to piezocone test data and identify the appropriate method for Lixia River lagoonal deposit soil. It is shown that the correlation based on the net tip resistance has much higher accuracy for estimating the consolidation yield stress of lagoonal deposit soil than other methods.展开更多
Year-round investigations were carried out to address the population dynamics of amphipod Ampithoe val- ida and its potential regulating factors in the Yundang Lagoon （a eutrophic subtropical coastal lagoon in Xiamen...Year-round investigations were carried out to address the population dynamics of amphipod Ampithoe val- ida and its potential regulating factors in the Yundang Lagoon （a eutrophic subtropical coastal lagoon in Xiamen City, China） from October 2007 to October 2008. The results show that A. valida population was largely composed of juveniles and reached a peak abundance （12.02× 10^3 ind./m2） in March, but sharply shrunk in July. The monthly variation pattern ofA. valida seemed to follow that of Ulva lactuca which is the main food resource for A. valida, indicating a strong influence of food availability on A. valida popu- lation dynamics. Life cycle studies in laboratory indicate that A. valida adopted an r-selected life strategy, e.g., rapid growth rate （0.216-0.302 mm/d）, consecutive breeding （4-10 times）, short reproductive rhythm （9-17 d） and huge fecundity （24-192 eggs or 6-94 juveniles per brood）, which contributed to the fast pop- ulation growth ofA. valida from January to March. Although temperature may also be a significant cause, A. valida could grow quickly and show normal reproductive traits （i.e., the timing of sexual differentiation or maturity, the reproductive rhythm, the number of broods all through its lifespan and offspring produc- tion） in temperature between 15-30~ C. Therefore, the temperature variation in the lagoon water should not account for the sharp variation of A. valida population by affecting the survival, growth and reproduction of the amphipod. However, negative correlation between water temperature and U. lactuca biomass in the lagoon suggested that temperature could have indirectly affected the population dynamics ofA. ualida by affecting its food availability. The authors conclude that, in the Yundang Lagoon, the population dynamics ofA. validawas mainly controlled by the food availability rather than water temperature.展开更多
识别学科交叉研究的前沿主题,并对演化趋势进行分析,有助于揭示学科交叉融合的方向,为未来创新性、突破性研究提供参考。首先,基于引文视角构建测度论文学科交叉性的指标,识别具有学科交叉性的研究论文;其次,通过BERT-LDA模型识别研究主...识别学科交叉研究的前沿主题,并对演化趋势进行分析,有助于揭示学科交叉融合的方向,为未来创新性、突破性研究提供参考。首先,基于引文视角构建测度论文学科交叉性的指标,识别具有学科交叉性的研究论文;其次,通过BERT-LDA模型识别研究主题,利用余弦相似度计算主题之间的相似度,构建主题演化路径;最后,基于新颖度、增长性、关注度、影响力构建前沿主题识别指标体系,识别具有前沿性的学科交叉研究主题。以图书情报学(Library and Information Science,LIS)为例展开研究,研究结果显示,2004—2023年该学科领域的交叉研究主题呈现出逐渐细化和深入的特点,主要集中在信息挖掘与知识发现、互联网信息行为、医疗信息学3个方面;现阶段学科交叉研究前沿主题为医疗数据模型、舆情治理与情感分析、机器学习与深度学习;基于信息技术的研究方法和其在不同领域的应用研究具有良好的应用前景,有可能成为未来LIS领域的核心研究主题。展开更多
基金supported by the National Natural Science Foundation of China(Nos.52172214,52272221,52171182)the Postdoctoral Innovation Project of Shandong Province(No.202102003)+2 种基金The Key Research and Development Program of Shandong Province(2021ZLGX01)the Qilu Young Scholar ProgramHPC Cloud Platform of Shandong University are also thanked.
文摘The risk of flammability is an unavoidable issue for gel polymer electrolytes(GPEs).Usually,flameretardant solvents are necessary to be used,but most of them would react with anode/cathode easily and cause serious interfacial instability,which is a big challenge for design and application of nonflammable GPEs.Here,a nonflammable GPE(SGPE)is developed by in situ polymerizing trifluoroethyl methacrylate(TFMA)monomers with flame-retardant triethyl phosphate(TEP)solvents and LiTFSI–LiDFOB dual lithium salts.TEP is strongly anchored to PTFMA matrix via polarity interaction between-P=O and-CH_(2)CF_(3).It reduces free TEP molecules,which obviously mitigates interfacial reactions,and enhances flame-retardant performance of TEP surprisingly.Anchored TEP molecules are also inhibited in solvation of Li^(+),leading to anion-dominated solvation sheath,which creates inorganic-rich solid electrolyte interface/cathode electrolyte interface layers.Such coordination structure changes Li^(+)transport from sluggish vehicular to fast structural transport,raising ionic conductivity to 1.03 mS cm^(-1) and transfer number to 0.41 at 30℃.The Li|SGPE|Li cell presents highly reversible Li stripping/plating performance for over 1000 h at 0.1 mA cm^(−2),and 4.2 V LiCoO_(2)|SGPE|Li battery delivers high average specific capacity>120 mAh g^(−1) over 200 cycles.This study paves a new way to make nonflammable GPE that is compatible with Li metal anode.
基金financial support provided by National Natural Science Foundation of China(52303283,52372232,52064049)the Major Science and Technology Projects of Yunnan Province(202302AB080019-3)+2 种基金National Natural Science Foundation of Yunnan Province(202301AS070040,202401AU070201)the Analysis and Measurements Center of Yunnan University for the sample testing servicethe Electron Microscope Center of Yunnan University for the support of this work.
文摘Regulation the electronic density of solid-state electrolyte by donor–acceptor(D–A)system can achieve highly-selective Li^(+)transportation and conduction in solid-state Li metal batteries.This study reports a high-performance solid-state electrolyte thorough D–A-linked covalent organic frameworks(COFs)based on intramolecular charge transfer interactions.Unlike other reported COFbased solid-state electrolyte,the developed concept with D–A-linked COFs not only achieves electronic modulation to promote highly-selective Li^(+)migration and inhibit Li dendrite,but also offers a crucial opportunity to understand the role of electronic density in solid-state Li metal batteries.The introduced strong electronegativity F-based ligand in COF electrolyte results in highlyselective Li^(+)(transference number 0.83),high ionic conductivity(6.7×10^(-4)S cm^(−1)),excellent cyclic ability(1000 h)in Li metal symmetric cell and high-capacity retention in Li/LiFePO_(4)cell(90.8%for 300 cycles at 5C)than substituted C-and N-based ligands.This is ascribed to outstanding D–A interaction between donor porphyrin and acceptor F atoms,which effectively expedites electron transferring from porphyrin to F-based ligand and enhances Li^(+)kinetics.Consequently,we anticipate that this work creates insight into the strategy for accelerating Li^(+)conduction in high-performance solid-state Li metal batteries through D–A system.
基金supported by the National Natural Science Foundation of China(No.92372123)Guangdong Basic and Applied Basic Research Foundation(No.2022A1515012057,2022B1515020005,2023B1515130004)Guangzhou Basic and Applied Basic Research Foundation(No.202201011342).
文摘Porous organic cages(POCs)with permanent porosity and excellent host–guest property hold great potentials in regulating ion transport behavior,yet their feasibility as solid-state electrolytes has never been testified in a practical battery.Herein,we design and fabricate a quasi-solid-state electrolyte(QSSE)based on a POC to enable the stable operation of Li-metal batteries(LMBs).Benefiting from the ordered channels and cavity-induced anion-trapping effect of POC,the resulting POC-based QSSE exhibits a high Li+transference number of 0.67 and a high ionic conductivity of 1.25×10^(−4) S cm^(−1) with a low activation energy of 0.17 eV.These allow for homogeneous Li deposition and highly reversible Li plating/stripping for over 2000 h.As a proof of concept,the LMB assembled with POC-based QSSE demonstrates extremely stable cycling performance with 85%capacity retention after 1000 cycles.Therefore,our work demonstrates the practical applicability of POC as SSEs for LMBs and could be extended to other energy-storage systems,such as Na and K batteries.
基金supported by the High-tech Industry Technology Innovation Leading Plan of Hunan Province,China(No.2022GK4032)the State Key Laboratory of Precision Manufacturing for Extreme Service Performance at Central South University,China.
文摘The impact of cryorolling(CR)and room temperature rolling(RTR)followed by artificial aging on the corrosion characteristics of 2195 Al−Li alloy(AA2195)was studied.Transmission electron microscope,scanning electron microscope,optical microscope,intergranular corrosion experiment,and electrochemical experiment were used.Throughout different stages of aging treatment,the corrosion behavior of both CR and RTR samples exhibited a sequential progression of pitting corrosion,followed by intergranular corrosion,and then pitting corrosion again.The corrosion rates of both samples initially showed an increase,followed by a gradual stabilization over time.The size and density of T1 phase significantly influenced the corrosion performance of the alloy.During the peak aging and over-aging stages,the CR sample exhibited superior corrosion resistance to the RTR sample,attributed to its finer T1 phase.
基金Jiangsu Transportation Research Program Fund (No03Y007)
文摘Existing empirical methods for interpreting the consolidation yield stress and the overconsolidation ratio （OCR） in clays from piezocone tests are briefly reviewed. It can be seen that no universal correlation exists for all worldwide sites. However, for a given clay deposit, there does exist a most appropriate method to reflect the consolidation yield stress and the OCR based on piezocone test data. Three empirical methods are compared based on the piezocone test data collected on Lixia River lagoonal deposit soil sites in the north of Jiangsu province. The objective of this study is to evaluate the validity of the existing relationships linking the consolidation yield stress to piezocone test data and identify the appropriate method for Lixia River lagoonal deposit soil. It is shown that the correlation based on the net tip resistance has much higher accuracy for estimating the consolidation yield stress of lagoonal deposit soil than other methods.
基金Public Science and Technology Research Funds Projects of Ocean under contract No.201205009-3Key Sci-Tech Program of Xiamen City under contract No.3502Z20102004
文摘Year-round investigations were carried out to address the population dynamics of amphipod Ampithoe val- ida and its potential regulating factors in the Yundang Lagoon （a eutrophic subtropical coastal lagoon in Xiamen City, China） from October 2007 to October 2008. The results show that A. valida population was largely composed of juveniles and reached a peak abundance （12.02× 10^3 ind./m2） in March, but sharply shrunk in July. The monthly variation pattern ofA. valida seemed to follow that of Ulva lactuca which is the main food resource for A. valida, indicating a strong influence of food availability on A. valida popu- lation dynamics. Life cycle studies in laboratory indicate that A. valida adopted an r-selected life strategy, e.g., rapid growth rate （0.216-0.302 mm/d）, consecutive breeding （4-10 times）, short reproductive rhythm （9-17 d） and huge fecundity （24-192 eggs or 6-94 juveniles per brood）, which contributed to the fast pop- ulation growth ofA. valida from January to March. Although temperature may also be a significant cause, A. valida could grow quickly and show normal reproductive traits （i.e., the timing of sexual differentiation or maturity, the reproductive rhythm, the number of broods all through its lifespan and offspring produc- tion） in temperature between 15-30~ C. Therefore, the temperature variation in the lagoon water should not account for the sharp variation of A. valida population by affecting the survival, growth and reproduction of the amphipod. However, negative correlation between water temperature and U. lactuca biomass in the lagoon suggested that temperature could have indirectly affected the population dynamics ofA. ualida by affecting its food availability. The authors conclude that, in the Yundang Lagoon, the population dynamics ofA. validawas mainly controlled by the food availability rather than water temperature.
文摘识别学科交叉研究的前沿主题,并对演化趋势进行分析,有助于揭示学科交叉融合的方向,为未来创新性、突破性研究提供参考。首先,基于引文视角构建测度论文学科交叉性的指标,识别具有学科交叉性的研究论文;其次,通过BERT-LDA模型识别研究主题,利用余弦相似度计算主题之间的相似度,构建主题演化路径;最后,基于新颖度、增长性、关注度、影响力构建前沿主题识别指标体系,识别具有前沿性的学科交叉研究主题。以图书情报学(Library and Information Science,LIS)为例展开研究,研究结果显示,2004—2023年该学科领域的交叉研究主题呈现出逐渐细化和深入的特点,主要集中在信息挖掘与知识发现、互联网信息行为、医疗信息学3个方面;现阶段学科交叉研究前沿主题为医疗数据模型、舆情治理与情感分析、机器学习与深度学习;基于信息技术的研究方法和其在不同领域的应用研究具有良好的应用前景,有可能成为未来LIS领域的核心研究主题。
