Na_(3)V_(2)(PO_(4))_(3)(NVP)cathode material of the sodium ion battery(1 C=117 mAh g-1)has a NASICON-type structure,which not only facilitates the rapid migration of sodium ions,but also has a small volume deformation...Na_(3)V_(2)(PO_(4))_(3)(NVP)cathode material of the sodium ion battery(1 C=117 mAh g-1)has a NASICON-type structure,which not only facilitates the rapid migration of sodium ions,but also has a small volume deformation during sodium ion de-intercalation and the main frame mechanism remains unchanged,and thus is seen as an energy storage material for a wide range of applications,but has a limited electronic conductivity due to its structure.In this paper,NVP cathode materials with finer primary particles are successfully prepared using a simple hydrothermal treatment-assisted sol-gel method.The increased pore size of the NVP materials prepared under the hydrothermal process allows for more active sites and more effective resistance to the volume deformation of sodium ions during insertion/extraction processes,effectively facilitating the diffusion of ions and electrons.The Na_(3)V_(2)(PO_(4))_(3) material obtained by the optimized process exhibited good crystallinity in XRD characterization,as well as superior electrochemical properties in a series of electrochemical tests.A specific capacitance of 106.3 mAh g^(-1) at 0.2 C is demonstrated,compared to 96.5 mAh g^(-1) for Na_(3)V_(2)(PO_(4))_(3) without hydrothermal treatment,and cycling performance is also improved with 93%capacity retention.The calculated sodium ion diffusion coefficient(DNa=5.68×10^(-14))obtained after EIS curve fitting of the improved sample illustrates that the pore structure is beneficial to the performance of the Na_(3)V_(2)(PO_(4))_(3)cathode material.展开更多
以酚醛树脂为碳源,分别采用了固相法和溶胶凝胶法合成了锂离子电池正极材料Li3V2(PO4)3/C。结果表明,高分子材料酚醛树脂是一种优良的碳源材料,其热解后得到的导电网络能够有效的提高Li3V2(PO4)3的电化学性能;两种试样的充放电曲线和交...以酚醛树脂为碳源,分别采用了固相法和溶胶凝胶法合成了锂离子电池正极材料Li3V2(PO4)3/C。结果表明,高分子材料酚醛树脂是一种优良的碳源材料,其热解后得到的导电网络能够有效的提高Li3V2(PO4)3的电化学性能;两种试样的充放电曲线和交流阻抗图谱体现出了试样良好的可逆性,其极化程度很低,电荷转移电阻小;而相对于固相法来讲,溶胶凝胶法和表面活性剂CTAB(十六烷基三甲基溴化铵)的共同作用能够有效的将颗粒粒径控制在纳米级别。用这种方法合成的试样在15 C下充放电比容量也能高于90 m Ah/g,5 C倍率下循环50次比容量无衰减,证明了以酚醛树脂为碳源并采用溶胶凝胶法合成的试样具有很好的倍率性能与循环性能。展开更多
基金Project(2007BAQ01055)supported by the National Key Technology R&D Program of ChinaProject(2011SCU11081)supported by the Sichuan University Funds for Young Scientists,ChinaProject(20120181120103)supported by Ph.D.Programs Foundation of the Ministry of Education of China
基金supported by the China Postdoctoral Science Foundation (2014M562322)Research Fund for the Doctoral Program of Higher Education, Ministry of Education of China (20120181120103)~~
文摘Na_(3)V_(2)(PO_(4))_(3)(NVP)cathode material of the sodium ion battery(1 C=117 mAh g-1)has a NASICON-type structure,which not only facilitates the rapid migration of sodium ions,but also has a small volume deformation during sodium ion de-intercalation and the main frame mechanism remains unchanged,and thus is seen as an energy storage material for a wide range of applications,but has a limited electronic conductivity due to its structure.In this paper,NVP cathode materials with finer primary particles are successfully prepared using a simple hydrothermal treatment-assisted sol-gel method.The increased pore size of the NVP materials prepared under the hydrothermal process allows for more active sites and more effective resistance to the volume deformation of sodium ions during insertion/extraction processes,effectively facilitating the diffusion of ions and electrons.The Na_(3)V_(2)(PO_(4))_(3) material obtained by the optimized process exhibited good crystallinity in XRD characterization,as well as superior electrochemical properties in a series of electrochemical tests.A specific capacitance of 106.3 mAh g^(-1) at 0.2 C is demonstrated,compared to 96.5 mAh g^(-1) for Na_(3)V_(2)(PO_(4))_(3) without hydrothermal treatment,and cycling performance is also improved with 93%capacity retention.The calculated sodium ion diffusion coefficient(DNa=5.68×10^(-14))obtained after EIS curve fitting of the improved sample illustrates that the pore structure is beneficial to the performance of the Na_(3)V_(2)(PO_(4))_(3)cathode material.
文摘以酚醛树脂为碳源,分别采用了固相法和溶胶凝胶法合成了锂离子电池正极材料Li3V2(PO4)3/C。结果表明,高分子材料酚醛树脂是一种优良的碳源材料,其热解后得到的导电网络能够有效的提高Li3V2(PO4)3的电化学性能;两种试样的充放电曲线和交流阻抗图谱体现出了试样良好的可逆性,其极化程度很低,电荷转移电阻小;而相对于固相法来讲,溶胶凝胶法和表面活性剂CTAB(十六烷基三甲基溴化铵)的共同作用能够有效的将颗粒粒径控制在纳米级别。用这种方法合成的试样在15 C下充放电比容量也能高于90 m Ah/g,5 C倍率下循环50次比容量无衰减,证明了以酚醛树脂为碳源并采用溶胶凝胶法合成的试样具有很好的倍率性能与循环性能。
