The falling film of an ionic liquid([EMIM][DMP]+H_(2)O)and its effect on a refrigeration system are numerically simulated in the framework of a Volume of Fluid(VOF)method(as available in the ANSYS Fluent computational...The falling film of an ionic liquid([EMIM][DMP]+H_(2)O)and its effect on a refrigeration system are numerically simulated in the framework of a Volume of Fluid(VOF)method(as available in the ANSYS Fluent computational platform).The properties of the liquid film and the wall shear stress(WSS)are compared with those obtained for a potassium bromide solution.Different working conditions are considered.It is noted that the ionic liquid demonstrates a better absorption capability,with a coefficient of performance(COP)of 0.55.It is proved that the[EMIM][DMP]+H_(2)O ionic liquid working substance is superior to the potassium bromide solution in terms of heat and mass transfer.展开更多
A comparative study of Na2MoO4·2H2O and Na2HPO4·12H2O as inhibitors for magnetic refrigeration material La-Fe-Co-Si compound corrosion in distilled water at room temperature was carried out.Moreover,the inhi...A comparative study of Na2MoO4·2H2O and Na2HPO4·12H2O as inhibitors for magnetic refrigeration material La-Fe-Co-Si compound corrosion in distilled water at room temperature was carried out.Moreover,the inhibiting behavior of the mixture of Na2MoO4·2H2O and Na2HPO4·12H2O was investigated.Potentiodynamic polarization curves and electrochemical impedance spectroscopy （EIS） measurements were applied to study the corrosion behavior of the compound in the absence or presence of different concentrations of these inhibitors under the same experimental conditions.The study revealed that the mixture of 3.0×10–3 kg/L Na2MoO4·2H2O and 5.0×10–3 kg/L Na2HPO4·12H2O was the best inhibitor reaching the value of inhibition efficiency （ε%） up to 93.9%.Polarization curves showed that the studied compounds acted as anodic inhibitors.The potential of zero charge （PZC） of La-Fe-Co-Si compound was determined in distilled water in the absence of the studied inhibitors.Corrosion inhibition mechanisms for inhibitors were proposed in this work.展开更多
文摘The falling film of an ionic liquid([EMIM][DMP]+H_(2)O)and its effect on a refrigeration system are numerically simulated in the framework of a Volume of Fluid(VOF)method(as available in the ANSYS Fluent computational platform).The properties of the liquid film and the wall shear stress(WSS)are compared with those obtained for a potassium bromide solution.Different working conditions are considered.It is noted that the ionic liquid demonstrates a better absorption capability,with a coefficient of performance(COP)of 0.55.It is proved that the[EMIM][DMP]+H_(2)O ionic liquid working substance is superior to the potassium bromide solution in terms of heat and mass transfer.
基金Project supported by the National High Technology Research and Development Program of China,the National Basic Research Program of China, and the National Natural Science Foundation of China (50971022, 50731007)
文摘A comparative study of Na2MoO4·2H2O and Na2HPO4·12H2O as inhibitors for magnetic refrigeration material La-Fe-Co-Si compound corrosion in distilled water at room temperature was carried out.Moreover,the inhibiting behavior of the mixture of Na2MoO4·2H2O and Na2HPO4·12H2O was investigated.Potentiodynamic polarization curves and electrochemical impedance spectroscopy （EIS） measurements were applied to study the corrosion behavior of the compound in the absence or presence of different concentrations of these inhibitors under the same experimental conditions.The study revealed that the mixture of 3.0×10–3 kg/L Na2MoO4·2H2O and 5.0×10–3 kg/L Na2HPO4·12H2O was the best inhibitor reaching the value of inhibition efficiency （ε%） up to 93.9%.Polarization curves showed that the studied compounds acted as anodic inhibitors.The potential of zero charge （PZC） of La-Fe-Co-Si compound was determined in distilled water in the absence of the studied inhibitors.Corrosion inhibition mechanisms for inhibitors were proposed in this work.
