Lithium-ion batteries are used in a wide range of applications.However,their cycle life suffers from the problem of capacity fade,which includes calendar and cycle aging.The effects of storage time,temperature and par...Lithium-ion batteries are used in a wide range of applications.However,their cycle life suffers from the problem of capacity fade,which includes calendar and cycle aging.The effects of storage time,temperature and partial charge-discharge cycling on the capacity fade of Li-ion batteries are investigated in this study.The calendar aging and cycle aging are presented based on the storage and cycling experiment on LiCoO_(2)/graphite cells under different storage temperature and different ranges of state of charge(SOC).Based on the measurement data,a one-component and a double-component aging model are presented to respectively describe the capacity fade caused by calendar and cycle aging.The calendar aging of LiCoO_(2)/graphite batteries is mainly affected by temperature and SOC during the storage.Mean SOC and change in SOC(ΔSOC)are the main factors affecting battery degradation during cycling operation.展开更多
The tradeoff between energy and power densities is a critical challenge for commercial tape-cast lithium-ion batteries(LIBs).In this study,three-dimensional(3D)LIBs with interdigitated electrode structures are designe...The tradeoff between energy and power densities is a critical challenge for commercial tape-cast lithium-ion batteries(LIBs).In this study,three-dimensional(3D)LIBs with interdigitated electrode structures are designed and fabricated via 3D printing to overcome this tradeoff.The evolution of battery design from tape-cast thin planar electrodes to interdigitated 3D electrodes is discussed.Numerical simulations based on COMSOL Multiphysics are performed to elucidate the advantages of interdigitated battery design.Interdigitated LIBs composed of comb-like 3D high-voltage LiCoO2(HV-LCO)cathodes and comb-like 3D natural graphite anodes are fabricated via 3D printing.Additionally,printable HV-LCO inks with appropriate rheological properties are developed for 3D printing.HV-LCO half-cells with Li foil as the counter electrode and an interdigitated full battery with NG anodes as the counter electrode are assembled to test the electrochemical performance.The results show that interdigitated full batteries fabricated via 3D printing offer high specific capacities and stable cycling performance.Full batteries with an electrode thickness of 882µm can achieve a high areal capacity of 5.88 mAh·cm−2@0.1 C,an areal energy density of 41.4 J·cm−2,and an areal power density of 41.0 mW·cm−2@1.0 C,which are approximately 10 times the values afforded by conventional tape-cast thin batteries.展开更多
基金supported by Shandong University Seed Fund Program for International Research Cooperation。
文摘Lithium-ion batteries are used in a wide range of applications.However,their cycle life suffers from the problem of capacity fade,which includes calendar and cycle aging.The effects of storage time,temperature and partial charge-discharge cycling on the capacity fade of Li-ion batteries are investigated in this study.The calendar aging and cycle aging are presented based on the storage and cycling experiment on LiCoO_(2)/graphite cells under different storage temperature and different ranges of state of charge(SOC).Based on the measurement data,a one-component and a double-component aging model are presented to respectively describe the capacity fade caused by calendar and cycle aging.The calendar aging of LiCoO_(2)/graphite batteries is mainly affected by temperature and SOC during the storage.Mean SOC and change in SOC(ΔSOC)are the main factors affecting battery degradation during cycling operation.
基金Shenzhen Municipal Science&Technology Projects of China(Grant Nos.JCYJ20200109105618137,GJHZ20200731095805016).
文摘The tradeoff between energy and power densities is a critical challenge for commercial tape-cast lithium-ion batteries(LIBs).In this study,three-dimensional(3D)LIBs with interdigitated electrode structures are designed and fabricated via 3D printing to overcome this tradeoff.The evolution of battery design from tape-cast thin planar electrodes to interdigitated 3D electrodes is discussed.Numerical simulations based on COMSOL Multiphysics are performed to elucidate the advantages of interdigitated battery design.Interdigitated LIBs composed of comb-like 3D high-voltage LiCoO2(HV-LCO)cathodes and comb-like 3D natural graphite anodes are fabricated via 3D printing.Additionally,printable HV-LCO inks with appropriate rheological properties are developed for 3D printing.HV-LCO half-cells with Li foil as the counter electrode and an interdigitated full battery with NG anodes as the counter electrode are assembled to test the electrochemical performance.The results show that interdigitated full batteries fabricated via 3D printing offer high specific capacities and stable cycling performance.Full batteries with an electrode thickness of 882µm can achieve a high areal capacity of 5.88 mAh·cm−2@0.1 C,an areal energy density of 41.4 J·cm−2,and an areal power density of 41.0 mW·cm−2@1.0 C,which are approximately 10 times the values afforded by conventional tape-cast thin batteries.
