Europium doped LiNiPO4 and undoped LiNiPO4 were prepared by Pechini method. Compound formation temperature was confirmed from thermogravimetry and differential thermal analysis （TG/DTA）. Powder X-ray diffraction （...Europium doped LiNiPO4 and undoped LiNiPO4 were prepared by Pechini method. Compound formation temperature was confirmed from thermogravimetry and differential thermal analysis （TG/DTA）. Powder X-ray diffraction （XRD） pattern confirmed the formation of pure LiNiPO4 compound with an orthorhombic structure. The conductivity and modulus analyses of the samples were carried out at different temperatures and frequencies using the complex impedance spectroscopy technique. The conductivity parameters such as ion hopping frequency and the charge cartier concentration term were calculated using Almond and West formalisms. An increase of one order of magnitude in the ionic conductivity has been observed for 1.0% Eu-doped LiNiPO4. （mole fraction）. The complex modulus studies suggest the presence of non-Debye type of relaxation in the materials.展开更多
1 Results Stoichimetric quantities of lithium acetate,nickel acetate and ammonium dihydrogen phosphate were mixed with ethanol and stirred with heating until complete dissolution.A solution of 1 g chitosan in 1% aceti...1 Results Stoichimetric quantities of lithium acetate,nickel acetate and ammonium dihydrogen phosphate were mixed with ethanol and stirred with heating until complete dissolution.A solution of 1 g chitosan in 1% acetic acid was then poured into the heated and stirred solution until all solvents have evaporated.The precursor was then sintered at 500,600,700,800,900 and 1 000 ℃ for 3 hours.X-ray diffraction results showed that single phase LiNiPO4 was obtained at sintering temperatures above 600 ℃.TEM res...展开更多
文摘Europium doped LiNiPO4 and undoped LiNiPO4 were prepared by Pechini method. Compound formation temperature was confirmed from thermogravimetry and differential thermal analysis （TG/DTA）. Powder X-ray diffraction （XRD） pattern confirmed the formation of pure LiNiPO4 compound with an orthorhombic structure. The conductivity and modulus analyses of the samples were carried out at different temperatures and frequencies using the complex impedance spectroscopy technique. The conductivity parameters such as ion hopping frequency and the charge cartier concentration term were calculated using Almond and West formalisms. An increase of one order of magnitude in the ionic conductivity has been observed for 1.0% Eu-doped LiNiPO4. （mole fraction）. The complex modulus studies suggest the presence of non-Debye type of relaxation in the materials.
文摘1 Results Stoichimetric quantities of lithium acetate,nickel acetate and ammonium dihydrogen phosphate were mixed with ethanol and stirred with heating until complete dissolution.A solution of 1 g chitosan in 1% acetic acid was then poured into the heated and stirred solution until all solvents have evaporated.The precursor was then sintered at 500,600,700,800,900 and 1 000 ℃ for 3 hours.X-ray diffraction results showed that single phase LiNiPO4 was obtained at sintering temperatures above 600 ℃.TEM res...
