Metal hydroxides (MAH) consisting of magnesium hydroxide and aluminum hydroxide with a mass ratio of 1-2 were surface-modified by γ-diethoxyphosphorous ester propyldiethoxymethylsilane, boric acid and diphenylsilaned...Metal hydroxides (MAH) consisting of magnesium hydroxide and aluminum hydroxide with a mass ratio of 1-2 were surface-modified by γ-diethoxyphosphorous ester propyldiethoxymethylsilane, boric acid and diphenylsilanediol in xylene under dibutyl tin dilaurate catalyst at 140 ℃. Phosphorus, silicon and boron elements covalently bonded to metal hydroxide particles were detected by X-ray photoelectron spectroscopy. The degradation behavior of the surface-modified MAH was characterized by thermogravimetric analysis. The results show that linear low density polyethylene (LLDPE) composite, filled with 50% (mass fraction) of MAH modified by 5.0% (mass fraction) of modifiers, passes the V-0 rating of UL-94 test and shows the limited oxygen index of 34%, and its heat release rate and average effective heat combustion in a cone calorimeter measurement decrease obviously; The mechanical properties of MAH can be improved by surface-modification. The uniform dispersion of particles and strong interfacial bonding between particles and matrix are obtained.展开更多
为了降低直流电缆绝缘材料的电导率,并提升电导率及直流击穿场强的温度稳定性,同时改善绝缘的高温力学性能,文中引入低交联度线性低密度聚乙烯(linear low density polyethylene,LLDPE)作为直流电缆绝缘材料。文中对比添加不同含量过氧...为了降低直流电缆绝缘材料的电导率,并提升电导率及直流击穿场强的温度稳定性,同时改善绝缘的高温力学性能,文中引入低交联度线性低密度聚乙烯(linear low density polyethylene,LLDPE)作为直流电缆绝缘材料。文中对比添加不同含量过氧化二异丙苯(dicumyl peroxide,DCP)的LLDPE和低密度聚乙烯(low density polyethylene,LDPE),通过热延伸、动态热机械测试及拉伸试验分析其力学性能,并测试直流电导率和直流击穿场强。结果表明,DCP质量分数为0.7%~2.0%范围内,交联LLDPE具有更低的热延伸率,DCP质量分数为0.7%即可满足高压直流电缆对交联聚乙烯(crosslinked polyethylene,XLPE)热延伸率的要求。由此结果,结合减少副产物的目的,选出DCP质量分数为0.7%的LLDPE作为传统XLPE(DCP质量分数为2.0%的LDPE)的对比及替代绝缘材料。动态热机械测试(dynamic mechanical analysis,DMA)及拉伸试验验证了DCP质量分数为0.7%的LLDPE比传统XLPE拥有更高的杨氏模量及断裂伸长率;电导率及直流击穿实验表明前者在30~90℃拥有更低的电导率及更优的电导率和直流击穿场强的温度稳定性。由于实际电缆中的交联副产物难以脱尽且分布不均,严重影响电缆长期安全运行,可考虑将DCP质量分数为0.7%的低交联度LLDPE用作直流电缆绝缘材料,从而在满足高温机械性能的同时降低直流电导率并增强电导率的温度稳定性。展开更多
The open-cell structure foams of linear low-density polyethylene（LLDPE） and linear low-density polyethylene（LLDPE）/multi-wall carbon nanotubes（MWCNTs） composites are prepared by using supercritical carbon dioxid...The open-cell structure foams of linear low-density polyethylene（LLDPE） and linear low-density polyethylene（LLDPE）/multi-wall carbon nanotubes（MWCNTs） composites are prepared by using supercritical carbon dioxide（sc-CO2）as a foaming agent. The effects of processing parameters（foaming temperature, saturation pressure, and depressurization rate） and the addition of MWCNTs on the evolution of cell opening are studied systematically. For LLDPE foaming, the foaming temperature and saturation pressure are two key factors for preparing open-cell foams. An increase in temperature and pressure promotes both the cell wall thinning and cell rupture, because a high temperature results in a decrease in the viscosity of the polymer, and a high pressure leads to a larger amount of cell nucleation. Moreover, for the given temperature and pressure, the high pressurization rate results in a high pressure gradient, favoring cell rupture. For LLDPE/MWCNTs foaming, the addition of MWCNTs not only promotes the cell heterogeneous nucleation, but also prevents the cell collapse during cell opening, which is critical to achieve the open-cell structures with small cell size and high cell density.展开更多
This paper reports a new kind catalytic system to produce linear low density polyethylene(LLDPE) from ethylene alone in a single reactor by combining the ability of Ti(OBu n ) 4/AlEt 3 to produce 1 butene with the abi...This paper reports a new kind catalytic system to produce linear low density polyethylene(LLDPE) from ethylene alone in a single reactor by combining the ability of Ti(OBu n ) 4/AlEt 3 to produce 1 butene with the ability of [Me 2SiN t BuInd]ZrCl 2/MAO to copolymerize ethylene with 1 butene. It was found that the dual functional catalytic system has high activity and get the good polymer with density ranging from 0.91-0.95 g/cm 3 in ethylene polymerization.展开更多
The oxygen-contained groups such as C—O,C—OH,CO,C(O)O and C(O)OH are introduced onto the molecular chains of linear low density polyethylene(LLDPE) through ultraviolet irradiation at environmental temperature of 70 ...The oxygen-contained groups such as C—O,C—OH,CO,C(O)O and C(O)OH are introduced onto the molecular chains of linear low density polyethylene(LLDPE) through ultraviolet irradiation at environmental temperature of 70 ℃ in air without adding any additives.The concentration of these groups increases with the iucrease of irradiation time.The gel appears in irradiated LLDPE,the gel content increases with the iucrease of irradiation time.The melt flow index decreases and reach minimum when the irradiation time is 24 h,and then increase.The interfacial adhesion between irradiated LLDPE and polyamide 66(PA66) and the mechanical properties of the PA66/irradiated LLDPE(80/20) blends are improved owing to the oxygen-contained polar groups introduced.Compared with those of PA66/LLDPE(80/20) blends,the tensile strength,Young′s modulus,bending strength and notch impact strength of PA66/irradiated LLDPE(80/20) blends for 24 h are increased from 48.3,908,64.8 MPa and 31 J/m\ to 62.0,984,83.1 MPa and 85 J/m,respectively.展开更多
A case of household water tanks, 1000 L capacity, made of RCC, LLDPE and mild steel (stainless steel) was evaluated for life cycle analysis. The scope of the research comprised of the raw materials, energy inputs and ...A case of household water tanks, 1000 L capacity, made of RCC, LLDPE and mild steel (stainless steel) was evaluated for life cycle analysis. The scope of the research comprised of the raw materials, energy inputs and corresponding emissions during all phases of product making such as extraction of raw material, it’s processing, followed by manufacturing and transport, as well as use and reuse of the product. Simapro 8 (System for Integrated environMental Assessment of PROducts), a modelling software, from Dutch PRé Consultants was used to conduct the life cycle analysis. Simapro 8 enables systematic and transparent modelling and analysis of complex life cycles based on the recommendations of the ISO 14040 series of standards. In the present study the most common method which is acceptable worldwide “Recipe Endpoint method” (ReCiPe) was employed. ReCiPe computes the impact categories and classifies them into two classes based on relevant arrays of characterization factors. Simapro addresses impact categories viz. ozone depletion, human toxicity, ionizing radiation, photochemical oxidant formation, particulate matter formation, terrestrial acidification, climate change, terrestrial ecotoxicity, agricultural land occupation, urban land occupation, natural land transformation, marine ecotoxicity, marine eutrophication, fresh water eutrophication, fresh water ecotoxicity, fossil fuel depletion, minerals depletion, fresh water depletion at the midpoint level. While at the Endpoint level, the impact categories are multiplied by corresponding damage factors and integrated to be represented as three Endpoint level categories, viz. human health, ecosystems and resource depletion. The three endpoint categories are normalized, weighted, and aggregated into a single score. LCA studies indicate that household water tanks of LLDPE have least environmental implications considering impacts on human health, ecosystems and resource depletion as compared to its counterparts viz. Household water tanks made up of mild steel and RCC. The sequence of the material with decreasing impacts is concrete tanks > mild steel tank > LLDPE tanks. The overall assessment is centred on the elements such as material inputs, energy inputs and environmental emissions.展开更多
基金Project(20574020) supported by the National Natural Science Foundation of ChinaProject(20061001) supported by the Opening Project of the Key Laboratory of Polymer Processing Engineering, Ministry of Education, ChinaProject (20060106-2) supported by Guangdong Key Projects
文摘Metal hydroxides (MAH) consisting of magnesium hydroxide and aluminum hydroxide with a mass ratio of 1-2 were surface-modified by γ-diethoxyphosphorous ester propyldiethoxymethylsilane, boric acid and diphenylsilanediol in xylene under dibutyl tin dilaurate catalyst at 140 ℃. Phosphorus, silicon and boron elements covalently bonded to metal hydroxide particles were detected by X-ray photoelectron spectroscopy. The degradation behavior of the surface-modified MAH was characterized by thermogravimetric analysis. The results show that linear low density polyethylene (LLDPE) composite, filled with 50% (mass fraction) of MAH modified by 5.0% (mass fraction) of modifiers, passes the V-0 rating of UL-94 test and shows the limited oxygen index of 34%, and its heat release rate and average effective heat combustion in a cone calorimeter measurement decrease obviously; The mechanical properties of MAH can be improved by surface-modification. The uniform dispersion of particles and strong interfacial bonding between particles and matrix are obtained.
文摘为了降低直流电缆绝缘材料的电导率,并提升电导率及直流击穿场强的温度稳定性,同时改善绝缘的高温力学性能,文中引入低交联度线性低密度聚乙烯(linear low density polyethylene,LLDPE)作为直流电缆绝缘材料。文中对比添加不同含量过氧化二异丙苯(dicumyl peroxide,DCP)的LLDPE和低密度聚乙烯(low density polyethylene,LDPE),通过热延伸、动态热机械测试及拉伸试验分析其力学性能,并测试直流电导率和直流击穿场强。结果表明,DCP质量分数为0.7%~2.0%范围内,交联LLDPE具有更低的热延伸率,DCP质量分数为0.7%即可满足高压直流电缆对交联聚乙烯(crosslinked polyethylene,XLPE)热延伸率的要求。由此结果,结合减少副产物的目的,选出DCP质量分数为0.7%的LLDPE作为传统XLPE(DCP质量分数为2.0%的LDPE)的对比及替代绝缘材料。动态热机械测试(dynamic mechanical analysis,DMA)及拉伸试验验证了DCP质量分数为0.7%的LLDPE比传统XLPE拥有更高的杨氏模量及断裂伸长率;电导率及直流击穿实验表明前者在30~90℃拥有更低的电导率及更优的电导率和直流击穿场强的温度稳定性。由于实际电缆中的交联副产物难以脱尽且分布不均,严重影响电缆长期安全运行,可考虑将DCP质量分数为0.7%的低交联度LLDPE用作直流电缆绝缘材料,从而在满足高温机械性能的同时降低直流电导率并增强电导率的温度稳定性。
基金financially supported by the National Natural Science Foundation of China(Nos.21306090 and 51403110)Scientific Research Fund of Zhejiang Provincial Education Department(Nos.Y201430774 and Y201327472)K.C.Wong Magna Fund in Ningbo University
文摘The open-cell structure foams of linear low-density polyethylene（LLDPE） and linear low-density polyethylene（LLDPE）/multi-wall carbon nanotubes（MWCNTs） composites are prepared by using supercritical carbon dioxide（sc-CO2）as a foaming agent. The effects of processing parameters（foaming temperature, saturation pressure, and depressurization rate） and the addition of MWCNTs on the evolution of cell opening are studied systematically. For LLDPE foaming, the foaming temperature and saturation pressure are two key factors for preparing open-cell foams. An increase in temperature and pressure promotes both the cell wall thinning and cell rupture, because a high temperature results in a decrease in the viscosity of the polymer, and a high pressure leads to a larger amount of cell nucleation. Moreover, for the given temperature and pressure, the high pressurization rate results in a high pressure gradient, favoring cell rupture. For LLDPE/MWCNTs foaming, the addition of MWCNTs not only promotes the cell heterogeneous nucleation, but also prevents the cell collapse during cell opening, which is critical to achieve the open-cell structures with small cell size and high cell density.
文摘This paper reports a new kind catalytic system to produce linear low density polyethylene(LLDPE) from ethylene alone in a single reactor by combining the ability of Ti(OBu n ) 4/AlEt 3 to produce 1 butene with the ability of [Me 2SiN t BuInd]ZrCl 2/MAO to copolymerize ethylene with 1 butene. It was found that the dual functional catalytic system has high activity and get the good polymer with density ranging from 0.91-0.95 g/cm 3 in ethylene polymerization.
文摘The oxygen-contained groups such as C—O,C—OH,CO,C(O)O and C(O)OH are introduced onto the molecular chains of linear low density polyethylene(LLDPE) through ultraviolet irradiation at environmental temperature of 70 ℃ in air without adding any additives.The concentration of these groups increases with the iucrease of irradiation time.The gel appears in irradiated LLDPE,the gel content increases with the iucrease of irradiation time.The melt flow index decreases and reach minimum when the irradiation time is 24 h,and then increase.The interfacial adhesion between irradiated LLDPE and polyamide 66(PA66) and the mechanical properties of the PA66/irradiated LLDPE(80/20) blends are improved owing to the oxygen-contained polar groups introduced.Compared with those of PA66/LLDPE(80/20) blends,the tensile strength,Young′s modulus,bending strength and notch impact strength of PA66/irradiated LLDPE(80/20) blends for 24 h are increased from 48.3,908,64.8 MPa and 31 J/m\ to 62.0,984,83.1 MPa and 85 J/m,respectively.
文摘A case of household water tanks, 1000 L capacity, made of RCC, LLDPE and mild steel (stainless steel) was evaluated for life cycle analysis. The scope of the research comprised of the raw materials, energy inputs and corresponding emissions during all phases of product making such as extraction of raw material, it’s processing, followed by manufacturing and transport, as well as use and reuse of the product. Simapro 8 (System for Integrated environMental Assessment of PROducts), a modelling software, from Dutch PRé Consultants was used to conduct the life cycle analysis. Simapro 8 enables systematic and transparent modelling and analysis of complex life cycles based on the recommendations of the ISO 14040 series of standards. In the present study the most common method which is acceptable worldwide “Recipe Endpoint method” (ReCiPe) was employed. ReCiPe computes the impact categories and classifies them into two classes based on relevant arrays of characterization factors. Simapro addresses impact categories viz. ozone depletion, human toxicity, ionizing radiation, photochemical oxidant formation, particulate matter formation, terrestrial acidification, climate change, terrestrial ecotoxicity, agricultural land occupation, urban land occupation, natural land transformation, marine ecotoxicity, marine eutrophication, fresh water eutrophication, fresh water ecotoxicity, fossil fuel depletion, minerals depletion, fresh water depletion at the midpoint level. While at the Endpoint level, the impact categories are multiplied by corresponding damage factors and integrated to be represented as three Endpoint level categories, viz. human health, ecosystems and resource depletion. The three endpoint categories are normalized, weighted, and aggregated into a single score. LCA studies indicate that household water tanks of LLDPE have least environmental implications considering impacts on human health, ecosystems and resource depletion as compared to its counterparts viz. Household water tanks made up of mild steel and RCC. The sequence of the material with decreasing impacts is concrete tanks > mild steel tank > LLDPE tanks. The overall assessment is centred on the elements such as material inputs, energy inputs and environmental emissions.
