Application of Linear Thermodynamics to the Atmospheric System.Part Ⅱ: Exemplification of Linear Phenomenological Relations in the Atmospheric System

The linear phenomenological relations in the atmospheric boundary layer are proved indirectly using observational facts to combine linear thermodynamic theory and similarity theory in the boundary layer. Furthermore, it is proved that Ihe turbulent transport coefficients are in proportion to Ihe corresponding linear phenomenological coefficients. But the experimental facts show that the linear phenomenological relations are not (tenable in the atmospheric mixing layer because the turbulenl transport process is an intense non-linear process in the mixing layer. Hence the convection boundary layer is a thermodynamic stale in a non-linear region far from the equilibrium state. The geostrophic wind is a special cross-coupling phenomenon between the dynamic process and the thermodynamic process in the atmospheric system. It is a practical exemplification of a cross-coupling phenomenon in the atmospheric system.

Nonequilibrium Thermodynamics of Dark Energy on Cosmic Apparent Horizon

In recent several years,some works have been done on cosmic thermodynamics.The apparent horizonwas regarded as the key characteristic supersurface where thermodynamics can be built on perfectly.However,if theirreversible process is considered,the proper position for building thermodynamics will not be the apparent horizonanymore.The new position is related to dark energy state equation and the irreversible process parameters.

The Influence of Convergence Movement on Turbulent Transportation in the Atmospheric Boundary Layer

Classical turbulent K closure theory of the atmospheric boundary layer assumes that the vertical turbulent transport flux of any macroscopic quantity is equivalent to that quantity's vertical gradient transport flux. But a cross coupling between the thermodynamic processes and the dynamic processes in the atmospheric system is demonstrated based on the Curier-Prigogine principle of cross coupling of linear thermodynamics. The vertical turbulent transportation of energy and substance in the atmospheric boundary layer is related not only to their macroscopic gradient but also to the convergence and the divergence movement. The transportation of the convergence or divergence movement is important for the atmospheric boundary layer of the heterogeneous underlying surface and the convection boundary layer. Based on this, the turbulent transportation in the atmospheric boundary layer, the energy budget of the heterogeneous underlying surface and the convection boundary layer, and the boundary layer parameterization of land surface processes over the heterogeneous underlying surface are studied. This research offers clues not only for establishing the atmospheric boundary layer theory about the heterogeneous underlying surface, but also for overcoming the difficulties encountered recently in the application of the atmospheric boundary layer theory.

Principle of Cross Coupling Between Vertical Heat Turbulent Transport and Vertical Velocity and Determination of Cross Coupling Coefficient

It has been proved that there exists a cross coupling between vertical heat turbulent transport and vertical velocity by using linear thermodynamics. This result asserts that the vertical component of heat turbulent transport flux is composed of both the transport of the vertical potential temperature gradient and the coupling transport of the vertical velocity. In this paper, the coupling effect of vertical velocity on vertical heat turbulent transportation is validated by using observed data from the atmospheric boundary layer to determine cross coupling coefficients, and a series of significant properties of turbulent transportation are opened out. These properties indicate that the cross coupling coefficient is a logarithm function of the dimensionless vertical velocity and dimensionless height, and is not only related to the friction velocity u., but also to the coupling roughness height zwo and the coupling temperature Two of the vertical velocity. In addition, the function relations suggest that only when the vertical velocity magnitude conforms to the limitation IW/u. I # 1, and is above the level zwo, then the vertical velocity leads to the cross coupling effect on the vertical heat turbulent transport flux. The cross coupling theory and experimental results provide a challenge to the traditional turbulent K closure theory and the Monin-Obukhov similarity theory.

Power-optimization of multistage non-isothermal chemical engine system via Onsager equations,Hamilton-Jacobi-Bellman theory and dynamic programming

The research on the output rate performance limit of the multi-stage energy conversion system based on modern optimal control theory is one of the hot spots of finite time thermodynamics.The existing research mainly focuses on the multi-stage heat engine system with pure heat transfer and the multi-stage isothermal chemical engine(ICE)system with pure mass transfer,while the multi-stage non ICE system with heat and mass transfer coupling is less involved.A multistage endoreversible non-isothermal chemical engine(ENICE)system with a finite high-chemical-potential(HCP)source(driving fluid)and an infinite low-chemical-potential sink(environment)is researched.The multistage continuous system is treated as infinitesimal ENICEs located continuously.Each infinitesimal ENICE is assumed to be a single-stage ENICE with stationary reservoirs.Extending single-stage results,the maximum power output(MPO)of the multistage system is obtained.Heat and mass transfer processes between the reservoir and working fluid are assumed to obey Onsager equations.For the fixed initial time,fixed initial fluid temperature,and fixed initial concentration of key component(CKC)in the HCP source,continuous and discrete models of the multistage system are optimized.With given initial reservoir temperature,initial CKC,and total process time,the MPO of the multistage ENICE system is optimized with fixed and free final temperature and final concentration.If the final concentration and final temperature are free,there are optimal final temperature and optimal final concentration for the multistage ENICE system to achieve MPO;meanwhile,there are low limit values for final fluid temperature and final concentration.Special cases for multistage endoreversible Carnot heat engines and ICE systems are further obtained.For the model in this paper,the minimum entropy generation objective is not equivalent to MPO objective.