Unbalanced traffic distribution in cellular networks results in congestion and degrades spectrum efficiency.To tackle this problem,we propose an Unmanned Aerial Vehicle(UAV)-assisted wireless network in which the UAV ...Unbalanced traffic distribution in cellular networks results in congestion and degrades spectrum efficiency.To tackle this problem,we propose an Unmanned Aerial Vehicle(UAV)-assisted wireless network in which the UAV acts as an aerial relay to divert some traffic from the overloaded cell to its adjacent underloaded cell.To fully exploit its potential,we jointly optimize the UAV position,user association,spectrum allocation,and power allocation to maximize the sum-log-rate of all users in two adjacent cells.To tackle the complicated joint optimization problem,we first design a genetic-based algorithm to optimize the UAV position.Then,we simplify the problem by theoretical analysis and devise a low-complexity algorithm according to the branch-and-bound method,so as to obtain the optimal user association and spectrum allocation schemes.We further propose an iterative power allocation algorithm based on the sequential convex approximation theory.The simulation results indicate that the proposed UAV-assisted wireless network is superior to the terrestrial network in both utility and throughput,and the proposed algorithms can substantially improve the network performance in comparison with the other schemes.展开更多
This paper focuses on the scheduling problem of workflow tasks that exhibit interdependencies.Unlike indepen-dent batch tasks,workflows typically consist of multiple subtasks with intrinsic correlations and dependenci...This paper focuses on the scheduling problem of workflow tasks that exhibit interdependencies.Unlike indepen-dent batch tasks,workflows typically consist of multiple subtasks with intrinsic correlations and dependencies.It necessitates the distribution of various computational tasks to appropriate computing node resources in accor-dance with task dependencies to ensure the smooth completion of the entire workflow.Workflow scheduling must consider an array of factors,including task dependencies,availability of computational resources,and the schedulability of tasks.Therefore,this paper delves into the distributed graph database workflow task scheduling problem and proposes a workflow scheduling methodology based on deep reinforcement learning(DRL).The method optimizes the maximum completion time(makespan)and response time of workflow tasks,aiming to enhance the responsiveness of workflow tasks while ensuring the minimization of the makespan.The experimental results indicate that the Q-learning Deep Reinforcement Learning(Q-DRL)algorithm markedly diminishes the makespan and refines the average response time within distributed graph database environments.In quantifying makespan,Q-DRL achieves mean reductions of 12.4%and 11.9%over established First-fit and Random scheduling strategies,respectively.Additionally,Q-DRL surpasses the performance of both DRL-Cloud and Improved Deep Q-learning Network(IDQN)algorithms,with improvements standing at 4.4%and 2.6%,respectively.With reference to average response time,the Q-DRL approach exhibits a significantly enhanced performance in the scheduling of workflow tasks,decreasing the average by 2.27%and 4.71%when compared to IDQN and DRL-Cloud,respectively.The Q-DRL algorithm also demonstrates a notable increase in the efficiency of system resource utilization,reducing the average idle rate by 5.02%and 9.30%in comparison to IDQN and DRL-Cloud,respectively.These findings support the assertion that Q-DRL not only upholds a lower average idle rate but also effectively curtails the average response time,thereby substantially improving processing efficiency and optimizing resource utilization within distributed graph database systems.展开更多
Cloud Computing has the ability to provide on-demand access to a shared resource pool.It has completely changed the way businesses are managed,implement applications,and provide services.The rise in popularity has led...Cloud Computing has the ability to provide on-demand access to a shared resource pool.It has completely changed the way businesses are managed,implement applications,and provide services.The rise in popularity has led to a significant increase in the user demand for services.However,in cloud environments efficient load balancing is essential to ensure optimal performance and resource utilization.This systematic review targets a detailed description of load balancing techniques including static and dynamic load balancing algorithms.Specifically,metaheuristic-based dynamic load balancing algorithms are identified as the optimal solution in case of increased traffic.In a cloud-based context,this paper describes load balancing measurements,including the benefits and drawbacks associated with the selected load balancing techniques.It also summarizes the algorithms based on implementation,time complexity,adaptability,associated issue(s),and targeted QoS parameters.Additionally,the analysis evaluates the tools and instruments utilized in each investigated study.Moreover,comparative analysis among static,traditional dynamic and metaheuristic algorithms based on response time by using the CloudSim simulation tool is also performed.Finally,the key open problems and potential directions for the state-of-the-art metaheuristic-based approaches are also addressed.展开更多
The amount of oxygen blown into the converter is one of the key parameters for the control of the converter blowing process,which directly affects the tap-to-tap time of converter. In this study, a hybrid model based ...The amount of oxygen blown into the converter is one of the key parameters for the control of the converter blowing process,which directly affects the tap-to-tap time of converter. In this study, a hybrid model based on oxygen balance mechanism (OBM) and deep neural network (DNN) was established for predicting oxygen blowing time in converter. A three-step method was utilized in the hybrid model. First, the oxygen consumption volume was predicted by the OBM model and DNN model, respectively. Second, a more accurate oxygen consumption volume was obtained by integrating the OBM model and DNN model. Finally, the converter oxygen blowing time was calculated according to the oxygen consumption volume and the oxygen supply intensity of each heat. The proposed hybrid model was verified using the actual data collected from an integrated steel plant in China, and compared with multiple linear regression model, OBM model, and neural network model including extreme learning machine, back propagation neural network, and DNN. The test results indicate that the hybrid model with a network structure of 3 hidden layer layers, 32-16-8 neurons per hidden layer, and 0.1 learning rate has the best prediction accuracy and stronger generalization ability compared with other models. The predicted hit ratio of oxygen consumption volume within the error±300 m^(3)is 96.67%;determination coefficient (R^(2)) and root mean square error (RMSE) are0.6984 and 150.03 m^(3), respectively. The oxygen blow time prediction hit ratio within the error±0.6 min is 89.50%;R2and RMSE are0.9486 and 0.3592 min, respectively. As a result, the proposed model can effectively predict the oxygen consumption volume and oxygen blowing time in the converter.展开更多
With the continuous expansion of the data center network scale, changing network requirements, and increasing pressure on network bandwidth, the traditional network architecture can no longer meet people’s needs. The...With the continuous expansion of the data center network scale, changing network requirements, and increasing pressure on network bandwidth, the traditional network architecture can no longer meet people’s needs. The development of software defined networks has brought new opportunities and challenges to future networks. The data and control separation characteristics of SDN improve the performance of the entire network. Researchers have integrated SDN architecture into data centers to improve network resource utilization and performance. This paper first introduces the basic concepts of SDN and data center networks. Then it discusses SDN-based load balancing mechanisms for data centers from different perspectives. Finally, it summarizes and looks forward to the study on SDN-based load balancing mechanisms and its development trend.展开更多
In this study,new particle and energy balance equations have been developed to predict the electron temperature and density in locally bounded plasmas.Classical particle and energy balance equations assume that all pl...In this study,new particle and energy balance equations have been developed to predict the electron temperature and density in locally bounded plasmas.Classical particle and energy balance equations assume that all plasma within a reactor is completely confined only by the reactor walls.However,in industrial plasma reactors for semiconductor manufacturing,the plasma is partially confined by internal reactor structures.We predict the effect of the open boundary area(A′_(L,eff))and ion escape velocity(u_(i))on electron temperature and density by developing new particle and energy balance equations.Theoretically,we found a low ion escape velocity(u_(i)/u_(B)≈0.2)and high open boundary area(A′_(L,eff)/A_(T,eff)≈0.6)to result in an approximately 38%increase in electron density and an 8%decrease in electron temperature compared to values in a fully bounded reactor.Additionally,we suggest that the velocity of ions passing through the open boundary should exceedω_(pi)λ_(De)under the condition E^(2)_(0)?(Φ/λ_(De))^(2).展开更多
In this paper, a sender-initiated protocol is applied which uses fuzzy logic control method to improve computer networks performance by balancing loads among computers. This new model devises sender-initiated protocol...In this paper, a sender-initiated protocol is applied which uses fuzzy logic control method to improve computer networks performance by balancing loads among computers. This new model devises sender-initiated protocol for load transfer for load balancing. Groups are formed and every group has a node called a designated representative (DR). During load transferring processes, loads are transferred using the DR in each group to achieve load balancing purposes. The simulation results show that the performance of the protocol proposed is better than the compared conventional method. This protocol is more stable than the method without using the fuzzy logic control.展开更多
Hydrological models are very useful tools for evaluating water resources, and the hydroclimatic hazards associated with the water cycle. However, their calibration and validation require the use of performance criteri...Hydrological models are very useful tools for evaluating water resources, and the hydroclimatic hazards associated with the water cycle. However, their calibration and validation require the use of performance criteria which choice is not straightforward. This paper aims to evaluate the influence of the performance criteria on water balance components and water extremes using two global rainfall-runoff models (HBV and GR4J) over the Ouémé watershed at the Bonou and Savè outlets. Three (3) Efficacy criteria (Nash, coefficient of determination, and KGE) were considered for calibration and validation. The results show that the Nash criterion provides a good assessment of the simulation of the different parts of the hydrograph. KGE is better for simulating peak flows and water balance elements than other efficiency criteria. This study could serve as a basis for the choice of performance criteria in hydrological modelling.展开更多
We present a theoretical study of the medium modifications of the p_(T)balance (x_(J)) of dijets in Xe+Xe collisions at■.The initial production of dijets was carried out using the POWHEG+PYTHIA8 prescription,which ma...We present a theoretical study of the medium modifications of the p_(T)balance (x_(J)) of dijets in Xe+Xe collisions at■.The initial production of dijets was carried out using the POWHEG+PYTHIA8 prescription,which matches the next-toleading-order (NLO) QCD matrix elements with the parton shower (PS) effect.The SHELL model described the in-medium evolution of nucleus–nucleus collisions using a transport approach.The theoretical results of the dijet xJin the Xe+Xe collisions exhibit more imbalanced distributions than those in the p+p collisions,consistent with recently reported ATLAS data.By utilizing the Interleaved Flavor Neutralisation,an infrared-and-collinear-safe jet flavor algorithm,to identify the flavor of the reconstructed jets,we classify dijets processes into three categories:gluon–gluon (gg),quark–gluon (qg),and quark–quark (qq),and investigated the respective medium modification patterns and fraction changes of the gg,qg,and qq components of the dijet sample in Xe+Xe collisions.It is shown that the increased fraction of qg component at a small x_(J)contributes to the imbalance of the dijet;in particular,the q_(1)g_(2)(quark-jet-leading) dijets experience more significant asymmetric energy loss than the g_(1)q_(2)(gluon-jet-leading) dijets traversing the QGP.By comparing the■of inclusive,■ dijets in Xe+Xe collisions,we observe■.Moreover,ρ_(Xe),P_(b),the ratios of the nuclear modification factors of dijets in Xe+Xe to those in Pb+Pb,were calculated,which indicates that the yield suppression of dijets in Pb+Pb is more pronounced than that in Xe+Xe owing to the larger radius of the lead nucleus.展开更多
Evapotranspiration is an important parameter used to characterize the water cycle of ecosystems.To under-stand the properties of the evapotranspiration and energy balance of a subalpine forest in the southeastern Qing...Evapotranspiration is an important parameter used to characterize the water cycle of ecosystems.To under-stand the properties of the evapotranspiration and energy balance of a subalpine forest in the southeastern Qinghai-Tibet Plateau,an open-path eddy covariance system was set up to monitor the forest from November 2020 to October 2021 in a core area of the Three Parallel Rivers in the Qing-hai-Tibet Plateau.The results show that the evapotranspira-tion peaked daily,the maximum occurring between 11:00 and 15:00.Environmental factors had significant effects on evapotranspiration,among them,net radiation the greatest(R^(2)=0.487),and relative humidity the least(R^(2)=0.001).The energy flux varied considerably in different seasons and sensible heat flux accounted for the main part of turbulent energy.The energy balance ratio in the dormant season was less than that in the growing season,and there is an energy imbalance at the site on an annual time scale.展开更多
Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do ...Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do not involve any special data structure,and do not induce savings in memory requirements,they are easily implemented on existing codes and are recommended for 1D and 2D simulations when intensive testing is required.The multilevel technique can also be applied to balance laws,but in this case,numerical errors may be induced by the technique.We present a series of numerical tests that point out that the use of monotonicity-preserving interpolatory techniques eliminates the numerical errors observed when using the usual 4-point centered Lagrange interpolation,and leads to a more robust multilevel code for balance laws,while maintaining the efficiency rates observed forhyperbolic conservation laws.展开更多
A Josephson traveling wave parametric amplifier(JTWPA),which is a quantum-limited amplifier with high gain and large bandwidth,is the core device of large-scale measurement and control systems for quantum computing.A ...A Josephson traveling wave parametric amplifier(JTWPA),which is a quantum-limited amplifier with high gain and large bandwidth,is the core device of large-scale measurement and control systems for quantum computing.A typical JTWPA consists of thousands of Josephson junctions connected in series to form a transmission line and hundreds of shunt LC resonators periodically loaded along the line for phase matching.Because the variation of these capacitors and inductors can be detrimental to their high-frequency characteristics,the fabrication of a JTWPA typically necessitates precise processing equipment.To guide the fabrication process and further improve the design for manufacturability,it is necessary to understand how each electronic component affects the amplifier.In this paper,we use the harmonic balance method to conduct a comprehensive study on the impact of nonuniformity and fabrication yield of the electronic components on the performance of a JTWPA.The results provide insightful and scientific guidance for device design and fabrication processes.展开更多
The balance between metal and acid sites directly affects the preparation of high-performance cracking catalysts with high heat sink and low coking.Nevertheless,how to control acid-metal sites balance and its relation...The balance between metal and acid sites directly affects the preparation of high-performance cracking catalysts with high heat sink and low coking.Nevertheless,how to control acid-metal sites balance and its relationship with cracking performance are reported scarcely.In this work,a series of Pt/Al_(2)O_(3)-SiO_(2) dual sites catalysts with different metal to acid active sites ratio(C_(M)/C_(SA))were constructed by ethanolassisted impregnation method and the impact on n-decane cracking under supercritical conditions was systematically and deeply investigated.The results showed that the conversion and carbon deposition increased gradually with varied C_(M)/C_(SA)and reached the balance at C_(M)/C_(SA)of 0.13.The proper ratio C_(M)/C_(SA)(0.13)can balance the deep dehydrogenation coking over metal active sites and high heat sink of cracking over acid active sites,the chemical heat sink reaches amazing 1.75 MJ/kg and carbon deposition is only22.03 mg/cm^(2) at 750℃.Meanwhile,the few metal sites at low C_(M)/C_(SA)and the few strong acid sites at high C_(M)/C_(SA)are the main factors limiting the cracking activity.Low C_(M)/C_(SA)limit the activation of C-H bond and deep dehydrogenation of coking precursor,resulting in relative low cracking activity and carbon deposition,while high C_(M)/C_(SA)limit the activation of C-C bond and increase the deep dehydrogenation.In this contribution,design and construction of metal-acid dual sites can not only provide the technical solution for the preparation of high heat sink and low coking cracking catalyst,but also deepen the understanding of the cracking path of hydrocarbon fuel.展开更多
Using Euler’s first-order explicit(EE)method and the peridynamic differential operator(PDDO)to discretize the time and internal crystal-size derivatives,respectively,the Euler’s first-order explicit method–peridyna...Using Euler’s first-order explicit(EE)method and the peridynamic differential operator(PDDO)to discretize the time and internal crystal-size derivatives,respectively,the Euler’s first-order explicit method–peridynamic differential operator(EE–PDDO)was obtained for solving the one-dimensional population balance equation in crystallization.Four different conditions during crystallization were studied:size-independent growth,sizedependent growth in a batch process,nucleation and size-independent growth,and nucleation and size-dependent growth in a continuous process.The high accuracy of the EE–PDDO method was confirmed by comparing it with the numerical results obtained using the second-order upwind and HR-van methods.The method is characterized by non-oscillation and high accuracy,especially in the discontinuous and sharp crystal size distribution.The stability of the EE–PDDO method,choice of weight function in the PDDO method,and optimal time step are also discussed.展开更多
Internet of Things(IoT)empowers imaginative applications and permits new services when mobile nodes are included.For IoT-enabled low-power and lossy networks(LLN),the Routing Protocol for Low-power and Lossy Networks(...Internet of Things(IoT)empowers imaginative applications and permits new services when mobile nodes are included.For IoT-enabled low-power and lossy networks(LLN),the Routing Protocol for Low-power and Lossy Networks(RPL)has become an established standard routing protocol.Mobility under standard RPL remains a difficult issue as it causes continuous path disturbance,energy loss,and increases the end-to-end delay in the network.In this unique circumstance,a Balanced-load and Energy-efficient RPL(BE-RPL)is proposed.It is a routing technique that is both energy-efficient and mobility-aware.It responds quicker to link breakage through received signal strength-based mobility monitoring and selecting a new preferred parent reactively.The proposed system also implements load balancing among stationary nodes for leaf node allocation.Static nodes with more leaf nodes are restricted from participating in the election for a new preferred parent.The performance of BE-RPL is assessed using the COOJA simulator.It improves the energy use,network control overhead,frame acknowledgment ratio,and packet delivery ratio of the network.展开更多
Cyber-physical power system(CPPS)has significantly improved the operational efficiency of power systems.However,cross-space cascading failures may occur due to the coupling characteristics,which poses a great threat t...Cyber-physical power system(CPPS)has significantly improved the operational efficiency of power systems.However,cross-space cascading failures may occur due to the coupling characteristics,which poses a great threat to the safety and reliability of CPPS,and there is an acute need to reduce the probability of these failures.Towards this end,this paper first proposes a cascading failure index to identify and quantify the importance of different information in the same class of communication services.On this basis,a joint improved risk-balanced service function chain routing strategy(SFC-RS)is proposed,which is modeled as a robust optimization problem and solved by column-and-constraint generation(C-CG)algorithm.Compared with the traditional shortest-path routing algorithm,the superiority of SFC-RS is verified in the IEEE 30-bus system.The results demonstrate that SFC-RS effectively mitigates the risk associated with information transmission in the network,enhances information transmission accessibility,and effectively limits communication disruption from becoming the cause of cross-space cascading failures.展开更多
The advent of the big data era has provided many types of transportation datasets,such as metro smart card data,for studying residents’mobility and understanding how their mobility has been shaped and is shaping the ...The advent of the big data era has provided many types of transportation datasets,such as metro smart card data,for studying residents’mobility and understanding how their mobility has been shaped and is shaping the urban space.In this paper,we use metro smart card data from two Chinese metropolises,Shanghai and Shenzhen.Five metro mobility indicators are introduced,and association rules are established to explore the mobility patterns.The proportion of people entering and exiting the station is used to measure the jobs-housing balance.It is found that the average travel distance and duration of Shanghai passengers are higher than those of Shenzhen,and the proportion of metro commuters in Shanghai is higher than that of Shenzhen.The jobs-housing spatial relationship in Shenzhen based on metro travel is more balanced than that in Shanghai.The fundamental reason for the differences between the two cities is the difference in urban morphology.Compared with the monocentric structure of Shanghai,the polycentric structure of Shenzhen results in more scattered travel hotspots and more diverse travel routes,which helps Shenzhen to have a better jobs-housing balance.This paper fills a gap in comparative research among Chinese cities based on transportation big data analysis.The results provide support for planning metro routes,adjusting urban structure and land use to form a more reasonable metro network,and balancing the jobs-housing spatial relationship.展开更多
Real-time applications based on Wireless Sensor Network(WSN)tech-nologies are quickly increasing due to intelligent surroundings.Among the most significant resources in the WSN are battery power and security.Clustering...Real-time applications based on Wireless Sensor Network(WSN)tech-nologies are quickly increasing due to intelligent surroundings.Among the most significant resources in the WSN are battery power and security.Clustering stra-tegies improve the power factor and secure the WSN environment.It takes more electricity to forward data in a WSN.Though numerous clustering methods have been developed to provide energy consumption,there is indeed a risk of unequal load balancing,resulting in a decrease in the network’s lifetime due to network inequalities and less security.These possibilities arise due to the cluster head’s limited life span.These cluster heads(CH)are in charge of all activities and con-trol intra-cluster and inter-cluster interactions.The proposed method uses Lifetime centric load balancing mechanisms(LCLBM)and Cluster-based energy optimiza-tion using a mobile sink algorithm(CEOMS).LCLBM emphasizes the selection of CH,system architectures,and optimal distribution of CH.In addition,the LCLBM was added with an assistant cluster head(ACH)for load balancing.Power consumption,communications latency,the frequency of failing nodes,high security,and one-way delay are essential variables to consider while evaluating LCLBM.CEOMS will choose a cluster leader based on the influence of the fol-lowing parameters on the energy balance of WSNs.According to simulatedfind-ings,the suggested LCLBM-CEOMS method increases cluster head selection self-adaptability,improves the network’s lifetime,decreases data latency,and bal-ances network capacity.展开更多
BACKGROUND Jianpi-Huatan-Huoxue-Anshen formula[Tzu-Chi cancer-antagonizing&lifeprotecting II decoction(TCCL)]is a Chinese medical formula that has been clinically shown to reduce the gastrointestinal side effects ...BACKGROUND Jianpi-Huatan-Huoxue-Anshen formula[Tzu-Chi cancer-antagonizing&lifeprotecting II decoction(TCCL)]is a Chinese medical formula that has been clinically shown to reduce the gastrointestinal side effects of chemotherapy in cancer patients and improve their quality of life.However,its effect and mechanism on the intestinal microecology after chemotherapy are not yet clear.AIM To discover the potential mechanisms of TCCL on gastrointestinal inflammation and microecological imbalance in chemotherapy-treated mice transplanted with hepatocellular carcinoma(HCC).METHODS Ninety-six mice were inoculated subcutaneously with HCC cells.One week later,the mice received a large dose of 5-fluorouracil by intraperitoneal injection to establish a HCC chemotherapy model.Thirty-six mice were randomly selected before administration,and feces,ileal tissue,and ileal contents were collected from each mouse.The remaining mice were randomized into normal saline,continuous chemotherapy,Yangzheng Xiaoji capsulestreated,and three TCCL-treated groups.After treatment,feces,tumors,liver,spleen,thymus,stomach,jejunum,ileum,and colon tissues,and ileal contents were collected.Morphological changes,serum levels of IL-1β,IL-6,IL-8,IL-10,IL-22,TNF-α,and TGF-β,intestinal SIgA,and protein and mRNA expression of ZO-1,NF-κB,Occludin,MUC-2,Claudin-1,and IκB-αin colon tissues were documented.The effect of TCCL on the abundance and diversity of intestinal flora was analyzed using 16S rDNA sequencing.RESULTS TCCL treatment improved thymus and spleen weight,thymus and spleen indexes,and body weight,decreased tumor volumes and tumor tissue cell density,and alleviated injury to gastric,ileal,and colonic mucosal tissues.Among proteins and genes associated with inflammation,IL-10,TGF-β,SIgA,ZO-1,MUC-2,and Occludin were upregulated,whereas NF-κB,IL-1β,IL-6,TNF-α,IL-22,IL-8,and IκB-αwere downregulated.Additionally,TCCL increased the proportions of fecal Actinobacteria,AF12,Adlercreutzia,Clostridium,Coriobacteriaceae,and Paraprevotella in the intermediate stage of treatment,decreased the proportions of Mucipirillum,Odoribacter,RF32,YS2,and Rikenellaceae but increased the proportions of p_Deferribacteres and Lactobacillus at the end of treatment.Studies on ileal mucosal microbiota showed similar findings.Moreover,TCCL improved community richness,evenness,and the diversity of fecal and ileal mucosal flora.CONCLUSION TCCL relieves pathological changes in tumor tissue and chemotherapy-induced gastrointestinal injury,potentially by reducing the release of pro-inflammatory factors to repair the gastrointestinal mucosa,enhancing intestinal barrier function,and maintaining gastrointestinal microecological balance.Hence,TCCL is a very effective adjuvant to chemotherapy.展开更多
Metal oxide charge transport materials are preferable for realizing long-term stable and potentially low-cost perovskite solar cells(PSCs).However,due to some technical difficulties(e.g.,intricate fabrication protocol...Metal oxide charge transport materials are preferable for realizing long-term stable and potentially low-cost perovskite solar cells(PSCs).However,due to some technical difficulties(e.g.,intricate fabrication protocols,high-temperature heating process,incompatible solvents,etc.),it is still challenging to achieve efficient and reliable all-metal-oxide-based devices.Here,we developed efficient inverted PSCs(IPSCs)based on solution-processed nickel oxide(NiO_(x))and tin oxide(SnO_(2))nanoparticles,working as hole and electron transport materials respectively,enabling a fast and balanced charge transfer for photogenerated charge carriers.Through further understanding and optimizing the perovskite/metal oxide interfaces,we have realized an outstanding power conversion efficiency(PCE)of 23.5%(the bandgap of the perovskite is 1.62 eV),which is the highest efficiency among IPSCs based on all-metal-oxide charge transport materials.Thanks to these stable metal oxides and improved interface properties,ambient stability(retaining 95%of initial PCE after 1 month),thermal stability(retaining 80%of initial PCE after 2 weeks)and light stability(retaining 90%of initial PCE after 1000 hours aging)of resultant devices are enhanced significantly.In addition,owing to the low-temperature fabrication procedures of the entire device,we have obtained a PCE of over 21%for flexible IPSCs with enhanced operational stability.展开更多
基金supported in part by the National Key Research and Development Program of China under Grant 2020YFB1807003in part by the National Natural Science Foundation of China under Grants 61901381,62171385,and 61901378+3 种基金in part by the Aeronautical Science Foundation of China under Grant 2020z073053004in part by the Foundation of the State Key Laboratory of Integrated Services Networks of Xidian University under Grant ISN21-06in part by the Key Research Program and Industrial Innovation Chain Project of Shaanxi Province under Grant 2019ZDLGY07-10in part by the Natural Science Fundamental Research Program of Shaanxi Province under Grant 2021JM-069.
文摘Unbalanced traffic distribution in cellular networks results in congestion and degrades spectrum efficiency.To tackle this problem,we propose an Unmanned Aerial Vehicle(UAV)-assisted wireless network in which the UAV acts as an aerial relay to divert some traffic from the overloaded cell to its adjacent underloaded cell.To fully exploit its potential,we jointly optimize the UAV position,user association,spectrum allocation,and power allocation to maximize the sum-log-rate of all users in two adjacent cells.To tackle the complicated joint optimization problem,we first design a genetic-based algorithm to optimize the UAV position.Then,we simplify the problem by theoretical analysis and devise a low-complexity algorithm according to the branch-and-bound method,so as to obtain the optimal user association and spectrum allocation schemes.We further propose an iterative power allocation algorithm based on the sequential convex approximation theory.The simulation results indicate that the proposed UAV-assisted wireless network is superior to the terrestrial network in both utility and throughput,and the proposed algorithms can substantially improve the network performance in comparison with the other schemes.
基金funded by the Science and Technology Foundation of State Grid Corporation of China(Grant No.5108-202218280A-2-397-XG).
文摘This paper focuses on the scheduling problem of workflow tasks that exhibit interdependencies.Unlike indepen-dent batch tasks,workflows typically consist of multiple subtasks with intrinsic correlations and dependencies.It necessitates the distribution of various computational tasks to appropriate computing node resources in accor-dance with task dependencies to ensure the smooth completion of the entire workflow.Workflow scheduling must consider an array of factors,including task dependencies,availability of computational resources,and the schedulability of tasks.Therefore,this paper delves into the distributed graph database workflow task scheduling problem and proposes a workflow scheduling methodology based on deep reinforcement learning(DRL).The method optimizes the maximum completion time(makespan)and response time of workflow tasks,aiming to enhance the responsiveness of workflow tasks while ensuring the minimization of the makespan.The experimental results indicate that the Q-learning Deep Reinforcement Learning(Q-DRL)algorithm markedly diminishes the makespan and refines the average response time within distributed graph database environments.In quantifying makespan,Q-DRL achieves mean reductions of 12.4%and 11.9%over established First-fit and Random scheduling strategies,respectively.Additionally,Q-DRL surpasses the performance of both DRL-Cloud and Improved Deep Q-learning Network(IDQN)algorithms,with improvements standing at 4.4%and 2.6%,respectively.With reference to average response time,the Q-DRL approach exhibits a significantly enhanced performance in the scheduling of workflow tasks,decreasing the average by 2.27%and 4.71%when compared to IDQN and DRL-Cloud,respectively.The Q-DRL algorithm also demonstrates a notable increase in the efficiency of system resource utilization,reducing the average idle rate by 5.02%and 9.30%in comparison to IDQN and DRL-Cloud,respectively.These findings support the assertion that Q-DRL not only upholds a lower average idle rate but also effectively curtails the average response time,thereby substantially improving processing efficiency and optimizing resource utilization within distributed graph database systems.
文摘Cloud Computing has the ability to provide on-demand access to a shared resource pool.It has completely changed the way businesses are managed,implement applications,and provide services.The rise in popularity has led to a significant increase in the user demand for services.However,in cloud environments efficient load balancing is essential to ensure optimal performance and resource utilization.This systematic review targets a detailed description of load balancing techniques including static and dynamic load balancing algorithms.Specifically,metaheuristic-based dynamic load balancing algorithms are identified as the optimal solution in case of increased traffic.In a cloud-based context,this paper describes load balancing measurements,including the benefits and drawbacks associated with the selected load balancing techniques.It also summarizes the algorithms based on implementation,time complexity,adaptability,associated issue(s),and targeted QoS parameters.Additionally,the analysis evaluates the tools and instruments utilized in each investigated study.Moreover,comparative analysis among static,traditional dynamic and metaheuristic algorithms based on response time by using the CloudSim simulation tool is also performed.Finally,the key open problems and potential directions for the state-of-the-art metaheuristic-based approaches are also addressed.
基金financially supported by the National Natural Science Foundation of China (Nos.51974023 and52374321)the funding of State Key Laboratory of Advanced Metallurgy,University of Science and Technology Beijing,China (No.41620007)。
文摘The amount of oxygen blown into the converter is one of the key parameters for the control of the converter blowing process,which directly affects the tap-to-tap time of converter. In this study, a hybrid model based on oxygen balance mechanism (OBM) and deep neural network (DNN) was established for predicting oxygen blowing time in converter. A three-step method was utilized in the hybrid model. First, the oxygen consumption volume was predicted by the OBM model and DNN model, respectively. Second, a more accurate oxygen consumption volume was obtained by integrating the OBM model and DNN model. Finally, the converter oxygen blowing time was calculated according to the oxygen consumption volume and the oxygen supply intensity of each heat. The proposed hybrid model was verified using the actual data collected from an integrated steel plant in China, and compared with multiple linear regression model, OBM model, and neural network model including extreme learning machine, back propagation neural network, and DNN. The test results indicate that the hybrid model with a network structure of 3 hidden layer layers, 32-16-8 neurons per hidden layer, and 0.1 learning rate has the best prediction accuracy and stronger generalization ability compared with other models. The predicted hit ratio of oxygen consumption volume within the error±300 m^(3)is 96.67%;determination coefficient (R^(2)) and root mean square error (RMSE) are0.6984 and 150.03 m^(3), respectively. The oxygen blow time prediction hit ratio within the error±0.6 min is 89.50%;R2and RMSE are0.9486 and 0.3592 min, respectively. As a result, the proposed model can effectively predict the oxygen consumption volume and oxygen blowing time in the converter.
文摘With the continuous expansion of the data center network scale, changing network requirements, and increasing pressure on network bandwidth, the traditional network architecture can no longer meet people’s needs. The development of software defined networks has brought new opportunities and challenges to future networks. The data and control separation characteristics of SDN improve the performance of the entire network. Researchers have integrated SDN architecture into data centers to improve network resource utilization and performance. This paper first introduces the basic concepts of SDN and data center networks. Then it discusses SDN-based load balancing mechanisms for data centers from different perspectives. Finally, it summarizes and looks forward to the study on SDN-based load balancing mechanisms and its development trend.
文摘In this study,new particle and energy balance equations have been developed to predict the electron temperature and density in locally bounded plasmas.Classical particle and energy balance equations assume that all plasma within a reactor is completely confined only by the reactor walls.However,in industrial plasma reactors for semiconductor manufacturing,the plasma is partially confined by internal reactor structures.We predict the effect of the open boundary area(A′_(L,eff))and ion escape velocity(u_(i))on electron temperature and density by developing new particle and energy balance equations.Theoretically,we found a low ion escape velocity(u_(i)/u_(B)≈0.2)and high open boundary area(A′_(L,eff)/A_(T,eff)≈0.6)to result in an approximately 38%increase in electron density and an 8%decrease in electron temperature compared to values in a fully bounded reactor.Additionally,we suggest that the velocity of ions passing through the open boundary should exceedω_(pi)λ_(De)under the condition E^(2)_(0)?(Φ/λ_(De))^(2).
文摘In this paper, a sender-initiated protocol is applied which uses fuzzy logic control method to improve computer networks performance by balancing loads among computers. This new model devises sender-initiated protocol for load transfer for load balancing. Groups are formed and every group has a node called a designated representative (DR). During load transferring processes, loads are transferred using the DR in each group to achieve load balancing purposes. The simulation results show that the performance of the protocol proposed is better than the compared conventional method. This protocol is more stable than the method without using the fuzzy logic control.
文摘Hydrological models are very useful tools for evaluating water resources, and the hydroclimatic hazards associated with the water cycle. However, their calibration and validation require the use of performance criteria which choice is not straightforward. This paper aims to evaluate the influence of the performance criteria on water balance components and water extremes using two global rainfall-runoff models (HBV and GR4J) over the Ouémé watershed at the Bonou and Savè outlets. Three (3) Efficacy criteria (Nash, coefficient of determination, and KGE) were considered for calibration and validation. The results show that the Nash criterion provides a good assessment of the simulation of the different parts of the hydrograph. KGE is better for simulating peak flows and water balance elements than other efficiency criteria. This study could serve as a basis for the choice of performance criteria in hydrological modelling.
基金Guangdong Major Project of Basic and Applied Basic Research(No.2020B0301030008)National Natural Science Foundation of China with Project(Nos.11935007,12035007,12247127,and 12247132)China Postdoctoral Science Foundation supports S.Wang under project No.2021M701279.
文摘We present a theoretical study of the medium modifications of the p_(T)balance (x_(J)) of dijets in Xe+Xe collisions at■.The initial production of dijets was carried out using the POWHEG+PYTHIA8 prescription,which matches the next-toleading-order (NLO) QCD matrix elements with the parton shower (PS) effect.The SHELL model described the in-medium evolution of nucleus–nucleus collisions using a transport approach.The theoretical results of the dijet xJin the Xe+Xe collisions exhibit more imbalanced distributions than those in the p+p collisions,consistent with recently reported ATLAS data.By utilizing the Interleaved Flavor Neutralisation,an infrared-and-collinear-safe jet flavor algorithm,to identify the flavor of the reconstructed jets,we classify dijets processes into three categories:gluon–gluon (gg),quark–gluon (qg),and quark–quark (qq),and investigated the respective medium modification patterns and fraction changes of the gg,qg,and qq components of the dijet sample in Xe+Xe collisions.It is shown that the increased fraction of qg component at a small x_(J)contributes to the imbalance of the dijet;in particular,the q_(1)g_(2)(quark-jet-leading) dijets experience more significant asymmetric energy loss than the g_(1)q_(2)(gluon-jet-leading) dijets traversing the QGP.By comparing the■of inclusive,■ dijets in Xe+Xe collisions,we observe■.Moreover,ρ_(Xe),P_(b),the ratios of the nuclear modification factors of dijets in Xe+Xe to those in Pb+Pb,were calculated,which indicates that the yield suppression of dijets in Pb+Pb is more pronounced than that in Xe+Xe owing to the larger radius of the lead nucleus.
基金supported by the CAS"Light of West China"Program (2021XBZG-XBQNXZ-A-007)the National Natural Science Foundation of China (31971436)the State Key Laboratory of Cryospheric Science,Northwest Institute of Eco-Environment and Resources,Chinese Academy Sciences (SKLCS-OP-2021-06).
文摘Evapotranspiration is an important parameter used to characterize the water cycle of ecosystems.To under-stand the properties of the evapotranspiration and energy balance of a subalpine forest in the southeastern Qinghai-Tibet Plateau,an open-path eddy covariance system was set up to monitor the forest from November 2020 to October 2021 in a core area of the Three Parallel Rivers in the Qing-hai-Tibet Plateau.The results show that the evapotranspira-tion peaked daily,the maximum occurring between 11:00 and 15:00.Environmental factors had significant effects on evapotranspiration,among them,net radiation the greatest(R^(2)=0.487),and relative humidity the least(R^(2)=0.001).The energy flux varied considerably in different seasons and sensible heat flux accounted for the main part of turbulent energy.The energy balance ratio in the dormant season was less than that in the growing season,and there is an energy imbalance at the site on an annual time scale.
基金supported by Grant PID2020-117211GB-I00funded by MCIN/AEI/10.13039/501100011033+4 种基金by Grant CIAICO/2021/227funded by the Generalitat Valencianasupported by the Ministerio de Ciencia e Innovacion of Spain(Grant Ref.PID2021-125709OB-C21)funded by MCIN/AEI/10.13039/501100011033/FEDER,UEby the Generalitat Valenciana(CIAICO/2021/224).
文摘Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do not involve any special data structure,and do not induce savings in memory requirements,they are easily implemented on existing codes and are recommended for 1D and 2D simulations when intensive testing is required.The multilevel technique can also be applied to balance laws,but in this case,numerical errors may be induced by the technique.We present a series of numerical tests that point out that the use of monotonicity-preserving interpolatory techniques eliminates the numerical errors observed when using the usual 4-point centered Lagrange interpolation,and leads to a more robust multilevel code for balance laws,while maintaining the efficiency rates observed forhyperbolic conservation laws.
基金support from the Youth Innovation Promotion Association of Chinese Academy of Sciences (Grant No.2019319)support from the Start-up Foundation of Suzhou Institute of Nano-Tech and Nano-Bionics,CAS,Suzhou (Grant No.Y9AAD110)。
文摘A Josephson traveling wave parametric amplifier(JTWPA),which is a quantum-limited amplifier with high gain and large bandwidth,is the core device of large-scale measurement and control systems for quantum computing.A typical JTWPA consists of thousands of Josephson junctions connected in series to form a transmission line and hundreds of shunt LC resonators periodically loaded along the line for phase matching.Because the variation of these capacitors and inductors can be detrimental to their high-frequency characteristics,the fabrication of a JTWPA typically necessitates precise processing equipment.To guide the fabrication process and further improve the design for manufacturability,it is necessary to understand how each electronic component affects the amplifier.In this paper,we use the harmonic balance method to conduct a comprehensive study on the impact of nonuniformity and fabrication yield of the electronic components on the performance of a JTWPA.The results provide insightful and scientific guidance for device design and fabrication processes.
基金subsidized by Sichuan Province Science and Technology Program (2023NSFSC0093)Enterprises Entrust Technology Development Program (FJF22KX0055,202302914)。
文摘The balance between metal and acid sites directly affects the preparation of high-performance cracking catalysts with high heat sink and low coking.Nevertheless,how to control acid-metal sites balance and its relationship with cracking performance are reported scarcely.In this work,a series of Pt/Al_(2)O_(3)-SiO_(2) dual sites catalysts with different metal to acid active sites ratio(C_(M)/C_(SA))were constructed by ethanolassisted impregnation method and the impact on n-decane cracking under supercritical conditions was systematically and deeply investigated.The results showed that the conversion and carbon deposition increased gradually with varied C_(M)/C_(SA)and reached the balance at C_(M)/C_(SA)of 0.13.The proper ratio C_(M)/C_(SA)(0.13)can balance the deep dehydrogenation coking over metal active sites and high heat sink of cracking over acid active sites,the chemical heat sink reaches amazing 1.75 MJ/kg and carbon deposition is only22.03 mg/cm^(2) at 750℃.Meanwhile,the few metal sites at low C_(M)/C_(SA)and the few strong acid sites at high C_(M)/C_(SA)are the main factors limiting the cracking activity.Low C_(M)/C_(SA)limit the activation of C-H bond and deep dehydrogenation of coking precursor,resulting in relative low cracking activity and carbon deposition,while high C_(M)/C_(SA)limit the activation of C-C bond and increase the deep dehydrogenation.In this contribution,design and construction of metal-acid dual sites can not only provide the technical solution for the preparation of high heat sink and low coking cracking catalyst,but also deepen the understanding of the cracking path of hydrocarbon fuel.
文摘Using Euler’s first-order explicit(EE)method and the peridynamic differential operator(PDDO)to discretize the time and internal crystal-size derivatives,respectively,the Euler’s first-order explicit method–peridynamic differential operator(EE–PDDO)was obtained for solving the one-dimensional population balance equation in crystallization.Four different conditions during crystallization were studied:size-independent growth,sizedependent growth in a batch process,nucleation and size-independent growth,and nucleation and size-dependent growth in a continuous process.The high accuracy of the EE–PDDO method was confirmed by comparing it with the numerical results obtained using the second-order upwind and HR-van methods.The method is characterized by non-oscillation and high accuracy,especially in the discontinuous and sharp crystal size distribution.The stability of the EE–PDDO method,choice of weight function in the PDDO method,and optimal time step are also discussed.
文摘Internet of Things(IoT)empowers imaginative applications and permits new services when mobile nodes are included.For IoT-enabled low-power and lossy networks(LLN),the Routing Protocol for Low-power and Lossy Networks(RPL)has become an established standard routing protocol.Mobility under standard RPL remains a difficult issue as it causes continuous path disturbance,energy loss,and increases the end-to-end delay in the network.In this unique circumstance,a Balanced-load and Energy-efficient RPL(BE-RPL)is proposed.It is a routing technique that is both energy-efficient and mobility-aware.It responds quicker to link breakage through received signal strength-based mobility monitoring and selecting a new preferred parent reactively.The proposed system also implements load balancing among stationary nodes for leaf node allocation.Static nodes with more leaf nodes are restricted from participating in the election for a new preferred parent.The performance of BE-RPL is assessed using the COOJA simulator.It improves the energy use,network control overhead,frame acknowledgment ratio,and packet delivery ratio of the network.
基金funded by the National Natural Science Foundation of China under Grant 52177074.
文摘Cyber-physical power system(CPPS)has significantly improved the operational efficiency of power systems.However,cross-space cascading failures may occur due to the coupling characteristics,which poses a great threat to the safety and reliability of CPPS,and there is an acute need to reduce the probability of these failures.Towards this end,this paper first proposes a cascading failure index to identify and quantify the importance of different information in the same class of communication services.On this basis,a joint improved risk-balanced service function chain routing strategy(SFC-RS)is proposed,which is modeled as a robust optimization problem and solved by column-and-constraint generation(C-CG)algorithm.Compared with the traditional shortest-path routing algorithm,the superiority of SFC-RS is verified in the IEEE 30-bus system.The results demonstrate that SFC-RS effectively mitigates the risk associated with information transmission in the network,enhances information transmission accessibility,and effectively limits communication disruption from becoming the cause of cross-space cascading failures.
基金National Key R&D Program of China(No.2019YFB2103102)Hong Kong Polytechnic University(No.CD06,P0042540)。
文摘The advent of the big data era has provided many types of transportation datasets,such as metro smart card data,for studying residents’mobility and understanding how their mobility has been shaped and is shaping the urban space.In this paper,we use metro smart card data from two Chinese metropolises,Shanghai and Shenzhen.Five metro mobility indicators are introduced,and association rules are established to explore the mobility patterns.The proportion of people entering and exiting the station is used to measure the jobs-housing balance.It is found that the average travel distance and duration of Shanghai passengers are higher than those of Shenzhen,and the proportion of metro commuters in Shanghai is higher than that of Shenzhen.The jobs-housing spatial relationship in Shenzhen based on metro travel is more balanced than that in Shanghai.The fundamental reason for the differences between the two cities is the difference in urban morphology.Compared with the monocentric structure of Shanghai,the polycentric structure of Shenzhen results in more scattered travel hotspots and more diverse travel routes,which helps Shenzhen to have a better jobs-housing balance.This paper fills a gap in comparative research among Chinese cities based on transportation big data analysis.The results provide support for planning metro routes,adjusting urban structure and land use to form a more reasonable metro network,and balancing the jobs-housing spatial relationship.
文摘Real-time applications based on Wireless Sensor Network(WSN)tech-nologies are quickly increasing due to intelligent surroundings.Among the most significant resources in the WSN are battery power and security.Clustering stra-tegies improve the power factor and secure the WSN environment.It takes more electricity to forward data in a WSN.Though numerous clustering methods have been developed to provide energy consumption,there is indeed a risk of unequal load balancing,resulting in a decrease in the network’s lifetime due to network inequalities and less security.These possibilities arise due to the cluster head’s limited life span.These cluster heads(CH)are in charge of all activities and con-trol intra-cluster and inter-cluster interactions.The proposed method uses Lifetime centric load balancing mechanisms(LCLBM)and Cluster-based energy optimiza-tion using a mobile sink algorithm(CEOMS).LCLBM emphasizes the selection of CH,system architectures,and optimal distribution of CH.In addition,the LCLBM was added with an assistant cluster head(ACH)for load balancing.Power consumption,communications latency,the frequency of failing nodes,high security,and one-way delay are essential variables to consider while evaluating LCLBM.CEOMS will choose a cluster leader based on the influence of the fol-lowing parameters on the energy balance of WSNs.According to simulatedfind-ings,the suggested LCLBM-CEOMS method increases cluster head selection self-adaptability,improves the network’s lifetime,decreases data latency,and bal-ances network capacity.
基金Supported by Natural Science Foundation of Xiamen,China,No.3502Z20227171the Young Investigator Research Program of Xiang’an Hospital of Xiamen University,No.XAH23005+2 种基金the Traditional Chinese Medicine Foundation of Xiamen,No.XWZY-2023-0103Natural Science Foundation of Fujian,China,No.2018J01136National Natural Science Foundation of China,No.81202659.
文摘BACKGROUND Jianpi-Huatan-Huoxue-Anshen formula[Tzu-Chi cancer-antagonizing&lifeprotecting II decoction(TCCL)]is a Chinese medical formula that has been clinically shown to reduce the gastrointestinal side effects of chemotherapy in cancer patients and improve their quality of life.However,its effect and mechanism on the intestinal microecology after chemotherapy are not yet clear.AIM To discover the potential mechanisms of TCCL on gastrointestinal inflammation and microecological imbalance in chemotherapy-treated mice transplanted with hepatocellular carcinoma(HCC).METHODS Ninety-six mice were inoculated subcutaneously with HCC cells.One week later,the mice received a large dose of 5-fluorouracil by intraperitoneal injection to establish a HCC chemotherapy model.Thirty-six mice were randomly selected before administration,and feces,ileal tissue,and ileal contents were collected from each mouse.The remaining mice were randomized into normal saline,continuous chemotherapy,Yangzheng Xiaoji capsulestreated,and three TCCL-treated groups.After treatment,feces,tumors,liver,spleen,thymus,stomach,jejunum,ileum,and colon tissues,and ileal contents were collected.Morphological changes,serum levels of IL-1β,IL-6,IL-8,IL-10,IL-22,TNF-α,and TGF-β,intestinal SIgA,and protein and mRNA expression of ZO-1,NF-κB,Occludin,MUC-2,Claudin-1,and IκB-αin colon tissues were documented.The effect of TCCL on the abundance and diversity of intestinal flora was analyzed using 16S rDNA sequencing.RESULTS TCCL treatment improved thymus and spleen weight,thymus and spleen indexes,and body weight,decreased tumor volumes and tumor tissue cell density,and alleviated injury to gastric,ileal,and colonic mucosal tissues.Among proteins and genes associated with inflammation,IL-10,TGF-β,SIgA,ZO-1,MUC-2,and Occludin were upregulated,whereas NF-κB,IL-1β,IL-6,TNF-α,IL-22,IL-8,and IκB-αwere downregulated.Additionally,TCCL increased the proportions of fecal Actinobacteria,AF12,Adlercreutzia,Clostridium,Coriobacteriaceae,and Paraprevotella in the intermediate stage of treatment,decreased the proportions of Mucipirillum,Odoribacter,RF32,YS2,and Rikenellaceae but increased the proportions of p_Deferribacteres and Lactobacillus at the end of treatment.Studies on ileal mucosal microbiota showed similar findings.Moreover,TCCL improved community richness,evenness,and the diversity of fecal and ileal mucosal flora.CONCLUSION TCCL relieves pathological changes in tumor tissue and chemotherapy-induced gastrointestinal injury,potentially by reducing the release of pro-inflammatory factors to repair the gastrointestinal mucosa,enhancing intestinal barrier function,and maintaining gastrointestinal microecological balance.Hence,TCCL is a very effective adjuvant to chemotherapy.
基金UK Engineering and Physical Sciences Research Council(EPSRC)New Investigator Award(2018,EP/R043272/1)Newton Advanced Fellowship(192097)for financial support+3 种基金the Royal Society,the Engineering and Physical Sciences Research Council(EPSRC,EP/R023980/1,EP/V027131/1)the European Research Council(ERC)under the European Union's Horizon 2020 research and innovation program(HYPERION,Grant Agreement Number 756962)the Royal Society and Tata Group(UF150033)EPSRC SPECIFIC IKC(EP/N020863/1)
文摘Metal oxide charge transport materials are preferable for realizing long-term stable and potentially low-cost perovskite solar cells(PSCs).However,due to some technical difficulties(e.g.,intricate fabrication protocols,high-temperature heating process,incompatible solvents,etc.),it is still challenging to achieve efficient and reliable all-metal-oxide-based devices.Here,we developed efficient inverted PSCs(IPSCs)based on solution-processed nickel oxide(NiO_(x))and tin oxide(SnO_(2))nanoparticles,working as hole and electron transport materials respectively,enabling a fast and balanced charge transfer for photogenerated charge carriers.Through further understanding and optimizing the perovskite/metal oxide interfaces,we have realized an outstanding power conversion efficiency(PCE)of 23.5%(the bandgap of the perovskite is 1.62 eV),which is the highest efficiency among IPSCs based on all-metal-oxide charge transport materials.Thanks to these stable metal oxides and improved interface properties,ambient stability(retaining 95%of initial PCE after 1 month),thermal stability(retaining 80%of initial PCE after 2 weeks)and light stability(retaining 90%of initial PCE after 1000 hours aging)of resultant devices are enhanced significantly.In addition,owing to the low-temperature fabrication procedures of the entire device,we have obtained a PCE of over 21%for flexible IPSCs with enhanced operational stability.