Improving the operational stability of perovskite solar cells with cesium-doped graphene oxide interlayer

Perovskite solar cells(PSCs)have made great advances in terms of power conversion efficiency(PCE),yet their subpar stability continues to hinder their commercialization.The interface between the perovskite layer and the charge-carrier transporting layers plays a crucial role in undermining the stability of PSCs.In this work,we propose a strategy to stabilize high-performance PSCs with PCE over 23%by introducing a cesium-doped graphene oxide(GO-Cs)as an interlayer between the perovskite and hole-transporting material.The GO-Cs treated PSCs exhibit excellent operational stability with a projected T80(the time where the device PCE reduces to 80%of its initial value)of 2143 h of operation at the maximum powering point under one sun illumination.

Stability and Credibility Should Be Valued in China-U.S.Ties

While stressing the paramount importance of a right strategic perception of each other between China and the United States,President Xi Jinping underlined three overarching principles that should guide the bilateral relations in 2024,involving peace,stability,and credibility.

Retrospective Case Series on The Enduring Rotational Stability of The AcrySof IQ Toric Intraocular Lens in Cataract Patients Suffering from Myopia

Objective:To analyze the enduring rotational steadiness of AcrySof IQ Toric intraocular lens(IOL)in cataract patients suffering from myopia in a long-term study.Methods:A retrospective study was conducted on a case series involving 78 patients.A total of 120 eyes with an axial length(AL)ranging from 24-30 mm and corneal astigmatism≥1.50 D underwent implantation of AcrySof IQ Toric IOL guided by the version navigation system.The eyes were divided into two groups based on AL.Group A included 60 eyes with high myopia(AL≥26 mm),while Group B consisted of eyes with low to moderate myopia(24 mm≤AL<26 mm).Data on the preoperative AL were collected.Measurements were taken for residual astigmatism,the best corrected visual acuity(BCDVA),corneal astigmatism,and IOL rotation occurring between 24-and 48-months post-surgery.The percentage of eyes with an IOL rotation of under 5°and 10°was analyzed.Results:The mean length of follow-up times was recorded as 34.27±4.98,and the average rotation was 2.73±1.29°.Group A exhibited a slightly higher average rotation of 2.87±1.31°,compared to the rotation of 2.59±1.27°observed in Group B.At both the 24-36 month and 26-48 month post-operation marks,the degree of IOL rotation did not show a statistically significant difference between the two groups,with none of the patients experiencing a rotation exceeding 10°(P>0.05).The percentage of rotation degrees under 5°was recorded as 98.22%.After the procedure,the BCDVA was 0.1322±0.03 LogMAR.There was a substantial increase in theχvalue after the operation as compared to the pre-operativeχ^(2) value(χ^(2)=76.79).The standard deviation of preoperative corneal astigmatism was statistically significant(P<0.05)at 2.17±1.08 D.Following the surgical procedure,the remaining astigmatism was measured at 0.41±0.26 D.The data showed a notable gap in statistical significance(t=4.281,P<0.05).Conclusion:The AcrySof Toric IOL was a reliable solution for managing corneal astigmatism in cataract patients with myopia,demonstrating excellent long-term rotational stability.

Application of an amphipathic molecule at the NiO_(x)/perovskite interface for improving the efficiency and long-term stability of the inverted perovskite solar cells

The presence of defects and detrimental reactions at NiO_(x)/perovskite interface extremely limit the efficiency performance and long-term stability of the perovskite solar cells(PSCs) based on NiO_(x).Herein,an amphipathic molecule Triton X100(Triton) is modified on the NiO_(x)surface.The hydrophilic chain of Triton as a Lewis base additive can coordinate with the Ni3+on the NiO_(x)surface which can passivate the interfacial defects and hinder the detrimental reactions at the NiO_(x)/perovskite interface.Additionally,the hydrophobic chain of Triton protrudes from the NiO_(x)surface to prevent moisture from penetrating into the NiO_(x)/perovskite interface.Consequently,the NiO_(x)/Triton-based devices(MAPbI3as absorbing layer) show superior moisture and thermal stability,retaining 88.4% and 64.3% of the initial power conversion efficiency after storage in air(40%-50% relative humidity(RH)) at 25 ℃ for 1070 h and in N2at 85℃ for 800 h,respectively.Moreover,the efficiency increases from 17.59% to 19.89% because of the passivation defect and enhanced hole-extraction capability.Besides,the NiO_(x)/Triton-based PSCs with Cs_(0.05)(MA_(0.15)FA_(0.85))_(0.95)Pb(I_(0.85)Br_(0.15))3perovskite as the light-absorbing layer also exhibits better moisture and thermal stability compared to the control devices,indicating the viability of our strategies.Of particular note,a champion PCE of 22.35% and 20.46% was achieved for small-area(0.1 cm^(2)) and large-area(1.2 cm^(2)) NiO_(x)/Triton-based devices,respectively.

Non-Fullerene-Based Inverted Organic Photovoltaic Device with Long-Term Stability

In this work,we developed the PM6:Y6-based inverted structure organic photovoltaic(i-OPV)with improved power conversion efficiency(PCE)and long-term stability by resolving the origins of the performance deterioration.The deep defects between the metal oxide-based electron transport layer and bulk-heterojunction photoactive layer interface were responsible for suboptimal PCE and facilitated degradation of devices.While the density of deep traps is increased during the storage of i-OPV,the penetrative oxygen-containing defects additionally generated shallow traps below the band-edge of Y6,causing an additional loss in the open-circuit voltage.The suppression of interfacial defects by chemical modification effectively improved the PCE and long-term stability of i-OPV.The modified i-OPV(mi-OPV)achieved a PCE of 17.42%,which is the highest value among the reported PM6:Y6-based i-OPV devices.Moreover,long-term stability was significantly improved:~90%and~80%retention of its initial PCE after 1200 h of air storage and illumination,respectively.

Could Long-Term Stability Last Forever?

The subject of the present paper is to prove that the recently introduced conjecture of boundedness puts a ban over the view of stability as asymptotic property. This result comes in sharp contrast with the prescription of the traditional thermodynamics and statistical physics which consider the existence of equilibrium as asymptotic property of all systems. The difference commences from the use of infinitesimal calculus as the basic implement for modelling by the latter while the primary premise of the conjecture of boundedness is sustaining the energy/matter/information permanently bounded and finite. The latter property overrules the infinitesimal calculus as the major implement of modelling because, among all, it is proven that the traditional one suffers unsoluble difficulties.

Enhancing the stability of planar perovskite solar cells by green and inexpensive cellulose acetate butyrate

Although the efficiency of organic–inorganic hybrid halide perovskite solar cells has been improved rapidly, the intrinsic instability of perovskite materials restricts their commercial application. Here, an eco-friendly and low-cost organic polymer, cellulose acetate butyrate(CAB), was introduced to the grain boundaries and surfaces of perovskite, resulting in a high-quality and low-defect perovskite film with a nearly tenfold improvement in carrier lifetime. More importantly, the CAB-treated perovskite films have a well-matched energy level with the charge transport layers, thus suppressing carrier nonradiative recombination and carrier accumulation. As a result, the optimized CAB-based device achieved a champion efficiency of 21.5% compared to the control device(18.2%). Since the ester group in CAB bonds with Pb in perovskite, and the H and O in the hydroxyl group bond with the I and organic cations in perovskite,respectively, it will contribute to superior stability under heat, high humidity, and light soaking conditions. After aging under 35% humidity(relative humidity, RH) for 3300 h, the optimized device can still maintain more than 90% of the initial efficiency;it can also retain more than 90% of the initial efficiency after aging at 65 ℃, 65% RH, or light(AM 1.5G) for 500 h. This simple optimization strategy for perovskite stability could facilitate the commercial application of perovskite solar cells.

Long-term inorganic plus organic fertilization increases yield and yield stability of winter wheat

An understanding of wheat yield and yield stability response to fertilization is important for sustainable wheat production. A 36-year long-term fertilization experiment was employed to evaluate the yield and yield stability of winter wheat. Five fertilization regimes were compared,including(1) CK, no fertilizer;(2) NPK, inorganic fertilizer only;(3) O, organic fertilizer only;(4)NPKO, 50% of NPK plus 50% of O, and(5) HNPKO, 80% of NPK plus 80% of O. The greatest yield increase was recorded in HNPKO, followed by NPKO, with O producing the lowest mean yield increase. Over the 36 years, the rate of wheat yield increase in fertilized plots ranged from95.31 kg ha-1 year-1 in the HNPKO to 138.65 kg ha-1 year-1 in the O. Yield stability analysis using the additive main effects and multiplicative interactions(AMMI) method assigned 62.3%, 26.3%,and 11.4% of sums of squares to fertilization effect, environmental effect, and fertilization ×environment interaction effect, respectively. The combination of inorganic and organic fertilization(NPKO and HNPKO) appeared to produce more stable yields than O or NPK, with lower coefficients of variation and AMMI stability value. However, wheat grown with O seemed to be the most susceptible to climate change and the least productive among the fertilized plots.Significant correlations of grain yield with soil properties and with mean air temperature were observed. These findings suggest that inorganic + organic fertilizer can increase wheat yield and its stability by improvement in soil fertility and reduction in variability to climate change.

Long-term straw incorporation increases rice yield stability under high fertilization level conditions in the rice–wheat system

Straw incorporation is a global common practice to improve soil fertility and rice yield.However,the effect of straw incorporation on rice yield stability is still unknown,especially under high fertilization level conditions.Here,we reported the effect of straw returning on rice yield and yield stability under high fertilization levels in the rice–wheat system over nine years.The results showed that straw incorporation did not significantly affect the average rice yield of nine years.Straw incorporation reduced the coefficient of variation of rice yield by 25.8%and increased the sustainable yield index by 8.2%.The rice yield positively correlated with mean photosynthetically active radiation (PAR) of rice growth season and the effects of straw incorporation on rice yield depended on the PAR.Straw incorporation increased the rice yield by 5.4%in the low PAR years,whereas it did not affect the rice yield in the high PAR years.Long-term straw incorporation lowered soil bulk density but improved the soil organic matter,total N,available N,available P,and available K more strongly than straw removal.Our findings suggest that straw incorporation can increase rice yield stability through improving the resistance of rice plant growth to low PAR.

Dimensionality regulation in tin halide perovskite solar cells: Toward high performance and stability

Tin halide perovskites(THPs)have received extensive attention due to their low toxicity and excellent optoelectronic properties,and are considered to be the most promising alternatives to develop efficient lead-free perovskite solar cells.However,due to the unique and inherent characteristics of Sn^(2+)being easily oxidized to Sn^(4+)and fast crystallization,tin perovskite solar cells(TPSCs)show relatively poor performance and stability,compared to the lead counterparts.Recently,the introduction of bulky organic spacers into three-dimensional(3D)THPs for dimensional regulation can not only prevent the intrusion of water and oxygen,but also inhibit the self-doping effect and ion migration.In this review,we will detail how dimensional regulation enables TPSCs with high performance and superior stability.First,we summarize the intrinsic properties of THPs and analyze the root causes of their poor performance and instability.Next,we discuss the specific structure and types of the dimensional regulation strategy.Then,the mechanism of dimensional regulation is discussed in detail,mainly from inhibiting the Sn^(2+)oxidation,optimizing crystallization,passivating defects,and improving energy level alignment.Finally,future challenges and prospects for dimensional regulation are elaborated to help researchers develop more efficient and stable TPSCs.

Kriging-based reliability analysis of the long-term stability of a deep driftconstructed in the Callovo-Oxfordian claystone

Callovo-Oxfordian(COx)claystone has been considered as a potential host rock for geological radioactive waste disposal in France(Cigéo project).During the exploitation phase(100 years),the stability of drifts(e.g.galleries/alveoli)within the disposal is assured by the liner,which includes two layers:concrete arch segment and compressible material.The latter exhibits a significant deformation capacity(about 50%)under low stress(<3 MPa).Although the response of these underground structures can be governed by complex thermo-hydro-mechanical coupling,the creep behavior of COx claystone has been considered as the main factor controlling the increase of stress state in the concrete liner and hence the long-term stability of drifts.Therefore,by focusing only on the purely mechanical behavior,this study aims at investigating the uncertainty effect of the COx claystone time-dependent properties on the stability of an alveolus of Cigéo during the exploitation period.To describe the creep behavior of COx claystone,we use Lemaitre’s viscoplastic model with three parameters whose uncertainties are identified from laboratory creep tests.For the reliability analysis,an extension of a well-known Kriging metamodeling technique is proposed to assess the exceedance probability of acceptable stress in the concrete liner of the alveolus.The open-source code Code_Aster is chosen for the direct numerical evaluations of the performance function.The Kriging-based reliability analysis elucidates the effect of the uncertainty of COx claystone on the long-term stability of the concrete liner.Moreover,the role of the compressible material layer between the concrete liner and the host rock is also highlighted.

Gadolinium-incorporated CsPbI_(2)Br for boosting efficiency and long-term stability of all-inorganic perovskite solar cells

All-inorganic CsPbI_(2)Br perovskite solar cells(PSCs)have received extensive research interests recently.Nevertheless,their low efficiency and poor long-term stability are still obstacles for further commercial application.Herein,we demonstrate that high efficiency and exceptional long-term stability are realized by incorporating gadolinium(III)chloride(GdCl_(3))into the CsPbI_(2)Br perovskite film.The incorporation of GdCl_(3) enhances the Goldschmidt tolerance factor of CsPbI_(2)Br perovskite,yielding a dense perovskite film with small grains,thus the a-phase CsPbI_(2)Br is remarkably stabilized.Additionally,it is found that the GdCl_(3)-incorporated perovskite film achieves suppressed charge recombination and appropriate energy level alignment compared with the pristine CsPbI_(2)Br film.The noticeable increment in efficiency from14.01%(control PSC)to 16.24%is achieved for GdCl_(3)-incorporated PSC.Moreover,the nonencapsulated GdCl_(3)-incorporated PSC exhibits excellent environmental and thermal stability,remaining over 91%or90%of the original efficiency after 1200 h aging at 40%relative humidity or 480 h heating at 85℃ in nitrogen glove box respectively.The encapsulated GdCl_(3)-incorporated PSC presents an improved operational stability with over 88%of initial efficiency under maximum power point(MPP)tracking at 45℃ for1000 h.This work presents an effective ion-incorporation approach for boosting efficiency and long-term stability of all-inorganic PSCs.

Back analysis of long-term stability of a 92 m span ancient quarrying cavern

Long-term stability of large-span caverns is a challenging issue for design and construction of underground rock engineering.The Heidong cavern group consisting of 21 caverns was constructed about 1400 years ago for quarrying in massive Cretaceous tuff.The cavern No.5 of the Heidong cavern group is characterized by an unsupported span up to 92 m,with the overburden thickness of only 3-25 m.To analyze its long-term stability,a detailed investigation was conducted to obtain its geometry and rock mass characteristics,and to monitor surrounding rock displacements.Based on field survey and laboratory tests,numerical simulations were performed using the finite difference code FLAC;.The analysis results revealed that for the long-term stability of the cavern No.5,some major factors should be carefully considered,such as cavern excavation method in hard massive rocks,site investigation using trial pits,tools like short iron chisel and hammer for manual excavation,geometric dome roof,and waste rocks within abutment or on the floor.The highlights of the technologies obtained from this large-scale ancient underground project can provide reference for other similar project excavations in practice.

Model test and numerical simulation on the dynamic stability of the bedding rock slope under frequent microseisms

Shake table testing was performed to investigate the dynamic stability of a mid-dip bedding rock slope under frequent earthquakes. Then, numerical modelling was established to further study the slope dynamic stability under purely microseisms and the influence of five factors, including seismic amplitude, slope height, slope angle, strata inclination and strata thickness, were considered. The experimental results show that the natural frequency of the slope decreases and damping ratio increases as the earthquake loading times increase. The dynamic strength reduction method is adopted for the stability evaluation of the bedding rock slope in numerical simulation, and the slope stability decreases with the increase of seismic amplitude, increase of slope height, reduction of strata thickness and increase of slope angle. The failure mode of a mid-dip bedding rock slope in the shaking table test is integral slipping along the bedding surface with dipping tensile cracks at the slope rear edge going through the bedding surfaces. In the numerical simulation, the long-term stability of a mid-dip bedding slope is worst under frequent microseisms and the slope is at risk of integral sliding instability, whereas the slope rock mass is more broken than shown in the shaking table test. The research results are of practical significance to better understand the formation mechanism of reservoir landslides and prevent future landslide disasters.

Climate change and permafrost stability in the eastern Canada Cordillera:The results of 33 years of measurements

Over the last 33 years,a network of climate stations has been set up at high altitude mountain permafrost sites from Plateau Mountain near Claresholm,Alberta,north to Sheldon Lake on the North Canol Road in the Yukon.Taken together with the data from the US National Weather Service and the Canadian Atmospheric Environment Service,the results indicate a cooling of mean annual air temperature south of Calgary,no significant change in Calgary,a slight warming at Jasper,and a major warming at Summit Lake,west of Fort Nelson.In contrast,the south eastern and central Yukon show only a minor warming trend that lies well within the limits of a sixty-year record measured by the Canadian Atmospheric Environment Service.Along the Mackenzie valley and on the North Slope of Alaska,the mean annual air temperature is rising.Permafrost is aggrading on Plateau Mountain,degrading at Summit Lake,and appears to be stable in southern Yukon and southern Alaska.This is in contrast to the warming occurring on the Arctic coastal plain and along the Mackenzie valley.It therefore appears that changes in climate vary considera-bly from place to place,and even where warming may occur,it may not continue indefinitely.There has been a northward shift of the arctic front due to a weakening of air pressure in the Yukon and Alaska relative to the continental tropical(cT) and maritime polar(mT) air masses to the south.Any actual changes that may be occurring appear to undergo amplification along the Mackenzie valley and Arctic coastal plain and reduction by buffering in the interior Yukon and Alaskan mountains,a result of mi-cro-environmental factors.Continued,careful monitoring of the climate is required and needs to be expanded in the National Parks in the mountains in order to provide data on the changes that may be taking place.Such measurements can provide a sound basis for interpreting ecological and other climate-related data.The existing climate models are not working satisfactorily because we do not know enough about the causes and processes involved in climate change.Improved results can indicate where best to site structures such as pipelines so as to minimize maintenance costs.Models may also help explain why certain areas such as Beringia,which saw reduced climate change,acted as important refugia during the glaciations.

Long-term stabilization of the optical fiber phase control using dual PID

We propose an approach of long-term stabilization of optical fiber phase by controlling a piezo-based phase modulator and a Peltier component attached to the fiber via a phase-locked loop( PLL) circuit w ith dual proportional-integral- derivative( PID) adjustment. With this approach,we can suppress the fast disturbance and slow drifting of optical fiber to satisfy the requirements of optical phase long-term locking. In theory,a mathematical model of an optical fiber phase control system is established. The disturbance term induced by environment influence is considered into the PLL model. The monotonous and continuous changing environment disturbance w ill cause a steady-state error in this theory model. The experimental results accords w ell w ith the theory. The steady-state performance,adjusting time,and overshoot can be improved by using the dual PID control. As a result,the long-term,highly stable and low noise fiber phase locking is realized experimentally.

Effectively Inhibit Phase Separation to Improve Efficiency and Stability of All-Inorganic Planar CsPbIBr2 Perovskite Solar Cells

The advancement in a power conversion efficiency(PCE)to reach 25%,the inorganic perovskites are being explored intensively as promising optoelectronic materials due to their excellent photovoltaic performance,i.e.,thermal stability and efficiency.Lately,the inorganic cesium lead halide perovskite is studied to show enhanced light absorption,however,it suffers from the phase separate into I-rich and Br-rich phase which leads to poor film quality due to difference of electronegativity.Herein,we propose a unique solution of controlling the rate of solvent volatilization followed by gel method to inhibit phase separation effectively to obtain the homogenous and pinhole-free CsPbIBr2 films with high crystalline quality.In this study,an inverted planar device based on a light absorber of CsPbIBr2 is prepared to achieve a power conversion efficiency of 8.8%(maintain a stabilized value of 8%in ambient air conditions).Surprisingly,the optimized cell without encapsulation shows excellent long-term stability,as it maintained 90%initial efficiency over 500 h and controlled storage at around 45%relative humidity and 25℃.

Experimental Study on the Stability of Shuji Tablets

[Objectives]To investigate the stability of Shuji tablets.[Methods]Accelerated test and long-term test were used to investigate the changes of tablet properties,weight difference,alcohol-soluble extract,disintegration time and microbial limit.[Results]All the indicators of the three batches of samples(after 6 months of accelerated test and 18 months of long-term test)basically remained unchanged and all met the standards of the quality standard.[Conclusions]The preparation is stable and reliable,and the stability test provides a reliable basis for its validity.

Stability Test of Naomai Xingshen Capsules

[Objectives]To explore the stability of Naomai Xingshen Capsules.[Methods]Accelerated test and long-term test were carried out to investigate the changes in properties,identification,moisture,disintegration time and microbial limit of Naomai Xingshen Capsules.[Results]There were basically no changes in all indicators for the three batches of samples(after 6-month accelerated test and 24-month long-term test),and they all met the requirements of quality standards.[Conclusions]The preparation of Naomai Xingshen Capsules is stable and reliable,and the stability test provides a reliable basis for its expiration date.