Effects of Long-term Located Fertilization on the Physico-chemical Property of Soil Humus

A systematic study concerning the effects of a long-term stationary fertilization on content and property of soil humus in fluvo-aquic soil sampled from Malan Farm, Xinji City, Hebei, and arid red soil and paddy red soil sampled from the Institute of Red Soil, Jinxian County, Jiangxi was conducted. The results showed that long-term fertilization had effects not only on the content and composition of soil humus, but also on the physico-chemical property of humus. With applying organic manure or combined application of organic manure and chemical fertilizer, E4 and E6 values of humic acid decreased in fluvo-aquic soil and arid red soil, but increased in paddy red soil. In paddy red soil, E4 and E6 values of humic acid increased also with a single application of chemical fertilizer, but E4 and E6 values had less change of humic acid in fluvo-aquic soil and arid red soil. The effects on the visible spectroscopic property of f ulvic acid were different from that of humic acid. Long-term application of organic manure or combined application of organic manure and chemical fertilizer could increase E4 and E6 values of f ulvic acid in three types of soil. Single application of chemical fertilizer had less effect on the E4 and E6. Long-term fertilization could also influence the ultraviolet spectroscopic property of humus. With a single application of organic manure or combined application of organic manure and chemical fertilizer, the ultraviolet absorbance of humic acid and f ulvic acid increased in the three types of soil. But this effect was obvious only in short wave length, and the effect could decrease if the wave length increased. With a single application of chemical fertilizer the ultraviolet absorbance of fulvic acid could increase, but it of humic acid increased only in fluvo-aquic soil. Long-term application of organic manure or combined application of organic manure and chemical fertilizer could increase the content of total acidic groups, carboxy groups and phenolic hydroxy groups of humic acid and fuvic acid in the three types of soil. Single application of chemical fertilizer had less effect on the content of total acidic groups, carboxy groups and phenolic hydroxy groups of humic acid and fuvic acid in the three types of soil.

长期定位施肥对土壤腐殖质理化性质的影响

以潮土、旱地红壤和红壤性水稻土为研究对象 ,探讨了长期施肥对土壤腐殖质含量与性质的影响。结果表明 ,长期施肥不仅影响土壤腐殖质的含量与组成 ,还影响腐殖质的理化性质。施有机肥或有机无机肥配施降低潮土和旱地红壤胡敏酸的E4和E6值 ,提高红壤性水稻土胡敏酸的E4和E6值。单施化肥也能提高红壤性水稻土胡敏酸的E4和E6值 ,但对潮土和旱地红壤胡敏酸E4和E6值影响不大。长期施肥对土壤耕层富里酸可见光谱的影响与胡敏酸不同 ,施有机肥或有机无机肥配施均能提高 3种土壤富里酸的E4和E6值 ,单施化肥对 3种土壤富里酸的E4和E6值基本上没有影响。长期施肥也影响腐殖质的紫外吸收光谱 ,长期施用有机肥或有机无机肥配施均能提高 3种土壤胡敏酸和富里酸的紫外吸收光谱值 ,但这种作用只在短波长方向明显 ,随着波长的增加影响减小。单施化肥也可以提高富里酸的紫外吸收值 ,但只能提高潮土胡敏酸的紫外吸收值。长期施用有机肥或有机无机肥配施均能提高 3种土壤胡敏酸和富里酸的总酸性基、羧基和酚羟基含量 。