This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 K. A polynomial equation of he...This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 K. A polynomial equation of heat capacities as a function of temperature was fitted by the least-squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at intervals of 5 K. The constant-volume energy of combustion of the compound was determined by means of a precision rotating-bomb combustion calorimeter. The standard molar enthalpy of combustion of the compound was derived from the constant-volume energy of combustion. The standard molar enthalpy of formation of the compound was calculated from a combination of the datum of the standard molar enthalpy of combustion of the compound with other auxiliary thermodynamic quantities through a Hess thermochemical cycle.展开更多
This paper reports that low-temperature heat capacities of 4-（2-aminoethyl）-phenol （C8H11NO） are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial eq...This paper reports that low-temperature heat capacities of 4-（2-aminoethyl）-phenol （C8H11NO） are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15K were calculated and tabulated at the interval of 5K. The energy equivalent, εcalor, of the oxygen-bomb combustion calorimeter has been determined from 0.68g of NIST 39i benzoic acid to be εcalor=（14674.69±17.49）J·K^-1. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter to be ΔcU=-（32374.25±12.93）J·g^-1. The standard molar enthalpy of combustion for the compound was calculated to be ΔcHm = -（4445.47 ± 1.77） kJ·mol^-1 according to the definition of enthalpy of combustion and other thermodynamic principles. Finally, the standard molar enthalpy of formation of the compound was derived to be ΔfHm（C8H11NO, s）=-（274.68 ±2.06） kJ·mol^-1, in accordance with Hess law.展开更多
A prediction model for Current Efficiency (CE) of low temperature aluminum electrolysis (LTAE) with the low molar ratioelectfolyte of Na3AIF6-AIF3 - CaF2-MgF2-LiF -Al2O3 system was investigated based on artificial neu...A prediction model for Current Efficiency (CE) of low temperature aluminum electrolysis (LTAE) with the low molar ratioelectfolyte of Na3AIF6-AIF3 - CaF2-MgF2-LiF -Al2O3 system was investigated based on artificial neural network principles. The nonlinearmapping between CE of LATE and various electrolytic conditions was obtained from a number of experimental data and used to predictCE of LATE. The trsined neural networks possessed high precision and resulted in a good predicting effect. As a result, attificial neuralnetworks as a new cooperating and predicting technology provide a new approach to the further studies on low temperature aluminumelectrolysis.展开更多
Extraction of the lower third molar is one of the most common procedures performed in oral surgery. In general, impacted tooth extraction involves sectioning the tooth’s crown and roots. In order to divide the impact...Extraction of the lower third molar is one of the most common procedures performed in oral surgery. In general, impacted tooth extraction involves sectioning the tooth’s crown and roots. In order to divide the impacted tooth so that it can be extracted, high-speed air turbine drills are frequently used. However, complications related to air turbine drills may occur. In this report, we propose an alternative tooth sectioning method that obviates the need for air turbine drill use by using a low-speed straight handpiece and carbide bur. A 21-year-old female patient presented to the institute’s dental hospital complaining of symptoms localized to the left lower third molar tooth that were suggestive of impaction. After physical examination, tooth extraction of the impacted left lower third molar was proposed and the patient consented to the procedure. The crown was divided using a conventional straight low-speed handpiece and carbide bur. This carbide bur can easily cut through the enamel of crown. On post-operative day number five, suture was removed and the wound was extremely clear. This technique could minimise intra-operative time and reduce the morbidity associated with air turbine drill assisted lower third molar extraction.展开更多
The amorphous boron nitride ceramic powders were prepared at 750-950 ℃ by the low-cost urea route, and the effects of preparation temperatures, molar ratios of the raw materials and oxidation treatment on the composi...The amorphous boron nitride ceramic powders were prepared at 750-950 ℃ by the low-cost urea route, and the effects of preparation temperatures, molar ratios of the raw materials and oxidation treatment on the composition, structure and surface morphology of the products were investigated through FT-IR, XRD and SEM. The results show that the products ceramize and crystallize gradually with the increase of the temperature. When the molar ratio and reaction temperature are 3：2 and 850 ℃, respectively, the products have high purity, compact structure and nice shape. The oxidation treatment at 450 ℃ will not impair the composition and structure of boron nitride but effectively remove the impurities.展开更多
In this study, we used a simple impregnation method to prepare Fe-Ce-O<sub> x </sub> catalysts and tested them regarding their low-temperature (200-300 °C) selective catalytic reduction (SCR) of ...In this study, we used a simple impregnation method to prepare Fe-Ce-O<sub> x </sub> catalysts and tested them regarding their low-temperature (200-300 °C) selective catalytic reduction (SCR) of NO using NH<sub>3</sub>. We investigated the effects of Fe/Ce molar ratio, the gas hourly space velocity (GHSV), the stability and SO<sub>2</sub>/H<sub>2</sub>O resistance of the catalysts. The results showed that the FeCe(1:6)O<sub> x </sub> (Ce/Fe molar ratio is 1:6) catalyst, which has some ordered parallel channels, exhibited good SCR performance. The FeCe(1:6)O<sub> x </sub> catalyst had the highest NO conversion with an activity of 94-99% at temperatures between 200 and 300 °C at a space velocity of 28,800 h<sup>−1</sup>. The NO conversion for the FeCe(1:6)O<sub> x </sub> catalyst also reached 80-98% between 200 and 300 °C at a space velocity of 204,000 h<sup>−1</sup>. In addition, the FeCe(1:6)O<sub> x </sub> catalyst demonstrated good stability in a 10-h SCR reaction at 200-300 °C. Even in the presence of SO<sub>2</sub> and H<sub>2</sub>O, the FeCe(1:6)O<sub> x </sub> catalyst exhibited good SCR performance.展开更多
基金Project supported by the National Natural Science Foundations of China (Grant Nos.20673050 and 20973089)
文摘This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 K. A polynomial equation of heat capacities as a function of temperature was fitted by the least-squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at intervals of 5 K. The constant-volume energy of combustion of the compound was determined by means of a precision rotating-bomb combustion calorimeter. The standard molar enthalpy of combustion of the compound was derived from the constant-volume energy of combustion. The standard molar enthalpy of formation of the compound was calculated from a combination of the datum of the standard molar enthalpy of combustion of the compound with other auxiliary thermodynamic quantities through a Hess thermochemical cycle.
基金supported by the National Natural Science Foundation of China (Grant No 20673050)
文摘This paper reports that low-temperature heat capacities of 4-（2-aminoethyl）-phenol （C8H11NO） are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15K were calculated and tabulated at the interval of 5K. The energy equivalent, εcalor, of the oxygen-bomb combustion calorimeter has been determined from 0.68g of NIST 39i benzoic acid to be εcalor=（14674.69±17.49）J·K^-1. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter to be ΔcU=-（32374.25±12.93）J·g^-1. The standard molar enthalpy of combustion for the compound was calculated to be ΔcHm = -（4445.47 ± 1.77） kJ·mol^-1 according to the definition of enthalpy of combustion and other thermodynamic principles. Finally, the standard molar enthalpy of formation of the compound was derived to be ΔfHm（C8H11NO, s）=-（274.68 ±2.06） kJ·mol^-1, in accordance with Hess law.
文摘A prediction model for Current Efficiency (CE) of low temperature aluminum electrolysis (LTAE) with the low molar ratioelectfolyte of Na3AIF6-AIF3 - CaF2-MgF2-LiF -Al2O3 system was investigated based on artificial neural network principles. The nonlinearmapping between CE of LATE and various electrolytic conditions was obtained from a number of experimental data and used to predictCE of LATE. The trsined neural networks possessed high precision and resulted in a good predicting effect. As a result, attificial neuralnetworks as a new cooperating and predicting technology provide a new approach to the further studies on low temperature aluminumelectrolysis.
文摘Extraction of the lower third molar is one of the most common procedures performed in oral surgery. In general, impacted tooth extraction involves sectioning the tooth’s crown and roots. In order to divide the impacted tooth so that it can be extracted, high-speed air turbine drills are frequently used. However, complications related to air turbine drills may occur. In this report, we propose an alternative tooth sectioning method that obviates the need for air turbine drill use by using a low-speed straight handpiece and carbide bur. A 21-year-old female patient presented to the institute’s dental hospital complaining of symptoms localized to the left lower third molar tooth that were suggestive of impaction. After physical examination, tooth extraction of the impacted left lower third molar was proposed and the patient consented to the procedure. The crown was divided using a conventional straight low-speed handpiece and carbide bur. This carbide bur can easily cut through the enamel of crown. On post-operative day number five, suture was removed and the wound was extremely clear. This technique could minimise intra-operative time and reduce the morbidity associated with air turbine drill assisted lower third molar extraction.
基金Funded by the National Natural Science Foundation of China (Nos.50902150 & 90916019)the Graduate Innovation Foundation of the National University of Defense Technology(No.S100103)
文摘The amorphous boron nitride ceramic powders were prepared at 750-950 ℃ by the low-cost urea route, and the effects of preparation temperatures, molar ratios of the raw materials and oxidation treatment on the composition, structure and surface morphology of the products were investigated through FT-IR, XRD and SEM. The results show that the products ceramize and crystallize gradually with the increase of the temperature. When the molar ratio and reaction temperature are 3：2 and 850 ℃, respectively, the products have high purity, compact structure and nice shape. The oxidation treatment at 450 ℃ will not impair the composition and structure of boron nitride but effectively remove the impurities.
基金supported by the National Natural Science Foundation of China (No.21206108)Tianjin Municipal Science and Technology Commission (No.14JCYBJC21200)
文摘In this study, we used a simple impregnation method to prepare Fe-Ce-O<sub> x </sub> catalysts and tested them regarding their low-temperature (200-300 °C) selective catalytic reduction (SCR) of NO using NH<sub>3</sub>. We investigated the effects of Fe/Ce molar ratio, the gas hourly space velocity (GHSV), the stability and SO<sub>2</sub>/H<sub>2</sub>O resistance of the catalysts. The results showed that the FeCe(1:6)O<sub> x </sub> (Ce/Fe molar ratio is 1:6) catalyst, which has some ordered parallel channels, exhibited good SCR performance. The FeCe(1:6)O<sub> x </sub> catalyst had the highest NO conversion with an activity of 94-99% at temperatures between 200 and 300 °C at a space velocity of 28,800 h<sup>−1</sup>. The NO conversion for the FeCe(1:6)O<sub> x </sub> catalyst also reached 80-98% between 200 and 300 °C at a space velocity of 204,000 h<sup>−1</sup>. In addition, the FeCe(1:6)O<sub> x </sub> catalyst demonstrated good stability in a 10-h SCR reaction at 200-300 °C. Even in the presence of SO<sub>2</sub> and H<sub>2</sub>O, the FeCe(1:6)O<sub> x </sub> catalyst exhibited good SCR performance.
