Development of Superhydrophobic Nano-SiO_(2)and Its Field Application in Low-permeability,High-temperature,and High-salinity Oil Reservoirs

In this study,to meet the stringent requirements on the hydrophobicity of nano-SiO_(2)particles for use in depressurization and enhanced injection operations in high-temperature and high-salinity oil reservoirs,secondary chemical grafting modification of nano-SiO_(2)is performed using a silane coupling agent to prepare superhydrophobic nano-SiO_(2) particles.Using these superhydrophobic nano-SiO_(2)particles as the core agent,and liquid paraffin or diesel as the dispersion medium,a uniform dispersion of nano-SiO_(2)particles is achieved under high-speed stirring,and a chemically enhanced water injection system with colloidal stability that can be maintained for more than 60 d is successfully developed.Using this system,a field test of depressurization and enhanced injection is carried out on six wells in an oilfield,and the daily oil production level is increased by 11 t.The cumulative increased water injection is 58784 m^(3),the effective rate of the measures was 100%,and the average validity period is 661 d.

The control effect of low-amplitude structure on oil-gaswater enrichment and development performance of ultra-low permeability reservoirs

Based on drilling, logging, test production and dynamic monitoring data, the control effects of low-amplitude structure on hydrocarbon accumulation and development performance of ultra-low permeability reservoirs were discussed by using the methods of dense well pattern, multi-factor geological modeling, macro and micro analysis and static and dynamic analysis. The results show that the low-amplitude structure always had a significant control and influence on the distribution and accumulation of original hydrocarbon and water and the evolution trend of water flooding performance in ultra-low permeability reservoirs, and it was not only the direction of oil and gas migration, but also a favorable place for relative accumulation of oil and gas. The controlling effect of low-amplitude structure on ultra-low permeability reservoir mainly depended on its tectonic amplitude and scale;the larger the tectonic amplitude and scale, and the higher the tectonic position of the low amplitude structure, the better the reservoir characteristic parameters, oil and gas enrichment degree and development effect, and the larger the spatial scope it controlled and influenced;water cut and oil well output always fluctuated orderly with the height of the low-amplitude structure;the dynamic response of waterflooding was closely related to the relative structural position of the injection and production wells;the injected water always advanced to the low-lying area of the structure first and then moved up to the high-lying area of the structure gradually;with the continuous expansion of the flooded area, part of the oil and gas in the low-lying part of the structure was forced to be distributed to the high part of the structure, resulting in a new oil and gas enrichment, so that the dynamic reserves of oil wells in the high part increased, and the production capacity remained stable.

Method of moderate water injection and its application in ultra-low permeability oil reservoirs of Yanchang Oilfield, NW China

To explore the method of improving development effect and solving the problem of water breakthrough and water out for ultralow permeability fractured reservoirs, an indoor evaluation method of dynamic imbibition for fracture-matrix system was established taking the Chang 8 reservoir in southern Yanchang Oilfield as a research target. Key factors for the imbibition effect were obtained, an imbibition's rate expression was obtained, a model considering the double effects of imbibition-displacement was built and optimal injection and production parameters for the research area were obtained as well. The results show that an optimum displacement rate that maximizes the oil displacement efficiency exists in the water displacing oil process, and the optimal displacing rate becomes smaller as the permeability decreases. The imbibition displacement efficiency increases as the reservoir quality index and water wettability index of rock become bigger. But the larger the initial water saturation or oil-water viscosity ratio is, the smaller the imbibition displacement efficiency is. The optimal injection-production ratio for the Chang 8 reservoir of southern Yanchang Oilfield is 0.95, and the predicted recovery is 17.2% when the water cut is 95%, it is 2.9% higher than the recovery of conventional injection-production ratio 1.2. By using the moderate water injection technique based on the double effects of imbibition-displacement mechanism, the water injection development effect for the ultra-low permeability fractured reservoirs can be improved significantly.

Water-sensitive damage mechanism and the injection water source optimization of low permeability sandy conglomerate reservoirs

The global mobility theory was used to evaluate the experimental results of oil displacement with water of different salinities.The results of scanning electron microscopy,X diffraction of clay minerals,nonlinear seepage and nuclear magnetic resonance experiments and particle migration inhibition experiments before and after water flooding were compared to determine the mechanisms of water sensitive damage and enhanced water flooding mechanism of low permeability sandy conglomerate reservoirs in Wushi region of Beibuwan Basin,China.A production equation of the oil-water two phase flow well considering low-speed non-Darcy seepage and reservoir stress sensitivity was established to evaluate the effect of changes in reservoir properties and oil-water two-phase seepage capacity on reservoir productivity quantitatively,and injection water source suitable for the low permeability sandy conglomerate reservoirs in Wushi region was selected according to dynamic compatibility experimental results of different types of injected water.The seepage capacity of reservoir is the strongest when the injected water is formation water of 2 times salinity.The water-sensitive damage mechanisms of the reservoirs in Wushi region include hydration of clay minerals and particle migration.By increasing the content of cations(especially K+and Mg2+)in the injected water,the water-sensitive damage of the reservoir can be effectively inhibited.The formation water of Weizhou Formation can be used as the injection water source of low permeability sandy conglomerate reservoirs in the Wushi region.

A novel profile modification HPF-Co gel satisfied with fractured low permeability reservoirs in high temperature and high salinity

Conformance control and water plugging are a widely used EOR method in mature oilfields.However,majority of conformance control and water plugging agents are unavoidable dehydrated situation in high-temperature and high-salinity low permeability reservoirs.Consequently,a novel conformance control system HPF-Co gel,based on high-temperature stabilizer(CoCl_(2)·H_(2)O,CCH)is developed.The HPF-Co bulk gel has better performances with high temperature(120℃)and high salinity(1×10^(5)mg/L).According to Sydansk coding system,the gel strength of HPF-Co with CCH is increased to code G.The dehydration rate of HPF-Co gel is 32.0%after aging for 150 d at 120℃,showing excellent thermal stability.The rheological properties of HPF gel and HPF-Co gel are also studied.The results show that the storage modulus(G′)of HPF-Co gel is always greater than that of HPF gel.The effect of CCH on the microstructure of the gel is studied.The results show that the HPF-Co gel with CCH has a denser gel network,and the diameter of the three-dimensional network skeleton is 1.5-3.5μm.After 90 d of aging,HPF-Co gel still has a good three-dimensional structure.Infrared spectroscopy results show that CCH forms coordination bonds with N and O atoms in the gel amide group,which can suppress the vibration of cross-linked sites and improve the stability at high temperature.Fractured core plugging test determines the optimized polymer gel injection strategy and injection velocity with HPF-Co bulk gel system,plugging rate exceeding 98%.Moreover,the results of subsequent waterflooding recovery can be improved by 17%.

On the Development of an Effective Pressure Driving System for Ultra-Low Permeability Reservoirs

Given its relevance to the exploitation of ultra-low permeability reservoirs,which account for a substantial proportion of the world’s exploited and still unexploited reserves,in the present study the development of an adequate water injection system is considered.Due to the poor properties and weak seepage capacity of these reservoirs,the water injection pressure typically increases continuously during water flooding.In this research,the impact on such a process of factors as permeability,row spacing,and pressure gradient is evaluated experimentally using a high-pressure large-scale outcrop model.On this basis,a comprehensive evaluation coefficient is introduced able to account for the effective driving pressure.

Study on Reducing Injection Pressure of Low Permeability Reservoirs Characterized by High Temperature and High Salinity

In view of the problems of high injection pressure and low water injection rate in water injection wells of low permeability reservoirs featuring high temperature and high salinity,two new surfactants were synthesized,including a quaternary ammonium surfactant and a betaine amphoteric surfactant.The composite surfactant system BYJ-1 was formed by mixing two kinds of surfactants.The minimum interfacial tension between BYJ-1 solution and the crude oil could reach 1.4×10^(-3) mN/m.The temperature resistance was up to 140℃,and the salt resistance could reach up to 120 g/L.For the low permeability core fully saturated with water phase,BYJ-1 could obviously reduce the starting pressure gradient of low permeability core.While for the core with residual oil,BYJ-1 could obviously reduce the injection pressure and improve the oil recovery.Moreover,the field test showed that BYJ-1 could effectively reduce the injection pressure of the water injection well,increase the injection volume,and increase the liquid production and oil production of the corresponding production well.

Development of the theory and technology for low permeability reservoirs in China

The development theories of low-permeability oil and gas reservoirs are refined, the key development technologies are summarized, and the prospect and technical direction of sustainable development are discussed based on the understanding and research on developed low-permeability oil and gas resources in China. The main achievements include:(1) the theories of low-permeability reservoir seepage, dual-medium seepage, relative homogeneity, etc.(2) the well location optimization technology combining favorable area of reservoir with gas-bearing prediction and combining pre-stack with post-stack;(3) oriented perforating multi-fracture, multistage sand adding, multistage temporary plugging, vertical well multilayer, horizontal and other fracturing techniques to improve productivity of single well;(4) the technology of increasing injection and keeping pressure, such as overall decreasing pressure, local pressurization, shaped charge stamping and plugging removal, fine separate injection, mild advanced water injection and so on;(5) enhanced recovery technology of optimization of injection-production well network in horizontal wells. To continue to develop low-permeability reserves economically and effectively, there are three aspects of work to be done well:(1) depending on technical improvement, continue to innovate new technologies and methods, establish a new mode of low quality reservoir development economically, determine the main technical boundaries and form replacement technology reserves of advanced development;(2) adhering to the management system of low cost technology & low cost, set up a complete set of low-cost dual integration innovation system through continuous innovation in technology and management;(3) striving for national preferential policies.

Timing of advanced water flooding in low permeability reservoirs

It is very important to design the optimum starting time of water injection for the development of low permeability reservoirs. In this type of reservoir the starting time of water injection will be affected by a reservoir pressure-sensitive effect. In order to optimize the starting time of water injection in low permeability reservoirs, this effect of pressure change on rock permeability of low permeability reservoirs was, at first, studied by physical simulation. It was shown that the rock permeability decreases exponentially with an increase in formation pressure. Secondly, we conducted a reservoir engineering study, from which we obtained analytic relationships between formation pressure, oil production rate, water production rate and water injection rate. After our physical, theoretical and economical analyses, we proposed an approach which takes the pressure-sensitive effect into consideration and designed the optimum starting time of water injection, based on the principle of material balance. Finally, the corresponding software was developed and applied to one block of the Jiangsu Oilfield. It is shown that water injection, in advance of production, can decrease the adverse impact of the pressure-sensitive effect on low permeability reservoir development. A water-flooding project should be preferably initiated in advance of production for no more than one year and the optimum ratio of formation pressure to initial formation pressure should be maintained at a level between 1.05 and 1.2.

Optimum development options and strategies for water injection development of carbonate reservoirs in the Middle East

Through the research on several carbonate reservoirs developed in the Middle East, the basic characteristics of different types of carbonate reservoirs are determined, and a set of high-efficiency water injection development options and strategies are presented. Hidden baffles and barriers exist in carbonate reservoirs in the Middle East, so the reservoirs could be divided into different separated development units based on the baffles and barriers characteristics. Flexible and diverse profile control techniques such as high angle wells and simple and applicative zonal water injection have been introduced to improve the control and development degree of reservoirs. Three principal water injection development methods suitable for different carbonate reservoirs in the Middle East are proposed, including the combination of crestal gas injection and peripheral water injection, bottom interval injection and top interval production(buoyancy underpinning), and "weak point and strong plane" area well pattern. Based on the characteristics of very low shale content, fast and far pressure transmission in the Middle East carbonate reservoirs, a large well-spacing flood pattern is recommended, and reasonable development strategies have been made such as moderate water injection rate and maintaining reasonable production pressure drawdown and voidage replacement ratio, so as to maximize the recovery of reservoirs in the none or low water cut period.

An overview of efficient development practices at low permeability sandstone reservoirs in China

Low permeability sandstone reservoirs in China typically have more complicated geological conditions, pore structures, and flow characteristics as compared to medium-to-high-permeability sandstone reservoirs. Traditional geological and seepage theories, and engineering methods are not applicable to the development of these low permeability reservoirs, and wells drilled into them often produce oil and gas at very low rates. Recent breakthroughs in reservoir exploitation technology have greatly improved the productivity of low permeability reservoirs, making them the primary target for oil exploration and extraction in China. The development theories and practices applied to low permeability reservoirs in China are reviewed in this study— based on relevant geological and engineering practices, including drilling, fracturing, recovery, and surface engineering. A unique series of technological advances that aid the development of low permeability reservoirs in China are summarized here. This study may serve as a meaningful guide in achieving scale efficiency for the development of low permeability reservoirs.

Development of Acidizing Techniques for Low－permeability Carbonate Reservoirs

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Permeability damage micro-mechanisms and stimulation of low-permeability sandstone reservoirs: A case study from Jiyang Depression, Bohai Bay Basin, China

According to the characteristics of"structural elements"(framework grain,interstitial material and pore throat structure)of low-permeability sandstone reservoir,the"step by step dissolution and separation"acidification and acid fracturing technology has been developed and tested in field.There are three main mechanisms affecting permeability of low-permeability sandstone reservoir:(1)The mud fillings between the framework grains block the seepage channels.(2)In the process of burial,the products from crystallization caused by changes in salinity and solubility and uneven migration and variation of the syn-sedimentary formation water occupy the pores and throat between grains.(3)Under the action of gradual increase of overburden pressure,the framework grains of the rock is compacted tighter,making the seepage channels turn narrower.The"step by step dissolution and separation"acidification(acid fracturing)technology uses sustained release acid as main acidizing fluid,supramolecular solvent instead of hydrochloric acid to dissolve carbonate,and a composite system of ammonium hydrogen fluoride,fluoroboric acid,and fluorophosphoric acid to dissolve silicate,and dissolving and implementing step by step,finally reaching the goal of increasing porosity and permeability.By using the technology,the main blocking interstitial material can be dissolved effectively and the dissolution residual can be removed from the rock frame,thus expanding the effective drainage radius and increasing production and injection of single well.This technology has been proved effective by field test.

Development of the Extra-low Permeability Oilfield of Ansai

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Water-cut rising mechanism and optimized water injection technology for deepwater turbidite sandstone oilfield: A case study of AKPO Oilfield in Niger Delta Basin, West Africa

Through the analysis of the reservoir connection relationship and the water-cut rising rules after water breakthrough in the highly volatile oil AKPO oilfield, a new model of water-cut rising was established, and the timing and strategy of water injection were put forward. The water-cut rising shapes of producers after water breakthrough can be divided into three types, and their water-cut rising mechanism is mainly controlled by reservoir connectivity. For the producers which directly connect with injectors in the single-phase sand body of the single-phase channel or lobe with good reservoir connectivity, the water-cut rising curve is "sub-convex". For the producers which connect with injectors through sand bodies developed in multi-phases with good inner sand connectivity but poorer physical property and connectivity at the overlapping parts of sands, the response to water injection is slow and the water-cut rising curve is "sub-concave". For the producers which connect with injectors through multi-phase sand bodies with reservoir physical properties, connectivity in between the former two and characteristics of both direct connection and overlapping connection, the response to water injection is slightly slower and the water-cut rising curve is "sub-S". Based on ratio relationship of oil and water relative permeability, a new model of water cut rising was established. Through the fitting analysis of actual production data, the optimal timing and corresponding technology for water injection after water breakthrough were put forward. Composite channel and lobe reservoirs can adopt water injection strategies concentrating on improving the vertical sweep efficiency and areal sweep efficiency respectively. This technology has worked well in the AKPO oilfield and can guide the development of similar oilfields.

Experiments on the influences of well pattern on water flooding characteristics of dissolution vug-cave reservoir

Based on the similarity criterion, volcanic rock samples were taken from outcrops to make experimental models. Water flooding experiments of five-spot well pattern, nine-spot well pattern, five-spot to nine-spot well pattern, the relationship between relative well and fracture positions, and injection rate in dissolution vug-cave reservoirs with/without fractures were carried out to analyze variation regularities of development indexes, find out development characteristics of water flooding with different well patterns and sort out the optimal water flooding development mode. For dissolution vug-cave reservoirs without fractures, five-spot well pattern waterflooding has very small sweeping area, serious water channeling and low oil recovery. When the well pattern was adjusted from five-spot to nine-spot well pattern, oil recovery could be largely improved, but the corner well far from the injector is little affected. In dissolution vug-cave reservoirs with fractures, when the injector and producer are not connected by fractures, the fractures could effectively connect the poorly linked vugs to improve the development effect of water flooding. Whether there are fractures or not in dissolution vug-cave reservoirs, the development effect of nine-spot well-pattern is much better than that of five-spot well pattern and five-spot to nine-spot well pattern, this is more evident when there are fractures, and the edge well has better development indexes than corner well. At the high-water cut stage of water flooding with nine-spot well pattern, the oil recovery can be further improved with staggered line-drive pattern by converting the corner well into injection well. It is helpful to increase the oil production of corner well of nine-spot well pattern by increasing the injection rate, and improve ultimate oil recovery, but the water-free production period would be greatly shortened and water-free recovery would decrease.

中低渗油藏高倍数水驱过程中水相渗透率变化特征

冀东油田G76断块在注水开发过程中出现注水井注入压力升高,注水难度增加等问题。为了分析注水过程中储层物性的变化规律,开展了基于二维核磁共振技术的岩心高倍数水驱实验。对目标油藏岩心进行激光粒度测试分析,获得岩心的粒度分布;进行X射线衍射矿物含量分析,获得不同矿物含量占比;开展基于核磁共振技术的高倍数水驱油实验,分析储层物性变化规律。研究结果表明:岩心5-1和岩心6-1分别为含中砂粉砂质细砂岩和含粉砂中砂质细砂岩,其细砂、细粉砂和黏土矿物含量较多。水相相对渗透率及核磁孔隙度随着注水倍数的增加上升到某一高值后呈下降趋势,核磁T_2谱中随着注水倍数的增加,右侧端点值及中、大孔隙对应的曲线左移,二维图谱中自由水信号强度随着注水倍数的不断增加而增加。注入水由束缚水状态至累计注水倍数为500PV时,束缚水信号不断增加;累计注水倍数为>500~1 000 PV时,岩心5-1的束缚水信号持续增强而岩心6-1的束缚水信号发生减弱。研究认为:注水前期由于黏土矿物发生微弱的水化作用,注水后期因受到水的冲刷,细粉砂粒以及胶结物中的黏土矿物容易脱落运移至喉道处发生堵塞,对孔隙喉道产生一定损害,导致水相渗透率降低。研究成果揭示了中低渗油藏注水井出现注水困难和注水压力增大等问题的原因,对有效降低污染、进一步提升注水开发油藏开发效果提供一定的指导。

The effect of physical property change on the water flooding development in Changqing oilfield Jurassic low permeability reservoir

Changqing old oilfield Jurassic reservoir's average calibration recovery is 24.7%,with geological reserves recovery of 16.6%,water cut of 65.2%.And most of Jurassic reservoirs are in the middle and later field life,part of them has entered the high water cut and high recovery stage.Traditional water flooding way for improving oil recovery becomes more difficult,and new method has to be considered.Maling oilfield BS district is a typical representative,with high water cut of 90.8%,high recovery percent of 26.1%and low oil recovery rate of 0.25%.To explore the new way to improve oil recovery,the polymer and surfactant(SP for short)important pilot test has been developed.The low permeability reservoir indoor core data in high water cut stage and inspection well results indicate that the reservoir permeability,pore combination characteristics and pore type changed greatly after long-term water flooding development.These changes bring more difficulties to the continue development,especially the high injection pressure,which can cause other problems for well pattern infilling and EOR.This paper takes the high injection pressure problem of Maling BS district Jurassic reservoir for example,analyzes the physical property change law on the following aspects:the development mode in the past,core analysis,formation sensitivity,interstitial matter,well test interpretation results,in order to help to further effective development and provide important parameters for tertiary oil recovery technique for similar reservoirs and others.

低渗透砂岩油藏不同流体驱油效率实验

准噶尔盆地东缘低渗透砂岩油藏注水开发中—后期,开发效果变差,含水率变高,需要新的有效开发手段,选取不同流体开展驱油效率实验。利用天然岩心组合成长岩心并模拟地层条件,进行全程水驱及水驱至油藏目前采出程度后转注N_(2)、CH_(4)和CO_(2)的驱油实验,并对不同流体注入前后,进行岩心核磁共振扫描及原油赋存孔隙直径反演。研究结果表明,CO_(2)驱可提高原油采出程度21.58%,驱油效率及原油动用程度从大到小依次为CO_(2)、CH_(4)、H_(2)O和N_(2)。N_(2)主要动用较大孔隙中的原油,动用孔隙直径下限为170.9 nm;CH_(4)主要动用中—大孔隙中的原油,动用孔隙直径下限为48.7 nm;CO_(2)可以动用各个尺寸孔隙中的原油,动用孔隙直径下限最低,为27.8 nm。油田现场建立CO_(2)驱先导试验区,注CO_(2)后产液量上升,含水率下降,产油量增加,研究成果在现场应用效果良好。

特低渗气藏水的赋存状态及其对A气田开发的影响

特低渗气藏气水关系复杂,地层水赋存状态与常规气藏差异大。通过压汞实验和相渗实验确定特低渗气藏水的赋存状态及地层水饱和度,采用圈闭闭合高度法分析气水分异情况。在测井曲线预测单井不同状态地层水饱和度分布的基础上,分析地层水对产能的影响。结果表明:研究区地层水以强束缚水和弱束缚水为主,含有少量可动水,不存在明显的气水分异特征。黏土水膜是强束缚水的重要组成部分,在细砂岩和碳酸盐胶结物含量高的砂岩中,弱束缚水饱和度更高。研究区可动水饱和度普遍低于6%,初期产水较少,对产能影响较小。